Fabrication of a novel high electrical conductivity Si3N4 matrix composite with Cu three-dimensional network structure by spark plasma sintering

Abstract

Silicon nitride (Si3N4) ceramic matrix conductive composite materials have shown great promise as conductive layer materials for electrical transmission components. However, existing conductive phases struggle to form a three-dimensional (3D) interconnected network in Si3N4 matrix, resulting in poor electrical conductivity. This study proposed a spark plasma sintering (SPS) process utilizing Si3N4 as the substrate and Cu particles as the reinforcement phase to fabricate a novel electrical conductivity Si3N4/Cu composite material. The results indicated that the diffusion of Si atoms in Si3N4 facilitated the formation of copper silicide (CuiSi) interface between the two constituents during sintering, creating a strong chemical bonding for high conductivity. Simultaneously, composite materials with optimized Cu content formed a 3D interconnect network structure, providing a continuous path for electrical conduction. At Cu content of 30 vol%, the Si3N4/Cu composite exhibited a satisfying electrical conductivity of 295.37 S/m, which was 14 orders of magnitude higher than that of Si3N4. The composites also demonstrated a percolation phenomenon, with a theoretical percolation threshold of Cu particles at just 0.1 vol%, an order of magnitude lower than that of carbon reinforcement particles. Furthermore, an integrated design featuring external insulation and internal conductivity was achieved by wrapping a Si3N4 insulation layer around the conductive Si3N4/Cu composites. The fabricated insulation layer exhibited higher resistivity (1.12×1014 Ω) and a lower wear rate (1.3×10−6 mm3/N·m) compared to some contemporary insulation ceramics, while the conductive layer had a lower calorific value, making them excellent candidates for electrical transmission component materials.