Aqueous zinc ion batteries (AZIBs), featuring its low cost and environmental protection, are regarded as the promising alternative for traditional energy storage devices acting on clean power generation and electrical vehicles. Prussian blue analogues (PBAs) have received a lot of attention for a potential cathode candidate in AZIBs due to its competence in accommodating various ions with good electrochemical stability. However, conventional PBAs have some inherent problems in Zn ions de-intercalation involving of high discharge potential separation, low structural stability, and high raw material cost. Herein, titanium hexacyanoferrate/carbon nanotube composite (TiHCF-CNT) is synthesized and applied to the cathode materials for aqueous sodium/zinc ion batteries at the first time. The resultant material exhibits not only a high capacity for 134.6 mAh g−1 at 0.05 A g−1, but also excellent cycling stability of 93.7 % capacity retention after 300 cycles at 0.3 A g−1. Na+ in the electrolyte can decrease the resistance of electrolyte and co-insert in the material structure with Zn2+, thus elevate the electrochemical performances remarkably. Moreover, the defects in the structure are identified as Ti vacancies, and these defects can be occupied by Zn2+ reversibly at the charging-discharging process, which lead to a high reversible capacity and cycle stability accordingly.