In the high-temperature environment, a larger thermal expansion mismatch of a bimaterial leads to pronounced thermal stresses and interface crack growth. In this paper, a generalized fractional heat conduction model is used to determine the instantaneous thermal fracture behaviors of a bimaterial interface crack. An axisymmetric thermoelastic problem is solved with the aid of Goodier's thermoelastic displacement potential and Love's potential functions. A mixed initial-boundary value problem is then converted to a singular integral equation of second kind by using the Hankel and Laplace integral transforms. Numerical results of the intensity factors of heat flux and thermal stresses are evaluated using Stehfest's Laplace inversion scheme. The influence of fractional kernel functions with power and exponential law are analyzed, respectively, for aluminum-steel and steel-epoxy, respectively. The thermal stress intensity factors exhibit more wave-like behaviors based on Riemann-Liouville and Atangana-Baleanu models which is different from Caputo-Fabrizio and the complete diffusion model.