Abstract
Polybenzoxazine (PBz) aerogels have garnered considerable attention as an innovative and excellent thermal insulation material, celebrated for its lightweight, low thermal conductivity, and outstanding mechanical properties. However, the use of high boiling point toxic solvents in the preparation process requires a cumbersome solvent exchange procedure coupled with insufficient flame-retardant properties, which hinder the potential application of PBz aerogels. Herein, we employed tetraethyl orthosilicate (TEOS) into PBz using an easy, eco-friendly, and cost-less process to achieve hybrid structure polybenzoxazine/silica (PBz/SiO2) aerogels, by thermal catalysis (72 °C) ring-opening polymerization and polycondensation in water-ethanol solvent without any catalysts. The resulting PBz/SiO2 aerogels were characterized with low density (0.181 g/cm3), low thermal conductivity (0.0315 W/(m·K)), excellent flame-retardancy (PHRR value of 32.3 W/g and THR value of 6.3 kJ/g), and superhydrophobicity (the water contact angle up to 155°). Environment-friendly preparation strategy for the PBz/SiO2 aerogels with excellent comprehensive performance, poised to play a pivotal role in energy-saving buildings and fire-resistant applications.
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