Temperature Modulation Research Articles

Experimental Comparison of Glazed and Unglazed Hybrid Solar Modules Considering Power Productivity and Cell Temperature

AbstractThis study presents the effect of cell temperature on the hybrid solar collectors PV/T for modules with and without using a front glass cover. A numerical model of thermal behaviour was carried out for glazed (PV/Tg ) and unglazed (PV/Tun) modules. As a result of this experimental investigation conducted for presented PV/T modules, a sufficient decrease in the cell temperature of PV/Tun compared to the PV/Tg, PV/Tun module exceeded the PV/Tg by 19%. Thus, the electrical productivity of the PV/Tun module was higher; it was 3.44% higher than the PV/Tg value. The outlet liquid temperature of the un-covered module was 6.34% higher than the outlet liquid temperature of the glass-covered module. Besides, the total efficiency of the PV/Tg was higher during the periods of study. In this sense, the glass-covered module is preferable for applications that deal with overall efficiency as a desirable factor. The un-covered module is much beneficial for applications that need high electrical productivity.

Orientation of Chitin Nanofibers Dispersed in a Thermoplastic Polymer Matrix Through Dry Thermal Stretching

AbstractNanostructures derived from structural polysaccharides, such as cellulose and chitin, are notable for their sustainability, lightweight properties, and superior mechanical attributes. The macroscopic performance of these materials largely depends on the orientation of nanostructures. This study explores the preferential orientation of chitinous nanofibers (NFs) within a thermoplastic polymer matrix (PM) comprising poly(N‐vinylpyrrolidone) and glycerol, achieved through dry thermal stretching techniques. Altering the PM composition enables the modulation of the system's glass transition temperature (Tg). Chitin NFs are effectively dispersed within the PM, with their orientation enhanced by stretching at temperatures ≈30 °C above the Tg of the composites, resulting in an elongation at rupture (ε) of 105%. Under similar temperature conditions, composites with chitosan NFs show strong interactions with the PM, hindering the stretching process (ε = 10%). In contrast, composites with acetylated chitin NFs demonstrate increased stretchability (ε = 170%) but have insufficient interactions to stabilize their orientation. These interactions, identified as hydrogen bonds through FTIR, vary significantly based on the functional groups present on the NF surfaces. This variation is supported by DSC and dynamic mechanical analysis. Oriented ChNFs hold potential for bioactive applications.

Product differentiation of Sarawak premium rice using MOS gas sensors: comparison between transient and frequency response

In Malaysia, rice, ranked as the third most crucial crop, faces challenges due to domestic consumption outpacing production, resulting in increased instances of rice adulteration. This underscores the imperative of maintaining integrity and quality standards across the entire supply chain. This study uses an electronic nose, comprising four metal oxide semiconductor (MOS) gas sensors, and employing temperature modulation, Principal Component Analysis (PCA) and supervised machine learning (classification models) to distinguish rice varieties such as Bario, Bajong, Borneo Fragrant, Biris, and Jasmine. The study evaluated 30 classifiers based on their classification and validation accuracy. Sensor data was first extracted from the transient response of sensors output voltage, yielding a 12-dimension dataset with response times of 30 s, 50 s, and 95 s. Classification models trained from this dataset achieved classification (training) accuracy of up to 100% and validation accuracy of up to 96%, where the best performing models are subspace discriminant and kernel naïve bayes classifiers. An attempt was also made to analyze the sensor data frequency response for rice classification. Comparison between the prediction results in the transient and frequency domains showed that transient response is better suited for the classification of rice.

Numerical study on heat dissipation of double layer enhanced liquid cooling plate for lithium battery module

The thermal management system's architecture is crucial for lithium batteries' efficiency and financial viability, predominantly influencing their security and longevity. We conceptualized a double-layer enhanced LCP, meticulously crafted to augment the heat dissipation capabilities of the battery assembly. This novel design targets the reduction of peak temperatures and pressure drops, fostering an even internal temperature profile. Comprehensively evaluate the performance of different settings of the coolant cooling system, and the monitoring points are strategically set in horizontal and vertical directions. Analyzing the data, it becomes evident that the system's vertical orientation significantly affects the battery module's peak temperature and temperature variation. Furthermore, extensive investigations were conducted on the impact of layout, coolant flow rate, and inlet temperature on thermal dissipation. Our findings indicate that the double-layer enhanced liquid cooling plates outperform conventional designs. There is a substantial 2.41 % decrease in the peak battery module temperature and an 80.6 % reduction in voltage decline. Operating at a flow rate of 10 g per second and an entry temperature of 25 °C, our liquid cooling system demonstrates superior cooling efficiency with minimal power consumption. It proficiently restrains the maximum battery module temperature below 30.43 °C and restricts temperature variance to merely 3.48 °C. The suggested approach in this research contributes to improved thermal equilibrium, diminishes temperature disparities and pressure concerns, thereby fostering the technological advancement of electric vehicle's liquid cooling systems.

Design of Intelligent Window Automatic Monitoring System Based on Microcontroller Control

To ensure the safety of residents’ lives and property by using automatic opening and closing of ordinary windows, this article designs an intelligent window automatic monitoring system. The article proposes a software and hardware design scheme for the system, which comprises a microcontroller control module, temperature and humidity detection module, harmful gas detection module, rainfall detection module, human thermal radiation induction module, Organic Light-Emitting Diode (OLED) display module, stepper motor drive module, Wi-Fi communication module, etc. Users use this system to monitor environmental data such as temperature, humidity, rainfall, harmful gas concentrations, and human health. Users can control the opening and closing of windows through manual, microcontroller, and mobile application (app) remote methods, providing users with a more convenient, comfortable, and safe living environment.

Study on thermal runaway propagation characteristics of the lithium-ion battery module by two-phase flow of nitrogen and water mist in longitudinal ventilation environment

To prevent and control the thermal runaway (TR) and its propagation of lithium-ion batteries (LIBs) is a key problem for its sustainable development and wide application. However, there is still a gap in the research on the characteristics of two-phase flow of nitrogen(N2) and water mist (NWM) controlling TR and its propagation in different longitudinal ventilation environments. In this study, the influence of wind velocity on 0.5 MPa NWM to control TR and its propagation characteristic parameters of LIB module was studied experimentally. The results show that with the increase of wind velocities, the opening time of the safety valve and TR trigger temperature of the LIB module gradually increased. At the same wind velocity, TR trigger temperature of cell 1 to cell 5 was successively reduced after 0.5 MPa NWM was applied. The cooling and asphyxiation effect of 0.5 MPa NWM is the best in natural ventilation environment, but the suppression effect of 0.5 MPa NWM on TR propagation of the LIB module is weakened under the influence of forced ventilation. However, different wind velocities have little effect on TR trigger temperature of the blocked LIB module. At the same time, a quasi-steady state thermal equilibrium of the NWM in a ventilation environment was established for the LIB module, and the influence of the coupling effect of different longitudinal ventilation environments and 0.5 MPa NWM on TR propagation characteristic parameters of the LIB module and the heat transfer mechanism in the thermal runaway propagation process were compared under the two conditions of within or without battery case. It is found that the convection effect of the wind plays a leading role in the heat dissipation of the blocked LIB module when the wind velocity is less than 4.5 m/s. The heat conduction of the battery case plays a leading role when the wind velocity is greater than 4.5 m/s. Moreover, in any ventilation environments, TR propagation time of the blocked LIB module is smaller than that of the unblocked LIB module. Under the same wind velocity, TR trigger temperature of the blocked LIB module and the maximum temperature of each cell are higher than that without battery case. This work provides a new perspective for controlling TR propagation of the LIBs. At the same time, it can provide theoretical guidance for ensuring process safety and firefighters to fight LIB fire accidents.

A novel characteristic curve for thermoelectric cooler application in realistic thermal circumstances: Theory and experiment

On the materials level, the performance of thermoelectric (TE) devices can be defined by the thermoelectric figure of merit (zT). This, however, does not provide a complete picture due to the complex interplay between electronic and thermal transport properties and the uncertain thermal impedance matching between external and internal thermal resistances in different realistic thermal circumstances. Appropriate design of individual material properties and geometry parameters considering the realistic thermal circumstance can greatly enhance the device-level performance of TE devices. In this work, we develop a framework to clarify such interactions in thermoelectric coolers (TEC) with a newly proposed q-h characteristic curve, which can be used to identify how a TEC design is of effectiveness for a specific realistic thermal circumstance. The effects of zT, the individual TE material properties (i.e., thermal conductivity k, electrical conductivity σ and Seebeck coefficient S) as well as the geometry parameters (i.e., pillar height and filling factor) on the q-h characteristic curve are theoretically and experimentally investigated, respectively. TEC modules with higher zT, short pillars and high filling factor show stronger capability to handle high heat flux load, especially for the cases with high heat dissipation coefficient at hot side. The thermal property (k) and electrical properties (σ and S) are responsible for the low heat flux load (e.g., wearable TEC) and high heat flux load (e.g., on-chip TEC cooling), respectively. For wearable TEC, increasing the internal thermal resistance can prevent the back flow heat, which can be achieved with tall pillars, low filling factor and optimizing zT towards lowering thermal conductivity k. For on-chip TEC cooling, reducing the Joule heating and increasing the thermoelectric effect become dominant factors in lowering the code-side temperature of TEC modules. This can be achieved with short pillars, high filling factor and optimizing zT towards increasing the power factor S2σ. This work provides significant insights into the complex interplay between material-level properties, device-level parameters and the external thermal circumstance in determining the performance of TEC devices. The results enable researchers to design optimal TEC devices for realistic applications with different boundary conditions.

Comparative analysis of control strategies impact on power losses in IGBT power modules with a multiphysics‐circuit coupling method

AbstractPower losses in semiconductor devices present a significant impediment to advancing power electronics systems for achieving higher frequencies, improved efficiency, and greater integration. A major challenge lies in directly coupling power losses with various control strategies, considering the variations in manufacturers, packaging, and process structures within the power electronics field. This paper introduces a field‐circuit coupling simulation methodology of the insulated gate bipolar transistor (IGBT) within the Simulink/COMSOL environment, using a conventional three‐phase six‐switch voltage source inverter (VSI) IGBT module as a case study. A composite transfer function interconnects the electrical and thermal aspects, enabling bidirectional coupling between IGBT temperature and losses. This study aims to comprehensively compare the effects of various control strategies, namely, single‐vector, dual‐vector, and three‐vector current model predictive control (CMPC) and space vector pulse width modulation (SVPWM), on the losses and temperature of IGBT power modules. The findings emphasize that losses are significantly influenced by the selection of weighting factor coefficients and power factor settings under the same CMPC control strategy with a fixed switching frequency. Additionally, the selection of control strategies, such as CMPC and SVPWM, substantially impacts power losses in power electronic devices.

Suitability of thermally modified wood for binderless particleboard production: Effects of temperature and moisture content in hot pressing

The use of thermally modified wood has grown significantly worldwide over the past 20 years owing to its natural, chemical-free properties, enhanced dimensional stability, and improved biological durability. The binderless particleboard (BP) production process offers an effective way to recycle waste from thermally modified wood. In this study, Fourier-transform infrared (FTIR) spectroscopy and modulated temperature technology were employed to investigate the chemical changes in thermally modified wood as a function of temperature. The impact of moisture content (MC) and temperature on the compression characteristics of particleboards was also examined. The resulting particleboards were subjected to tests for thickness swell and structural morphology (SEM) and vertical density profile analyses. The particleboards produced from thermally modified wood with an MC of 20 % and at a hot-pressing temperature of 170 °C exhibited superior properties to those produced at 8 % MC and 150 and 190 °C. This superior performance can be attributed to the chemical changes in wood, particle size, and the heat transfer and conductivity of the particleboards at high temperature and MC, which renders them more malleable during hot pressing. The particleboards manufactured at 20 % MC and at a hot-pressing temperature of 170 °C demonstrated an internal bonding (IB) of 0.77 MPa, a thickness swell (TS) of 8.14 %, and a homogeneous density distribution. The study provides valuable insights into the production of particleboards from thermally modified wood by optimising the MC and temperature conditions for hot pressing. This research offers a sustainable approach to reusing thermally modified wood waste and promotes the development of more efficient particleboard production processes. Future research could focus on broadening the application scope and exploring the long-term durability and performance of the particleboards produced under the identified optimal conditions.

Optimization and analysis of battery thermal management system structure based on flat heat pipes and biomimetic fins

As one of the key components of electric vehicles, the enhancement of the performance of the power battery is closely intertwined with an efficient Battery Thermal Management System (BTMS). In the realm of BTMS, Flat Heat Pipes (FHP) have garnered considerable attention due to their lightweight structure and excellent thermal conductivity. Thus, a BTMS configuration scheme based on FHP is proposed in this study. Utilizing orthogonal design and fuzzy grey relational analysis as the evaluation methods, coupled with numerical simulations, an investigation into the influence of four structural parameters of the novel biomimetic fins (namely, the diameter, height, spacing of protrusions, and height of cooling fins) on the temperature distribution of the battery pack is conducted. The research findings indicate that to maintain the battery within an optimal operational temperature range, the optimal dimensional parameters should be controlled at 17.5 mm, 4 mm, 13 mm, and 90 mm, respectively. Subsequent sensitivity analysis reveals that the height of the protrusions exhibits the most significant influence on the maximum temperature of the module, whereas the height of the cooling fins exerts a considerable impact on the consistency of the module temperature. The optimized maximum temperature is determined to be 36.52 °C, with a temperature difference of 2.65 °C.

Feed-forward compensation for emulator-type testing facilities

Defining the required trackability level of the target condition for the testing facility reconditioning unit represents an unresolved challenge in improving the reproducibility of load-based tests and corresponding performance rating standards development. To enhance the reproducibility of such testing methodology, this paper presents and discusses a new feed-forward compensation technique based on the development of a transfer function model for the delay and offset characteristics of the psychrometric room's air temperature and humidity modulations with reference to the target signal from the room emulator. It is demonstrated that the proposed methodology enables offset and delay reduction in the trackability of the return air condition within 60 s at different testing conditions, enhances the reproducibility of the test results to limit performance deviations to within 2 %, and achieves closely matched controlled parameter modulations during load-based tests.

Modulation of the Superconducting Phase Transition in Multilayer 2H-NbSe2 Induced by Uniform Biaxial Compressive Strain.

Strain is a powerful tool for tuning the properties of two-dimensional materials. Here, we investigated the effects of large, uniform biaxial compressive strain on the superconducting phase transition of multilayered 2H-NbSe2 flakes. We observed a consistent decrease in the critical temperature of NbSe2 flakes induced by the large thermal compression of a polymeric substrate (>1.2%) at cryogenic temperatures. For thin flakes (∼10 nm thick), a strong modulation of the critical temperature up to 1.5 K is observed, which monotonically decreases with increasing flake thickness. The effects of biaxial compressive strain remain significant even for relatively thick samples up to 80 nm thick, indicating efficient transfer of strain not only from the substrate to the flakes but also across several van der Waals layers. This work demonstrates that compressive strain induced from substrate thermal deformation can effectively tune phase transitions at low temperatures in 2D materials.

Temperature modulation of Northern Mid-Latitude Westerly winds intensity and displacement across the warm Pliocene

The mid-latitude westerly winds are fundamental components of the Earth's climate system. However, their detailed variations during the entire Pliocene, a critical epoch often considered the closest analogue to future climate scenarios, remain poorly constrained. Here, we investigate the continuous, long-term evolution of Northern Hemisphere Mid-latitude Westerly winds (NHMW) between 6.5 and 2.5 Ma, using diatoms, aeolian dust grain size, and chemical weathering conditions from a sediment core in the central-north Pacific Ocean. Our records suggest that NHMW weakened and shifted northward from ∼5.8 to 4.4 Ma, followed by a sustained strengthening and equatorward shift after ∼4.4 Ma. NHMW dynamics during the Pliocene were linked tightly to the sea surface temperature gradient between tropical and temperate regions and affected the strength of the Asian Summer Monsoon (ASM), with weaker and more poleward NHMW increasing the intensity of and rainfall generated by the ASM. These findings underscore the importance of past dynamics of NHMW for predicting the hydroclimatological impacts of future global climate change on the functioning of major regional ocean-atmosphere and rainfall systems as the earth continues to warm.

Energy-Efficient Smart Window Based on a Thermochromic Hydrogel with Adjustable Critical Response Temperature and High Solar Modulation Ability.

Thermochromic smart windows realize an intelligent response to changes in environmental temperature through reversible physical phase transitions. They complete a real-time adjustment of solar transmittance, create a livable indoor temperature for humans, and reduce the energy consumption of buildings. Nevertheless, conventional materials that are used to prepare thermochromic smart windows face challenges, including fixed transition temperatures, limited solar modulation capabilities, and inadequate mechanical properties. In this study, a novel thermochromic hydrogel was synthesized from 2-hydroxy-3-butoxypropyl hydroxyethyl celluloses (HBPEC) and poly(N-isopropylacrylamide) (PNIPAM) by using a simple one-step low-temperature polymerization method. The HBPEC/PNIPAM hydrogel demonstrates a wide response temperature (24.1-33.2 °C), high light transmittance (Tlum = 87.5%), excellent solar modulation (ΔTsol = 71.2%), and robust mechanical properties. HBPEC is a functional material that can be used to adjust the lower critical solution temperature (LCST) of the smart window over a wide range by changing the degree of substitution (DS) of the butoxy group in its structure. In addition, the use of HBPEC effectively improves the light transmittance and mechanical properties of the hydrogels. After 100 heating and cooling cycles, the hydrogel still has excellent stability. Furthermore, indoor simulation experiments show that HBPEC/PNIPAM hydrogel smart windows have better indoor temperature regulation capabilities than traditional windows, making these smart windows potential candidates for energy-saving building materials.

Influence of the Presence of Different Signatures on the Heat Transfer Profile of Laminar Flow Inside a Microchannel

Abstract The process of transferring heat and mass involves a high-pressure decline. Hence microchannels are utilized in extremely efficient heat and mass transfer processes, such as in the systems of the lungs and kidneys. Due to their high surface-to-volume ratio and compact volume, microchannels have demonstrated superior thermal performance. In this work, micro-fins of different topologies and arrangements were used inside microchannels for modulating heat transfer from the surface of the fins, in the presence of flowing media. The influx of media was simulated in sinusoidal form, reproducing simplified form of physiological circulatory blood flow. The study was conducted in numerical domain, while heat transfer and mass transfer equations were solved using pardiso solver. Temperature modulation at the fin surfaces was conducted to examine the transient profile of heat transfer, as function of both variable fluid velocity as well as variable feeding heat sources. In case of different input boundary conditions, the effect of heat distributions on fluid flow with respect to spatial distribution of micro-fins within a microchannel was evaluated. Results revealed the difference in heat transfer profiles in microchannels in presence of different sets of fin configurations. It was found that rectangular fins have the highest heat transfer in fluid at all its spatial configurations; while semi-ellipsoidal-shaped fins had shown the least heat transfer profile at same surface area. At the same time, it was also observed that the rate of heat dissipation was faster and limited in semi-ellipsoidal-shaped fins configuration; while the heat transfer rate was found symmetrical and low in presence of rectangular fins. Hence, this article emphasizes the modulation of temperature and velocity variations within the working fluid by emphasizing the thermo-fluid coupling effects in microchannels.

Enhancing the performance of photovoltaic using exhausted air from thermal comfort spaces

This paper presents an experimental investigation using the exhaust air from the central air conditioning system as cooling air for the PV modules. Experimental tests were conducted under harsh outdoor weather conditions in Baghdad, Iraq, during the summer session, where the recorded ambient temperature was around 33 to 47 °C. In this study, the exhaust air was flowing in the back side of the PV module to reduce the operating temperature of the PV module and thus improve its performance and electrical efficiency. The results show that the temperature of the PV module decreased from 62.42 to 47.42 °C, the output voltage increased from 14.28 to 16.17 V, the generated electrical power increased from 80.39 to 87.89 W, and the electrical efficiency increased from 13.88% to 15.18%. Overall, the enhancement percentage of the PV temperature, voltage, power, and electrical efficiency is 23.7%, 13%, 9.33%, and 9.33%, respectively, compared to the PV module without cooling.

Polysquaramides.

Thermoplastics, while advantageous for their processability and recyclability, often compromise thermochemical stability and mechanical strength compared to thermosets. Addressing this limitation, we introduce an innovative approach employing reversibly cross-linked polymers, utilizing squaramide moieties to reconcile recyclability and robustness. Herein, we detail the synthesis of supramolecularly cross-linked polysquaramides through the condensation polymerization of diethyl squarate with primary and secondary diamines. This methodology embeds hydrogen-bonding squaramide motifs into the polymer chains, yielding materials with significantly enhanced storage moduli, reaching up to 1.2 GPa. Material characterization via dynamic mechanical analysis, creep-recovery, and stress relaxation experiments delineate a distinctive rubbery plateau across a broad temperature range, excellent creep resistance, and multimodal viscoelastic flow, respectively, attributable to the dynamic nature of the supramolecular cross-links. Additionally, the study showcases the modulation of glass transition temperature (Tg) by altering the monomer composition and stoichiometry, demonstrating the tunability of polymer viscoelastic properties through precise control over hydrogen bonding interactions. Overall, the incorporation of squaramide motifs not only provides the structural integrity and mechanical performance of these thermoplastics but also leads to engineering materials with tailored viscoelastic characteristics.

Chemisorption of hydrogen on metal oxides with palladium (II) oxide additives

Chemisorption can lead to a change in electrical conductivity, which allows using semiconductor materials to create gas sensors. On the other hand, semiconductor sensors can be used as devices for studying the chemisorption of gases. In this work, we set two tasks. The first of them was to create a sensor for the selective determination of hydrogen in air, including in a mixture with other gases. The second task was to determine the mechanism of hydrogen chemisorption on the surface of metal oxides with palladium (II) oxide additives. We obtained and characterised nanodispersed materials based on SnO2 and WO3 with additions of 3% PdO by weight. We compared the electrical characteristics of these materials in stationary temperature conditions as well as with temperature modulation in the presence of hydrogen, methane, and their mixtures. The specific features of hydrogen chemisorption were determined on the surface of metal oxide semiconductors based on SnO2 and WO3 with PdO additives in the temperature modulation mode of the sensor. It was shown that the extrema in the dependence of the sensor’s electrical conductivity on temperature can be explained by the contribution of proton transfer to the total electrical conductivity. The presence of extrema in the electrical conductivity of sensors, which were observed in thermal modulation mode in the presence of hydrogen, allows conducting qualitative and quantitative analysis of not only single-component gas systems, but also of mixtures of hydrogen with other analyte gases. In particular, this work demonstrated that it was possible to determine the composition of a hydrogen-methane mixture in air using a single metal oxide sensor. The advantage of this approach is that multidimensional data arrays can be easily processed.

Dynamic Infrared Radiation Regulator Enabling Positive and Reversible Modulation of Emissivity and Temperature

AbstractThe ongoing advancements and growing adoption of infrared detection technology have spurred a tremendous amount of interest in thermal camouflage technology. Various approaches are employed to develop infrared camouflage materials capable of manipulating emissivity or surface temperature. However, the range of thermal radiation regulation implemented by these materials is still somewhat limited. In this paper, a combined emissivity and temperature regulation strategy that integrates a thermoelectric device (TED) and a thermochromic structure is proposed. By utilizing this strategy, it becomes possible to simultaneously control the surface temperature and the emissivity without needing additional complex excitation. As a concept demonstration, large tunabilities of 0.38 for long‐wave infrared (8–14 µm) emittance and 87 °C for surface temperature are observed, resulting in a prominent tunability of the thermal radiation temperature that is 15.4 °C greater than that of a conventional TED with constant emissivity. This work aims to introduce a new design paradigm for future thermal radiation management and camouflage techniques.

Synergistic oxidation of levofloxacin in electro-peroxone system with enhanced in-situ N, P self-standing carbon cathode derived from Chlorella: In-situ H2O2 generation, peroxone activation and catalytic ozonation

An intrinsic N, P self-standing carbon block (NP SSCB) cathode prepared with Chlorella as a precursor was used to enhance the electro-peroxone (EP) process under acidic conditions through a temperature modulation strategy. The results exhibited that NP SSCB-800-EP had a synergistic effect on levofloxacin (LEV) degradation by 42.1% and produced in situ H2O2 up to 70 mg L−1. Quenching and EPR tests confirmed that ·OH, HO2·/O2·- and 1O2 were responsible for degradation of LEV. The quantitative results showed that EP process produced radicals in the order of 1O2> HO2·/O2·->·OH. X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) calculations under acidic conditions confirmed that pyridinic N, pyrrolic N, C-O-P and the defects were active sites for in-situ H2O2 production. Furthermore, pyridinic N, pyrrolic N and C-P-O groups contributed to the reaction of H2O2 with O3 to form HO2/O2·- and O3·- intermediates, free from overcoming the limitations associated with traditional HO2− production. Graphitic N and C3-PO were possible active sites for triggering the 1O2 and *Oad production. This work provides a new strategy for the preparation of self-standing carbon-based cathodes and achieves multiple functions of EP process under acidic conditions, presenting new insights into structure-functional relationships in carbon-based advanced oxidation processes.