Tetragonal Structure Research Articles

Electronic structure evolution during martensitic phase transition in all-d-metal Heusler compounds: the case of Pd2MnTi

Abstract In this study, taking Pd2MnTi as a representative example, the electronic structure evolution during martensitic phase transition in all-d-metal Heusler compounds was systematically studied and revealed theoretically. The calculation and theoretical analysis suggest that Pd2MnTi is not stable in cubic structure and prones to transform to low-symmetric tetragonal structure. By tetragonal deformation, the shrinkage of lattice parameters and the decrease of symmetry promote the electron accumulation between Pd and its first nearest neighboring Ti atom, resulting in the increased covalent hybridization. The occurrence of pesudogap in density of states (DOSs) of tetragonal Pd2MnTi near the Fermi level also verifies the enhancement of covalent bond. Comparatively, the stronger interatomic bond in tetragonal Pd2MnTi, i.e., covalent bond here, would strengthen interatomic coupling and consequently lower the energy of the material. By the martensitic phase transition, more stable state in energy was achieved. Thus, based on the analysis of electronic structure evolution, the nature of martensitic phase transition is a process wherein symmetry breaking weakens the original weak chemical bonds in high-symmetric parent phase and induces the strong chemical bond to lower the energy of the materials and achieve a more stable state. This study could help to deepen the understanding of martensitic phase transition and the exploration of novel materials for potential technical applications.

Borophosphate glass based electrolyte composite for high lithium ionic conductivity

The application requirements of solid-state lithium (Li) metal batteries are satisfied by the ionic conductivity of composite solid-state electrolytes, attributed to their minimal interfacial resistance. Herein, composite solid electrolytes were obtained by mixing a crystalline Li0.5La0.5TiO3 (LLTO) perovskite with different amount of 47Li2O-30B2O3-23P2O5 (LBP) glass phase. The results show that the crystal phase of the composite samples exhibit a tetragonal perovskite structure with a P4/mmm space group. Frequency dependent AC conductivity shows that composite containing 1 % LBP glass avoids the phenomenon of charge carrier blocking at low frequency and low temperature at the same time. The room temperature maximum total ionic conductivity was obtained for sample with 0.5 % LBP glass presenting a conductivity that is almost three times higher than that of pure LLTO. The factors influencing ionic conductivity are not only grain morphology and size, and activation energy, but also lithium content, and entropic effects contribute to the facility or difficulty with which Li+ can migrate into the LLTO solid electrolyte.

Unraveling Oxygen Vacancies Effect on Chemical Composition, Electronic Structure and Optical Properties of Eu Doped SnO2.

The influence of Eu doping (0.5, 1 and 2 mol.%) and annealing in an oxygen-deficient atmosphere on the structure and optical properties of SnO2 nanoparticles were investigated in relation to electronic structure. The X-ray diffraction (XRD) patterns revealed single-phase tetragonal rutile structure for both synthesized and annealed Eu-doped SnO2 samples, except for the annealed sample with 2 mol.% Eu. The results of X-ray photoelectron spectroscopy (XPS) emphasized that europium incorporated into the SnO2 host lattice with an oxidation state of 3+, which was accompanied by the formation of oxygen vacancies under cation substitution of tetravalent Sn. Moreover, XPS spectra showed the O/Sn ratio, which has been reduced under annealing for creating additional oxygen vacancies. The pulse cathodoluminescence (PCL) demonstrated the concentration dependence of Eu site symmetry. Combination of XRD, XPS and PCL revealed that Eu doping and following annealing induce strongly disordering of the SnO2 crystal lattice. Our findings provide new insight into the interaction of rare-earth metals (Eu) with host SnO2 matrix and new evidence for the importance of oxygen vacancies for optical and electronic structure formation.

Investigation on Melting Curves and Phase Diagrams for CaO3 Using Deep Learning Potentials.

Melting in the deep rocky parts of planets plays an important role in geological processes such as planet formation, seismicity, magnetic field generation, thermal convection, and crustal evolution. Such processes are the key way to understanding the dynamics of planetary interiors and the history as well as mechanisms of planetary evolution. We herein investigate the melting curves and pressure-temperature (P-T)-phase diagrams for CaO3, a candidate mineral for the lower mantle, by means of the deep learning potential model. Using first-principles, molecular dynamics, and quasi-harmonic approximation, the reliability of the deep learning potential model is verified by calculating the high-temperature and high-pressure equations of state and phase transition pressures for the orthorhombic and tetragonal structures of CaO3 described by space groups Aea2 and P4̅21m, respectively. The melting temperatures of 975, 850, and 755 K at zero pressure are obtained by the single-phase, void, and two-phase methods, respectively, and their melting temperatures are analyzed by the radial distribution function and mean-square displacement to analyze the melting process. Finally, the melting phase diagrams of CaO3 at 0-135 GPa were obtained by the two-phase method.

Structural Phase Transitions and Metallization in Zirconium Disulfide (ZrS2) under High Pressure.

The high-pressure study on zirconium disulfide (ZrS2) has been conducted up to ∼33.9 GPa by using in-situ synchrotron X-ray diffraction at room temperature and electrical transport measurements, aiming to investigate the pressure-induced structural phase transitions and the metallization of the material. The experiments indicated that a progressive structural evolution occurs as the sequence below: hexagonal (space group (SG): P3̅m1) → monoclinic (SG: P21/m) started at 2.8 GPa → orthorhombic (SG: Immm) started at 9.9 GPa → tetragonal (SG: I4/mmm) started at 30.4 GPa. The lattice parameters and bulk modulus of the phases at high pressure are calculated. The decompression results demonstrate the coexistence of ZrS2 stability in monoclinic (SG: P21/m) and orthorhombic (SG: Immm) structures. The electrical transport results demonstrate a significant enhancement in the conductivity of ZrS2 at 8 GPa, and metallization occurs at ∼29.8 GPa. Combined with XRD results, the metallization is coincident with the phase transition to the tetragonal (SG: I4/mmm) structure. Our study presents a more precise phase transition sequence, calculates the cell parameters and bulk modulus of ZrS2 under high-pressure conditions based on experimental results, and confirms that metallization is induced by the structural phase transition. These findings provide an experimental basis for the further utilization of transition metal sulfides (TMDs) under high pressure.

Short-Period Skyrmion Crystals in Itinerant Body-Centered Tetragonal Magnets

In this study, we investigate the stability of a magnetic skyrmion crystal with short-period magnetic modulations in a centrosymmetric body-centered tetragonal system. By performing the simulated annealing for the spin model, incorporating the effects of the biquadratic interaction and high-harmonic wave–vector interaction in momentum space, we find that the double-Q square skyrmion crystal consisting of two spin density waves is stabilized in an external magnetic field. We also show that double-Q states appear in both low- and high-field regions; the low-field spin configuration is characterized by an anisotropic double-Q modulation consisting of a superposition of the spiral wave and sinusoidal wave, while the high-field spin configuration is characterized by an isotropic double-Q modulation consisting of a superposition of two sinusoidal waves. Furthermore, we show that the obtained multiple-Q instabilities can be realized for various ordering wave vectors. The results provide the possibility of realizing the short-period skyrmion crystals under the body-centered tetragonal lattice structure.

Synthesis, characterization, and electrical properties of Nd3+‐doped (Bi0.4Na0.2K0.2Ba0.2)TiO3 high‐entropy ceramics

AbstractRecently, high‐entropy perovskites have attracted considerable attention due to their diverse chemical composition and multifunctionality. In this study, the high‐entropy approach was employed in a (Bi0.4Na0.2K0.2Ba0.2)TiO3 matrix, and Nd3+ was introduced to enhance the configurational entropy and modify its dielectric and ferroelectric properties. Notably, despite Nd3+ doping, all samples maintained a tetragonal perovskite structure at room temperature. The configurational entropy increased with the Nd3+ concentration, consequently leading to a gradual decline in the ferroelectric properties along with the associated temperature (Tm) and maximum dielectric constant (εm). The P–E loops of the ceramics also became thinner as Pm and Pr decreased, resulting in a slow decrease in the recoverable energy density (Wrec) and a simultaneous increase in the energy storage efficiency (η). Especially, the energy storage performance reached its peak at an Nd3+ concentration of 12 mol%, exhibiting an energy storage efficiency of 85.8% and a recoverable energy storage density of 0.74 J/cm3 at a low electric field of 100 kV/cm. These results highlight the potential of this material for dielectric applications in low electric fields and contribute to the advancement of alternative high‐entropy energy storage perovskite ceramics.

Influence of sulfurization process in tin sulfide and sulfur mixed vapors on the morphology of Cu2SnS3 thin films

Abstract Cu2SnS3 (CTS) is expected to be an absorber material for next-generation solar cells because it is composed of nontoxic, low-cost elements and has an absorption coefficient of >104 cm−1. In this study, the effects of sulfurization in tin sulfide (Sn x S y ) and S mixed vapors on various properties of CTS were investigated by using a 3-zone tube furnace to suppress carrier recombination at the grain boundaries and control the composition of the CTS. The CTS deposited via sulfurization in S vapor only (1-zone CTS) contained different monoclinic and tetragonal CTS structures. The grain size of the CTS thin films deposited via sulfurization in Sn x S y and S mixed vapors was not increased. On the other hand, crystal structure analysis revealed that the CTS had grown to single-phase monoclinic CTS. The results suggest that precipitation in Sn x S y and S mixed vapors contributes to the growth of monoclinic CTS with suitable power-generation characteristics. This finding is important for realizing high-efficiency CTS-based solar cells.

Effects of Samarium Doping on the Dielectric Properties of BaBi2Nb2O9 Aurivillius Ceramics.

This study investigates the influence of samarium (Sm3+) doping on the structural, microstructural, mechanical, and dielectric properties of BaBi2Nb2O9 (BBN) ceramics. Using the solid-state reaction method, samples of BaBi2-xSmxNb2O9 with varying concentrations of Sm (x = 0.01; 0.02; 0.04; 0.06; 0.08; 0.1) were prepared. Thermal analysis, microstructure characterization via SEM and EDS, X-ray diffraction, mechanical testing, and dielectric measurements were conducted. The results revealed that increasing Sm3+ concentration led to the formation of single-phase materials with a tetragonal structure at room temperature. Mechanical properties, such as Young's modulus and stiffness, improved with Sm doping, indicating stronger atomic bonding. Dielectric properties showed that low concentrations of Sm3+ slightly increased electrical permittivity, while higher concentrations reduced it. The presence of Sm3⁺ also affected the relaxor properties, evidenced by changes in the freezing temperature and activation energy. Overall, the study concludes that samarium doping enhances the structural and functional properties of BBN ceramics, making them promising candidates for high-temperature piezoelectric and dielectric applications. The findings provide valuable insights into tailoring ceramic materials for advanced technological applications.

High Sensitivity Of Nanocrystalline SnO2-Y2O3 Thin Films Based UV-Detector Prepared Using Chemical Bath Deposition

Nanocrystalline Tin dioxide - Yttrium oxide (NC SnO2-Y2O3) thin film was effectively created by employing the chemical bath deposition approach on SiO2/Si substrates. X-ray diffraction, field emission scanning electron microscopy [FESEM], and energy-dispersive X-ray spectroscopy were used to analyze the structural and the surface morphology of the annealed sample at 500°C for two hours in air. When annealed at 500°C, the SnO2-Y2O3 film crystallized was accomplished with a tetragonal rutile structure. The nanocrystalline SnO2 thin film was effectively employed as a UV photodetector device (UV PDs). A UV photo detector based on nanocrystalline SnO2-Y2O3 film showed 2988% sensitivity when exposed to a 360 nm wavelength (6 mW/cm2) at an applied voltage of 3 V. In contrast, the responsivity value was 3.247 A/W. The rise and full times were determined by calculating to be 0.663 s and 0.436 s, respectively. The excellent performance of the device could be correlated with high surface-to-volume proportions including its elevated crystal performance. Given its outstanding stability and reliability, the nanocrystalline SnO2-Y2O3 thin film sensor is the optimum option for commercially photo-electronic applications.

Resolving the Role of Configurational Entropy in the Optimization of Mechanical, Thermal, and Microwave Dielectric Properties of SrLa(Al0.50-xGaxZn0.125Mg0.125Ti0.25)O4 Ceramics.

The demand for high-performance microwave dielectric ceramics has surged with the proliferation of fifth-generation (5G) communication networks. In this work, SrLa(Al0.50-xGaxZn0.125Mg0.125Ti0.25)O4 (x = 0-0.20) ceramics were designed by leveraging the unique properties of SrLaAlO4 ceramics and high-entropy engineering. The effects of configurational entropy (Sconf = 1.23R - 1.54R) on the mechanical, thermal, and microwave dielectric properties of SrLa(Al0.50-xGaxZn0.125Mg0.125Ti0.25)O4 ceramics were investigated. X-ray diffractometer and transmission electron microscope analyses confirmed that each composition belonged to the tetragonal structure with a space group of I4/mmm. Significant improvements in Vickers hardness were observed with increasing Sconf, reaching 8.05 GPa at Sconf = 1.54R compared to 5.64 GPa in SrLaAlO4 ceramics. Additionally, the increasing entropy showed great potential in reducing the thermal expansion coefficient (CTE) from 12.32 to 11.49 ppm/°C. The optimal quality factor (Q × f) of 98,000 GHz was achieved at Sconf = 1.37R, attributed to the optimization of intrinsic lattice energy and infrared-damped modes. The temperature coefficient of resonant frequency (τf) was successfully modified toward zero due to entropy-driven CTE and structural modifications. Excellent microwave dielectric properties with εr = 22.5, Q × f = 98,000 GHz, and τf = -2.0 ppm/°C were obtained at Sconf = 1.37R. This work highlights the potential of entropy-engineering in developing high-performance microwave dielectric ceramics, offering a promising pathway for the advancement of 5G communication components.

Ferroelectric tungsten bronze-based ceramics with high-energy storage performance via weakly coupled relaxor design and grain boundary optimization

A multiscale regulation strategy has been demonstrated for synthetic energy storage enhancement in a tetragonal tungsten bronze structure ferroelectric. Grain refining and second-phase precipitation (perovskite phase) are introduced in the BaSrTiNb2-xTaxO9 ceramics by regulating the composition and sintering process. Disordered polarization and distribution, chemical inhomogeneity, and insulating boundary layers are achieved to provide the fundamental structural origin of the relaxation characteristic, high breakdown strength, and superior energy storage performance. Thus, an ultrahigh energy storage density of 12.2 J cm−3 with an low energy consumption was achieved at an electric field of 950 kV cm−1. This is the highest known energy storage performance in tetragonal tungsten bronze-based ferroelectric. Notably, this ceramic shows remarkable stability over frequency, temperature, and cycling electric fields. This work brings new material candidates and structure design for developing of energy storage capacitors apart from the predominant perovskite ferroelectric ceramics.

Laser and thermal control over structure and magnetic properties of PrDy-FeCo-B microwires

Magnetic microcombs are necessary in microrobotics, MEMS technologies, actuator and magnetic flow analyzer industries. Usually, magnetic microcombs are artificial linear magnets of periodic shape. We propose another type of microcombs based of microwires, where periodicity of magnetization is caused by equidistant alternation of natural domains. We have demonstrated the presence of quasi-periodic radial magnetization and the effect of temperature and magnetic field on magnetic relief in PrDyFeCoB microwires. Accurate analysis of chemical, phase and structural composition of the microwires allowed us to reveal necessary conditions for the creation of periodical magnetic relief. Annealing affects magnetic relief and changes structure of initially amorphous microwires. Crystal structure of inclusions enriched with Fe and Co instead of Dy and Pr is body-centered cubic (BCC), while the bulk of the microwire has tetragonal structure. We have found laser stimulated amorphization of surface of PrDy-FeCo-B microwires. Partial restoration of the amorphous structure in polycrystalline microwires under single laser pulse of irradiation of 1mJ power and 120 ns duration has been found in 1–2 μm depth.

Fabrication of kesterite Cu2ZnSnS4 thin films using sequentially sputtered multilayers of Cu2SnS3 and Zinc.

Radio-frequency sputtered Cu2ZnSnS4 (CZTS) thin films deposited on glass substrates were characterized. The film deposition was carried out in an argon atmosphere with RF powers of 200 W for zinc and 300 W for the CTS films. After the deposition, the films were annealed at temperatures ranging from 350 °C to 500 °C in a nitrogen and sulfur atmosphere. By using X-ray diffraction, the CZTS films were observed to crystallize in a tetragonal structure with some minor secondary phases in some samples. The absorption coefficient and optical band gap are identified by the ultraviolet-visible-near-infrared optical transmission measurements and the calculated band gap was found to range between 1.4 eV and 1.51 eV. This research comprehensively addresses the effects of layer thickness and annealing temperature on our CTS/Zn films. The annealing process was oberved to result in a significant improvement in electrical conductivity, particularly in films without secondary phases.

Characterization of SrMoO4 synthesized at different temperatures and its photocatalytic performance toward Carbendazim fungicide degradation under UV light

The Scheelite SrMoO4 synthesized by co-precipitation, non-calcined and calcined at different temperature (500 – 800 °C) has been characterized physically and photoelectrochemically. The XRD analysis showed the formation of single phase at room temperature (SMO), crystallizing in a tetragonal structure and the oxide is thermally stable after calcination at 500 °C (SMO5) and 800 °C (SMO8). The crystallites size (D) increases with increasing thee calcination temperature (TC). The Raman spectra presents the characteristic vibrations of the tetragonal structure. Although its low temperature (TC), the specific surface area calculated by the BET method for SMO is weak (4.61 m2 g−1). The SEM images showed the effect of the temperature TC on the morphology of SrMoO4 and as expected the grain size increases with increasing TC. Diffuse reflectance showed a wide optical gap (4.26 eV) for SMO, in accordance with its white color and decreases only slightly (4.10 eV) with increasing TC. The points of zero charge (PZC) calculated by the Drift method for SMO, SMO5 and SMO8 are 5.92, 6.13 and 6.70 respectively. The photocatalytic properties of the powders were assessed through the degradation of Carbendazim (MBC), a hazardous and persistent pesticide, under UV irradiation (λmax = 365 nm). The degradation reached an abatement of 96 % after 15 min under optimal conditions ([SMO] = 0.8 g/L, [MBC] = 8 mg/L, at room temperature and natural pH 5.7) and increasing TC, reduces the degradation capacity of SrMoO4. The oxidation mechanism was elucidated by using scavengers and liquid chromatography (LC-MS/ESI) which showed that the holes (h+) and •OH radicals are responsible for the MBC degradation. The Total Organic Carbon (TOC) reached 70 % for the same period.

Structural, electronic and optical characterization of thin film CH3 NH3 PbX3 (X =I and Br) compared to first-principles calculations

The present work reports the theoretical and experimental studies of structural, the electronic and optical properties of the and thin film as precursor materials for perovskite based optoelectronic devices. X-ray diffraction, photoluminescence, atomic force microscopy and ultraviolet–visible–near infrared spectrophotometry were used to obtain, respectively, structural, morphological and optical properties of deposited films. This research used density functional theory (DFT) computation, using the GGA-PBE approximation, to investigate in depth the properties of and hybrid perovskites. The X-ray diffraction () analysis revealed that the synthesized materials possess a high degree of crystallinity. The linearized enhanced plane wave full potential (FP- LAPW) approach based on the density functional theory (DFT) has been used to theoretically examine structural, the electronic, and optical properties of the and thin film. The thin film crystallizes in a tetragonal structure, while both perovskite thin film choose a cubic structure with different lattice parameters. The films exhibit homogeneity and a well-ordered crystalline structure, with distinct atomic planes visible in the analysis and high absorbance in the UV–Vis range, with bandgap energy around and for and , respectively). The values we obtained are consistent with the theoretical predictions of the band gap energies as 2.04 eV for MAPBr3 and 1.14 eV for MAPI3. Moreover, both MAPI3 and MAPBr3 thin films demonstrate significant absorption in the visible region, around 80%. This work is a detailed characterization of lab-synthesized materials to pave the way toward their commercialization as precursors for perovskite based optoelectronic devices.

Simulation of diffraction patterns for Ruddlesden–Popper (RP) tetragonal structures with RP faults

A theoretical analysis of diffraction patterns was performed for two representatives of layered perovskite-type tetragonal phases of the Ruddlesden–Popper series (RP) with the general formula A n+1 B n O3n+1 (n = 1, 2), which contain RP faults (layer alternation defects) in a wide range of concentrations. The results of theoretical calculations can be used in the future for correct interpretation of X-ray powder diffraction experimental data and for quantitative estimation of the deviation from stoichiometry and structural perfection of this type of compound.

An Effect of Al on the Properties of ZnIn2Se4 Thin Film

Abstract Zinc-indium-selenide ZnIn2Se4 (ZIS) ternary chalcopyrite thin film on glass with a 500 nm thickness was fabricated by using the thermal evaporation system with a pressure of approximately 2.5×10−5 mbar and a deposition rate of 12 Å/s. The effect of aluminum (Al) doping with 0.02 and 0.04 ratios on the structural and optical properties of film was examined. The utilization of X-ray diffraction (XRD) was employed to showcase the influence of aluminum doping on structural properties. XRD shows that thin ZIS-pure, Al-doped films at RT are polycrystalline with tetragonal structure and preferred (112) orientation. Where the degree of crystallinity is raised. The effect of Al content on surface roughness and average diameter was studied by atomic force microscopy (AFM), which showed that both surface roughness and average diameter increased with an increasing Al ratio until they reached their maximum values of 12.93 nm and 61.56 nm, respectively. Optical characteristics of ZIS thin film and the impact of aluminum on optical parameters have been investigated, and it was found that the optical energy ( E g opt ), absorption coefficient (α), extinction coefficient (k), refractive index (n), both the real (εr) and imaginary (εi) components of the dielectric constant have values of (1.8 eV), (3.11×104 cm−1), (0.111), (2.3), (5.36), and (0.517), respectively, for ZIS thin films at an Al ratio equal to 0.04.

Evidence of multiferroic behavior in sintered BaTiO3 obtained from high-energy ball-milled powders

Multiferroic BaTiO3 exhibiting ferroelectric and ferromagnetic behavior was synthesized via the high-energy ball milling of pure BaTiO3 (BTO) powders for durations ranging from 15 to 60 min, followed by pressing and sintering at 1200°C X-ray diffraction patterns of all synthesized samples predominantly revealed a BTO phase with a tetragonal structure and a secondary Ba12Fe28Ti15O84 (BFTO) phase. The BFTO phase was formed after milling for more than 30 min because of chemical interactions between the BTO powder and milling media. Vibrating sample magnetometry confirmed the ferromagnetic nature of the sintered pellets. The specific magnetization increased with increasing milling duration, reaching a maximum value of 1.15 emu/g after 60 min of milling. This increase can be attributed to the distortion of the crystal structure and presence of a secondary phase, as confirmed by scanning electron microscopy and energy-dispersive X-ray spectroscopy. Additionally, electrical characterization revealed the dielectric nature of the materials, with relative permittivity ranging from 500 to 1800, maximum spontaneous polarization from 9.77 to 11.31 μC/cm2, coercive field from 3.86 to 11.12 kV/cm, and AC conductivity from 1 x 10−6 to 1 x 10−3 S/cm. The method described in this study is a simple and cost-effective approach to produce multiferroic materials with ferroelectric and relaxor ferroelectric behavior at room temperature, broadening their potential for technological applications.

Multifunctional BiOCl: Sm3+ nanophosphors: A luminescent platform for solid-state lighting applications, optical thermometry, photocatalytic and forensic applications

Rare earth-activated phosphor materials have been widely used as active probes in optical materials for multidimensional applications. Here, we report a series of ultrahigh purity orange-red emitting BiOCl: xSm3+ (x= 0.5- 2.5 mol %) nanophosphors synthesized via conventional solid-state method at relatively low temperatures for various photonic and forensic applications. XRD and Rietveld refinement results confirmed the tetragonal crystal structure of the synthesized phosphor materials with space group P4/nmm. Fourier transform infrared (FT-IR) and Raman spectroscopy were used to perform the functional group analysis. The UV-Vis-NIR spectra were analyzed to determine the Judd-Ofelt (JO) intensity parameters (Ω2, Ω4, Ω6) and to identify the bonding structure and spontaneous emission properties of the samples. The prepared phosphors exhibit intense orange-red emission under 408 nm excitation and beyond 1 mol% doping of Sm3+ ions, the emission intensity decreases due to concentration quenching mechanism via, dipole-dipole interaction between the optically active Sm3+ ions in the phosphor sample. The synthesized BiOCl: Sm3+ nanophosphors possess low correlated color temperature (CCT), admirable high color purity (99.4%) and outstanding internal quantum efficiency (IQE) of 95.27%. The optical thermometry behavior of the optimized sample has been investigated in detail. Moreover, the optimized nanophosphor stains on porous and non-porous surfaces show clear ridge patterns with high sensitivity, efficiency, and minimal background hindrance for latent fingerprints and lip print detection in forensic applications and are used as security ink in anti-counterfeiting applications. Overall, the results revealed the potential prospects of BiOCl: Sm3+ nanophosphors in the field of display applications, optical thermometry, and forensic sciences.