Thai Thermoelectric Society, E-mail: actsact2020@gmail.comThe 5th Asian Conference on Thermoelectrics and the 6th Southeast Asia Conference on Thermoelectrics (ACT&SACT2020) were successfully held through a virtual conference platform on 17 December 2020. These conferences were promoted by the Thai Thermoelectric Society, Asian Association of Thermoelectrics, Sakon Nakhon Rajabhat University and Rajamangala University of Technology Isan for favoring the dissemination of scientific and technical progresses in the field of Thermoelectrics in Asia, enhancing the communication between research institutions and industries for promotion of TE applications as well as providing a forum for exchange of information and achievements. Experts, scientists and engineers from Research and Industry around Asia and abroad were all invited and expected for attending the conferences and discussing 1) thermoelectric materials & modeling, 2) thermoelectric characterization and new phenomena, 3) thermoelectric modules and devices, 4) thermoelectric applications: present and future, and 5) other materials and applications.The conferences were initially planned to be held conventionally at Sakon Nakhon. Unfortunately, the outbreak of COVID-19 pandemic leading to the consequent lockdowns and restrictions all over the country at the time, affected traveling to the potential place of the conferences. Hence, the video conference platform, Zoom was introduced to conduct the online conferences hosted at Sakon Nakhon Rajabhat University. Keynote and invited speaker took 45 minutes talk. An individual speaker took 15 minutes for presenting his/her work and answering any question through the platform. Along with the internet communication was good and online platform was perfect, the discussion and commenting for 43 oral presentations and 28 posters were completely accomplished. Thanks to the high capacity ethernet at the hosted university.Eventually, the 27 selected papers were accepted to publish in Journal of Physics: Conference Series (SCOPUS, SJR 0.23), after peer reviewing.Even though all of us did not meet in the presence of each other, we feel confident that everyone enjoyed the online event. The organizing and editorial committee hopes you enjoy the reading of this volume of the JPCS. Furthermore, we wish to thank everyone associated for valuable contributions and made these conferences a truly memorable event at this difficult time for all of us.List of Committee, Sponsors, Photographs are available in this pdf.