Forest fires arise from anthropogenic load and lightning activity. The formation of a thunderstorm front is due to the influence of a number of factors, including the emission of aerosol particles from forest fires. The purpose of this study is mathematical modeling of heat and mass transfer in vegetation firebrand carried out from a forest fire front, taking into account the formation of soot particles to predict forest fire danger from thunderstorm activity. Research objectives: (1) development of a deterministic mathematical model of heat and mass transfer in a pyrolyzed firebrand of vegetation, taking into account soot formation; (2) development of a probabilistic criterion for assessing forest fire danger from thunderstorms, taking into account aerosol emissions; (3) scenario modeling of heat and mass transfer and the formation of a thunderstorm front; (4) and the formulation of conclusions and proposals for the practical application of the developed deterministic–probabilistic approach to the prediction of forest fires from thunderstorms, taking into account aerosol emissions. The novelty of this study lies in the development of a new model of heat and mass transfer in a pyrolyzed vegetation firebrand and a new probabilistic criterion for forest fire danger due to thunderstorm activity, taking into account aerosol emission. The distributions of temperature and volume fractions of phases in a firebrand are obtained for various scenarios. Scenarios of surface fires, crown forest fires, and a fire storm are considered for typical types of coniferous vegetation. Cubic firebrands are considered in the approximation of a two-dimensional mathematical model. To describe the heat and mass transfer in the firebrand structure, a differential heat conduction equation is used with the corresponding initial and boundary conditions, taking into account the kinetic scheme of pyrolysis and soot formation. Variants of using the developed mathematical model and probabilistic criterion in the practice of protecting forests from fires are proposed. Key findings: (1) linear deterministic–probabilistic mathematical model to assess forest fire occurrence probability taking into account aerosol emission and lightning activity; (2) results of mathematical modeling of heat and mass transfer in firebrand taking into account soot formation; (3) and results of scenario modeling of forest fire occurrence probability for different conditions of lightning activity and aerosol emission.
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