Experimental data, along with theoretical modelling, are combined to explore the potential for the separation of an azeotropic polar/non-polar solvent mixture through an OSN membrane. A mixture of toluene/butanol was used for the model development, and then applied to toluene/ethanol, and toluene/heptane mixtures. Experimental data was obtained at various testing conditions to validate simulation results from a non-ideal solution diffusion transport model incorporating the Flory–Huggins ternary equations. Accounting for the effects of non-ideality in the feed and permeate solutions generated a better fit to the experimental data. The system of equations was solved using parameters obtained from mono component membrane data only. The model developed can be used as a pre screening check for the separation of a potential solvent mixture that an OSN membrane can offer prior to embarking upon an extensive experimental program.
Read full abstract