Thermally stimulated discharge current (TSDC) studies have been carried out on blends of polymethyl methacrylate (PMMA) and polyvinyl acetate (PVA). The effects of polarization temperature and field on the TSDC peaks of polyblends indicate that the polarization in the polyblends is due to charge-carrier trapping in deep traps which leads to induced dipole formation. The results of a.c. dielectric bridge measurements are also compared with the TSDC results. The dielectric relaxation parameters are also reported.