A green method based on magnetic micro-solid phase extraction (MNP-TW-μ-SPE) of tea waste impregnated with magnetic nanoparticles (MNP-TW) was developed for the extraction of ibuprofen (IBP) in water samples prior to UV-Vis spectrophotometric analysis. Experimenting parameters that affect the extraction efficiency of IBP, such as pH of the sample solution, sorbent dosage, extraction time, ionic strength, volume of the sample, type of desorption solvent, desorption time, and desorption volume, were studied and optimized in detail. The characterization studies for the MNP-TW were carried out by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction spectrometry (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) analysis, a vibrating sample magnetometer (VSM), and thermogravimetric analysis (TGA). Under the optimum conditions, the linearity ranges from 30 to 700 μg L-1 for IBP, with determination coefficients (R2) of 0.9983. The limit of detection (LOD) and limit of quantification (LOQ) were 9.40 μg L-1 and 28.50 μg L-1, respectively. The method also demonstrated good precision in reproducibility (RSD ≤ 1.53%), repeatability (RSD ≤ 1.48%), and recovery (86-115%). This method represents the advantages of low solvent consumption, flexibility, and better sensitivity compared to other studies employing spectrophotometric analysis. The usage of tea waste in the extraction process presents many advantages, as it is biodegradable, versatile, and contributes to an intelligent and sustainable economic strategy projected toward a circular economy approach.