Thermoplastic Materials Research Articles

Combined role of stearic acid and maleic anhydride in the development of thermoplastic starch-based materials with ultrahigh ductility and durability

The diverse properties reported for starch-based materials indicate their potential for use in the preparation of biodegradable flexible actuators. However, their natural brittleness and lack of durability after modification limit their practical application. Therefore, we propose a strategy for preparing flexible starch-based composites. The results of macro/micro property characterizations and molecular dynamics simulations indicated that using starch, maleic anhydride, and stearic acid (SA), the mobility of the starch chains was enhanced and retrogradation was inhibited through the synergistic effects induced by chain breaking, complex formation with SA, and esterification of the starch molecules. In addition, the elongation at break of the modified starch (MS) reached 2070 %, and considerable ductility (>1000 %) as well as well-complexed structure were maintained after six months. Furthermore, the MS was able to undergo self-healing after fracture or a temperature-controlled stiffness transition. Moreover, it underwent complete degradation in soil within 30 d. Finally, an actuator was prepared by doping the MS with nano-Fe3O4 particles to realize a dual magnetic and optical response. Dynamic monitoring was also achieved based on the electrical signal, thereby demonstrating the broad application scope of this material in the development of biodegradable flexible actuators.

Effect of low‐pressure plasma processing parameters on the surface topography of a CF/PEEK composite for adhesive bonding

AbstractIn recent decades, thermoplastic matrix fiber composites have become attractive for many modern aerospace structural applications. However, their adhesive bonding remains challenging, so it is essential to study surface pre‐treatments to improve their potential for adhesive bonding. In this study, an aerospace‐grade carbon fiber reinforced poly ether ether ketone composite, which was adhesively bonded with a structural epoxy‐film adhesive, has been investigated. The composite adherends were pre‐treated using low‐pressure oxygen plasma across a range of processing parameters. The treated surfaces were analyzed using scanning electron microscopy, X‐ray photoelectron spectroscopy, and contact angle analysis to characterize the surface topography, chemistry, and wettability of the composite after the different levels of treatment. A plasma treatment power of 180 W for a duration of 5 min was shown to provide the best results in surface characterization and single‐lap‐shear joint testing. Compared to the traditional thermosetting composites, a lower power or/and shorter duration of the plasma treatment was sufficient to achieve good adhesion for the thermoplastic composites. A nano‐etching effect induced by relatively long treatment times was observed, which contributed to the formation of nano‐grooves on the surface of the adherends without exposing fibers on the surfaces.Highlights A plasma treatment improves the adhesive performance of the CF/PEEK composite. Better adhesion is due to enhanced surface activation and nano‐etching. The optimized parameter for better SLS strength is 180 W for 5 min. A lower power or shorter duration of PL is sufficient for TPCs than TSCs.

Physicochemical and antimicrobial characteristics of polypropylene-based nanocomposite containing SiO2-Ag nanoparticles prepared by gamma irradiation

This article evaluates the physicochemical and antimicrobial properties when silver-coated silica (SiO2-Ag) nanoparticles as active nanofiller are incorporated into the polypropylene (PP) thermoplastic matrix. The silica (SiO2) nanoparticles were prepared by precipitation method using sodium silicate. After that, silver-coated silica (SiO2-Ag) nanoparticles were synthesized by gamma radiation technique. X-ray diffraction (XRD), Infrared spectroscopy analysis (FTIR) and Transmission electron microscopy (TEM) analysis clarified the formation of SiO2-Ag nanoparticles. SiO2-Ag nanoparticles has a particle size with an average of 70 nm. The melt mixing procedure operated to fabricate PP thermoplastic nanocomposites with various ratios of 1.0, 2.0, and 3.0 part per hundred resin (phr) of the SiO2-Ag nanoparticles. To examine the effect of ionizing radiation on the prepared PP/SiO2-Ag nanocomposites, the samples were exposed to 20 kGy of gamma-irradiation. FTIR, XRD, mechanical analysis, thermogravimetric analysis (TGA), and scanning electron microscope (SEM) were utilized to characterize the physico-chemical alterations of the PP when loaded with SiO2-Ag nanoparticles. It is found that PP/1.0 phr SiO2-Ag nanocomposite revealed superior physico-chemical characteristics than the other two components. The irradiated specimens revealed superior tensile strength (TS) and elastic modulus (EM) over unirradiated ones, whereas inverse effects were predominant in case elongation at break (E%). Tmax of the native PP increased from 335°C to nearly 370°C of PP/1.0 phr SiO2-Ag nanocomposite. It is established that the fabricated PP/SiO2-Ag nanocomposites exhibited potent antimicrobial activity and can be a good candidate for food packaging applications.

Mechanical and shape memory properties of Eucommia ulmoides gum-based elastic fibers with various architectures

Eucommia ulmoides gum (EUG) is composed of trans-1,4-polyisoprene with high flexibility and crystallinity, and could be utilized as elastic and thermoplastic materials. Taking advantage of the unique crystallization characteristics, a series of EUG-based complex elastic fibers were prepared by wet-spinning method using different types of needles. It was found that the EUG fiber displayed excellent mechanical properties including high tensile strength (42.8 MPa), elongation at break (572%), and toughness (136.8 MJ m−3). The complex elastic fibers combining different compositions and various architectures have higher temperature sensitivity and excellent shape memory recovery ability compared to EUG elastomer. Meanwhile, the elastic fibers containing EUG and butyl rubber (IIR) exhibited better damping properties than pristine EUG. Therefore, this work provided a way to enhance the functionality and expand the application of bio-based EUG materials.

Development of a heavy vehicle torque rod applying continuous fiber reinforced thermoplastic composite materials instead of forged steel material: Design, analysis and optimization

The torque rod is an important component of the suspension system that connects the axle to the chassis in heavy commercial vehicles. The main motivation of this study is the development of a torque rod made of (1) plus cross-section, (2) continuous carbon and glass fiber reinforced hybrid thermoplastic composites, which can replace a forged steel torque rod used in heavy vehicles, has superior mechanical properties, provides minimum cost and weight. This study aims to develop a torque rod before its production within the framework of integration with Computer Aided Design (CAD), Finite Element Analysis (FEA), and Multi-Criteria Decision Making (MCDM). In this study, the design data and the properties of the composite materials were chosen as control factors. The minimum displacement, the best mechanical properties such as tensile stress, compressive stress, torsional shear stress, maximum critical buckling load, and the minimum part weight minimum production cost per piece were selected as quality characteristics. As a result of the FEA study, considering the experimental set of the Taguchi Method L25 orthogonal array, the data on mechanical properties, weight, and production cost per piece were subjected to the MCDM process using the Entropy Weighted TOPSIS method. As a result of the MCDM study, a torque rod made of continuous fiber-reinforced thermoplastic composite material, instead of a torque rod produced by forged steel, had the highest mechanical properties produced, the weight of the torque rod can be reduced by 64.76%, and the production costs per piece can be reduced by 37.5%. This study’s findings have shown that the torque rod produced from continuous fiber-reinforced thermoplastic composite materials in a new geometry with a plus cross-section can be substituted for the torque rod produced by steel forging. Thus, it will contribute to reducing the fixed vehicle weight, especially in heavy commercial vehicles, reducing CO2 emissions, and increasing the range of the vehicles.

Microstructure generation and full-field multi-scale analyses for short fiber reinforced thermoplastics: Application to PA66GF composites

Short Fiber Reinforced Thermoplastics (SFRTs) like PA66GF composites are highly heterogeneous materials with a rather complex microstructure such that the characterization and the prediction of their mechanical behavior remain quite challenging. So far, most of the research efforts have employed phenomenological and mean-field multi-scale models to deal with SFRTs. The present contribution rather focuses on a full-field multi-scale approach that incorporates advanced techniques in terms of microstructural representation and material modeling, allowing a deep insight of the dominating deformation mechanisms occurring in PA66GF composites. The proposed approach is based on an automatic periodic mesh generation algorithm for matrix-inclusion Representative Volume Elements (RVE) with randomly positioned fibers that follow a given Orientation Distribution Function (ODF). At the microscopic scale, while the fibers are assumed to be elastic, the behavior of the thermoplastic matrix is described by a phenomenological multi-mechanism constitutive model accounting for viscoelasticity, viscoplasticity and ductile damage. It results an advanced multi-scale model that enables to visualize the local deformation and degradation mechanisms occurring at the microscopic scale while simultaneously analyzing their influence on the macroscopic response of the composite upon monotonic, persistent and cyclic loading. The potential of the proposed approach is further evaluated by comparing the predicted responses against experimental data.

Thermoplastic polymers as water substitutes

Background. New applications of 3D printing have recently appeared in the fields of radiotherapy and radiology, but the knowledge of many radiological characteristics of the compounds involved is still limited. Therefore, studies are needed to improve our understanding about the transport and interaction of ionizing radiation in these materials. Purpose. The purpose of this study is to perform an analysis of the most important radiation interaction parameters in thermoplastic materials used in Fused Deposition Modeling 3D printing. Additionally, we propose improvements to bring their characteristics closer to those of water and use them as water substitutes in applications such as radiodiagnosis, external radiotherapy, and brachytherapy. Methods. We have calculated different magnitudes as mass linear attenuation, mass energy absorption coefficients, as well as stopping power and electronic density of several thermoplastic materials along with various compounds that have been used as water substitutes and in a new proposed blend. To perform these computations, we have used the XCOM and ESTAR databases from NIST and the EGSnrc code for Montecarlo simulations. Results. From the representation of the calculated interaction parameters, we have been able to establish relationships between their properties and the proportion of certain chemical elements. In addition, studying these same characteristics in different commercial solutions used as substitutes for water phantoms allows us to extrapolate improvements for these polymers. Conclusion. The radiological characteristics of the analyzed thermoplastic materials can be improved by adding some chemical elements with atomic numbers higher than oxygen and by using polyethylene in new blends.

Investigation of flexural properties of hexagonal boron nitride added thermoplastic composites

In this study, weight percentages (wps) of 0%, 0.5%, 2% hexagonal boron nitrides (hBN) were added to 30 wt.% short glass fiber reinforced Polyamide (PA) 66 matrix (GF30) to fabricate the thermoplastic composite materials. The hBN additives were applied by coating of granules of 30 wt.% short glass fiber reinforced PA 66 (GF30) materials. The hBN coated thermoplastic materials were produced by plastic injection method. The effect of different wps of hBNs on the flexural properties of thermoplastic composites were examined in the produced samples. The produced samples were subjected to three-point bending tests. When looking at the results of the three-point bending tests, the highest increase of flexural properties was obtained in the sample of PA66/GF30/2% hBN added thermoplastic composite. The samples with 2 wt% hBN showed the best flexural properties with an improvement of 85 and 52% flexural modulus and strength, respectively, compared to the samples without hBN (PA66/GF30). According to the obtained results of this study, as the percentage of the hBN weight contents increased, the flexural strengths and flexural modulus increased significantly. It was concluded that hBN coated thermoplastic composite samples demonstrated high improvements of flexural properties at optimum rates of hBN.

Microstructural evolution of highly aligned discontinuous fiber composites during longitudinal extension in forming

The longitudinal extensional viscosity of a highly aligned discontinuous fiber (ADF) thermoplastic matrix composite is investigated to develop a model and validate microstructural evolutionary mechanisms. Samples stretched at constant temperature and strain rate are shown to exhibit a strain softening behavior. X-ray CT analysis and optical micrographs show that the composite microstructure deconsolidates before forming and evolves with deformation. The conventional unit cell micromechanical model includes the effects of matrix viscosity, fiber aspect ratio and fiber volume fraction. This model is modified to include the stiffening effect of fiber spacing variability, and the softening effects of porosity and decreasing fiber overlap length with elongation. Calibration of the model reveals that matrix shear strain rate is an order of magnitude higher than previously predicted due to local fiber spacing. This effect is captured by a fiber spacing variability parameter which scales average spacing down by an order of magnitude. The observed strain softening behavior is described and a combinations of fiber overlap length reduction and local fiber spacing increase.

Perspective on the Development of Monomer Recovery Technologies from Plastics Designed to Last.

In order to prevent the current unsustainable waste handling of the enormous volumes of end-of-use organic polymer material sent to landfilling or incineration, extensive research efforts have been devoted toward the development of appropriate solutions for the recycling of commercial thermoset polymers. The inability of such cross-linked polymers to be remelted once cured implies that mechanical recycling processes used for thermoplastic materials do not translate to the recycling of thermoset polymers. Moreover, the structural diversity within the materials from the use of different monomers as well as the use of such polymers for the fabrication of fiber-reinforced polymer composites make recycling of these materials highly challenging. In this Perspective, depolymerization strategies for thermoset polymers are discussed with an emphasis on recent advancements within our group on recovering polymer building blocks from polyurethane (PU) and epoxy-based materials. While these two represent the largest thermoset polymer groups with respect to the production volumes, the recycling landscapes for these classes of materials are vastly different. For PU, increased collaboration between academia and industry has resulted in major advancements within solvolysis, acidolysis, aminolysis, and split-phase glycolysis for polyol recovery, where several processes are being evaluated for further scaling studies. For epoxy-based materials, the molecular skeleton has no obvious target for chemical scission. Nevertheless, we have recently demonstrated the possibility of the disassembly of the epoxy polymer in fiber-reinforced composites for bisphenol A (BPA) recovery through catalytic C-O bond cleavage. Furthermore, a base promoted cleavage developed by us and others shows tremendous potential for the recovery of BPA from epoxy polymers. Further efforts are still required for evaluating the suitability of such monomer recovery strategies for epoxy materials at an industrial scale. Nonetheless, recent advancements as illustrated with the presented chemistry suggest that the future of thermoset polymer recycling could include processes that emphasize monomer recovery in an energy efficient manner for closed-loop recycling.

PBAT-modified starch blended film extract induces in vitro toxicity in L-02 cells: induction of oxidative stress, inflammation, and modulation of AMPK pathway

PBAT-modified starch blended film are thermoplastic biodegradable materials with good properties and a wide range of applications. In this study, L-02 cells were used as an in vitro toxicity evaluation system for risk assessment of PBAT-modified starch films with migration studies obtained in different food simulants. Determination of total migration and organic matter revealed that the results were in accordance with the standard except for the total organic matter under 95% (v/v) ethanol food simulant which exceeded the standard. The CCK-8 assay showed that these compounds affect the cell viability of L-02 cells. It was observed that the compounds made the cells express increased AST, ALT, TNF-α, IL-6, IL-1β, and ROS, and decreased SOD, GSH, and ATP. In addition, we explored the effect of migration in PBAT-modified starch composites on protein and gene expression levels in L-02 cells using a transcriptomic approach and found that the AMPK signaling pathway was affected. The expression of AMPK signaling pathway-related proteins was detected by Western Blot, and the expression levels of p-AMPK/AMPK were found to be upregulated, and those of p-mTOR/mTOR, SIRT1, PGC-1α, NRF1 and TFAM were downregulated. The above data suggest that the compounds migrating into the PBAT-modified starch film when exposed to food may induce oxidative stress and inflammation in hepatocytes, and may cause damage to hepatocytes through the AMPK pathway.

Hydrogen permeability testing of fibre reinforced thermoplastics under cryogenic conditions – validation of a test rig concept

The need to decrease the gross weight of cryogenic hydrogen fuel systems in future zero emission mobility leads to increasing activities in the field of cryogenic lightweight engineering. Fibre reinforced thermoplastic composite materials (FRT) are considered for cryogenic applications despite their bias towards permeation. However, permeation through plastic materials is of major concern in cryogenic applications. Even tiny fluxes can very much compromise the insulating power of high vacuum spaces required for insulation of cryogenic systems such as tank structures or transfer lines. Hence, it is essential to qualify those FRT in terms of their hydrogen permeability for future usage in mobile cryogenic applications. The conventional concepts for measuring permeability in plastic materials are not sufficient for cryogenic measurements of FRT as shown in a previous paper. For that, a novel laboratory test rig concept was proposed. In this paper, we validate this concept and show its eligibility for measuring permeation of hydrogen through thermoplastic materials. Therefore, we report results of helium permeation through polytetrafluoroethylene (PTFE) at room temperature and compare those results to literature permeability data.

Microbial Adhesion to Different Thermoplastic Denture Base Materials in Kennedy Class I Partially Edentulous Patients.

Introduction Since the polished and fitting surface of the denture base may promote the colonization of microorganisms, it is essential to know how the different types of denture bases prevent or encourage the adhesion of microorganisms. This study aimed to compare the microbial adhesion to the polished and fitting surfaces of thermoplastic nylon, thermoplastic acetal, and thermoplastic acrylic denture bases in Kennedy Class Ⅰ, partially edentulous patients. Materials and methods Thirteen patients were included in the study. The group consisted of eight males (61.54%) and five females (38.46%), with an age range of 41-50 years (mean age 46.1 years). Three types (groups) of removable partial dentures will be made for each patient using different thermoplastic denture base materials: thermoplastic nylon; thermoplastic acetal; and thermoplastic acrylic. The polished and fitting surfaces of the denture bases were swabbed after a one-month follow-up period. Microbial adhesion was evaluated by counting the microorganisms' colony-forming units (CFU) in the collected specimens. The data were collected and statistically analyzed. Results The study revealed no statistically significant difference in microbial adhesion to both polished and fitting surfaces between all types of studied thermoplastic denture base materials. However, the results showed that for the polished surface, the microbial adhesion median of thermoplastic acrylic denture base (40.5 CC x 102/ml) was higher than that of thermoplastic acetal (29.0 CC x 102/ml) and thermoplastic nylon (16.0 CC x 102/ml). Regarding the fitting surface, the microbial adhesion median of thermoplastic acrylic (51.0 CC x 102/ml) is higher than that of thermoplastic acetal (41.0 CC x 102/ml) and thermoplastic nylon (23.0 CC x 102/ml). Conclusion The thermoplastic nylon denture base materials showed less microbial adhesion among the studied thermoplastic materials, so it may be recommended to be used as a denture base material for individuals at high risk of denture stomatitis.

Analysing the mechanical behaviour of thermoformed dental clear aligners using acoustic emission technique

Clear aligners have been widely preferred in recent years for aesthetically pleasant orthodontic treatments. However, their efficacy in treating dental malposition and malocclusion is yet to be studied extensively. Clear aligners are mostly made from thermoplastic materials that guarantee sufficient elasticity while lowering the plastic deformations during their use. This is to guarantee a stable level of forces acting on teeth to be repositioned. This work aims to get insight into the mechanical behaviour of these devices during their period of use, by comparing aligners produced from two different thermoplastic materials: polyethylene terephthalate-glycol modified (PET-G) and polyurethane (PU) supplied by Dooris and Ghost Aligners, respectively. The aligners were subjected to cyclic compression loading, to simulate the swallowing act throughout 15 days of use. Tests were conducted by surrounding the aligners with artificial saliva to simulate the intraoral environment. The Acoustic Emission (AE) technique was used to analyse the damage progression in the aligners during the loading. Furthermore, the AE results were compared with the energy absorbed and the stiffness changes in the aligners. Finally, the damage evolution in the aligners post-loading was validated using optical microscopy. The AE results revealed a good correlation with mechanical and optical microscopy data, thus contributing to the understanding of the mechanical behaviour of the clear aligners.

Assessment of different forecasting strategies for the breaking load resistance in notched specimens 3d-printed in PLA using additive manufacturing (FFF) technology

The introduction of fused deposition modelling in the industrial sector to produce functional components in thermoplastic materials, such as PLA, requires knowledge of the performance limits of such elements during the design phase. Predicting the breaking load resistance of notched specimens is essential to evaluate the mechanical performance of components manufactured using this technology. This study compares different methodologies based on the critical distance criterion (TCD) for predicting the static breaking strength of printed notched specimens made with Fused Filament Fabrication (FFF) technology using PLA material. Specimens with different topologies of V-notches were printed according to a standardized configuration. Various analysis techniques were applied to determine the breaking strength of each specimen. By comparing the results obtained with experimental data to assess their accuracy and reliability, it has been demonstrated that these methodologies, coupled with the concept of equivalent elastic material (EMC), can be useful for predicting static breaking load.

Investigation of recovery behavior on 3D-printed continuous plant fiber-reinforced composites

The mechanical properties and accuracy of 3D-printed composites can be significantly affected by printing parameters. This work discovered a noteworthy recovery phenomenon during 3D printing of continuous flax fiber-reinforced composites (CFFRCs). The yarn count and printing speed are the critical factors that influence the recovery behavior, which, in turn, affects the thickness, the fiber volume fraction, and the void content of CFFRCs, ultimately impacting the mechanical properties. Smaller yarn counts have a greater effect on the recovery behavior of CFFRCs. Increasing the printing speed from 5 mm/s to 15 mm/s leads to the loss of tensile properties and flexural modulus in CFFRCs up to 30 % and 58 %, respectively. The recovery mechanism of the CFFRCs is further elucidated with the observation of temperature distribution during the printing process. This indicates that recovery is more likely to occur in the compressed yarn with a twisted structure when the deposited thermoplastic matrix exceeds the glass transition temperature. The results and findings have the potential to enhance the process optimization of 3D-printed continuous plant fiber composite parts, ensuring high mechanical properties and dimensional precision.

Intravenous catheter flanges as an external nasal stent: a novel technique.

External nasal splints are commonly used for immobilization following nasal fracture reduction or rhinoplasty procedures. The literature documents the use of various materials like thermoplastic materials, aluminum, Orthoplast, fiberglass, plaster of Paris, and polyvinyl siloxane. These materials are bulky, time-consuming, expensive, and cumbersome to use, and have been associated with complications including contact dermatitis and epidermolysis. Furthermore, they cannot be retained if the situation warrants prolonged stabilization and immobilization. We introduce a new technique using readily available scalp vein catheter flanges as an external nasal stent. The technique is easy to master, inexpensive, and limits edema and ecchymosis, while stabilizing the reconstructed nasal skeleton in position during the healing period.

Novel thermoplastic matrix resin with low processing temperature and good interfacial strength for carbon fiber-reinforced polyethersulfone

Owing to the increased demand for carbon fiber-reinforced thermoplastic composites with excellent recyclability, there is a need to improve the interfacial bonding between the fiber and matrix. Hydroxy-functionalized polyethersulfone (PES), i.e., PES-OH, and epoxy resin (ER) were included to impart functionality to PES. A mixture of PES, PES-OH, and ERs with a weight ratio of 8:1:1 reduced the Tg by −18% compared with 100% PES. The enhancement of the interfacial properties increased the interlaminar shear, tensile, compressive, and residual compressive strengths by 50%, 22%, 43%, and 25%, respectively. This study can contribute to the development of carbon fiber composites for future mobility.

Experimental Design of the Adhesion between a PEI/Glass Fiber Composite and the AA1100 Aluminum Alloy with Oxide Coating Produced via Plasma Electrolytic Oxidation (PEO)

In this study, the AA1100 aluminum alloy underwent the plasma electrolytic oxidation (PEO) process to enhance its adhesion to a thermoplastic composite of polyetherimide (PEI) reinforced with glass fiber, following ASTM D1002:10 standards. A 23 factorial design was employed, varying three parameters in the oxidation process: immersion time, applied electric potential, and electrolyte concentration (Na2B4O7). The joining of aluminum and thermoplastic composite samples was achieved through oxy-fuel welding (OFW), using oxygen and acetylene gases. For the characterization of the joined samples, a universal tensile testing machine was utilized with a displacement speed of 1.5 mm/min. The analysis of the oxide coating involved scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and Fourier transform infrared spectroscopy (FT-IR). Through variance analysis, it was determined that the statistical model encompasses approximately 80% of the variability in the adhesion process between materials. An improvement of up to 104% in adhesion between the materials was observed with the process, indicating an effective bond due to the presence of the thermoplastic matrix in the treated aluminum sample. This improvement is attributed to the morphology of the oxide coating, resembling corals, with micro-pores and recesses that facilitated mechanical anchoring.

Decomposition Kinetics and Lifetime Estimation of Thermoplastic Composite Materials Reinforced with rCFRP.

Because of the high demand for carbon fiber reinforced polymer (CFRP) materials across all industries, the reuse and/or recycling of these materials (rCFRP) is necessary in order to meet the principles of the circular economy, including recycling and reuse. The objective of this study is to estimate the lifespan of thermoplastic matrix composite materials reinforced with waste materials (CFRP), which undergo only a mechanical cutting process. This estimation is carried out through the thermal decomposition of polymers, including polymer matrix composite materials, which is a complex process due to the numerous reactions involved. Some authors calculate these kinetic parameters using thermogravimetric analysis (TGA) as it is a quick method, and it allows the identification of gases released during decomposition, provided that the equipment is prepared for it. This study includes a comparison between polyamides 11 and 12, as well as between polyamide composite materials with carbon fiber (CF) and polyamides reinforced with CF/epoxy composite material. The latter is treated with plasma to improve adhesion with polyamides. The behavior of weight as a function of temperature was studied at speeds of 3, 6, 10, 13, 17, and 20 °C/min, finding stability of the polyamides up to a temperature of 400 °C, which was consistent with the analysis by mass spectroscopy, where gas evolution is evident after 400 °C. The estimation of the lifespan was carried out using two different methods including the Toop equation and the free kinetics model (MFK). The energy of the decomposition process was determined using the MFK model, which establishes the energy as a function of the degree of conversion. It is estimated that at 5% decomposition, mechanical properties are lost.