Silica aerogels are regarded as potential thermal and acoustic insulation materials with low density and porous structure. However, the hydrophilicity due to surface hydroxyl groups and the low mechanical intensity have limited its further application. Generally, it can be achieved by adjusting the process parameters of the sol-gel to refine the structure of silica aerogels and optimize performance. In this study, we adopted an appropriate modification strategy of incorporating glass fiber felts as the reinforcing phase and trimethylchlorosilane (TMCS) as the hydrophobic modifier. By adjusting the solvent exchange time, the micro-nano structure, i.e. hierarchical networks, was optimized. The TMCS-modified silica aerogel/glass fiber/hot-melt fiber composites (TSGMs) exhibited great sound insulation, and the maximum sound transmission loss (STL) was up to 34 dB at 6300 Hz. Compared to unmodified, STL improved by 8 dB in simulated practical applications. In addition, TSGMs also exhibited high hydrophobicity with a water contact angle of 147° and excellent thermal insulation with a thermal conductivity of 0.0345 W (m k)-1. The results could contribute to the refinement in the preparation process of silica aerogel composites and use in the fields of thermal and acoustic insulation.