The low environmental impacts and good performance of carbonate-activated binders have attracted substantial interest, while their intrinsically delayed reaction and prolonged setting times constrain widespread implementation. This study aims to investigate the early-age reaction kinetics of carbonate-activated binders, elucidate the underlying mechanisms and propose controlling methods. Results reveal that hydrotalcite and C-A-S-H gel precursors rapidly reach supersaturation within hours, yet precipitation of these phases remains absent. This phenomenon, coupled with high Si/Ca ratios in the pore solution, exhibits characteristics that may contribute to the observed reaction delays. A prolonged induction period and lethargic strength development are observed owing to the lack of strength-giving phases. The hydrotalcite and C-A-S-H concentrations surpass their theoretical solubility thresholds due to rising ionic strength and salt-in effects. The addition of a pH-neutral layered double hydroxide salt accelerates the reaction, confirming seeding impacts control pore solution saturation limits, constituting the underlying accelerator mechanism.
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