Ti Plasma Research Articles

Electron density diagnosis of laser-produced plasmas based on spectral line broadening of highly charged ions

SynopsisSpectral line profile of Ti XII 11.64 nm was measured using spatio-temporally resolved laser-produced plasma technique. The electron density of laser-produced Ti plasmas was calculated based on the spectral line Stark broadening of highly charged ions.

Tailoring the texture of titanium thin films deposited by high-power pulsed magnetron sputtering

Titanium (Ti) thin films with (002) or (100) texture are favored for many applications. In this paper, Ti thin films were prepared by high-power pulsed magnetron sputtering, and the texture of Ti thin films was successfully tailored by adjusting the pulse width, substrate bias and magnetic field strength. It is found that the peak power and average power of the Ti target are increased by increasing sputtering pulse width and decreasing magnetic field strength, which raise the Ti plasma flux and ion/atom ratio of Ti ions in front of the substrate simultaneously. Ti thin films with a highly (002) out-of-plane texture can be obtained with higher pulse width and lower magnetic field strength. The Ti thin films with highly (100) out-of-plane texture can be achieved with shorter pulse width, lower magnetic field strength and substrate bias.

Two-channel high-resolution quasi-monochromatic X-ray imager for Al and Ti plasma.

High-resolution, high-sensitivity X-ray imaging is a real challenge in high-energy density plasma experiments. We present an improved design of the Fresnel ultra high-resolution imager instrument. Using an Ultra-High-Intensity (UHI) laser to generate hot and dense plasma in a small volume of an Al-Ti mixed target provides simultaneous imaging of both Al and Ti X-ray emission. Specifically, the Al Heβ (or Lyβ) and the Ti Heα lines are imaged with a resolution of (2.7 ± 0.3) μm and (5.5 ± 0.3) μm, respectively. It features two transmission Fresnel phase zone plates fabricated on the same substrate, each associated with a multilayer mirror for spectral selection. Their spatial resolution has been measured on the PTB synchrotron radiation facility laboratory at BESSY II and on the EQUINOX laser facility. Results obtained on an UHI experiment highlight the difference of emission zone sizes between Al and Ti lines and the versatility of this instrument.

Realization of high Ti plasmas and confinement characteristics of ITB plasmas in the LHD deuterium experiments

The deuterium (D) operation was initiated in the LHD in 2017. In the first campaign of the D experiments, we successfully extended the high temperature regime in the LHD. The new record of the ion temperature (Ti) of 10 keV associated with the ion internal transport barrier (ITB) was achieved due to several operational optimization. The thermal confinement characteristics of ITB plasmas were compared between hydrogen and D discharges. The effective ion thermal diffusivity of the ion-ITB plasmas was found to be smaller in the D discharges than that in the H discharges. The profiles of the Ti, the electron density, and the impurity of the high Ti plasmas strongly depended on the magnetic configuration and these profiles tended to peaked in the inward-shifted configuration. It was also found that the electron thermal confinement of the electron-ITB plasmas was clearly improved in the deuterium case. The GKV simulation showed the linear growth rate of TEM/ITG reduced in the plasmas with D both for the ion ITB and the electron ITB plasmas and qualitatively agreed with the tendency of the change in the thermal diffusivity obtained from the power balance analysis.

Resistance of coated polyetheretherketone lumbar interbody fusion cages against abrasion under simulated impaction into the disc space

In order to improve osseointegration, polyetheretherketone (PEEK) interbody fusion cages are frequently surface coated. The bonding strength of the coatings is mostly investigated under unrealistic loading conditions. To close this gap, in this study, uncoated and coated cages were loaded in a clinical setup in order to investigate their real resistance against abrasion. Six uncoated, six calcium phosphate (CaP) nanocoated, and six titanium (Ti) nanocoated PEEK cages were tested in this study. The experimental setup was designed to mimic cage impaction into the intervertebral disc space using polyurethane (PU) foam blocks as vertebral body substitutes. The cage surface was inspected before and after impaction, and their weight was measured. Impaction resulted in abrasion at the tip of the ridges on the implant surface. The mean weight loss was 0.39 mg for the uncoated cages, 0.57 mg for the CaP nanocoated cages, and 0.75 mg for the Ti nanocoated cages. These differences were statistically significant. In conclusion, differences between the three cage types were found concerning the amount of abrasion. However, all three cages lost less weight than a comparative Ti plasma spray coated cage, which showed a mean weight loss of 2.02 mg. This may be because the plasma spray coating is significantly thicker than the two nanocoatings. If compared with the permitted amount of weight loss derived from an FDA guidance document, which is approximately 1.7 mg, the wear of the Ti plasma spray coated cage is above this limit, whereas the wear for all other cage types is below.

Improved TiN Deposition on the SKD11 with Equally Spaced Multi-Sources of Cathode Arc

The Multi-Sources of Cathode Arc (MSCA) were installed in the vacuum chamber in order to increase the substrate temperature and to provide a plenty of Ti plasmas from titanium plate inside the chamber. The increase rate of the substrate temperature of the SKD11 substrate against the deposition time for two thicknesses of the substrate by operations with both single ion source and MSCA was obtained. It was known that MSCA were useful for the film synthesis for the larger substrate both in size and in number. A wider diffusion interface between TiN film and SKD11 substrate was formed by dissolution of both TiN and Ti2N into the substrate more actively due to plenty Ti ion numbers supplied by MSCA. Due to the thick diffusion interface the adhesion of the film increased and thus the hardness increased up to twice. The peaks of Ti2N(111) and Ti2N(211) which are indicators of high hardness were observed in XRD pattern. The pseudo-diffusion interface between the outer TiN film and substrate formed and it improved the film adhesion. By using MSCA the hardness of SKD11 surface was improved up to 126 from 58 in Rockwell-C scale by the TiN deposition in this study.

Effect of Ti Content on Physical Properties and Electrical Characteristics of High-k Yb2TiO5 Gate Dielectrics for InZnSnO Thin-Film Transistors

In this study, we investigated the impact of Ti content on structural properties and electrical characteristics of high-k Yb2TiO5 gate dielectrics for amorphous indium–zinc–tin-oxide (a-InZnSnO) thin-film transistor (TFT) devices. The Yb2TiO5 thin films with different Ti plasma conditions were integrated in metal-insulator-metal structures to check the electrical capabilities. The Yb2TiO5 a-InZnSnO TFT device fabricated at the 120 W condition exhibited excellent electrical characteristics in terms of a small threshold voltage (VTH) of 0.14 V, a low subthreshold swing of 202 mV/decade, a large field-effect mobility of 29.8 cm2/V-s, and a high Ion/Ioff current ratio of 2.7×108. In addition, the VTH stability of Yb2TiO5 a-InZnSnO TFT device was studied under both positive bias stress and negative bias stress conditions. The Yb2TiO5 thin film is a promising gate dielectric material for the fabrication of a-InZnSnO TFTs.

Relative spectral response calibration using Ti plasma lines

This work introduces the branching ratio (BR) method for determining relative spectral responses, which are needed routinely in laser induced breakdown spectroscopy (LIBS). Neutral and singly ionized Ti lines in the 250–498 nm spectral range are investigated by measuring laser-induced micro plasma near a Ti plate and used to calculate the relative spectral response of an entire LIBS detection system. The results are compared with those of the conventional relative spectral response calibration method using a tungsten halogen lamp, and certain lines available for the BR method are selected. The study supports the common manner of using BRs to calibrate the detection system in LIBS setups.

Fixation of revision implants is improved by new surgical technique to crack the sclerotic endosteal rim.

We used an experimental model producing a tissue response with a sclerotic endosteal neo-cortical rim associated with implant loosening in humans: a 6 mm PMMA cylinder pistoned 500 m concentrically in a 7.5 mm hole, with polyethylene particles. At a second operation at eight weeks, the standard revision procedure removed the fibrous membrane in one knee, and the crack revision procedure was used to crack the sclerotic endosteal rim in the contralateral knee. Once stability was achieved following the revision procedures, loaded Ti plasma sprayed implants were inserted into the revision cavities of 8 dogs for an additional 4 weeks. Revision implant fixation (ultimate shear strength and energy absorption) was significantly enhanced by cracking the sclerotic endosteal rim. In conclusion, we demonstrated a simple technique of cracking the sclerotic endosteal rim as an additional method for improving revision fixation. (Hip International 2002; 2: 77-9).

Collisional heating and adiabatic expansion of warm dense matter with intense relativistic electrons.

Adiabatic expansion of a warm dense Ti plasma has been observed after isochoric heating of a 100-μm-thick Ti foil with an ∼100-ns-long intense relativistic electron bunch at an energy of 19.8 MeV and a current of 1.7kA. The expansion fits well with the analytical point-source solution. After 10 J is deposited and the plasma rapidly expands out of the warm dense phase, a stable degenerate plasma (T∼1.2eV) with n_{e}>10^{17}cm^{-3} is measured for >100 ns. This is the first temporal measurement of the generation and adiabatic expansion of a large volume (3×10^{-4}cm^{3}) of warm dense plasma isochorically heated by intense monochromatic electrons. The suite of diagnostics is presented, which includes time-resolved plasma plume expansion measurements on a single shot, visible spectroscopy measurements of the emission and absorption spectrum, measurements of the beam distribution, and plans for the future.

Influence of NH3 plasma and Ti doping on pH-sensitive CeO2 electrolyte-insulator-semiconductor biosensors

In this study, CeO2 pH-sensitive sensing membranes in electrolyte-insulator-semiconductor structures on silicon substrate were fabricated. To enhance sensing performance, the membrane underwent Ti doping and NH3 plasma treatment on the surface. To examine the effects of Ti doping and plasma treatment, multiple material properties evaluations were conducted using field-emission scanning electron microscopy, X-ray diffraction, atomic force microscopy, and secondary ion mass spectroscopy. Results indicate that Ti doping and plasma treatment can remove defects and enhance crystallization, thereby achieving improved pH-sensing performance of the membrane with high sensitivity, high linearity, low hysteresis voltage and low drift voltage. CeO2-based EIS membranes with Ti doping and NH3 plasma treatment show promise for future portable pH-sensitive biosensors.

Core@shell, Au@TiOx nanoparticles by gas phase synthesis.

Herein, gas phase synthesis and characterization of multifunctional core@shell, Au@TiOx nanoparticles have been reported. The nanoparticles were produced via a one-step process using a multiple-ion cluster source under a controlled environment that guaranteed the purity of the nanoparticles. The growth of the Au cores (6 nm diameter) is stopped when they pass through the Ti plasma where they are covered by an ultra-thin (1 nm thick) and homogeneous titanium shell that is oxidized in-flight before the soft-landing of the nanoparticles. The Au cores were found to be highly crystalline with icosahedral (44%) and decahedral (66%) structures, whereas the shell, mainly composed of TiO2 (79%), was not ordered. The highly electrical insulating behaviour of the titanium oxide shell was confirmed by the charging effect produced during X-ray photoemission spectroscopy.

Effect of ambient pressure on a femtosecond laser induced titanium plasma

Femtosecond laser induced Ti plasma has been characterized as a function of pressure by means of femtosecond laser induced breakdown spectroscopy (fs-LIBS). Experiments were performed with a Ti: sapphire laser system (100 fs, 800 nm), in an air pressure from 10 Pa to 104 Pa. The time-resolved spectrum has been acquired and the spectral intensities of different plasma species have been investigated with a changing ambient pressure. The Ti atomic lines decay while the ionic ones grow with an increasing pressure. The enhancement of nitrogen ionic line has also been observed. The time of flight spectroscopy is adopted to measure the expanding velocity of the plasma plume. The increasing pressure slows the plasma expansion along both axial and radial directions. The electron density and temperature are measured by means of Boltzmann plot method and Stark width method, respectively. It is concluded that higher pressure will increase the energy absorption and retard the plasma expansion, leading to larger electron density and temperature.

Spectroscopic and morphological study of laser ablated Titanium

The laser-induced breakdown spectroscopy (LIBS) and surface morphology of Titanium (Ti) plasma as a function of laser irradiance have been investigated under ambient environment of argon at fixed pressure of 50 Torr. Ablation was performed by employing Q-switched Nd:YAG laser pulses (λ ≈ 1064 nm, τ ≈ 10 ns, repetition rate ≈ 10 Hz). Ti targets were exposed to various laser intensities ranging from 6 to 50 GW/cm2. LIBS analysis has been employed for the investigation of plasma parameters. Scanning Electron Microscope (SEM) analysis was employed for investigation of surface morphology. Ablation depth was measured by optical microscopy technique. It was observed that both plasma parameters, i.e., excitation temperature and electron density have been significantly influenced by laser irradiance. It is observed that with increasing laser irradiance up to 13 GW/cm2, the electron temperature decreases whereas number density significantly increases and attains its maxima. Afterwards by increasing irradiance electron temperature increases, attains its maxima and a decrease in electron number density is observed at irradiance of 19 GW/cm2. Further increase in irradiance causes saturation with insignificant changes in both electron temperature and electron number density. This saturation in both excitation temperature and electron number density is explainable on the basis of self-sustaining regime. SEM micrographs reveal the ripple and coneformation at the boundaries of ablated region of Ti. The height of cones as well as the ablation depth is maximum at irradiance of 13 GW/cm2 whereas electron number density is also maximum. The maximum electron number density is considered to be responsible for maximum ablation as well as mass removal. A strong correlation between plasma parameters and surface morphology is established.

Effect of Ti Content on the Structural and Electrical Characteristics of ErTixOyCharge Storage Layer in InGaZnO Thin-Film Transistor Nonvolatile Memories

This paper describes the effect of titanium content on the structural and electrical properties of ErTi x O y charge storage layers in amorphous indium–gallium–zinc oxide ( $\alpha $ -IGZO) thin-film transistor (TFT) nonvolatile memory (NVM) devices. X-ray diffraction, Auger electron spectroscopy, and X-ray photoelectron spectroscopy were used to study the film structural, depth profiling, and chemical features, respectively, of these films as the functions of the growth conditions (Ti plasma powers of 60, 100, and 140 W). The ErTi x O y IGZO TFT NVM devices fabricated at the 100-W condition exhibited a larger memory window of 4.1 V, a smaller charge loss of 13% (after ten years), and a better endurance characteristic (up to $10^{5}$ program/erase cycles), as compared with other conditions. This result suggests that the Er2TiO5 film featuring a high dielectric constant and reducing an Er(OH) x layer can provide the higher charge-trapping efficiency and deeper electron trapping levels.

Combining thermo-diffusing titanium and plasma nitriding to modify C61900 Cu–Al alloy

To improve the mechanical properties of C61900 copper–aluminum alloy, a multi-phases coating was fabricated by the combination of thermo-diffusing Ti film and plasma nitriding. The results showed that a smooth coating with fine and uniform grains could be achieved, and the 9 μm thick multi-phases coating, containing Ti–Cu–Al intermetallics (CuTi2, CuTi, AlCu2Ti) and titanium nitride (Ti2N) formed on the nitrided surfaces. The surface hardness of the coating was obviously improved to be 630 HV0.01, and the cross-sectional hardness decreased gradually to that of C61900 Cu–Al alloy. Moreover, the wear rate of the coated specimen decreased significantly, dropping 95.5% compared with the untreated Cu–Al alloy.

Antibacterial activity and cell compatibility of TiZrN, TiZrCN, and TiZr-amorphous carbon coatings

A cathodic-arc evaporation system with plasma-enhanced duct equipment was used to deposit TiZrN, TiZrCN, and TiZr/a-C coatings. Reactive gases (N2 and C2H2) activated by the Ti and Zr plasma in the evaporation process was used to deposit the TiZrCN and TiZr/a-C coatings with different C and nitrogen contents. The crystalline structures and bonding states of coatings were analyzed by X-ray diffraction and X-ray photoelectron spectroscopy. The microbial activity of the coatings was evaluated against Staphylococcus aureus (Gram-positive bacteria) and Actinobacillus actinomycetemcomitans (Gram-negative bacteria) by in vitro antibacterial analysis using a fluorescence staining method employing SYTO9 and a bacterial-viability test on an agar plate. The cell compatibility and morphology related to CCD-966SK cell-line human skin fibroblast cells on the coated samples were also determined using the 3-(4, 5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazolium bromide assay, reverse-transcriptase-polymerase chain reaction, and scanning electron microscopy. The results suggest that the TiZrCN coatings not only possess better antibacterial performance than TiZrN and TiZr/a-C coatings but also maintain good compatibility with human skin fibroblast cells.

Dynamics of femtosecond pulsed laser induced Ti plasmas under different pressures

Dynamics of femtosecond pulsed laser induced Ti plasmas under different pressures

Characterization of highly charged titanium ions produced by nanosecond pulsed laser

AbstractIn this work, plasma is produced by irradiating a Ti target with 10 ns pulsed Nd:YAG (λ = 1064 nm) laser. The laser fluence at the target was varied in the range of 2–20.3 J/cm2. The ion signal from freely expanding Ti plasma in vacuum was characterized with the help of ion collector and time-of-flight electrostatic energy analyzer. The ion charge state was found to increase with the laser fluence and maximum available ion charge in this fluence range is Ti4+. A correlation between the intensities of various ion charge states was observed, which indicates that higher charge states are most probably produced through stepwise ionization mechanism. It is also observed that charge state distribution of plasma can be controlled by variation of the laser fluence. In addition, energy distribution of ion charge states Tin+ (n = 1–4) is measured by varying back plate voltage of the electrostatic energy analyzer for a fixed laser fluence of 20.3 J/cm2. Ions energy distributions were in the range of 0.36–3.0 keV and the most probable ion energy was found to increase linearly with ion charge state. The estimated equivalent potential at the laser fluence of 20.3 J/cm2 is about 310 V. These results are in good agreement with the predictions of electrostatic model of ion acceleration in laser plasma.

Effect of the RF wall conditioning on the high performance plasmas in the Large Helical Device

The wall conditioning using radio frequency (RF) plasma was carried out using Ion Cyclotron Range of Frequency (ICRF) heating and/or Electron Cyclotron Resonance Heating (ECRH) with the working gas of helium under the established confinement magnetic field. After sufficient numbers of repetitive wall discharge conditioning (DC, ICDC for ICRF and ECDC for ECRH), the formation of the parabolic electron density profile and the increase of the central ion temperature Ti were observed. There was no difference in the attained central Ti of the NBI discharge just after the conditioning using a similar value of input energy regardless of the applied RF source. Thus, it is concluded that both ICDC and the ECDC are effective for the higher Ti plasma production under the established magnetic field in the Large Helical Device. The effective RF wall conditioning scenarios are also investigated for high Ti plasma production.