Thermal Switching Research Articles

Tunable electrocaloric effect in selective ferroelectric bilayers via electrostatics for solid-state refrigeration and microelectronics thermal management

Ferroelectric (FE) electrocaloric materials research has been blossoming worldwide for solid-state refrigeration and potential cooling systems replacing thermoelectric Peltier coolers in microelectronics. In this work, we report the outcomes from a systematic study of combined phase transition (thermodynamics) based on the phenomenological Landau theory and distributed electric field (electrostatics of thin film interfaces) in FE bilayer films. Specifically, the compositional variation of ferroelectric bilayers results in broken spatial inversion symmetry leading to asymmetric thermodynamic potentials due to a combination of normal (first- and second-order phase transition) and relaxor (dispersive dielectric constant) ferroelectric behaviors devised for efficient electrocaloric cooling effects. Extensive theoretical analyses conducted for bilayers consisting of insulating materials highlight modified phase transition temperature behavior and self-poling by effective electric field amplification arising due to bilayers’ electrostatic coupling yielding significant changes in isothermal entropy (ΔS) and adiabatic temperature (ΔT). The theoretical calculation insights supported with experimental results signify, through case studies for a combination of materials experimental parameters, that amplification of the local electric field and materials engineering maximize the number of coexisting phases at or away from the morphotropic phase boundary of constituent layers in bilayer thin film architectures, which can be applicable toward other classes of materials and multilayer systems. These are effective ways for efficient cooling, in general, and for microelectronics thermal management either directly or by developing a thermal switch with phase change materials integrated with thermoelectric coolers for residual heat dissipation, both at the system and on-chip levels.

Thermal switch for localized heating based on spatial electric field distribution regulation

At present, the thermal switch for localized heating is becoming a hot research topic in MEMS packaging technology. A method of using a liquid-based thermal switch is proposed in this paper. A plate local heating device based on electric field distribution control is constructed, where a thermal liquid column can be formed under the action of the electric field. The electric field controls the formation and dissipation of the liquid column to realize the on-off and off-on function of the thermal switch. Through the control of the different conductive substrates in the plate, the localized heat transfer can be further realized, and the heat transfer position is precisely regulated. Furthermore, due to the fluidity of the liquid, the prepared thermal switch can also realize movable heating. The experimental results show that the heating time and speed can be controlled precisely by adjusting the driven voltage and the conductive area of the upper substrate.

Tunable broadband metamaterial absorber with voltage and temperature modulation

It is well known that VO2 has temperature-controllable phase transition properties, and that graphene surface conductivity's can be changed by applying a gate voltage to control the Fermi energy level. On the basis of temperature and voltage controllability, we numerically simulate a broad-band mid-infrared absorber. The metamaterial absorber (MA) operates in the mid-infrared band of 7∼30 μm, and when VO2 is in the metallic state, the absorption bandwidth can reach 9 μm and the average absorption can reach 98%. The absorption bandwidth is temperature-adjustable. By maintaining graphene's Fermi energy level (EF) at 0.4 EF. When VO2 transitions between insulating and metallic states, MA can achieve mid-infrared narrowband-broadband interconversion. When VO2 is in the insulating state, tuning the EF of graphene, MA can achieve single-peak and double-peak absorption in mid-infrared wavelength, respectively. When VO2 is in the metallic state, the EF can be used to dynamically modulate the absorption bandwidth. The MA reveals its thermal switching properties. This research is expected to have promising future applications in the fields of multiparameter tunable optical devices, temperature sensing, infrared detection, etc.

Cavity structure-based active controllable thermal switch for battery thermal management

Batteries may degrade fast at extreme temperatures, posing a challenge in meeting the dual requirements of heat preservation at low temperatures and efficient cooling at high temperatures. To address this issue, we propose a cavity structure-based active controllable thermal switch. It has a potential switch ratio (SR) of approximately 300, with an experimental SR of 15.4. Furthermore, the thermal resistance can be actively controlled. The "OFF State" of the thermal switch increases energy discharge at low temperatures. Pre-heating with the "OFF State" consumes only 60% of the energy required in the "ON State". By employing the "ON State" at an ambient temperature of 20°C, the battery temperature can be maintained below 35°C. And the "ON+ State" keeps the maximum battery temperature remaining below 42°C under extreme conditions. These findings demonstrate that the implementation of the proposed thermal switch enhances the usability of batteries in extreme environments.

Electrically gated molecular thermal switch.

Controlling heat flow is a key challenge for applications ranging from thermal management in electronics to energy systems, industrial processing, and thermal therapy. However, progress has generally been limited by slow response times and low tunability in thermal conductance. In this work, we demonstrate an electronically gated solid-state thermal switch using self-assembled molecular junctions to achieve excellent performance at room temperature. In this three-terminal device, heat flow is continuously and reversibly modulated by an electric field through carefully controlled chemical bonding and charge distributions within the molecular interface. The devices have ultrahigh switching speeds above 1 megahertz, have on/off ratios in thermal conductance greater than 1300%, and can be switched more than 1 million times. We anticipate that these advances will generate opportunities in molecular engineering for thermal management systems and thermal circuit design.

Photonic thermal switch via metamaterials made of vanadium dioxide-coated nanoparticles.

In this work, a photonic thermal switch is proposed based on the phase-change material vanadium dioxide (VO2) within the framework of near-field radiative heat transfer (NFRHT). The switch consists of two metamaterials filled with core-shell nanoparticles, with the shell made of VO2. Compared to traditional VO2 slabs, the proposed switch exhibits a more than two times increase in the switching ratio, reaching as high as 90.29% with a 100 nm vacuum gap. The improved switching effect is attributed to the capability of the VO2 shell to couple with the core, greatly enhancing heat transfer with the insulating VO2, while blocking the motivation of the core in the metallic state of VO2. The proposed switch opens pathways for active control of NFRHT and holds practical significance for developing thermal photon-based logic circuits.

Smectic solid electrolytes containing lamellar conducting channels for solvent-free lithium-ion batteries with a thermal switch on/off performance

Developing electrolytes with desirable electrochemical performance and robust stability remains a huge challenge to meet the efficiency and durability demands of energy storage and conversion devices. Herein, the potential of ionic liquid crystals as high-performance electrolytes is demonstrated. Smectic ionic liquid crystals only consisting of conventional [C14Mim][BF4] and LiBF4 are designed and prepared as electrolytes for solvent-free lithium-ion batteries. [C14Mim][BF4] has good miscibility with LiBF4 to form smectic liquid crystals. LiBF4 is highly concentrated by [C14Mim][BF4] layers in the smectic electrolytes to form dynamic lamellar conducting channels, which enable considerable ion conductivities of 10–4 ∼ 10–3 S cm−1. The smectic electrolytes possess robust cyclic stability and energy conversion efficiency in Li/LiFePO4 batteries, which show a charge/discharge capacity of 154.7 mA h g−1 at a 1 C current density, as well as stable performance after 100 charge/discharge cycles even at 80 ℃. Additionally, the phase transition behavior of the electrolytes can be applied as a smart switch to thermally tune on/off the batteries. The electrolytes show almost no charge/discharge behavior under crystal phase, but automatically operate efficiently with charge/discharge capacities >150 mA h g−1 once entering the smectic phase. The present work sheds new light on developing high-performance and smart electrolytes for solvent-free Li-ion batteries.

High-performance magnetic thermal switch based on MnFe[formula omitted]O[formula omitted]/Ethylene Glycol:Water refrigerant dispersion

The use of magnetic nanoparticles for the remote control of heat transfer in electronic devices can overcome the current limitations of appliance engineering. In this work, we demonstrate that a thermal switch based on a low-cost and stable MnFe2O4/Ethylene Glycol:Water (MFO/EG:W) dispersion can increase the span temperatures as high as 60% in the 0.01–0.60 Hz operating frequency range under the same heat supply for different recipient filling ratios (FR). Under the optimum condition of FR = 80%, the efficiency of our new MFO/EG:W colloidal dispersion is twice the obtained for the commercial Fe3O4/paraffin oil fluid. From numerical calculation, we demonstrate that the improved heat exchange efficiency relates to the three-steps effective thermal conductivity variation during operation, expanding the contact time between the heat and cold sources. Thus, the combination of an EG:W refrigerant solution and superparamagnetic MFO nanoparticles with high saturation magnetization allows their use for heat management control of electronic systems for long operation periods.

Ultrafast Switching of Interfacial Thermal Conductance.

Dynamical control of thermal transport at the nanoscale provides a time-domain strategy for optimizing thermal management in nanoelectronics, magnetic devices, and thermoelectric devices. However, the rate of change available for thermal switches and regulators is limited to millisecond time scales, calling for a faster modulation speed. Here, time-resolved X-ray diffraction measurements and thermal transport modeling reveal an ultrafast modulation of the interfacial thermal conductance of an FeRh/MgO heterostructure as a result of a structural phase transition driven by optical excitation. Within 90 ps after optical excitation, the interfacial thermal conductance is reduced by a factor of 5 and lasts for a few nanoseconds, in comparison to the value at the equilibrium FeRh/MgO interface. The experimental results combined with thermal transport calculations suggest that the reduced interfacial thermal conductance results from enhanced phonon scattering at the interface where the lattice experiences transient in-plane biaxial stress due to the structural phase transition of FeRh. Our results suggest that optically driven phase transitions can be utilized for ultrafast nanoscale thermal switches for device application.

Synchronous Switching of Dielectric Constant and Photoluminescence in Cyanidonitridorhenate-Based Crystals.

Switching of multiple physical properties by external stimuli in dynamic materials enables applications in, e.g., smart sensors, biomedical tools, as well as data-storage devices. Among stimuli-responsive materials, inorganic-organic molecular hybrids exhibiting thermal order-disorder phase transitions were tested as promising molecular switches of electrical characteristics, including dielectric constant. We aimed at broadening the multifunctional potential of such hybrid materials towards the switching of not only electrical but also other physical properties, e.g., light emission. We report two ionic salts based on luminescent tetracyanidonitridorhenate(V) anions bearing two different diamine ligands, 1,2-diaminoethane (1) and 1,3-diaminopropane (2), both crystallizing with polar N-methyl-dabconium cations. They exhibit an order-disorder phase transition related to the heating-induced turning-on of the rotation of polar cations. This leads to a unique synchronous switching of the dielectric constant as well as metal-complex-centered photoluminescence, as demonstrated by changes in, e.g., emission lifetime. The roles of organic cations, non-trivial Re(V) complexes, and their interaction in achieving the coupled thermal switching of electrical and optical properties are discussed utilizing experimental and theoretical approaches.

Synchronous Switching of Dielectric Constant and Photoluminescence in Cyanidonitridorhenate‐Based Crystals

AbstractSwitching of multiple physical properties by external stimuli in dynamic materials enables applications in, e.g., smart sensors, biomedical tools, as well as data‐storage devices. Among stimuli‐responsive materials, inorganic‐organic molecular hybrids exhibiting thermal order‐disorder phase transitions were tested as promising molecular switches of electrical characteristics, including dielectric constant. We aimed at broadening the multifunctional potential of such hybrid materials towards the switching of not only electrical but also other physical properties, e.g., light emission. We report two ionic salts based on luminescent tetracyanidonitridorhenate(V) anions bearing two different diamine ligands, 1,2‐diaminoethane (1) and 1,3‐diaminopropane (2), both crystallizing with polar N‐methyl‐dabconium cations. They exhibit an order‐disorder phase transition related to the heating‐induced turning‐on of the rotation of polar cations. This leads to a unique synchronous switching of the dielectric constant as well as metal‐complex‐centered photoluminescence, as demonstrated by changes in, e.g., emission lifetime. The roles of organic cations, non‐trivial Re(V) complexes, and their interaction in achieving the coupled thermal switching of electrical and optical properties are discussed utilizing experimental and theoretical approaches.

Thermally Reentrant Crystalline Phase Change in Perovskite-Derivative Nickelate Enabling Reversible Switching of Room-Temperature Electrical Resistivity.

Reversible switching of room-temperature electrical resistivity due to crystal-amorphous transition is demonstrated in various chalcogenides for development of non-volatile phase change memory. However, such reversible thermal switching of room-temperature electrical resistivity has not reported in transition metal oxides so far, despite their enormous studies on the electrical conduction like metal-insulator transition and colossal magnetoresistance effect. In this study, a thermally reversible switching of room-temperature electrical resistivity is reported with gigantic variation in a layered nickelate Sr2.5 Bi0.5 NiO5 (1201-SBNO) composed of (Sr1.5 Bi0.5 )O2 rock-salt and SrNiO3 perovskite layers via unique crystalline phase changes between the conducting 1201-SBNO with ordered (O-1201), disordered Sr/Bi arrangements in the (Sr1.5 Bi0.5 )O2 layer (D-1201), and insulating oxygen-deficient double perovskite Sr2 BiNiO4.5 (d-perovskite). The O-1201 is reentrant by high-temperature annealing of ≈1000°C through crystalline phase change into the D-1201 and d-perovskite, resulting in the thermally reversible switching of room-temperature electrical resistivity with 102 - and 109 -fold variation, respectively. The 1201-SBNO is the first oxide to show the thermally reversible switching of room-temperature electrical resistivity via the crystalline phase changes, providing a new perspective on the electrical conduction for transition metal oxides.

Development of empirical correlations for assessing the CuAlMn based shape memory alloy thermal switch phase transition temperatures

Development of empirical correlations for assessing the CuAlMn based shape memory alloy thermal switch phase transition temperatures

Multiple magnetoplasmon polaritons of magneto-optical graphene in near-field radiative heat transfer

Graphene, as a two-dimensional magneto-optical material, supports magnetoplasmon polaritons (MPP) when exposed to an applied magnetic field. Recently, MPP of a single-layer graphene has shown an excellent capability in the modulation of near-field radiative heat transfer (NFRHT). In this study, we present a comprehensive theoretical analysis of NFRHT between two multilayered graphene structures, with a particular focus on the multiple MPP effect. We reveal the physical mechanism and evolution law of the multiple MPP, and we demonstrate that the multiple MPP allow one to mediate, enhance, and tune the NFRHT by appropriately engineering the properties of graphene, the number of graphene sheets, the intensity of magnetic fields, as well as the geometric structure of systems. We show that the multiple MPP have a quite significant distinction relative to the single MPP or multiple surface plasmon polaritons (SPPs) in terms of modulating and manipulating NFRHT. We demonstrate that this remarkable behavior is attributed to the coupling between the significant contributions of surface states at multiple surfaces and Shubnikov–de Haas-like oscillations in the spectrum, indicating a transformation of intraband and interband transitions. Notably, we find that the evolution from single MPP to multiple MPP is absolutely different from that from single SPPs to multiple SPPs. Finally, a thermal magnetoresistance effect and a negative-positive transition of the relative thermal magnetoresistance ratio are predicted in the multilayered system under consideration. Our study paves the way for a flexible control of NFRHT and it offers the possibility for the thermal photon-based communication technology and a magnetically controllable thermal switch.

Large magneto-thermal-switching ratio in superconducting Pb wires

Thermal switching by magnetic fields is one of the important functionalities in thermal management technologies. In low-temperature devices, superconducting states can be used as a magneto-thermal-switching (MTS) component because carrier thermal conductivity (κ) is strongly suppressed in superconducting states. Recently, we demonstrated that the MTS ratio (MTSR) of pure Nb reached 650% at a temperature (T) of 2.5 K under a magnetic field (H) of 4.0 kOe [Yoshida et al., Appl. Phys. Express 16, 033002 (2023)]. In this study, to enrich knowledge on MTS of superconductors, the MTSRs of pure Pb wires with 5 N and 3 N purities were investigated by measuring the temperature or magnetic-field dependences of κ. For 5N-Pb, a large MTSR exceeding 1000% was observed below 3.6 K under H > 600 Oe. Although higher MTSRs were expected at lower temperatures under H > 600 Oe, the obtained data under those conditions were accompanied by large errors due to magnetic-field-induced huge κ at low temperatures. In contrast, the κ for 3N-Pb was observed to be clearly lower than that for 5N-Pb. Although the magnetic-field-induced change in κ was small, the MTSR at T = 2.5 K was 300%. These results suggest that Pb is a promising material for low-temperature magneto-thermal switching because of wide-range κ tunable by magnetic field and purity.

Energetics of phase transitions in homogeneous antiferromagnets

Spatially uniform static phases in an antiferromagnet (AFM) at 0 K accessible by varying an external magnetic field along the anisotropy axis are investigated. Using the macrospin model, the energy contributions are comprised of the external field, effective anisotropy, and spatially homogeneous AFM exchange. The critical energy configurations are fully cataloged, and local energy concavity is used to identify stable states. Relative energy levels are taken into account to classify phase transitions. Phase diagrams for energetic stability and phase transitions are provided in terms of the strength of the applied field and the ratio between anisotropy and the AFM exchange. Two nonstandard critical energy states are identified as energy saddle points so are not stable but function as energy barriers between multiple stable states. The results determine thermal switching rates and suggest interesting AFM textures and solitons.

In-situ measurement of thermal depolarization in tetragonal BS-PT piezoelectric ceramics

High temperature depolarization poses a significant challenge to the practical application of piezoelectric/ferroelectric materials. Determining the depolarization temperature (Td) in such materials is crucial for evaluating their performance under high temperature conditions. Here, we propose a method for observing thermal depolarization by examining the 90º domain switching induced strain. Our results show that the differential thermal expansivities of unpoled and poled tetragonal BiScO3-PbTiO3 (BS-PT) piezoelectric ceramic samples can distinguish between thermal expansion strain and 90º domain switching induced strain. The effectiveness of our proposed method is further confirmed by quantitatively analyzing the 90º domain via X-ray diffraction. Compared to the in-situ resonance-antiresonance impedance spectrum, our method allows for more accurate testing of depolarization temperature, demonstrating significant potential for the direct observation of thermal depolarization in piezoelectric/ferroelectric materials.

Noninvasive measurement of local temperature using ultrasound-switchable fluorescence.

Measuring the local background temperature in diseased and inflamed tissues is highly desirable, especially in a non-invasive way. In this work, ultrasound-switchable fluorescence (USF) technique was utilized to estimate the local background temperature for the first time by analyzing the temperature dependence of fluorescence emission from USF contrast agents induced by a focused ultrasound (FU) beam. First, temperature-sensitive USF agents with distinct temperature switching-on thresholds were synthesized, and their thermal switching characteristics were quantified using an independent spectrometer system. Second, the USF contrast agent suspension was injected into a microtube that was embedded into a phantom and the dynamic USF signal was acquired using a camera-based USF system. The differential profile of the measured dynamic USF signal was computed and compared with the thermal switching characteristics. This allowed for the calculation of the local background temperature of the sample in the FU focal volume based on the estimation of heating speed. An infrared (IR) camera was used to acquire the surface temperature of the sample and further compare it with the USF system. The results showed that the difference between the temperatures acquired from the USF thermometry and the IR thermography was 0.64 ± 0.43 °C when operating at the physiological temperature range from 35.27 to 39.31 °C. These results indicated the potential use of the USF system for measuring the local temperature in diseased tissues non-invasively. The designed USF-based thermometry shows a broad application prospect in high spatial resolution temperature imaging with a tunable measurement range in deep tissue.

Performance assessment of active insulation systems in residential buildings for energy savings and peak demand reduction

Active insulation systems (AISs) in buildings are envelopes that integrate thermal insulation, thermal energy storage, and controls. Although different designs for AISs have been proposed in the literature, a comprehensive analysis of feasible AISs is lacking. This paper discusses the energy performance, peak demand reduction potential, and performance characteristics of an AIS that uses a concrete wall as thermal mass sandwiched between two solid-state thermal switches (STSs). These STSs change their thermal conductivity using an on/off metal switch to create or break a thermal bridge across the STS. This paper first describes the experimental setup, used to determine the ratio of thermal resistance during R-high (low thermal conductivity) and R-low (high thermal conductivity) states of the STSs. This ratio was then used in whole-building energy simulations to evaluate the performance of AIS walls across different climate zones with/without a freeze timer of 60 min. The timer was added to reduce the number of switches of STSs from one state to another, and hence the energy needed for these switches. Analysis of the switching frequency and interval of STSs, thermal conductivity of walls, impact of wall orientation, and heat transfer through the wall from the use of AIS at different climate zones/locations were performed. The simulation results show that the AIS can achieve energy savings ranging from ∼ 980 to 2,290 kWh in a single-family home with a floor area of ∼ 220 m2 compared with an IECC 2018 baseline. The energy savings was higher in dry climate zones which represent 17% of residential buildings in the United States, compared to humid or marine climate.

A conceptual design of a thermal switch capacitor in a magnetocaloric device: experimental characterization of properties and simulations of operating characteristics

The quest for better performance from magnetocaloric devices has led to the development of thermal control devices, such as thermal switches, thermal diodes, and thermal capacitors. These devices are capable of controlling the intensity and direction of the heat flowing between the magnetocaloric material and the heat source or heat sink, and therefore have the potential to simultaneously improve the power density and energy efficiency of magnetocaloric systems. We have developed a new type of thermal control device, i.e., a silicon mechanical thermal switch capacitor (TSC). In this paper we first review recently developed thermal switches based on micro-electromechanical systems and present the operation and structure of our new TSC. Then, the results of the parametric experimental study on the thermal contact resistance, as one of the most important parameters affecting the thermal performance of the device, are presented. These experimental data were later used in a numerical model for a magnetocaloric device with a thermal switch-capacitor. The results of the study show that for a single embodiment, a maximum cooling power density of 970 W m−2 (510 W kgmcm −1) could be achieved for a zero-temperature span and an operating frequency of 5 Hz. However, a larger temperature span could be achieved by cascading multiple magnetocaloric elements with TSCs. We have shown that the compact TSC can be used in caloric devices, even with small temperature variations, and can be used in a variety of practical applications requiring thermal regulation.