Terrestrial Sources Research Articles

Ten golden rules for restoration to secure resilient and just seagrass social‐ecological systems

Societal Impact StatementSeagrass meadows are a globally important habitat subject to significant loss. As efforts to restore these sensitive habitats are hampered by their high cost and low levels of reliability, rigorous guidance is required to improve effectiveness and ensure they are cost‐effective. Here, we define 10 golden rules for how we can undertake seagrass restoration. We do this by considering that for seagrass restoration to be successful, it needs to take place with people and not against people. The framework we present aims to direct efforts for seagrass restoration that are holistic and achieve broad goals for people, biodiversity and the planet.SummaryThe world has lost a significant proportion of its seagrass, and although glimmers of hope for its recovery exist, losses and degradations continue. First and foremost, evidence highlights the need to put the world on a global pathway to seagrass net gain. Achieving this outcome requires that conservation of what remains is a priority, but reaching net gain requires seagrass coverage to increase at rates unlikely to be achieved naturally; large‐scale active restoration is required to fill this gap. Novel finance mechanisms aligned to the climate emergency and biodiversity crises are increasingly leading to larger scale restoration projects. However, no clear framework exists for developing or prioritising approaches. With seagrass restoration expensive and unreliable, rigorous guidance is required to improve effectiveness and ensure it is cost‐effective. Building on evidence from terrestrial and marine sources, here, we apply the ‘10 golden rules’ concept, first outlined for reforestation and later applied to coral reefs, to seagrass restoration. In doing so, we follow international standards for ecological restoration and view seagrass restoration in a broad context, whereby regeneration can be achieved either by planting or by enhancing and facilitating natural recovery. These rules somewhat differ from those on reforestation and coral reef restoration, principally due to the relative immaturity of seagrass restoration science. These 10 golden rules for seagrass restoration are placed within a coupled social‐ecological systems context, and we present a framework for conservation more broadly, to achieve multiple goals pertaining to people, biodiversity and the planet.

Compound-specific radiocarbon analysis of sedimentary fatty acids: Potential as a dating tool for lake sediments of Mt. Fuji volcanic region, Japan

Compound-specific radiocarbon analysis (CSRA) is a promising tool for dating sediment sequences where traditional dating methods are impractical. However, the applicability of CSRA of short-chain fatty acids as a dating tool remains poorly understood, especially in lacustrine settings. Accordingly, we determined the radiocarbon content (Δ14C) of individual fatty acids in sediments of Lake Yamanaka (central Japan), as well as their stable carbon and hydrogen isotope ratios, to evaluate the potential of CSRA as a dating tool in volcanic lake environments. We found that the Δ14C values of plant-derived (C24, C26, and C28) n-fatty acids (–99‰ to –149‰) were considerably lower than the Δ14C of charred plants (139‰) within the sediments and those of living aquatic plants (–52‰ to –58‰) in Lake Yamanaka, suggesting that contributions from pre-aged terrestrial and aquatic plant materials likely affect these acids. Similarly, the Δ14C of C16n-fatty acid (–95‰) in surface sediments was much lower than the Δ14C of modern aquatic plants (–52‰ to –58‰), as well as the Δ14C of dissolved organic carbon (DIC) in surface water (–48‰). Together with the stable isotope results, we conclude that in addition to autochthonous aquatic sources, contributions from pre-aged terrestrial carbon sources significantly affect the Δ14C of C16n-fatty acids. Comparing fatty acid Δ14C and concentration data across lakes within the Mt. Fuji region suggests that CSRA of the C16 acid provides valid chronological information only when the C16 originates exclusively from autochthonous aquatic sources, with minor allochthonous terrestrial input.

The utilization of renewable energy and the economic potential of offshore wind power supported by digital finance

Colombia is well-positioned for the development of sustainable energy due to its abundance of natural resources, which include water, wind, and sun. Regulating the safe and sustainable use of offshore wind energy, which is considered non-conventional, is lacking in the nation, nonetheless. The development of offshore wind technology in Colombia shows potential to meet energy needs during dry hydrological conditions and El Niño/Southern Oscillation events when the hydroelectric system power supply is low. This study examines global initiatives that have encouraged nations to develop plans for cutting their CO2 emissions, stressing both their successes and shortcomings in putting offshore wind technology into practice. An examination of Colombia's renewable energy administrative framework finds a lack of data required to carry out offshore wind projects. Furthermore, a review of previous research on marine energy emphasizes how important it is to expand our knowledge of offshore wind generation. Although the majority of local renewable energy projects concentrate on terrestrial sources, an analysis of wind speed and wind power density in Colombia at different altitudes shows promising magnitudes and good trends.Digital finance plays a crucial role in this context by providing innovative funding mechanisms, enhancing financial accessibility, and reducing investment risks through improved financial technologies. These advancements support the mobilization of capital necessary for the development and expansion of offshore wind energy projects.As a result, the technical, economic, administrative, and legal data pertinent to renewable energy in Colombia is compiled in this study. It proposes to provide information to stakeholders involved in decision-making processes and promotes the possible installation of offshore wind farms in regions close to Colombia's Caribbean coast. Because of its plentiful resources, Colombia offers a great chance to implement offshore wind energy technology, which will lessen dependency on fossil fuels and provide a backup energy source in case of supply shortages. The integration of digital finance is key to unlocking the economic potential of these projects, ensuring sustainable and scalable energy solutions for the future.

Spatiotemporal response of the optical characteristics of dissolved organic matter to seasonality and land use in tropical island rivers.

Dissolved organic matter (DOM), a pivotal component in the global carbon cycle, plays a crucial role in maintaining the productivity and functionality of aquatic ecosystems. However, the driving factors of variations in the properties of riverine DOM in tropical islands still remain unclear. In this study, the spatiotemporal response of the optical characteristics of riverine DOM to seasonality and land use on Hainan Island in southern China was investigated. Our results revealed that DOM in the rivers of Hainan Island exhibited a relatively high proportion of fulvic acid and demonstrated strong terrestrial sources. The optical properties of DOM exhibited significant variations both seasonally and spatially. Land use exerted a dominant influence on riverine DOM. Specifically, during the wet season, riverine DOM exhibited larger molecular weight, increased chromophoric DOM (CDOM) abundance, and higher Fmax compared to the dry season. Furthermore, riverine DOM influenced by grassland and farmland showed higher CDOM abundance, Fmax, and humification degree in contrast to those impacted by forest and urban. Random forest and correlation analysis results indicated that grassland and farmland enhanced the Fmax of DOM by increasing levels of TP, NO3--N, Chl a, and NH4+-N in the dry season. However, during the wet season, the increased Fmax of DOM induced by grassland and farmland relied on the increments of Chl a and TP concentrations. This study improves our understanding of the spatiotemporal fluctuations of DOM in the rivers of Hainan Island, highlighting the effects of season and land use on DOM. It offers valuable support for improving water quality and contributes to enhancing human comprehension of the global carbon cycle.

Syndepositional and diagenetic processes in the pigmentation of Middle Ordovician carbonate red beds in South China

Marine red beds (MRBs) are often attributed to specific redox environments during syndepositional and early diagenetic phases. During the Middle Ordovician, a succession of reddish, deeper-water nodular argillaceous limestones (i.e., Zitai and Kuniutan formations) were deposited along the margin of Yangtze Platform in South China. However, the origin of their color remains enigmatic. In this study, we investigated the Middle Ordovician MRBs from a borehole core newly drilled in the Lower Yangtze area of South China whose stratigraphy frameworks are constrained by carbon isotope and biostratigraphy. This study investigates the pigmentation of these MRBs by integrating petrographic observations, elemental geochemistry, diffusive reflectance spectrometry (DRS), and scanning electron microscope (SEM) coupled with energy dispersive X-ray spectrometry (EDS). DRS results show that the red pigment is caused by hematite particles in submicron- to micron-level size. SEM demonstrates that the hematite grains are either detrital grains with traces of physical transport from terrestrial source, or flaky amorphous hematite aggregates situated within the calcite crystal interstices, implicating both syndepositional and early diagenetic origins, respectively. In terms of the geochemical result of the bulk rocks, the close positive correlation between Al2O3 and Fe2O3 indicates that the iron pigment materials may mainly originate from terrestrial Fe-bearing phyllosilicates. These observations are also consistent with the distribution patterns of rare earth elements (REEs) in carbonate leachates. The MRB limestones are characterized by MREE-bulged patterns and close to ~1 Ce anomalies, suggesting active reductive dissolution and subsequent reprecipitation of iron oxides during diagenesis in pore systems. This study proposes that the coloration of Middle Ordovician MRBs in Lower Yangtze Platform was linked to the enhanced input of terrestrial clay minerals rich in iron. The reductive dissolution released iron ions from terrestrial detrital and allowed subsequent reprecipitation of iron-oxides in pore water system during the fluid-buffered diagenesis. In this light, hematites formed during both the syndepositional and diagenetic processes thus could have involved the coloration of the Middle Ordovician carbonate red beds in this case.

Internal transformation and damming regulate the longitudinal variation of DOM bioavailability in a large river

Understanding the spatial patterns of dissolved organic matter (DOM) and factors that influence them is crucial for maintaining river ecosystem functions and riverine health, considering the significant role of DOM in water quality and aquatic ecosystems. Nevertheless, there is limited knowledge regarding the spatial variation of DOM bioavailability and the factors driving them in large river systems. This study involved 39 sampling locations along the main stem of the Changjiang River, spanning its entire length (>5000 km) during a dry season. Spatial patterns of DOM were assessed by measurements of DOC concentrations and eight fluorescence DOM indices, namely fluorescence index (FI-A and FI-B), Trytophan/Tyrosine, Humic A, Humic C, humification indices (HIX-A and HIX-B), and Freshness index (β/α). The results revealed that the water DOM in the main stem of the Changjiang River primarily originated from terrestrial sources. A decline in DOM bioavailability was observed from the upper to the lower basin, aligning with the carbon processing prediction rather than the river continuum concept (RCC). The pure effect of physicochemical factors (25.30%) was greater than that of geographic factors (9.40%). The internal transformation processes determined the significant longitudinal decreases of DOM bioavailability. While no significant difference in DOM bioavailability was observed between reaches before and after the dams, the construction of dams was found to improve DOM bioavailability at the subsection scale and reduce the spatial autocorrelation of DOM bioavailability across the entire basin.

Mercury in the Southwestern Atlantic reef-building coral Montastraea cavernosa (Cnidaria, Scleractinia)

Coastal ecosystems, such as coral reefs, are particularly vulnerable to mercury contamination due to direct contact with terrestrial sources. Here, we evaluated, for the first time, the concentration of mercury in coral reefs in the Southwestern Atlantic using the amphi-atlantic scleractinian coral Montastraea cavernosa. Sampling was realized over an extension of 200 km along different coral reefs. Our data show mercury values ranging from 0.01 to 0.27 mg kg−1 in the tissue and 0.001–0.06 mg kg−1 in the skeleton and higher values when compared to coral worldwide. The concentration of mercury in the tissue from Todos os Santos Bay was higher than in open sea regions but also higher compared to other coral reefs of the world, while the skeleton concentration did not indicate any differences when compared to the open sea regions. The data presented is of concern as we consider the importance of coral reefs and should be used in future environmental management planning.

A simple, safe method for preserving dissolved methane in freshwater samples using benzalkonium chloride

AbstractMethane (CH4) dissolved in water is readily consumed by CH4‐oxidizing bacteria, so the possibility of the dissolved CH4 concentration (dCH4) in sampled water changing before analysis is a concern. To determine the accurate in situ dCH4 level, mercury chloride (HgCl2) or sodium azide (NaN3) is traditionally used for sample preservation. However, these preservatives are very toxic and great care must be taken when adding them to samples. Benzalkonium chloride (BAC), a quaternary ammonium salt cationic surfactant, is a readily available disinfectant that is less harmful to the human body than HgCl2, NaN3, and other preservatives. In this study, we investigated the usefulness of BAC in preserving dCH4 in swamp water, which is a critical terrestrial source of CH4. The dCH4 in samples without BAC decreased immediately after sample collection, whereas the dCH4 in the samples with added BAC did not change significantly for at least 15 d. In addition, when BAC was added to 18 water samples with different water chemistries, the dCH4 did not change significantly from immediately after sampling to 1 week after sampling (average difference: 3%). Thus, in the water samples used in this study, BAC effectively preserved dCH4 in the samples for at least 1 week. Further testing of the effect of BAC on the preservation of dCH4 in different types of water samples worldwide will help to establish a more complete, simple, and safe method.

Watershed hydrology mediates the recovery of an arsenic impacted subarctic landscape

A holistic understanding of the chemical recovery of lakes from arsenic (As) pollution requires consideration of within-lake biogeochemical cycling of As and processes occurring in the surrounding catchment. This study used a watershed mass balance approach, complemented by experimental sediment incubations, to assess the mobility and transport of As within a subarctic watershed (155 km2) impacted by more than 60 years of atmospheric mining emissions. The period of record spanned a transition from drought to high streamflow between September 2017 and September 2019, which yielded insights into the interacting effects of hydrology and within-lake biogeochemical cycling of As. Internal loading of As from contaminated lake sediments (25–46 kg As year−1) and contributions from terrestrial sources (16–56 kg As yr−1) continue to negatively impact lake water quality (19–144 μg As L−1), but the relative importance of these loads varies seasonally and inter-annually in response to changing hydrological conditions. Wet conditions resulted in greater transport of As from terrestrial reservoirs and upstream areas, shorter lake water retention time, and increased the downstream export of As. During dry periods, the lake was disconnected from the surrounding watershed resulting in limited terrestrial contributions and longer lake water residence time, which delayed recovery due to the greater relative influence of internal loading from contaminated sediments. This study highlights that changing hydroclimatic regimes will alter trajectories of chemical recovery for arsenic impacted lakes through the coupling of within-lake and watershed transport processes.

Trends and Drivers of Terrestrial Sources and Sinks of Carbon Dioxide: An Overview of the TRENDY Project

Trends and Drivers of Terrestrial Sources and Sinks of Carbon Dioxide: An Overview of the TRENDY Project

Factors Controlling DMS Emission and Atmospheric Sulfate Aerosols in the Western Pacific Continental Sea

AbstractThe western Pacific continental sea significantly influences the regulation of climate‐active gases budget and the burden of sulfate aerosols. An underway shipboard measurement device was used to determine the dimethyl sulfide (DMS) in the surface seawater and overlying atmosphere in the East China Continental Sea. The average concentration of DMS in atmosphere and seawater was 122.8 ± 86.2pptv and 6.47 ± 3.58 nmol L−1, respectively. The variation trend of surface water DMS in the western Pacific continental sea was influenced by the abundance and composition of phytoplankton under different ocean current systems, with a significant impact from eddies on DMS production in the South China Sea. By eliminating the influence of terrestrial sources and limiting air mass transport within the marine boundary layer, strong correlations were established between atmospheric DMS and air mass exposure to chlorophyll (Echl), as well as between aerosol methanesulfonic acid (MSA) and Echl. During the aerosol sampling period, the atmospheric DMS levels (1,057 ± 371 ng/m3) were significantly higher than MSA levels (46.3 ± 59.8 ng/m3) in the East China Sea, where the conversion of DMS to MSA was not affected by changes in DMS concentration. The sea‐to‐air fluxes of DMS varied over a wide range, from 0.02 to 156.0 μmol m−2 d−1, with an average of 14.35 ± 18.58 μmol m−2 d−1. Marine DMS emissions play a critical role in the formation of sulfur aerosols on the western Pacific continental shelf, accounting for 24.6 ± 7.6% (14.8%–37.8%) of the total sulfate aerosols.

Nexus between the deficit in moisture transport and drought occurrence in regions with projected drought trends

In this article, we focus on studying the nexus between moisture transport deficit and drought occurrence in nine key regions across the world where the magnitude of meteorological drought is projected to increase from 1850 to 2100 under a high anthropogenic emission scenario. These regions are central America, southwestern South America, northern Brazil, the Amazon, northeastern Brazil, the western Mediterranean, southern Africa, the eastern Mediterranean, and southwestern Australia. Using the Lagrangian particle dispersion model FLEXPART, we identify the specific moisture sources of the regions (the own region, the nearby continental source and the oceanic sources) and obtain their contributions to the precipitation in the regions for the period 1980–2018. For each region and specific moisture source, the conditional probability of meteorological drought occurrence given an equivalent contribution deficit from the source is estimated using copula models, a statistical methodology that allows us to capture complex relationships between variables. We identify the dominant moisture source in each region, which is the source for which the contribution deficit maximises drought probability. A variety of cases are found: in three regions, the dominant source is the region itself, in one region, it is the nearby terrestrial source, and in five regions, it is an oceanic source. In general, contribution deficits from specific moisture sources are associated with only slightly greater drought probabilities than those from major global moisture sources. We also reveal that the source that contributes the most to precipitation in a given region is not necessarily the dominant source of drought in the region. These results highlight the importance of understanding the role of dominant moisture sources and moisture transport deficits on meteorological drought occurrence at a regional scale.

Examining the source and composition of organic matter through saturated hydrocarbons, δ13C, and δ15N in a subtropical water reservoir

The sources of organic matter in the sediments of the Passaúna reservoir, an important water supply for the local population, were thoroughly investigated. The objective was to identify the origins of organic matter through the analysis of saturated hydrocarbons, elemental composition (total organic carbon and total nitrogen), and the content of δ13C and δ15N isotopes. This comprehensive approach allowed us to trace the sources of organic matter and discerns indicating heightened primary productivity within the reservoir. To achieve this, two sediment cores spanning a 140-year interval (1880–2020) were retrieved from the reservoir. Core 2 accumulates the majority of sediments, particularly near the dam area. In these parts, sediment deposits can reach up to 1 m above the pre-impoundment soil. Sediments near the area where core 1 was collected contain more sand, resulting in lower thickness compared to core 2. Sediment core 1 primarily reflects terrestrial sources of organic matter, as supported by stable isotope values of δ13C and δ15N. The δ13C values ranged from −23.0 ‰ to −25.7 ‰ in core 1 and from −28.4 ‰ to −29.2 ‰ in core 2. Meanwhile, the δ15N values ranged from 6.6 ‰ to 10.8 ‰ in core 1 and from 3.8 ‰ to 7.6 ‰ in core 2. The distribution of saturated hydrocarbons revealed that organic matter originates from both allochthonous and autochthonous sources. Periods of intense primary productivity were indicated by the presence of n-C16, n-C17, n-C18, and n-C19 alkanes. Additionally, we observed periods characterized by high primary productivity, indicative of elevated nutrient input likely resulting from increased urbanization and industrial activity in the area.

Evaluate climate change and anthropogenic activities influencing geochemical variations in sediment between and within the avulsion period in the Lower Yellow River avulsion channels

The geochemical data from sediments in avulsion channels provide historical evidence of climate change and human-induced alterations in river basin environments. The present study focused on the particle size of sediments in cores and the level of geochemical variation in avulsion channels of the Lower Yellow River Delta (YRD), China. The sediment samples were collected in a depth range of 20–400 cm in avulsion channels. The collected samples were analyzed for sediment particle size and geochemical composition using standard methods. The results demonstrated rapid increases in agriculture practices, rainfall pattern changes, and terrestrial sediment runoff reduction in river basins after the 1960s. The reduced sediment loads in the Sanmenxia Reservoir significantly changed the sediment grain size and geochemical levels in the avulsion channel from August 1960.8 to January −1961.1. In particular, TC, TN, and C/N levels decreased with increasing sediment depth. The C/N values of <12 denoted completely reduced terrestrial sources of organic matter in the channel during the August 1960–January 1961 period compared to the July 1953–August 1960 period. The two-way ANOVA p-values were (p <0.016-p<0.001) strong between the avulsion periods but had no significant variation within the avulsion periods. We emphasize that this study provides a close interplay of different historical periods of geochemical variation in avulsion channel sediments in the alluvial fan YRD, and we argue that the evolution of the middle upstream river basin was subjective by climate change and human developmental actions, which impacted the YRD. In particular, reservoir-interrupted water flow and sediment reduction impacts associated with geochemical fluctuations are documented in the YRD.

Ecological risk assessment of dissolved heavy metals in the Yangtze River Estuary and Zhejiang coastal waters, China

The study applied a tiered ecological risk assessment method to evaluate the long-term status and trend of the ecological risks of dissolved heavy metals from 2011 to 2019 in the Yangtze River Estuary and Zhejiang coastal waters, China. The results for spring, summer, and autumn of 2019 indicated that Pb, Cd, and Zn posed no adverse ecological risk, Cu posed a potential ecological risk, and As posed an ecological risk. The annual results from 2011 to 2019 suggested that Pb, Cd, and Zn posed no adverse ecological risks, and As and Cu posed an ecological risk. The trend analysis in the nine years showed that the ecological risk of Cu is gradually decreasing, while that of As is still a concern. The overall trend is attributed to the environmental protection policies that reduced these contaminants' terrestrial sources and atmospheric sources.

Water residence time is an important predictor of dissolved organic matter composition and drinking water treatability

Freshwater ecosystems are critical resources for drinking water. In recent decades, dissolved organic matter (DOM) inputs into aquatic systems have increased significantly, particularly in central and northern Europe, due to climatic and anthropogenic drivers. The associated increase in dissolved organic carbon (DOC) concentration can change lake ecosystem services and adversely affect drinking water treatment processes. In this study, we examined spatial and temporal patterns of DOM treatability with granular activated carbon (GAC) and biological reactivity based on 14-day bacterial respiration incubations at 11 sites across Mälaren during six-time points between July 2019 and February 2021. Mälaren is the third largest lake in Sweden and provides drinking water for over 2 million people including the capital city Stockholm. In our spatio-temporal analysis, we assessed the influence of phytoplankton abundance, water chemistry, runoff, and climate on DOM composition, GAC removal efficiency, and biological reactivity. Variations in DOM composition were characterized using optical measurements and Orbitrap mass spectrometry. Multivariate statistical analyses indicated that DOM produced during warmer months was easier to remove by GAC. Removal efficiency of GAC varied from 41 to 87 %, and the best predictor of treatability using mass spectrometry was double bond equivalents (DBE), while the best optical predictors were specific UV absorbance (SUVA), and freshness index. The oxygen consumption rate (k) from the bacterial respiration incubations ranged from 0.04 to 0.71 d−1 and higher in warmer months and at deeper basins and was associated with more aliphatic and fresh DOM. The three deepest lake basins with the longest water residence time (WRT) were temporally the most stable in terms of DOM composition and had the highest DOC removal efficiency and k rates. DOM composition in these three lake basins was optically clearer than in basins located closer to terrestrial inputs and had a signature suggesting it was derived from in-lake processes including phytoplankton production and bacterial processing of terrestrial DOM. This means that with increasing WRT, DOM derived from terrestrial sources shifts to more aquatically produced DOM and becomes easier to remove with GAC. These findings indicate WRT can be highly relevant in shaping DOM composition and thereby likely to affect its ease of treatability for drinking water purposes.

The accumulation of microplastics in fish freshwater in the Mun river, Thailand

Background: Microplastic pollution mainly occurs from terrestrial sources, but research on plastic contamination in aquatic environments is limited. Freshwater fish are widely consumed throughout Southeast Asia. Microplastic contamination is becoming an important issue that leads to human health risks from consumption. Objectives: The study aimed to determine the accumulation of microplastics ingested by fish in freshwater in the Mun River. Methods: Freshwater fishes in the Mun River caught by local fishermen and the most dominant species consumed in the Mun River include Paralaubuca typus, Phalacronotus bleekeri, and Morulius chrysophekaion. Twenty-four samples from each species were collected. Microplastics in these species were analysed for abundance, size, shape, color, and type of polymer. Results: The results showed that the average amounts of microplastic contamination in the gastrointestinal tracts (GIT) and gills of Morulius chrysophekadion were 17.70±8.20 pieces/fish, Phalacronotus bleekeri were 11.83±8.74 pieces/fish, and Paralaubuca typus were 10.25±7.56 pieces/fish, respectively. The average number of microplastics found in the urban area was 26.50±4.21 pieces/fish; in the agricultural area, it was 9.77±4.10 pieces/fish; in the confluence of the Mun and Chi River areas, it was 9.50±3.51 pieces/fish; and the natural area had 7.27±4.15 pieces/fish, respectively. The average size of microplastics found in fish was 878.29±904.41μm. The most common polymer type microplastic was polyethylene (PE) where the most common shape was Fiber-shaped, and the most common colour was blue. Conclusion: The study findings indicate a prevalent form of microplastic accumulation in three fish species especially among Morulius chrysophekaion. And findings show that every fish species in the urban area have the most contamination. As a result, fish GIT and gills should be removed before consumption to reduce exposure to microplastics instead of consuming them.

Tracing sources of dissolved organic matter along the terrestrial-aquatic continuum in the Ore Mountains, Germany

There is growing concern about the rising levels of dissolved organic matter (DOM) in surface waters across the Northern hemisphere. However, only limited research has been conducted to unveil its precise origin. Compositional changes along terrestrial-aquatic pathways can help determine the terrestrial sources of DOM in streams. Stream water, soil water and soil horizons were sampled at four sites representing typical settings within a forested catchment in the Ore Mountains (Erzgebirge, Germany) from winter 2020 to spring 2022. The samples were analyzed using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). The resulting data were successfully subjected to semi-automatic processing of the molecular composition of DOM, reaching a percentage of identified peaks up to 98 %. Principal component analysis (PCA) and cluster analyses were carried out to identify distinct differences between DOM from the potential sources and in the streams. According to the PCA, organic soil horizons, soil water, and stream water samples could be clearly distinguished. Cluster analysis revealed that soil water DOM at all depths of Peats and deeper horizons of the Peaty Gleysols contributed the most to DOM in the stream section dominated by organic soils. In areas dominated by mineral soils, stream DOM resembled the DOM from the deeper mineral horizons of Cambisols and Podzols. Overall, our results suggested that most of the DOM exported from the catchment was derived from deeper mineral soil horizons, with little contribution of DOM derived from organic soils. Therefore, DOM fingerprint analysis of in-situ soil water proved to be a promising approach for tracing back the main sources of stream water DOM.

Pervasive accumulations of chert in the Equatorial Pacific during the early Eocene climatic optimum

Biosiliceous cherts hosting the transformation of biogenic silica to paracrystalline opal-CT, deposited in the low-latitude realms of Jurassic to Neogene, were recently interpreted as developing during episodes of elevated primary productivity along upwelling areas in equatorial and sub-equatorial paleo-latitudes. Geographically widespread distribution of chert and other rock types of biosiliceous origin, including porcellanite and siliceous claystones throughout the Eocene however indicates these diagenetic deposits are not in any case the dependable markers of latitude-driven upwelling regimes. This study aims to explore the dominance of early Eocene chert occurrences in the Equatorial Pacific (EP) sediments, and their contribution to the Cenozoic global climate change. Our new assessment of the age-abundance dispersal of EP Cenozoic chert sections accommodated by Deep Sea Drilling Project (DSDP)- and Ocean Drilling Program (ODP)-cored deposits realized that the cherts transformed from deposited opal-A sediments most commonly in the early Eocene, with a peak in abundance at ∼50 Ma. This age interval of significant chert occurrences coincided with the period of seawater-temperature maxima of the early Eocene climatic optimum (EECO), during which the world ocean was supposedly marked by highly reduced upwelling intensity and siliceous bioproduction. The spatio-temporal distribution model of the EP Cenozoic cherts with the peak occurrences during the EECO presented in this study bears close similarities to the global distribution patterns of chert during the Cenozoic, which strongly correspond to a global paleoclimatic driver rather than upwelling regimes. Following our survey, cherts occurred less frequently in the post-early Eocene, which is characterized by cooling bottom waters and amplified upwelling and bioproductivity. This model suggests the paleo-seawater rich in dissolved silicon (DSi) would have been imperative for peak incidences of early Eocene chert production, despite extreme surface warmth and greenhouse conditions of the EECO, making DSi available to opal-secreting phytoplankton via deep-water ventilation. These imply that the paleo-climate was more impactful to diagenetic chert production than latitudinally mediated ocean upwelling. The chert distribution events during the early Eocene reduced siliceous bioproductivity appear to have been insufficient to compensate for the significant silica input to the basin mainly from climate-controlled continental weathering. The DSi uptake by precipitation of authigenic clays which accompanies opal-A diagenesis in many depositional systems has been operative, with higher rates in carbonate- than clay-dominated sediments, so as to sustain balance between DSi released to the ocean from terrestrial sources and the silica expelled in sediments during the EECO weakened upwelling.

The Distinct Composition and Transformation of Terrestrial Organic Carbon in the Yukon River Delta and Plume During the Mighty Spring Freshet

AbstractArctic amplification is leading to increased terrestrial organic carbon (terrOC) mobilization with downstream impacts on riverine and marine biogeochemistry. To improve quantification and characterization of terrOC discharged to the Arctic Ocean, Yukon River delta samples were collected during three stages of the annual hydrograph (ascending limb/peak freshet, descending limb, late summer) and across a land‐to‐ocean salinity gradient (0.08–29.06 ppt). All samples were analyzed for dissolved organic carbon (DOC) concentration and lignin phenols to determine seasonal variability in riverine terrOC and salinity‐induced transformation of highly aromatic terrestrial compounds. Additionally, the relationship between lignin and absorbance at 350 and 412 nm was assessed to determine the feasibility of using optical proxies for accurate quantification, both seasonally and across expansive salinity gradients. Lignin phenols were highest during the ascending limb/peak freshet (0.58–0.97 mg/100 mg OC) when riverine DOC was dominated by young vascular plant sources, whereas lignin phenols were lower (0.15–0.89 mg/100 mg OC) and riverine DOC more variable in terrestrial source and diagenetic state during the descending limb and late summer. Across the sampled salinity gradient, there was disproportionate depletion of lignin (up to 73%) compared to DOC (up to 22%). Finally, while optical proxies can be used to quantify lignin within seasonal or spatial contexts, increased uncertainty is likely when expanding linear correlations across Arctic land‐ocean continuums. Overall, results indicate seasonal, spatial, interannual, and climatic controls that are amplified during high‐flow conditions and important to constrain when investigating Arctic terrOC cycling and land‐ocean DOC flux.