Thickness Of Intermetallic Layer Research Articles

EVALUATION OF ZINC IN LASER BEAM BRAZE WELDING OF GALVANIZED STEEL SHEETS

For more than a decade, the automotive industry has employed the laser welding-brazing process in the manufacturing of vehicle bodies, where the quality of the brazed seam is an important requirement, especially when exposed to the customer. One aspect that compromises the quality of the seam is the presence of zinc in the coating of galvanized steel sheets. In this context, a comparative study was conducted between two wire feeding methods in laser welding-brazing (pulling and pushing) to mitigate the presence of zinc in the brazed seam region and to evaluate the thickness of the iron-silicon intermetallic layer, which can impact the mechanical strength of the joint. A single laser beam was used for the welding-brazing, with silicon-copper wire addition and two sheet thicknesses. Scanning electron microscopy analyses with attached EDS showed that, despite the low detection, for the thinner sheet, there is a difference in the amount of zinc in the fused zone between the feeding techniques. Additionally, EDS mapping confirmed the presence of an intermetallic layer composed of iron and silicon, whose thickness is greater for the pushing wire addition method, considering the higher heat input compared to the pulling method.

The Effect of Bi on the Kinetics of Growths, Microstructure and Corrosion Resistance of Hot-Dip Galvanized Coatings.

This paper presents the results of studies on the growth kinetics, microstructure (SEM/EDS) and corrosion behavior of coatings obtained by hot-dip galvanizing process in baths containing Bi additive. The coatings for testing were produced on low-silicon steel in a Zn bath containing 0.04, 0.12 and 0.4 wt.% Bi. The corrosion resistance of the coatings was determined comparatively in standard Neutral Salt Spray Tests (NSST) (ISO 9227) and sulfur dioxide test (SDT) in a humid atmosphere (ISO 22479). Potentiodynamic tests and electrochemical impedance spectroscopy measurements were conducted. It was found that the addition of 0.04 and 0.12 wt.% Bi reduces the total thickness of the coatings and the thickness of intermetallic layers, while the content of 0.4 wt.% Bi in the bath increases the thickness of the layers forming the coating. Direct corrosion tests (NSST and SDT) and electrochemical tests showed that the addition of Bi to the zinc bath reduces the corrosion resistance of the coatings. The corrosion resistance of the coatings decreases with increasing Bi concentration in the zinc bath. In the microstructure of the coatings, it was found that Bi precipitates mainly on the surface of the coating, but also on the cross-section of the outer layer and ζ intermetallic layer. Bi precipitates, due to their cathodic nature, affect the reduction of the corrosion resistance of the coatings with the increase of their content in the bath.

Role of submerged friction stir welding in reducing intermetallic growth and enhancing microstructure in dissimilar Al-Ti joints

The integrity of dissimilar Al-Ti welds during conventional friction stir welding (CFSW) is compromised by excessive material mixing, leading to thick intermetallic layers. Underwater friction stir welding (UWFSW) mitigates these effects by inhibiting material mixing due to lower thermal conditions. Scanning electron microscopy revealed substantial Ti particles, appearing as blocks and strips, within the stir zone during CFSW. Static recrystallization, driven by exothermic reactions between Ti blocks and the Al matrix, resulted in over 93% recrystallized grains along stir zone, 10.7% higher than in UWFSW. In contrast, UWFSW resulted in a finer dispersion of Ti particles with reduced density due to lower frictional heat. The average grain size at the Ti interface of CFSW was 1.0 μm, compared to 2.6 μm in UWFSW. The inhomogeneous distribution of Ti particles in CFSW led to uneven dislocation distribution and increased stress concentrations, while finer Ti particles in UWFSW promoted a uniform grain structure, enhancing joint strength to 267 MPa, 13.4% higher than CFSW. Additionally, the γ-fibre and basal fibre texture in UWFSW increased joint ductility. The study highlights UWFSW’s effectiveness in joining dissimilar metals, offering significant advantages for industries such as aerospace and automotive.

Microstructure, Mechanical and Fractographic behaviour of the Diffusion Welded Joints of AA2219 and Ti-6Al-4V for aerospace applications

Diffusion welding is an advanced joining process that assures the feasibility of joining dissimilar metal alloys without producing metallurgical impurities at the joint interface. Two significant aerospace alloys, AA2219 and Ti-6Al-4V, are diffusion welded for the various holding times (30-120 minutes) by keeping the bonding temperature and pressure constant. The effect of holding time on the microstructure of the diffusion welded joints is evaluated using scanning electron microscopy (SEM), and the diffusion behaviour across the joint interface is ensued by the line scan energy dispersive spectroscopy (EDS). The obtained results show that the hardness across the joint interface is increased with increase in holding time. Furthermore, the maximum shear strength of 143.58 MPa is achieved for the joint formed at the holding time of 90 minutes and reduced thereafter. The formation of a thick intermetallic layer at a higher holding time strongly affects the shear strength. It is evident from the resulting fractured surfaces that the joints predominantly failed at the bonding interface, showcasing the brittle kind of failure. The X-ray diffraction (XRD) study on the fractured surfaces substantiates the formation of AlTi, Al2Ti and Al3Ti intermetallic compounds.

Effects of Main Alloying Elements on Interface Reaction between Tool Steel and Molten Aluminum

Effects of Si and Mg as main elements on interface reaction between tool steel and molten Al alloy at 700°C were investigated. Pure aluminum and Al-10mass%Mg alloy showed relatively simple interfacial layers, whereas thicker, multi-layered reaction bonds were found in the diffusion couple of A380 alloy. The diffusion of a large amount of Fe into Al matrix throughout the interfacial layer led to the formation of Al-Fe based intermetallic particles in the Al base metals. The diffusion couple of Al-10mass%Mg alloy showed a similar intermetallic layer as that of pure Al, indicating that 10mass%Mg in the Al melt rarely affected the formation of Al-Fe intermetallic layers. However, A380 alloy showed much expanded soldering area and increased thickness of intermetallic layers. Based on the phase diagram calculated, the solubility of Fe in liquid Al increased significantly with increasing Si content up to apploximately 5mass%, while, in the case of 10mass%Mg addition, the Fe solubility gradually decreased with increasing Mg content. Al-10mass%Mg alloy also showed the same tendency as that of pure Al in the formation and distribution of intermetallic compounds. However, in the Al-12mass%Si alloy, two types of Al-Fe-Si ternary compounds are present on the Al-rich side.

Coupling influence of laser-Nb interlayer on microstructure and performance of Ti/Al joint

Laser fusion welding of TC4 titanium (Ti) alloy and aviation 7075 aluminum (Al) alloy was conducted with the assistance of a niobium (Nb) interlayer. The effect of laser heat input and the alloying effect of Nb on the interfacial layer was analyzed. The study also investigated the coupling influence of the laser-Nb interlayer on the microstructure and performance of the Ti/Al joint. By utilizing a 0.1 mm-thick Nb interlayer and a welding velocity of 1800 mm/min, the results reveal an initial increase in tensile-shear force followed by a decline with the increase of laser power. The tensile-shear force reached a peak of 1663 N at 1.2 kW, representing a 36.76 % improvement over the 1 kW levels. Under appropriate laser power, the enhancement in joint performance is dominated by the controlled heat input and the effective Nb-alloying effect, which reduce the thickness and brittleness of the interfacial intermetallic layer, respectively. However, metallurgical regulation of Nb will be restricted by the insufficient Nb melting amount resulting from the low laser power, leading to a decrease in joint properties. Excessive laser power can lead to the formation of hot cracks and an excessive amount of Ti-Al intermetallic compounds, which can decrease the Nb content, thereby restricting the metallurgical regulation of Nb and the overall joint performance.

Microstructural and mechanical characterization of Al/Cu interface in a bimetallic composite produced by compound casting

The bimetal set (Al/Cu) with Cu wire with 2.0, 2.5, and 3.0 mm diameters were cast at different casting temperatures and solidification times through the compound casting method. The microstructure of solid/liquid diffusion bonding at the Al/Cu interface was investigated, and the shear strength of the Al/Cu interface was measured by punch test. By characterizing the diffusion layer, the optimum parameters of the compound casting, including the casting temperature and the solidification soaking time, as well as the Cu wire diameter, were acquired. The intermetallic compounds (IMCs) such as CuAl2 were observed in the diffusion layer. The types of intermetallic phases and diffusion layer thickness affect the hardness and the shear strength. The result of casting at 680 °C and solidification soaking time of 15 s for 3 mm Cu wire, shows that IMCs increased the micro-hardness of the Al/Cu bimetal up to 328 HV at the Al/Cu interface. Also, increasing the solidification soaking time at a constant temperature resulted in a growth of the interface layer’s thickness, which exhibits a lamellar eutectic microstructure containing IMCs. Furthermore, this action caused an increase in the shear strength.

Al-Cu intermetallic phase growth in hybrid metal extrusion & bonding welds exposed to isothermal annealing or direct current cycling

Joining of aluminium (Al) to copper (Cu) is of great interest to power generation, transportation and electronic industry. However, dissimilar metal joining often promotes intermetallic phase formation at the joined interface, which in redundancy can cause mechanical degradation and increased electrical resistance. The welding technique hybrid metal extrusion & bonding (HYB) is proven capable of joining dissimilar metals with a total intermetallic phase layer thickness <▪. To test how Al-Cu HYB joints perform as electrical conductors, a 6101 Al alloy HYB-welded to Cu is exposed to heat treatment at ▪ or cycling of direct current density up to ▪. In-depth micro- and nanostructure characterisation by (scanning) transmission electron microscopy and atom probe tomography are used to describe the structure and chemistry of the formed intermetallic phases.The Al-Cu HYB joints exhibited resilience against intermetallic phase growth during isothermal heat treatment or exposure to electric current. However, a non-symmetry is observed dependent on the current direction, creating voids in Cu near, and in the intermetallic layers when the current goes from Al to Cu. Detailed microstructure characterisation unveils Si and Mg in the intermetallic phase layers. Their origin and role in intermetallic phase growth are discussed.

The Feasibility of Static Shoulder Friction Stir Welding in Joining Dissimilar Metals of Al6061 and Ti6Al4V

In this study, static shoulder friction stir welding (SSFSW) is innovatively employed to join Al6061 and Ti6Al4V, aiming to minimize material mixing and intermetallic formation, significantly influencing the interfacial microstructure and joint strength. The results revealed that SSFSW reduced the intermetallic layer thickness at the interface, improving joint quality. The mutual interdiffusion of Al and Ti at the interface was influenced by an exothermic chemical reaction, forming an Al5Ti2–Al3Ti sequence due to the diffusion of Al into the Ti matrix. The microstructural analysis demonstrated better interfacial microstructural homogeneity in SSFSW joints than conventional FSW (CFSW), with finer titanium particle distribution. The larger particles resulted in coarser grains in CFSW, affecting the mobility of dislocations, which potentially led to the inhomogeneous concentration of dislocations at the interface. Recrystallization mechanisms varied between CFSW and SSFSW, with the Ti interface showing equiaxed and recrystallized grains due to the dynamic recovery driven by adiabatic shear bands. The tensile testing results of SSFSW exhibited a joint efficiency of 88%, demonstrating a 20.2% increase compared to CFSW, which can be attributed to differences in fracture modes. This study contributes to an understanding of dissimilar Al-Ti joining and provides insights for industries seeking to leverage the benefits of such combinations in lightweight and high-performance structures.

Research on the mechanical properties and fracture mechanism of ultrasonic vibration enhanced friction stir welded aluminum/steel joint

Friction stir welding (FSW) and ultrasonic vibration enhanced friction stir welding (UVeFSW) were used to connect 3 mm thick 2024-T3 Al alloy and Q235 carbon structural steel. The weld forming quality, mechanical properties, fracture location and interface behavior of the whole and layered joints were compared and analyzed, and the different mechanisms of the ultrasonic vibration to improve the tensile strength of the joint were summarized. As the results show, the ultrasonic vibration promoted the plastic flow ability of materials and improved the welding seam forming quality. Moreover, the ultrasonic vibration made the plastic deformation of the material in the nugget zone more uniform, which improved the strength of the nugget zone. In the middle layer of the joint, the ultrasonic vibration reduced the thickness of intermetallic compound layers (IMCLs), eliminated the laminated structure that harmed the connection quality of the joint, and formed a micromechanical interlocking structure in which IMCLs was inserted into the steel, which improved the interfacial bonding strength and improved the tensile strength by 11.1%. The ultrasonic vibration optimized the macro-mechanical interlocking structure in the joints of the lower layer, which enhanced its mechanical bonding ability with Al alloy.

Enhancing Microstructural, Textural, and Mechanical Properties of Al-Ti Dissimilar Joints via Static Shoulder Friction Stir Welding

Abstract The present study explores the application of static shoulder friction stir welding (SSFSW) to address the challenges of poor mechanical properties in conventional Al-Ti dissimilar friction stir joints, which arise due to significant material mixing and the formation of thick intermetallic layers. The results show that SSFSW inhibited material mixing and the mutual diffusion of Al and Ti were suppressed due to lower heat input. Mutual interdiffusion of Al and Ti was directed by an exothermic chemical reaction, forming an Al5Ti2 – Al3Ti sequence due to sluggish diffusion of Al in Ti at a temperature of 512°C achieved in this study. The microstructure at stir zone (SZ) comprised equiaxed grains with Ti particles acting as dispersoids for nucleation, whereas the presence of large Ti blocks at SZ of Conventional FSW (CFSW) resisted plastic deformation, resulting in non-homogeneous concentration of dislocations near its interface. A significant decrease in grain size at all the critical zones of weldment was due to rearrangement of dislocations through slip-and-climb mechanism, as evidenced by the occurrence of dynamic recrystallization. Emergence of γ-fiber and basal fiber texture increased the tensile strength of SSFSW to 289 MPa, which is about 11.2% higher than CFSW, with joint efficiency of about 88%. The study also analysed the contribution of various strengthening mechanisms to the yield strength improvement of SSFSW weldments in detail of SSFSW weldments in detail, and the results showed that grain boundary strengthening contributed the most to strength improvement in SSFSW.

Minimizing material flow in the dissimilar joining of Al6061 and Ti6Al4V to mitigate the adverse effects of intermetallic compounds

Static shoulder friction stir welding (SSFSW) offers a promising solution for joining Al6061 and Ti6Al4V by addressing material mixing and intermetallic formation encountered in conventional friction stir welding (CFSW). SSFSW effectively suppresses material mixing and Al-Ti interdiffusion, leading to an Al5Ti2 – Al3Ti sequence through an exothermic reaction. Comparative analysis with underwater friction stir welding (UWFSW) highlights SSFSW's effectiveness, showing a significant reduction in intermetallic layer thickness compared to UWFSW. The intermetallic layer thickness of SSFSW is measured at 2.169 µm, while UWFSW exhibits a thickness of 3.731 µm, and CFSW shows the highest at 5.485 µm. The inverse pole figure confirms reduced material flow and intermetallic formation in SSFSW compared to UWFSW and CFSW.

Mechanical behavior of AA5083/AA6061 friction stir welds using modal analysis

Abstract Solid-state joining is used for welding similar or dissimilar materials due to its many advantages like avoiding fusion and formation of a thick intermetallic layer, etc. Determination of the right process parameters (feed rate and rotation speed) and tool geometry (shoulder and pin) is of critical importance in friction stir welding in order to achieve adequate weld quality. The experiments were performed using three process parameters: feed rate (mm min−1), rotation speed (rpm) and pin geometry for friction stir welding of Al5083 and Al6061. Eighteen experiments were performed with different process parameters and mechanical tests (microhardness and tensile measurements) have been carried out to determine the weld quality. Results showed that the best results of ultimate strength (198.5 MPa) were achieved by the triangle pin geometry, 1250 rpm rotation speed and 100 mm min−1 feed rate. Similar results were observed in microhardness tests. Effects of tool geometry, feed rate, and rotation speed on the vibration properties and weld quality are also investigated experimentally. The effects of the FSW parameters used were assessed using vibration analysis.

Effect of Al2O3 and NiO Nanoparticle Additions on the Structure and Corrosion Behavior of Sn—4% Zn Alloy Coating Carbon Steel

The application of a higher corrosion resistance coating modified with nano additions can effectively decrease or prevent corrosion from occurring. In the present work, a novel method is successfully developed for the modification of carbon steel surfaces aiming for high corrosion resistance using Sn—4% Zn alloy/nanoparticle composite (NiO+ Al2O3) coating. Sn—4% Zn alloy/nanoparticle composite (NiO+ Al2O3) coatings were deposed on carbon steel using a direct tinning process that involved a power mixture of Sn—4% Zn alloy along with a flux mixture. Regular coating and interface structures were achieved by individual Al2O3 and both NiO and Al2O3 nanoparticle combined additions in the Sn-Zn coating. The maximum coating thickness of 70 ± 1.8 µm was achieved for Al2O3 nanoparticles in the Sn-Zn coating. Interfacial intermetallic layer thickness decreased with all used nanoparticle additions in individual and hybrid conditions. The minimum intermetallic layer thickness of about 2.29 ± 0.28 µm was achieved for Al2O3 nanoparticles in the Sn—Zn coating. Polarization and impedance measurements were used to investigate the influence of the incorporated Al2O3, NiO, and hybrid Al2O3/NiO nanoparticles on the passivation of the low-carbon steel (LCS) corrosion and the coated Sn—Zn LCS in sodium chloride solution. It was found that the presence of Al2O3, NiO, and Al2O3/NiO nanoparticles remarkably improved the corrosion resistance. The corrosion measurements confirmed that the corrosion resistance of the coated Sn-Zn carbon steel was increased in the presence of these nanoparticles in the following order: Al2O3/NiO &gt; NiO &gt; Al2O3.

DC pulsed plasma magnetron sputtering of CdO/Cu/CdO multilayers thin films for self-cleaning and optoelectronic applications

In this study, CdO/Cu/CdO multilayers thin films were organized on glass substrates with different Cu intermetallic layer thickness engaging DC plasma magnetron sputtering. The optoelectronic properties and structural characteristics of the multilayers at various Cu intermetallic layer thicknesses which were varied from 4 to 16 nm were explored. The calculated band gap was reduced from 2.66 eV to 2.48 eV as the Cu intermetallic layer thickness increased from 4 to 16 nm. The refractive index and coefficient of extinction of CdO/Cu/CdO multilayers increased with increasing the Cu intermetallic layer thickness. The resistivity is reduced from 1.8 × 10−2 Ω cm for CdO single layer to reach a value of 2.7 × 10−4 Ω cm for CdO/Cu (16 nm)/CdO multilayer. Further, the sheet resistance is decreased from 1000 to 13.8 Ω/sq. with the variation in Cu intermetallic layer thickness from 0 to 16 nm. CdO/Cu (4 nm)/CdO multilayer film recorded the best figure of merit (2.3 × 10−4 Ω−1). After sunlight illumination for the multilayers, the surface wettability was improved and the contact angle recorded lowest value of nearly 24° for CdO/Cu (8 nm)/CdO and CdO/Cu (12 nm)/CdO.

Experimental study on drawability of aluminium-copper composite in micro deep drawing

To meet the increasing demand of multifunctional applications of microcomponents, metal composites have been gradually noted in micromanufacturing. In this paper, the formability of aluminium (Al)-copper (Cu) composite foils in micro deep drawing (MDD) was studied, and the mechanism involved was discussed. A two-layered Al-Cu composite with the thickness of 235 µm was selected and first rolled to 50 µm, and then annealed at 200, 300, 400 and 500 °C for 5 min prior to the MDD experiments. The results show that Al-Cu composite foil possesses the best combination of strength and ductility after annealing at 400 °C. With the increase in annealing temperature, the grains of both Al and Cu layers are refined, and in the meantime, the thickness of intermetallic layer also increases. The results from MDD tests indicate that the existence of intermetallic layer has a greater influence on the formability of the composite foil compared to the finer distribution of grains. On the basis of the obtained results, the optimised heat treatment method with the annealing temperature of 300 °C for 1 h was proposed, which was then proved to significantly improve the performance of the Al-Cu composite foil in MDD.

Friction stud riveting (FSR) of thick high-strength aluminum alloy structure

7-series aluminum (Al) alloy is a promising material that can meet the ever-increasing lightweight demand for transportation tools. However, the assembly between Al alloy and steel components brings challenges to the existing stud pre-embedded technology. This study proposes a friction stud riveting (FSR) process to achieve high-performance and high-efficiency embedding of steel studs in Al alloy parts by shank undercut, grooves interlock, and intermetallic compounds bonding. The stud geometry and FSR process were first optimized by evaluating the macro morphology of the joints. Then, the microscopic characterizations were performed to understand the material flow behavior, plastic deformation, and microstructure evolution of the joint induced by the feeding and rotation of the stud. The results indicate that the transient thermo-mechanical coupled FSR process leads to a continuous transition of sliding, mixed sliding-sticking, and sticking contact conditions between the stud and the Al alloy, resulting in a thermo-mechanical affected zone (TMAZ) outside the stud and a trapped Al alloy (TAA) inside the stud with diverse dynamic recrystallization (DRX) states and microstructures. The rotation state evolution and temperature gradients of the material within the TAA create two DRX bands that dominate the fracture behavior of TAA under tensile and shear loads. The strengths of the optimized steel stud-thick Al FSR joints reach 101.3% and 118.5% of the 7A52 Al alloy base material in tensile and shear tests, respectively, which solves the problem of low joining strength between steel stud and Al alloy plate due to the brittle and thick intermetallic compounds layers in conventional stud welding processes.

Fracture Behavior and Reliability of Low-Silver Lead-Free Solder Joints

Abstract Low-silver solders are increasingly being used because silver improves the tensile strength. In this study, the variation in fracture behavior with silver content in lead-free solder joints was studied using double cantilever beam specimens. Fracture tests were done with solder joints made with Sn-0.7Cu, SACX0307, and SAC305 solder materials. The critical energy release rate for crack-initiation (Gci) of the joint was correlated with the plastic zone just ahead of the precrack tip, intermetallic compound layer thickness, energy dispersive spectroscopy analysis, and scanning electron microscopy based fractography study. The Gci for Sn-0.7Cu solder joint was observed to be significantly higher than the other two solder joints. The fractography study revealed that the failure was ductile for Sn-0.7Cu and a mix of ductile and brittle for the other two solder joints. The extent of the plastic zone ahead of the crack tip, obtained from finite element modeling, was found to be significantly larger and the intermetallic compound layer was relatively thinner for Sn-0.7Cu solder joint compared to the other two solder joints. The ductile failure, significantly larger plastic zone size and thinner intermetallic compound layer resulted in significantly higher Gci for Sn-0.7Cu solder joint.

Corrosion resistance and metallurgical behaviour of CMT welded Al-LCS dissimilar butt joint exposed in simulated industrial environment

Cold Metal Transfer welding is a predominant process for joining the Aluminium and Low Carbon Steel (LCS) dissimilar joints with enhanced properties. In addition, these joints have vast application in various simulated industrial environmental conditions. However, the formation of thick intermetallic layers during welding over these joints leads to invoking the corrosion attack and causing a catastrophic failure that is the primary concern in life prediction of the joint. Hence, the corrosion behaviour of AL-LCS dissimilar butt joint exposed in the simulated industrial environment has been studied experimentally and it has been compared with the Cold Metal Transfer (CMT) welded aluminium and LCS similar joints. The potentiodynamic polarization and the electrochemical impedance spectroscopy were carried out in 3.5% aggressive sodium chloride medium with varying benzotriazole corrosion inhibitor with varying the concentrations like 10 ppm, 15 ppm and 20 ppm. The results showed that the corrosion resistance behaviour of CMT welded dissimilar joints are increased with increasing inhibitor concentration. The inhibitor showed effective performance, and the efficiency is also found to be 78–80% at 20ppm, which revealed the enhanced corrosion resistance of dissimilar metal joints in simulated industrial conditions. Finally, the dissimilar joints are characterized by sophisticated analytical techniques.

Enhancement of Surface and Interface Properties of Low Carbon Steel by Hybrid ZnO and NiO Nanoparticles Reinforced Tin Coating

Tin matrix nanocomposite coatings containing ZnO and NiO nanoparticles, both individually and combined, were deposited on low carbon steel substrates. The aim was to investigate the effect of reinforcement of nanoparticles on microstructural morphology and thickness of tin coatings, modification in the interfacial layer between coating and substrate, and the corrosion resistance of low carbon steel substrate. Optical and scanning electron microscopy were employed for microstructural observation, while potentiostat-galvanostat was utilized for electrochemical investigation. It was found that the tin nanocomposite coatings with nanoparticles significantly modified the coating thickness, intermetallic layer thickness, and surface corrosion resistance. Coatings through the direct tinning process are considered to be a simple and low-cost route for protecting metallic materials from corrosion, and the presence of ZnO and NiO nanoparticles in tin coatings further increases the corrosion resistance of low carbon steels.