Components used in many manufacturing applications especially in the defence, automotive and aerospace are required to meet certain properties, such as elastic modulus, toughness, resistance to wear and corrosion. Additive manufacturing (AM) is a technique used for the fabrication of layer-by-layer geometries via three dimensional (3D) mechanisms at a certain process parameter. Titanium alloy and boron carbide (Ti6Al4V/B4C) composites coatings have been successfully fabricated on titanium alloy (Ti6Al4V, grade 5) by laser metal deposition (LMD) of additive manufacturing (AM) process. Microstructure analysis of the fabricated multiple clad is characterized by optical and scanning electron microscopy. The obtained multiple tracks show that the coatings are profound with TiC and TiB phases with dendrites of TiC particles in the coatings. The evolving microstructures of the deposited coatings at a laser power of 1000 W and 1200 W with a scanning speed of 1 m/min exhibit some lateral cracks which is associated to the brittle nature of ceramic boron carbide in the clad zone. The atomic level characterization of the coatings is determined through the surface roughness obtained by atomic force microscope (AFM). Microhardness analysis is performed at the cross-section surface of the coatings by Vickers pyramid indentation at 300 gf load with dwell time of 10 s on Zwick Roell microhardness tester. From the samples investigated, sample at a laser power of 1200 W has the highest hardness value of 548 HV0.3/10s.