Thermal Energy Research Articles

The Preparation and Selection Process for a New Form Stable Phase Change Material (FSPCM) Intended for Use as Thermal Storage in Applications at Intermediate Temperatures

Abstract There is a greater focus on solar energy since the food processing business requires a lot of thermal energy to remove moisture from agricultural products. This study thoroughly explains how to choose Phase Change Materials (PCMs) within a specific temperature range. The best PCM is selected from the Multiple Criteria Decision Making (MCDM) procedures based on a few characteristics. Based on the results of the MCDM method, the eutectic of paraffin and palmitic acid is chosen. PCM is bound, and FSPCM is formed using clay. The method of preparation of Clay-based FSPCM is described in detail. The amount of clay materials and different clay percentage combinations are chosen from the leakage experiment. Kaolin has the least amount of leakage out of all the clay materials tested. Kaolin-based FSPCM Exibit improvement in thermal conductivity compared to Pure PCM.

Low-temperature deposition of β-Ga2O3 thin films employing in situ pulsed laser-assisted RF sputtering system

Monoclinic β-phase Ga2O3, the most thermodynamically stable phase, is an interesting material for power electronics applications. In this study, we present an efficient approach, diverging from existing methods, for the successful deposition of β-Ga2O3 thin films at low substrate temperatures without any post-annealing. Instead of relying on high substrate temperatures, we supplied sufficient thermal energy to the substrate by directly irradiating it with a 1064 nm ytterbium pulsed laser during RF sputtering. This eliminated the need for post-annealing and significantly reduced processing time. It also allowed for excellent control over the crystal structure and crystallinity formation of the thin films by providing excellent particle energy through heat transfer on the surface. The X-ray diffraction (XRD) scan of the sample deposited by irradiating a pulse laser to the substrate shows only three peaks corresponding to (−201), (−402) and (−603) of β-Ga2O3, indicating superior crystalline quality. The sample deposited at 2.5 mTorr working pressure maintained a thin film thickness of 207 nm and a grain size of 40.07 nm, and the energy band gap of the thin films was measured in the range of 4.45–4.64 eV. XPS, Auger, and PL optical analysis observed characteristic core-level peaks of β-Ga2O3 and the suppression of oxygen vacancies due to the high binding energy. The oxygen content increased by 4.39 %, resulting in the O/Ga ratio rising to 1.19, which leads to a positive shift in the O 1s binding energy. Consequently, we demonstrated the induction of phase transition of Ga2O3 into a stable β phase by introducing an in-situ pulse laser process during low temperature RF sputtering. These results have significant potential in various applications and are expected to contribute significantly to technological advancements.

Analysis of Heat Transfer of Molten Salts Startup Flow in Cold Pipes Avoiding Freezing in Solar and Nuclear Energy Systems

Abstract Molten salts are employed as the heat transfer fluid to carry the thermal energy from a solar receiver or a nuclear reactor for delivering to thermal storage systems or thermal power plants for power generation. For the startup operation, molten salts need to be pumped to flow into the pipes which may have lower temperature than the freezing point of molten salt due to the cold ambient temperature overnight or over the suspension of operation. Preventing the freezing of molten salt in cold pipes becomes a critical issue to the safe operation of a concentrating solar thermal power plant or a molten salt nuclear power plant. This study conducted a basic heat transfer analysis of the transient heat transfer from flowing molten salt to a cold pipe to determine the length from entrance to the onset of freezing of the fluid. From our modeling and analytical solution using method of characteristics, the correlation of the location of onset of freezing of molten salt with respect to the flow velocity, heat capacities of molten salt and pipes, dimension of the pipes, and the initial temperatures of salts and pipes, have been understood clearly. The modeling and computational tool can fundamentally help engineers to design a system to avoid freezing and clogging at cold startup when molten salt is applied as a heat transfer fluid.

Modeling of a Solar Thermal Plant to Produce Hot Water and Steam for a Brewery Factory

The environmental impact caused by the intensive exploitation of fossil fuels to generate heat and electricity has already reached a critical level. Also, as the industrial sector is the largest energy consumer, mainly in the form of heat, it has then become compulsive to implement the use of renewable solar heat in industrial processes, such as those found in the food processing and beverages industries, which do not require high temperatures. Consequently, this study examines the viability of supplying heat as hot water at 80 °C and saturated steam at 160 °C to a medium-sized brewery factory through a hybrid solar plant composed of flat plate and parabolic trough collectors and sensible thermal energy storage. The study was conducted numerically using the meteorological conditions of a city different from that where the factory is located because it benefits from higher insolation levels. The mean annual solar fractions achieved were 49.9% for hot water production and 37.3% for steam generation, at a levelized cost of heat of 0.032 USD/kWh, which can be considered competitive if compared against the values reported in other similar solar projects. Also, the decrease in fossil fuel consumption allowed an annual reduction of 252 tons of carbon dioxide emissions.

Innovative decision-making for solar photovoltaic system installation in residential energy hubs: A probabilistic dynamic planning approach

This paper introduces an innovative probabilistic dynamic planning model tailored to optimize photovoltaic (PV) system installation within Residential Energy Hubs (REHs). The REH amalgamates diverse components, including PV systems, Combined Heat and Power (CHP) units, and gas boilers, to holistically fulfill residential thermal and electrical energy demands. The model's primary objective is to achieve an optimal equilibrium between minimizing initial investment costs associated with PV systems and managing ongoing energy expenses within the REH framework, encompassing potential PV energy losses over the planning horizon. To augment the flexibility and benefits of PV systems for residential consumers, the model integrates several pioneering features. Particularly notable is the introduction of a heating energy storage system, which complements the REH's thermal requirements and adeptly reacts to fluctuations in gas and electricity prices, thereby maximizing PV system benefits and ensuring homeowners' cost efficiency. Moreover, the model addresses the inherent uncertainty tied to PV generation by employing a two-point estimation method, offering a more realistic depiction of system performance and potential outcomes. To resolve the two-objective problem, an initial conversion into a single-objective problem via a weighted summation method precedes the application of an optimization algorithm inspired by symbiotic organisms. The paper demonstrates the practical application and efficacy of the proposed model through extensive simulations spanning a 10-year planning horizon. The results underscore the model's effectiveness and versatility in guiding residential consumers to make informed and economically viable decisions regarding PV system installation within the broader spectrum of their energy requirements. This research represents a significant stride towards empowering homeowners with invaluable tools for embracing sustainable energy solutions.

An impact of Richardson number on the inclined MHD mixed convective flow with heat and mass transfer

AbstractThe two‐dimensional mixed convective MHD flow with heat and mass transfer is investigated for its behavior with Dufour and Soret mechanisms over the porous sheet. The copper–alumina (Cu–Al2O3) hybrid nanoparticles are used in the base fluid water. The governing system of partial differential equations is converted into a system of ordinary differential equations via similarity transformations, obtaining the solution for velocity, temperature, and concentration fields in exponential form. The problem is demonstrated in the Darcy–Brinkman model, the impact of included parameters such as Richardson number, magnetic field, and Dufour numbers are studied for the obtained solution with the help of graphs. Increasing the magnetic field decreases both transverse and axial velocity profiles. Increasing the magnetic field and Richardson's number decreases the solution (Al2O3–H2O). Increasing the values magnetic field and Richardson's number decreases both transverse and axial velocity profiles. Increasing the values of the Dufour effect increases the axial and transverse velocity boundary layer. The magnetohydrodynamic hybrid nanofluid flow over porous media works efficiently in liquid cooling and, therefore, has significant applications in industrial heating and cooling systems, solar energy, magnetohydrodynamic flow meters and pumps, manufacturing, regenerative heat exchange, thermal energy storage, solar power collectors, geothermal recovery, and chemical catalytic reactors.

Robust and Superhydrophobic Polydimethylsiloxane/Ni@Ti3C2Tx Nanocomposite Coatings with Assembled Eyelash-Like Microstructure Array: A New Approach for Effective Passive Anti-Icing and Active Photothermal Deicing.

To solve the problem of ice condensation and adhesion, it is urgent to develop new anti-icing and deicing technologies. This study presented the development of a highly efficient photothermal-enhanced superhydrophobic PDMS/Ni@Ti3C2Tx composite film (m-NMPA) fabricated cost-effectively and straightforwardly. This film was fabricated utilizing PDMS as a hydrophobic agent, adhesive, and surface protector, while Ni@Ti3C2Tx as a magnetic photothermal filler innovatively. Through a simple spraying method, the filler is guided by a strong magnetic field to self-assemble into an eyelash-like microstructure array. The unique structure not only imparts superhydrophobic properties to the surface but also constructs an efficient "light-capturing" architecture. Remarkably, the m-NMPA film demonstrates outstanding superhydrophobic passive anti-icing and efficient photothermal active deicing performance without the use of fluorinated chemicals. The micro-/nanostructure of the film forms a gas layer, significantly delaying the freezing time of water. Particularly under extreme cold conditions (-30 °C), the freezing time is extended by a factor of 7.3 compared to the bare substrate. Furthermore, under sunlight exposure, surface droplets do not freeze. The excellent photothermal performance is attributed to the firm anchoring of nickel particles on the MXene surface, facilitating effective "point-to-face" photothermal synergy. The eyelash-like microarray structure enhances light-capturing capability, resulting in a high light absorption rate of 98%. Furthermore, the microstructure aids in maintaining heat at the uppermost layer of the surface, maximizing the utilization of thermal energy for ice melting and frost thawing. Under solar irradiation, the m-NMPA film can rapidly melt approximately a 4 mm thick ice layer within 558 s and expel the melted water promptly, reducing the risk of secondary icing. Additionally, the ice adhesion force on the surface of the m-NMPA film is remarkably low, with an adhesion strength of approximately 4.7 kPa for a 1 × 1 cm2 ice column. After undergoing rigorous durability tests, including xenon lamp weathering test, pressure resistance test, repeated adhesive tape testing, xenon lamp irradiation, water drop impact testing, and repeated brushing with hydrochloric acid and particles, the film's surface structure and superhydrophobic performance have remained exceptional. The photothermal superhydrophobic passive anti-icing and active deicing technology in this work rely on sustainable solar energy for efficient heat generation. It presents broad prospects for practical applications with advantages such as simple processing method, environmental friendliness, outstanding anti-icing effects, and exceptional durability.

Enhanced water production in hemispherical solar stills via solar collector and thermal storage integration: experimental validation

ABSTRACT In arid regions that face water scarcity, solar distillation offers hope by meeting the increasing need for clean drinking water. This study investigates the integration of a hot water storage system, heated by a flat plate solar collector, into a hemispherical solar still. Placing the storage tank below the still's absorber enhances heat input and efficiently stores excess daytime thermal energy. Conducted in Bouismail from December 2022 to October 2023, the study yielded significant results: the modified solar still outperformed the conventional one, with production increases of 157% in winter and 207% in summer. Moreover, the modified still demonstrated remarkable efficiency improvement in summer, reaching 37.42% compared to 20.38% for the conventional still. The orientation of the fins within the storage tank, with respect to the hot water entrance orifice, significantly impacted water production, with alterations of the angle resulting in decreases of up to 25%. Increasing saltwater depth led to reduced distilled water output, with declines of up to 37.08% for the modified still. Economic analysis showed a slightly higher cost per liter of water produced by the modified still ($0.1897) compared to the simple one ($0.1446).

A solar assisted grid-tied polygeneration system for hydrogen and electricity production: Future of energy transition from electrons to molecules

Climate change and energy crises are twin challenges that require collective wisdom and polygeneration energy systems for sustainable development. Hydrogen is an abundant element in the universe that can shape the future of energy transmission and storage from electrons to molecules. This paper presents utilization of a solar PV assisted hydrogen and electricity production and storage system for a university transportation fleet of 43 student transit buses to reduce annual 9842 liter fuel consumption and 26.52 Mt CO2 emissions. The system is designed, modeled, and simulated using TRNSYS® energy simulation software and optimized in TrnOpt linked to GenOpt for dynamic weather conditions of Gujrat (Pakistan), Fargo (USA), London (UK). As a model, the results of a 27kWp PV system are presented that assists an alkaline electrolyzer generating 12696 m3 hydrogen, 6348 m3 oxygen, 16848 KWh electricity exported to national grid and 11.56 GJ thermal energy annually. The proposed system generates energy vectors including hydrogen, electricity, heat, and oxygen with optimal performance during intermittent weathers. In this paper, a business model canvas is developed for solar PV assisted hydrogen production and storage system. These outputs can be accredited to the hydrogen as an energy alternative for green and sustainable future for transportation sector.

Selection of phase change material for latent heat thermal energy storage using a hair-pin heat exchanger: Numerical Study

Abstract Phase change materials (PCMs) are promising for storing thermal energy as latent heat, addressing power shortages. Growing demand for concentrated solar power systems has spurred the development of latent thermal energy storage, offering steady temperature release and compact heat exchanger designs. This study explores melting and solidification in a hairpin-type heat exchanger (HEX) using three PCMs (RT 50, RT 27, and RT 35). A 3D model of the hairpin type heat exchanger (HEX) is drawn using Ansys-workbench. High-temperature fluid/Low-temperature fluid (HTF/LTF) with Stefan numbers (0.44, 0.35, and 0.23) flows through the inner pipe to charge the outer pipe's PCM. The Enthalpy-porosity model is used to study the melting and solidification of various PCMs, and the results were compared. Also, individual thermophysical properties that affect the heat transfer during the melting and solidification process have been discussed. It is observed that low thermal conductivity material with high latent heat is preferred for cold climates. In this study, RT 27 excels in cold climates due to extended solidification time, while RT 50 is effective in tropical regions due to its high melting points and lower latent heat.

Assessing the impact of heat mitigation measures on thermal performance and energy demand at the community level: A pathway toward designing net-zero energy communities

AbstractIn the context of escalating global energy demands, urban areas, specifically the building sector, contribute to the largest energy consumption, with urban overheating exacerbating this issue. Utilizing urban modelling for heat-mitigation and reduction of energy demand is crucial steps towards a sustainable built-environment, complementing onsite energy generation in the design and development of Net-zero Energy (NZE) Settlement, especially in the context of Australian weather conditions. Addressing a significant gap in existing literature, this study offers empirical analysis on the climate and energy efficacy of integrated heat mitigation strategies applied in 14 neighbourhood typologies located in Sydney, Australia. Examining the application of cool materials on roads, pavements, and rooftops, alongside urban vegetation enhancement, the analysis demonstrates scenario effectiveness on heat mitigation that leads to reduce ambient temperature and energy demands along with CO2 emissions within the neighbourhoods. Considering building arrangement, built-area ratio, building height, and locations, ENVI-met and CitySim are utilized to assess the heat-mitigation and the energy demand of neighbourhoods, respectively. Results indicate that mitigation measures can lead up to a 2.71 °C reduction in ambient temperature and over 25% reduction in Cooling Degree Hours, with a 34.34% reduction in cooling energy demand and overall energy savings of up to 12.49%. In addition, the annual energy-saving yields a CO2 reduction of approximately 141.12 tonnes, where additional vegetation further amplifies these reductions by enhancing CO2 absorption. This study showcases the pathway towards achieving NZE goals in climates similar to that of Australia, highlighting significant benefits in heat-mitigation, environmental impact, and energy-savings.

Functional Soft Materials with Resistance to Liquid Leakage for Thermal Energy Storage

AbstractFunctional soft materials have great potential commercial applications in thermal energy storage, which are required to have a long life, good flexibility, and resistance to liquid leakage. Herein, a composite hydrogel with thermal storage properties is prepared through coupling molecular self‐assembly and in situ polymerization. Hydrophobic stearic acid (SA), as a thermal storage phase change material (PCM), is dispersed in polyacrylamide (PAM) hydrogel network in the form of oil–water emulsion (O/W). The PAM polymer network with good flexibility physically limits high‐frequency collision between SA PCM droplets. This unique design avoids demulsification in phase change emulsion so that the as‐prepared hydrogel composite can resist liquid leakage. The PAM hydrogel network plays the role of heterogeneous nucleation, resulting in the super‐cooling of SA emulsion at only 0.3 °C. On the other hand, SA PCM droplets in as‐prepared soft material do not directly contact with liquid water, so melting/crystallization process is independent of water. As a result, the soft material exhibits a thermal storage density of up to 99.3 J g−1. The present study is an important step toward designing soft energy storage materials.

Development and experimental evaluation of surface enhancement methods for laser powder directed energy deposition microchannels

ABSTRACT This research evaluates Laser Powder Directed Energy Deposition (LP-DED) for producing fine feature internal microchannels. This study is focused on enhancing and characterising the surfaces of microchannels produced using techniques such as abrasive flow machining, chemical milling, chemical mechanical polishing, electrochemical machining, and thermal energy method to modify internal surfaces of microchannels made from NASA HR-1 Fe-Ni-Cr alloy. Flow testing for discharge coefficient measurement is conducted on processed microchannel samples, followed by characterisation through optical microscopy, Scanning Electron Microscopy (SEM), and Computed Tomography. Findings reveal variations in surfaces due to powder adherence, melt pool undulations, and polishing mechanisms. The study emphasises the significance of removing material equivalent to the mean powder diameter to reduce surface roughness and impact the discharge coefficient. The research proposes a ratio for planarising roughness and waviness peak height and density, offering insights for tailored surface adjustments in specific applications requiring reduced flow resistance. Highlights Internal microchannels with thin-walls were fabricated using the laser powder directed energy deposition process. Various surface enhancements and polishing processes were developed to modify the surface texture of the LP-DED channels. Flow testing was conducted to determine the discharge coefficient. Post-test characterisation was completed to obtain cross sectional area, perimeter, surface texture, and general surface condition to analyse results. Ratio of roughness and waviness peak and density (Spk/Spd and Wp/WPc) is proposed as a relevant surface characterisation parameter. Tailored surface modifications for specific end-use applications.

Modification of steel slag to prepare chlorides based composite phase change materials with shape stability for high-temperature thermal energy storage

Using steel slag to prepare high-temperature (>500 °C) PCMs was an effective way to achieve its high value-added utilization as a potential heat storage medium in a variety of applications, such as solar energy storage, power peak shaving, and industrial waste heat recovery. However, the complex solid waste of steel slag might be corrosive to salt-based PCMs at high temperature. To address this issue, steel slag was firstly modified with another solid waste (i.e., CFA), which was then used to microencapsulate NaCl-KCl to prepare shape-stabilized C-PCMs in this work. Thermophysical and mechanical properties of C-PCMs were analyzed. Results showed that CFA modification greatly improved chemical compatibility between steel slag and eutectic salt through phase reconstruction. Steel slag modified with 30 wt% CFA at 1100 °C was identified as the optimum skeleton. The prepared C-PCMs containing 50 wt% salt showed a phase transition temperature of 653 °C with a high latent heat of 139 J/g and an excellent cycling stability. Additionally, its thermal conductivity reached 1.46 W/(m·K), 180 % higher than of pure salt. Compressive strength of the composite could be as high as 119 MPa, superior to other salt-based C-PCMs. A heat storage device was further designed to allow the numerical investigation of thermal performance of the prepared C-PCMs in practical conditions. Attributed by reasonable arrangement of bricks, the heat storage device possessed a uniform temperature distribution over the vertical cross-section of HTF, which contributed to a quick completion of charging and discharging process. This work could potentially lay a foundation for application of steel slag in the field of high-temperature thermal energy storage.

Thermal and irreversibility analyses of a suspension embodying nano-encapsulated phase change materials using power-law and Darcy-Brinkman-Forchheimer models

The study of natural convection and heat transfer in a trapezoidal cavity finds a wide range of technological applications including thermal energy storage systems, building ventilation/insulation, waste heat recovery, electronic device cooling, controlling PV panel temperature, energy conservation, exchangers, nuclear reactors, furnaces, glass production, food processing, and drying technologies. The purpose of the current study is to explore the entropy and natural convection of non-Newtonian nano-encapsulated phase change material (NEPCM) suspension in a saturated porous medium enshrouded in a trapezoid-shaped domain with three heated blocks fitted with the bottom surface. The novelty of the present work is the introduction of power-law (Ostwald-de Waele) model subject to NEPCM suspension in trapezoidal enclosure emplacing three heated fins at its bottom surface embedded in Brinkman-Forchheimer extended Darcy medium with variant porosity. The finite element method is implemented to solve the governing equations numerically. The important findings of the present study include streamlines, isotherms, velocities, and apparent viscosity enhance while entropy generation whittles down with rise in Darcy number. Entropy generation ameliorates by 519.16 % for low to high porosity of Brinkman-Forchheimer extended Darcy medium. The maximum apparent viscosity augments by 1441.24 % when power law index ameliorates.

Exploring Corn Cob Gasification as a Low-Carbon Technology in the Corn Flour Industry in Mexico

In 2021, Mexico produced approximately 24.2 million tons of white corn, generating 3.6 million tons of corn cob residue. The final disposal of corn cob poses an environmental challenge in certain regions. This study examines the technical–economic feasibility and the greenhouse gas (GHG) mitigation potential of integrating a small-scale cogenerating gasifier fueled by corn cob into a nixtamalized corn flour manufacturing small and medium-sized enterprise (SME). This integration enables the generation of heat and electricity from the produced synthesis gas. Moreover, the process yields residual carbon, which can be used as biochar for soil restoration and removing atmospheric CO2. This option holds significance for the corn flour agroindustry in Mexico, as, in 2021, it consumed approximately 601.9 GWh of electrical energy and 938,279 GJ of thermal energy from LP Gas in its manufacturing processes to produce 2.6 million tons of nixtamalized white corn flour. These processes contributed to a total emission of 410,232 tons of CO2 into the atmosphere. The findings of this study demonstrate a cumulative reduction of 51.7% in CO2 emissions, resulting in economic benefits of USD 85,401 in 2017 for a case study SME that annually produces 1039 tons of corn flour. This study reveals the integration of a gasifier–cogenerator system fueled by corn cob as an economically viable low-carbon technology in the corn flour manufacturing industry.

The Effects of Oil Price on Energy Production and the Ecuadorian Economy

Through an empirical analysis of the impact of variations in the international price of oil on the economic production of different strategic sectors and on energy production from various sources in Ecuador, the study seeks to show evidence on the economic effects of the price of oil. in a Latin American economy strongly linked to oil production. For this, relevant data were collected on production in different economic sectors, on the type of ownership in oil production and on energy production in various energy sources in Ecuador and statistical analyzes were carried out to evaluate the relationships between these and the international oil price. The results indicate that the effect of the oil price varies between the economic sectors of Ecuador. Some sectors, such as financial services and construction, show positive responses, while others, such as agriculture and fishing, appear less affected. The oil and mining sector in Ecuador is strongly linked to variations in the price of oil. The positive and significant response of the Oil and Mines GDP underlines the sensitivity of this sector to changes in international prices. Furthermore, energy production in Ecuador exhibits heterogeneous responses to variations in the price of oil. Forms of energy such as wind, solar, and thermal energy show positive and significant responses, while hydropower presents a negative response in some periods. Positive responses in forms of energy such as wind, solar, and thermal may indicate that the increase in the price of oil positively influences investment decisions in these energy sources. The study provides a significant contribution to the field of energy economics in oil-exporting countries and, particularly, in developing countries, as well as highlights the importance of energy diversification for these types of economies.

Thermo‐physical characterisation of natural rocks and impact analysis of variations in their thermo‐physical properties on thermal storage performance

AbstractIn this study, the thermal characterisation of natural rock samples from Zimbabwe for low‐temperature industrial thermal energy storage (TES) applications was carried out. Thermal stability, specific heat capacity, thermal diffusivity, thermal conductivity and density were determined. Variations in these parameters were evaluated and their impact on thermal storage performance was analysed. Basalt and dolerite samples from different locations were found to have average specific heat capacities of 826 and 853 J/kg K, respectively, at room temperature. Insignificant variations were observed with differences of 3.4% for basalt and 1.7% for dolerite samples. Also, negligible differences of 0.3% and 0.7% in densities for rocks of the same type but of different origins were obtained for basalt and dolerite samples, respectively. However, significant variations in thermal diffusivity of all the igneous and metamorphic samples were observed with quartzite rock exhibiting the highest value of 2.1 × 10−6 m2/s, while the values for the other samples range from 0.9 × 10−6 to 1.6 × 10−6 m2/s. This implies that the thermal efficiency of sensible TES systems that use different or the same rock types from different locations can be significantly high to be overlooked. Thermo‐gravimetric analysis results revealed that the rock samples studied have good thermal stability for low‐temperature heat storage applications.

Numerical Investigation of PV/T System by Using Graphene Based Nanofluids

The effective use of solar radiation can be maximized by the implementation of a novel hybrid device referred to as a photovoltaic thermal collector (PV/T), which has the capability to simultaneously generate both electrical and thermal energy. As temperature increases, the efficiency of the photovoltaic (PV) cell drops. The present work employs graphene nanofluids as a means to decrease the temperature of the system in order to evaluate the photovoltaic thermal (PV/T) performance. The PV/T system is subjected to Computational Fluid Dynamics (CFD) simulation, wherein graphene nanofluids of different volume concentrations (0%, 0.1%, 0.2%, and 0.3%) and mass flow rates (0.065, 0.075, and 0.085 kg/s) are employed. The PV/T system demonstrated enhanced performance as a result of the implementation of the proposed approach, which effectively reduced the temperature of the solar cell during the period of maximum solar radiation, spanning from 9 AM to 4 PM. The utilization of the system was employed for the generation of thermal and electrical energy due to its respective thermal and electrical efficiency of 67% and 11.5%. The completed research has demonstrated that the integration of graphene nanofluids has the potential to enhance the efficiency of PV/T systems.

Synthesis mechanism from graphene quantum dots to carbon nanotubes by ion-sputtering assisted chemical vapor deposition

We present the first work of the synthesis mechanism from graphene quantum dots (GQDs) to carbon nanotubes (CNTs) by an ion-sputtering assisted chemical vapor deposition. During the annealing process, a Pt thin film deposited by the ion-sputtering was dewetted and agglomerated to form many nanometer-sized particles, leading to Pt nanoparticles (PtNPs) that can act as catalysts for creating carbon allotropes. The shape of the allotropes can be effectively tailored from GQDs to CNTs by controlling three key parameters such as the dose of catalytic ions (D), amounts of carbon source (S), and thermal energy (T). In our work, it was clearly proved that the growth control from GQDs to CNTs has a comparably proportional relationship with D and S, but has a reverse proportional relationship with T. Furthermore, high-purity GQDs without any other by-products and the CNTs with the cap of PtNPs were generated. Their shapes were appropriately controlled, respectively, based on the established synthesis mechanism.Graphical abstract