Fluid Inclusion Temperatures Research Articles

Source and U-Pb Chronology of Diagenetic Fluids in the Permian Maokou Formation Dolomite Reservoir, Eastern Sichuan Basin, China

The hydrothermal dolomitization, facilitated by basement fault activities, had an important impact on the Permian Maokou Formation dolomite in the Sichuan Basin, which experienced complex diagenesis and presented strong reservoir heterogeneity. The source and age of diagenetic fluids in this succession remain controversial. In this study, various analyses were implemented on samples collected from outcrops and wells near the No. 15 fault in the eastern Sichuan Basin to reconstruct the multi-stage fluid activity and analyze the impact on reservoir development, including petrology, micro-domain isotopes, rare earth elements, homogenization temperature of fluid inclusions, and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) U-Pb dating. The homogenization temperature of primary brine inclusions in fine-grained matrix dolomite and saddle dolomite is concentrated between 100 and 150 °C, which indicates that the impacts of abnormally high temperatures of other geological bodies. The δ13C and δ18O value and low 87Sr/86Sr value indicate that the diagenetic fluid of fine-grained matrix dolomite is mainly Permian seawater. The U-Pb ages of fine-grained matrix dolomite are ~260 Ma, which coincides with the age of the main magmatism of Emeishan Large Igneous Province (ELIP), and hydrothermal fluid provided a favorable high-temperature environment in the penecontemporaneous stage. While highly radiogenic 87Sr/86Sr compositions suggests those of saddle dolomite, the high-temperature Sr-rich formation fluid. The U-Pb ages of saddle dolomite are 245–250 Ma, which coincides with the age of the 255~251 Ma magmatism of ELIP. This indicates that those should be the diagenetic products of the ELIP hydrothermal fluid in the shallow burial stage. The U-Pb age of coarse-grained calcite is 190–220 Ma, and it should be the diagenetic product of the deep burial stage. Brine inclusions associated with primary methane inclusions were developed in coarse-grained calcite, with a homogenization temperature range of 140.8–199.8 °C, which indicates that the formation fluid activities were related to hydrocarbon charging. The Permian Maokou Formation dolomite was firstly formed in the penecontemporaneous shallow burial stage, and then it was subjected to further hydrothermal dolomitization due to the basement faulting and the abnormally high heat flow during the active period of ELIP. Hydrothermal dolomitization contributed to the formation and maintenance of intercrystalline and dissolution pores, whereas it also formed saddle dolomite to fill the pores, and reduce the pore space. The influence of deep fluid activities on reservoir evolution is further distinguished.

Genesis of the Jianbeigou Gold Deposit on the Southern Margin of the North China Craton: Insights from Fluid Inclusions, H‐O‐S Isotopes, and Pyrite in situ Trace Element Analyses

AbstractThe Jianbeigou gold deposit is a typical lode gold deposit in the Qinling metallogenic belt, located on the southern margin of the North China Craton. Three stages of the hydrothermal process can be distinguished, including the quartz ± pyrite, quartz‐polymetallic sulfide, and quartz‐carbonate ± pyrite stages. From the early to late stages, the homogenization temperatures of primary fluid inclusions are 281–362°C, 227–331°C, and 149–261°C, respectively. The corresponding salinities estimated for these fluids are 3.9–9.9 wt%, 0.4–9.4 wt%, and 0.7–7.2 wt% NaCl equiv. Combined with laser Raman spectroscopy data, the ore‐forming fluid belongs to a H2O‐CO2‐NaCl ± CH4 system with medium–low temperature and salinity. The δ18Ofluid and δD values for the quartz veins are –1.0‰ to 6.0‰ and –105‰ to –84‰, respectively, which indicates that the ore‐forming fluid is of mixed source, mainly derived from magma, with a contribution from meteoric water. Pyrite has been identified into three generations based on mineral paragenetic sequencing, including Py1, Py2, and Py3. The pyrites have δ34S sulfur isotopic compositions from three stages between 3.7‰ and 8.4‰, indicating that sulfur mainly originated from magma. Te, Bi, Sb, and Cu contents in pyrite were all high and showed a strong correlation with Au concentrations. Native gold and the Au‐Ag‐Bi telluride minerals were formed concurrently, and the As concentration was low and decoupled from the Au content. Therefore, Te, Bi, Sb and other low‐melting point chalcophile elements play an important role for gold mineralization in arsenic‐deficient ore‐forming fluid. Combined with the geological setting, evolution of pyrite, and ore‐fluids geochemistry, we propose that the Jianbeigou deposit can be classified as a magmatic–hydrothermal lode gold deposit. Gold mineralization on the southern margin of the North China Craton is related to Early Cretaceous magmatism and formed in an extensional setting.

New constraints from in-situ U-Pb ages and fluid inclusions of calcite cement and structural analysis on multiple stages of strike-slip fault activities in the northern Tarim Basin, NW China

Dating the activity of complex faults and fracture systems is crucial for creating reliable geological models for various tectonics and subsurface engineering applications. This study presents a comprehensive study integrating U–Pb fracture cement dating, trace elements, and fluid inclusion temperature analysis with seismic analysis of faults, fault diagenesis, and burial history studies to better constrain faulting and fracture activities in an intra-cratonic strike-slip fault system in the northern Tarim Basin. Seismic profiles indicate at least three distinct phases of fault activity corresponding to the Middle Ordovician, Permian, and Paleogene periods. Fracture cementation and crosscutting relationships corroborate the identification of three fracturing stages. U–Pb dating of fractured cement has widely detected Middle Ordovician and Early Permian age intervals. Fluid inclusion homogenization temperatures from the fractured cements, ranging across < 50 °C, 70–130 °C, and 150–180 °C, correspond to three episodes of rapid subsidence during the Ordovician, Permian, and Neogene, respectively. These results suggest three phases of fault/fracture reactivation in the Middle Ordovician (prior to 470 Ma), Early Permian (prior to 295 Ma), and Cenozoic. The fault/fracture reactivation in the Ordovician is closely related to the regional tectonic transition from extension to compression, while fault and fracture reactivation in the Early Permian may be related to hydrothermal activity associated with large-scale igneous province and oil emplacement. Fault/fracture activity in the Cenozoic may be related to a reduction in subsidence, gradual reduction of geothermal gradients, and massive oil emplacement. This research underscores the significance of integrating geochemical and subsurface datasets for accurately determining the timing of faulting and fracturing in sedimentary basins.

The Spatial and Temporal Evolution of the Sadisdorf Li-Sn-(W-Cu) Magmatic-Hydrothermal Greisen and Vein System, Eastern Erzgebirge, Germany

Abstract The Sadisdorf Li-Sn-(W-Cu) prospect in eastern Germany is characterized by vein- and greisen-style mineralization hosted in and around a small granite stock that intruded into a shallow crustal environment. The nature and origin of this mineral system are evaluated in this contribution by a combination of petrography and fluid inclusion studies, complemented by Raman spectroscopy and whole-rock geochemical analyses. The early magmatic-hydrothermal evolution is characterized by a single-phase low-salinity (7.0 ± 4 wt % NaCl equiv), high-temperature (&amp;gt;340°C), CO2-CH4–bearing aqueous fluid, which caused greisen alteration and mineralization within the apical portions of the microgranite porphyry. The bimodal distribution of brine and vapor fluid inclusions, and the formation of a magmatic-hydrothermal breccia associated with the proximal vein mineralization are interpreted to mark the transition from lithostatic to hydrostatic pressure. The vein- and stockwork-style mineralization (main stage) displays lateral zonation, with quartz-cassiterite-wolframite-molybdenite mineral assemblages grading outward into base-metal sulfide-dominated assemblages with increasing distance from the intrusion. Late fluorite-bearing veinlets represent the waning stage in the evolution of the mineral system. The similarity in the homogenization temperature (250°–418°C) of fluid inclusions in quartz, cassiterite, and sphalerite across the Sadisdorf deposit suggests that cooling was not a significant factor in the mineral zonation. Instead, fluid-rock interaction along the fluid path is considered to have controlled this zonation. In contrast to quartz-, cassiterite- and sphalerite-hosted fluid inclusions, which have a salinity of 0.0 to 10.0 wt % NaCl equiv, the fluid inclusions in late fluorite veins that overprint all previous assemblages have a salinity of 0.0 to 3.0 wt % NaCl equiv and homogenize at temperatures of 120° to 270°C, thus indicating cooling with or without admixture of meteoric fluids during the waning stage of the mineral system. The Sadisdorf deposit shares similar characteristics with other deposits in the Erzgebirge region, including a shallow level of emplacement, similar mineralization/alteration styles, and a hydrothermal evolution that includes early-boiling, fluid-rock interaction, and late cooling. In contrast to most systems in the region, both proximal and distal mineralization are well preserved at Sadisdorf. The recognition of such spatial zoning may be a useful criterion for targeting greisen-related Li and Sn resources.

A numerical model for the quantification of fluid inclusion property variations caused by heterogeneous entrapment and post-entrapment modifications in the H2O-NaCl system

The primary geological conditions for hydrothermal systems can be reconstructed using fluid inclusions, which generally requires that fluid inclusions trapped a single homogeneous phase and experienced no mass and volume changes after entrapment (Roedder's Rules). However, heterogeneous entrapment and post-entrapment modifications have been frequently identified in fluid inclusion studies, making the recovery of primary fluid properties from fluid inclusion data challenging or impossible. In this study, we constructed a specific tool, FlincPro, for the calculations of ideal and nonideal Fluid inclusion Properties in the H2O-NaCl system (ideal here refers to fluid inclusions that adhere to Roedder's Rules). Multiple modules have been developed to quantify the variations of fluid inclusion properties caused by heterogeneous entrapment, volume contraction/expansion, and water loss. The developed software illustrates possibilities in the variation of fluid inclusions in a specific assemblage with the input of a certain starting point.We found that compositions of the vapor endmember fluid are more significantly affected by heterogeneous entrapment than the liquid endmember, as the latter may have several orders of magnitude higher salinity and density. Homogenization pressure and temperature of halite-bearing fluid inclusions trapped on the halite liquidus will increase sharply with the addition of halite, but the homogenization behavior will not be changed. Volume contraction/expansion are effective ways to change the homogenization behaviors, especially for high salinity fluid inclusions. Water loss is not likely to cause the homogenization behavior change from total homogenization by vapor disappearance to total homogenization by halite dissolution for a halite-bearing fluid inclusion without additional volume contraction. Low-salinity and low-density fluid inclusions with total homogenization temperature around the critical temperature of water are least affected by post-entrapment modifications. Therefore, the interpretation of fluid inclusions formation depends on more parameters, e.g., petrographic observations, density and composition variations in fluid inclusion assemblages, and geological information, than only microthermometric data.

Genesis of the Hajibolagh-Zalibolagh Cu-(Ag) intermediate-sulfidation epithermal deposit, Urumieh-Dokhtar magmatic arc, Iran: Evidence from ore geology, fluid inclusions, and stable isotopes

The Hajibolagh-Zalibolagh deposit located northeast of the city of Saveh in the central part of the Urumieh-Dokhtar magmatic arc of Iran, demonstrates vein and breccia vein style copper-(silver) mineralization hosted by Eocene volcano-sedimentary rocks. The main mineralization stage can be divided into four phases, respectively (1) jasperoid + quartz veins, chalcopyrite, and pyrite; (2) quartz veins along with chalcopyrite, bornite, chalcocite, arsenopyrite, and pyrite; (3) quartz-barite veins along with chalcopyrite, bornite, chalcocite and pyrite; and (4) veins of quartz, calcite, hematite, and oligist along with a small number of copper sulfides. The main stages of mineralization are cut by barren post-ore quartz and calcite veinlets. As a result of supergene processes, minerals are oxidized, and malachite, azurite, chrysocolla, chalcocite, covellite, goethite, and hematite are formed, presenting an important exploration guide. The hydrothermal alteration from the center of the vein-veinlets to the outside includes, respectively, silicification, sericitization, intermediate argillic, and propylitic. The average salinity and homogenization temperature (Th) of fluid inclusions is 14.2 wt% NaCl equiv. and 288 °C, respectively. The coexistence of the vapor phase, liquid-rich phase, and halite-bearing fluid inclusions is a sign of boiling in this hydrothermal system, which has contributed to copper saturation. Sulfur isotope values for pyrite, chalcopyrite, chalcocite, and bornite are mainly from –0.16 to 2.98 ‰, indicating a probable magmatic source for sulfur. Boiling, dilution, and mixing are the mechanisms for the ore deposition and facilitated the mineralization. The Hajibolagh-Zalibolagh deposit shows the highest similarity to intermediate-sulfidation epithermal deposits. The best environment for the mineralization and fluid circulation in these epithermal deposits is the intersection of faults with the Eocene volcanic and volcano-sedimentary rocks.

Стадийность формирования кварц-альбит-алланит-фукситовых прожилков на Au-Pd-месторождении Чудное (Приполярный Урал)

The gold-palladium mineralization of the Chudnoe deposit is represented by mineralized veined zones in fractured and brecciated rhyolites of the Riphean-Vendian age. Native gold and palladium minerals are concentrated mainly in veins of Cr-containing muscovite (fuchsite), in which allanite is present in small amounts; quartz, albite, calcite, potassium feldspar, titanite, apatite, zincochromite and other minerals are also found. Veins of allanite-albite-quartz composition are found in ore zones, in some cases containing abundant fuchsite secretions. It has been established that quartz-albite-allanite-fuchsite and other fuchsite-containing veins are the result of the superposition of quartz-albite vein execution on previously formed gold-bearing fuchsite veins. Quartz-albite vein material fills central parts of the combined veins and cements fragments (xenoliths) of fuchsite, while in some cases part of the gold was redeposited and fixed in the quartz-albite part of the veins. Based on the study of the decomposition structures of solid solutions in native gold, it was previously established that the temperature of gold formation in fuchsite veinlets exceeded 220 °C. The deposition temperature of the main part of the quartz-albite veins was noticeably lower. The homogenization temperature of fluid inclusions in vein minerals (quartz, albite, allanite, calcite) was mainly in the range of 96—168 °C, solutions were enriched with magnesium and calcium chlorides. Under these conditions, allanite, apatite, monazite, xenotime, and molibdosheelite were formed and redeposited, and fuchsite recrystallized.

Diagenetic evolution and origin of cements of the Cretaceous carbonates in the Akal Block, southeast Gulf of Mexico

The Cretaceous succession of deep marine facies (580 m-thick) of the Akal Block, southeast of the Gulf of Mexico, is dominated by lime mudstones that have been extensively affected by dolomitization. Petrographic examination, including cathodoluminescence (CL), and microthermometry reveal three phases of dolomitization that occurred as replacement and pore-/fracture-filling cements. These are (1) an early replacement dolomicrite (D1, <50 μm) with dull orange CL, (2) eu-to subhedral dolomite (D2, 60 μm–150 μm) with distinctive cloudy cores (dull CL) and clean edges (non-luminescent to dull CL), and intercrystalline porosity (6 %), and (3) anhedral vug-/fracture-filling dolomite (D3, 200 μm–500 μm) exhibiting CL zonation. The mean δ18O values of those dolomites show a trend of slight decrease from D1 to D3 (D1 = 0.0 ± 1.3‰ VPDB, D2 = −0.2 ± 1.1‰ VPDB, D3 = −1.2 ± 1.6‰ VPDB), which reflects the influence of progressive burial. The low Sr contents (101 ± 29 ppm) of D1, along with its near-micritic grain size and estimated δ18OD1fluid of parent dolomitizing fluid (−3.6‰–1.9‰ SMOW), support early-stage dolomitization at low temperature of near-surface conditions from solutions of mixed meteoric and seawaters. The higher estimated δ18Ofluid values of D2 and D3 (3.0–13.9‰ SMOW) are expected for fluids in burial settings of high temperatures. The homogenization temperatures of the primary two-phase fluid inclusions of D2 (Th = 99.1 ± 7.9 °C) and D3 (Th = 89.5 ± 11.2 °C) suggest precipitation at deeper burial settings, which is also consistent with their lower Sr contents (80 ± 14 ppm and 98 ± 33 ppm, respectively). The lower mean Th value of D3 than that of D2 likely reflects the influence of tectonic uplift that affected the Akal Block. The shale-normalized (REESN) patterns of the dolomites mimic that of modern seawater and those of D1 and D2, in particular, coincide with that of the lime mudstones (C1), thus suggesting that C1 was their precursor and also D3 originated almost from the same parent fluid that its geochemical composition evolved with progressive burial. The latest fracture-filling calcite cement (C2) postdated D3. The investigation of the products of burial diagenesis, such as fracturing, dissolution, and dolomitization events and their relationship with the tectonic uplift of the Akal Block allows a better understanding of the factors controlling the quality of Cretaceous reservoir rocks.

Solid bitumen as an indicator of petroleum migration, thermal maturity, and contact metamorphism: A case study in the Barrandian Basin (Silurian - Devonian), Czech Republic

Silurian and Devonian marine shales and limestones of the Barrandian Basin host abundant black solid, non-fluorescing bitumens that fill tectonic fractures and veins, and occlude fossil moulds and diagenetic concretions. Solid bitumen, interpreted as thermally degraded petroleum, entered the rocks during several successive episodes of fracture-bound petroleum migration that occurred during deeper burial of the strata. Regional distribution of bitumen reflectance values that range between ∼0.9–2.3% Rr, correlate with variations of its FT-IR and Raman spectroscopic characteristics and aromatic hydrocarbon composition, and collectively evidence the maturity trend increasing across the basin from the southwest to the northeast. The reflectance of chitinozoans and graptolites (∼0.8–1.9% Rr) in the country rocks and homogenization temperatures of hydrocarbon fluid inclusions document palaeotemperatures ranging between ∼90–150 °C, characteristic of the oil window zone grading into the gas/condensate zone. Although in a basin-wide perspective the averaged values of solid bitumen and zooclast optical reflectance converge and indicate the same northeastern-increasing regional diagenetic trend, solid bitumen reflectance values vary considerably at individual localities and even within some bitumen samples. The wide scatter of optical reflectance values and the heterogeneity of optical properties, which were attributed to the presence of multiple source rocks in the basin, the variable lithology of bitumen host rocks, or other variables, hamper the use of solid bitumen as a simple alternative to zooclast/vitrinite reflectance palaeothermometers in a given basin. On the other hand, the highly anisotropic domain and the mesophase “coking” textures of the solid bitumen that were recognized in the NE part of the basin provide unique evidence on an anomalous, hitherto unrecognized, geologically short-lasting thermal event that affected the Palaeozoic rocks. A line of indirect evidence suggests that the coking of the bitumen was caused by a cryptic intrusion, possibly a concealed branch of the Central Bohemian Pluton, which intruded into the strata during the Variscan orogeny. More rarely occurring semi-solid, vividly yellow fluorescing waxy bitumen, that postdates solid bitumen in some fractures and voids, does not reveal a regional thermal maturation trend. It precipitated from relict waxy oils that migrated through the strata during a post-Neogene uplift of the Barrandian region.

Characterization of reservoir quality in tight sandstones from the Benxi Formation, eastern Ordos Basin, China

The Benxi Formation in the eastern Ordos Basin harbors abundant natural gas resources and shows promising exploration and development potential. However, the reservoir characteristics are complex, and the primary controlling factors are unclear, presenting significant challenges for reservoir characterization. In response to these challenges, we conducted a systematic study on the characteristics of tight sandstone reservoirs in the Benxi Formation by integrating thin section analysis, scanning electron microscopy, high-pressure mercury injection, and conventional petrophysical analysis alongside well log data analysis. By applying empirical calculation formulas of a porosity evolution quantitative model, we elucidated the primary controlling factors of reservoir heterogeneity. Our research identified that the reservoirs in the eastern Ordos Basin, Benxi Formation, are predominantly composed of quartz sandstone and lithic quartz sandstone, with pore-filling cementation as the dominant cement type and the main storage spaces being intergranular pores and dissolved pores. The homogenization temperatures of fluid inclusions in authigenic quartz range from 92.8 to 185.7°C, indicating that the target layer is in the mesodiagenesis phase B. The main reasons for the differences in reservoir quality in the Benxi Formation are attributed to both sedimentation and diagenesis. In terms of sedimentation, two distinct sedimentary microfacies control the distribution of reservoir quality differences based on variations in quartz content and soluble components. Regarding diagenesis, the Benxi Formation underwent compaction, cementation, and dissolution, with compaction being the fundamental cause of widespread reservoir compaction.

Evolution of skarn to quartz-vein mineralization: Insights from the Tongshanling Cu–Pb–Zn deposit, South China

The Tongshanling Cu–Pb–Zn deposit, situated within the Qin-Hang intra-continental porphyry-skarn metallogenic belt in South China, presents a valuable case study of intrusion-related ore systems. This deposit is characterized by skarn mineralization closely associated with subsequent quartz-vein sulfide mineralization. While considerable research has been devoted to understanding the origin and evolution of the intrusions and mineralization processes, limited attention has been given to elucidating the relationship between the skarn and quartz-vein mineralization, along with the physicochemical conditions governing their formation. Here, we conducted a comprehensive mineralogical and isotopic investigation of sulfides, and a thorough analysis of fluid inclusion assemblages. We aimed to discern disparities in the sources of ore-forming materials, formation temperature, sulfide fugacity, and precipitation-alteration mechanisms of hydrothermal fluids for these two distinct orebodies. Although same sulfide species including arsenopyrite, pyrite, chalcopyrite, and sphalerite, some silicate minerals such as garnet, chlorite, and epidote are exclusive to the skarn orebodies and absent in the quartz veins.The homogeneous temperatures of fluid inclusions in the skarn orebody, ranging from the early to late stages of evolution, decrease from ∼310 to ∼290 °C. Simultaneously, salinity varies from 5.5 to 3.1 wt% NaCl eqv. In the quartz vein mineral body, the temperature reduction is more pronounced, decreasing from ∼270 to 186 °C, with salinity ranging from 3.6 to 1.4 wt% NaCl eqv. Sphalerite geothermometer indicates that peak hydrothermal fluid temperature in the skarn orebodies (∼300–340 °C) was relatively higher than that in the quartz-vein orebodies (<300 °C). Nevertheless, temperatures in both hydrothermal fluid systems declined as mineral precipitation proceeded, corresponding to a decrease in sulfur fugacity. The final stage of sphalerite represents the lowest temperature, salinity and sulfur fugacity with associated quartz displaying the lowest salinity across the entire hydrothermal fluid spectrum at the Tongshanling deposit, suggestive of meteoric water incorporation. This study delves into the multifaceted history of mineralization at the Tongshanling deposit, providing a fresh perspective on the origin and evolutionary relationships of Cu-polymetallic deposits associated with intrusions, particularly those involving multiple stages of mineralization in skarns and quartz veins, contributing to a better understanding of similar deposits worldwide.

Subaqueous carbonate speleothems as paleotemperature archives – clumped isotope thermometry and stable isotope compositions of inclusion-hosted water

Clumped isotope measurements of carbonates and stable isotope analyses of water trapped in fluid inclusions are both promising techniques to determine carbonate formation temperatures. Cave-hosted carbonate deposits (speleothems) are excellent targets for such studies, but kinetic fractionations and diagenetic influences frequently deteriorate the temperature data obtained from these methods. However, subaqueous carbonate deposits may provide reliable data, as kinetic fractionations are less significant in underwater environments. In this study, subaqueous speleothems, whose formation temperatures were directly measured in the water, were investigated. Additionally, temperatures calculated from the oxygen isotope fractionations between calcite and fluid inclusion-hosted water were compared with clumped isotope temperatures obtained for subaqueous carbonate formations in cave-hosted lakes. The clumped isotope temperatures fit the measured and calculated fluid inclusion temperatures within the analytical precisions. Carbonate deposits formed at elevated temperatures (~50°C or above) may undergo post-formational calcite-water oxygen isotope exchange, altering the composition of the inclusion-hosted water. In contrast, subaqueous speleothems formed at about 20-25°C appear to preserve the primary isotopic compositions. Our study shows that subaqueous carbonate speleothems are useful targets for clumped isotope and inclusion water analyses, making them valuable paleotemperature archives.

Distribution and Genesis of the Deep Buried, Fractured and Vuggy Dolostone Reservoir in the Lower Ordovician Succession, North Tarim Basin, Northwestern China

Recently, a series of prolific fracture-vug reservoirs have been discovered in the lower Ordovician dolostone successions of the northern Tarim Basin. However, the genesis of these reservoirs remains unclear. In this study, observations on drilling cores and thin sections identify the pore space characterized by dissolved fractures, fissures, and vugs. Petrology, cathodoluminescence, and homogenization temperatures of fluid inclusions aid in establishing the diagenetic paragenetic sequence. Dissolving enlargement occurred after chemical compaction of overlying limestone and before the Permian volcanic activity. Breccia pores containing unique fillings of terrestrial materials (quartz sand and allogenic kaolinite) and calcite cements with negative δ18OPDB values (−18.4‰) along with 87Sr/86Sr ratios (up to 0.71026) indicate that the dissolving fluid originated from meteoric freshwater at the surface. The δ18OSMOW values of the calcite precipitating fluid (−2.1‰ to −8.7‰) further suggest freshwater as the source of the dissolving fluid, buffered by the Ordovician wall rocks or formation water. As the distance from the unconformity surface increases, both the homogenization temperature and δ18OPDB values of the breccia pore-filling calcite in the southern study area gradually elevate and deplete, respectively, indicating a rise in temperature during the infiltration of meteoric freshwater with increasing subsurface temperatures. The abnormal reflection bodies identified as reservoirs in seismic profiles along deep-seated strike-slip faults delineate these faults as the channel for the infiltration of meteoric freshwater. The penetrating strata of these faults and the high 87Sr/86Sr values of breccia pore-filling calcite suggest that karstification occurred during the Devonian period. Accordingly, we establish a deep karst model in which the Devonian meteoric freshwater penetrated along the strike-slip faults and dissolved the Ordovician dolostones, resulting in the development of deep buried karstic fault reservoirs in the southern region of the northern Tarim Basin.

Origin of calcite cements in the Permian Lucaogou Formation tight reservoirs, Jimsar sag, Junggar basin, NW China: Constraints from geochemistry

Understanding the diagenetic evolution of carbonate cementation in hydrocarbon reservoirs is critical to better reconstruct the history of fluid flow during petroleum accumulation. The extensive occurrence of carbonate cements within the lower Permian Lucaogou Formation tight reservoirs is regarded as a major diagenetic factor that causes strong hydrocarbon reservoir heterogeneities. Petrographic and geochemical analyses, including optical microscopy fitted with cathodoluminescence, scanning electron microscopy, carbon and oxygen stable isotopes, in situ rare earth element, as well as fluid inclusion microthermometry, were carried out to decipher the origin of calcite cementation and understand its control on reservoirs quality. Petrography shows that the precipitating cements mostly consist of pore-filling blocky/mosaic calcite, with a dull orange luminescence color. Chondrite-normalized rare earth element (REE) patterns and C–O isotopic compositions of these calcite cements exhibit strongly negative Eu and Tb anomalies, enrichment in light REE, positive carbon (δ13CPDB = 0.58‰–7.45‰) and negative oxygen (δ18OPDB = −11.38‰ to −8.61‰) isotopic values, similar to the dolostone and micritized peloidal grains, suggesting that the calcite-precipitating fluids were derived from dissolution of lacustrine depositional carbonates. The relative timing of calcite precipitation in reservoirs was constrained based on the thermal-burial history of the study region and precipitation temperatures obtained from fluid inclusions. The results show that this cementation episode mainly occurred during the Late Triassic to Early Jurassic, which was synchronous with the tectonic uplift event. Moreover, homogenization temperatures of fluid inclusions and geochemical signatures of the calcite cement are similar to those of the fracture-fillings, suggesting that these two calcite phases may be genetically related and form coevally within one fluid flow system. It can be interpreted as a response to the compressional tectonic deformation given by the collision of the Qiangtang Block with the Eurasia Plate. This tectonic deformation event is regarded as the driver for calcite precipitation during the early burial stage, resulting in a considerable reduction of reservoir quality. Calcite cementation is pervasive and may play a main role in halting hydrocarbon migration through some of the permeable pathways in reservoirs.

Diagenesis of the Permian Fengcheng Formation in the Mahu Sag, Junggar Basin, China

The Fengcheng Formation in the Mahu sag of the Junggar Basin was primarily composed of detritus, pyroclastic material, carbonates, and evaporites. In order to establish the diagenesis pathways of the Fengcheng Formation, some methods of polarized light microscope, SEM, CL, EPMA, LR, and fluid inclusion analysis were applied to discuss the diagenesis process. The results showed the following: (a) The formation of an alkaline lake was the result of the influence of a high concentration of sodium-rich sources, and it led to the preservation of alkaline minerals in the stratum. (b) After the sediments were buried, three mineral assemblages were formed in the Fengcheng Formation, which are carbonate mineral assemblages (i.e., calcite + ferreous dolomite), reedmergnerite and carbonate mineral assemblages (i.e., reedmergnerite + calcite + ferreous dolomite), and reedmergnerite and alkaline mineral assemblages (i.e., reedmergnerite + shortite + trona), respectively. (c) According to the homogenization temperature of reedmergnerite primary fluid inclusions, the alkaline diagenesis of Fengcheng Formation was divided into an early stage (≤100 °C) and a middle stage (&gt;100 °C), respectively. The earlier stage is marked by the formation of ferrous saddle dolomite, quartz dissolution, and the agglutination of laumontite. These processes occurred under normal burial conditions. The latter is marked by the reedmergnerite’s appearance, which is correlated with the deep hydrothermal activity controlled by faults. (d) Based on sedimentary and diagenetic factors, including climate, provenance, diagenetic surroundings, and the action of subsurface fluid, the alkaline deposition-diagenesis model for shale series in four stages of the Fengcheng Formation was established.

Epithermal Deposits of Kamchatka, Russia

The results of studying the epithermal deposits of Kamchatka, one of the most promising gold-mining provinces of the Russian Federation, are generalized. The deposits are divided into acid–sulfate (Ac-Sul) and adularia–sericite (Ad-Ser) types (Heald et al., 1987). The disadvantages of the scheme, which is the most popular in the English-language literature and is based on the sulfidation state of mineral parageneses in ores (LS, IS, and HS types), are shown. The classification that we proposed includes differences in mineral associations in circum–ore metasomatites, which are determined by the acidity–alkalinity and an oxidation state of mineral-forming fluids, and are clearly diagnosed at the first stages of studying the deposits. Kamchatka epithermal deposits of the Ad-Ser-type are associated with andesite volcanism of the volcanic belts. Gold ore associations are concentrated in quartz, carbonate–quartz, and adularia–quartz veins, as well as in sericitized metasomatites, which are replaced by argillizites and propylites towards the periphery. The Ad-Ser-type is characterized by combination with polysulfide (Pb, Zn) (Amethyst, Kumroch, Vilyuchinskoe deposits), sulfosalt (Ag, Sb, As, Bi, Sn) (Ozernovskoe, Baranyevskoe), and selenide (Ag, Se) (Amethyst, Asachinskoe, Rodnikovoe) assemblages. Low-fineness native gold (220–310‰) is typical of the early polysulfide assemblage. With an increase in the fugacity of Te and Se, the gold fineness increases to 510–740‰, and with the progressive activity of Sb, As and Bi and the formation of sulfosalt associations, it reaches 998‰. The homogenization temperatures of primary fluid inclusions in quartz from gold-bearing associations of the Ad-Ser-type are 260–250°C; the minerals crystallize from solutions containing no more than 3 wt % NaCl eq. Maletoyvayam, the only Ac-Sul-type deposit in Kamchatka, is localized in quartz, secondary quartzites, and alunite–sericite–kaolinite–quartz metasomatites. Gold-bearing parageneses indicate the leading role of selenium in mineral formation, contain high-fineness native gold, sulfoselenotellurides, tellurides, and selenides of Au, which crystallize from acidic fluids with salinity of 1–5 wt % NaCl eq. at temperatures of 290–175°C.

Diagenetic history of calcite fractures in Vaca Muerta shales (Argentina) inferred from paired Δ47 and fluid inclusion geothermometry

Many low-permeability, hydrocarbon-bearing rocks are productive for petroleum because natural fractures enhance hydrocarbon delivery to wellbores. Exploration and development decisions often must be made in the face of uncertainty about the presence and properties of natural fractures at scales of beds, field and plays, and how they contribute to production. Fractures patterns in subsurface rocks are challenging to predict or characterize owing to the difficulty in obtaining representative samples of fractures and the sparse set of tools for reconstructing how and when fractures grow during sedimentary basin evolution. In this study, we investigate bed-parallel fracture diagenesis in the Vaca Muerta shales (Argentina) based on a set of calcite vein collected from core across a thermal maturity sequence that ranges from the oil to dry gas window. We characterize these samples using secondary ions mass spectrometry (SIMS) measurements of stable isotope ratios, carbonate clumped isotope geothermometry and fluid inclusion analysis. These measurements precisely reconstruct the evolution of fluid geochemistry, temperature and pore fluid pressure during fracture opening. Here we show that within each studied site, all bedding parallel fibrous veins calcite formed at similar ranges of temperature. The fracture mineralization temperature increases substantially at the basin scale, from 90 °C to 120 °C, correlated with host-rock thermal maturity. We compare our constraints on carbonate and fluid temperature with apatite fission track thermal models and find that most of the fractures of the Vaca Muerta shales have formed in a relatively early stage of subsidence of the basin (c.a. 90 to 70 Ma). These ages estimations are consistent with recently published U–Pb ages on calcite veins from the outcropping area (117–61 Ma). The presence of petroleum inclusions (oil, condensate, and gas) in most of the vein's calcite fibers from cores also provides clear evidence that fracture formation was contemporaneous or posterior with petroleum generation, constraining the timing of catagenesis in the Vaca Muerta. Reconstructed paleo pressures conditions of veins formation from fluid inclusion analysis highlight significant fluid overpressure in the shale interval, which likely contributed to fracture initiation and growth. Preserved apparent Δ47 temperatures in fibrous veins carbonates mineralization evolves gradually from 130 °C to 175 °C with increasing host rock thermal maturity. These clumped-isotope-based temperatures are systematically higher than trapping temperatures of associated fluid inclusions; one interpretation of this observation is that carbonate clumped isotope compositions re-equilibrated to near maximum burial conditions by solid-state isotopic re-ordering, yielding a record of the maximum burial temperature the shale unit experienced. The combination of paleothermometry techniques used in this study illustrates the importance of simultaneously exploring several independent geothermometers, particularly the informative combination of fluid inclusion and clumped isotope constraints, which provides a means of understanding the complex diagenesis of old sedimentary rocks that have experienced burial temperatures in the oil and gas thermal windows.

Tectono-thermal evolution of the northern Tarim Basin, Central Asia: New insights from apatite low-temperature thermochronometers

The research on the tectono-thermal histories of the northern Tarim Basin, particularly the eastern Kuqa fold-and-thrust belt (KFTB) is crucial for comprehending the basin-mountain tectonic evolution and related coupling in the central Asia. This study aims to reconstruct the tectono-thermal history of the eastern KFTB with a combination of apatite fission track (AFT) ages, apatite (U-Th)/He (AHe) ages and vitrinite reflectance data. The central AFT ages of the samples range from 22.93 Ma to 156.59 Ma, which are younger than the corresponding stratigraphic ages. The single-grain AHe ages range from 4.23 Ma to 24.92 Ma and display some dispersion, likely due to radiation damage and/or grain size effects. Thermal modeling results indicate that the eastern KFTB mainly experienced the Cretaceous and Miocene rapid cooling events (althouth the timing and magnitude of these events varied among the samples), which were related to the collisions of the Qiangtang-Lhasa Terranes and India Plate with the southern margin of the Eurasia Plate. The paleo-heat flow of the eastern KFTB decreased from the Late Triassic (54 ∼ 55 mW/m2) to the Early Miocene (44 ∼ 47 mW/m2) and then increased since the Late Miocene due to thrust fault activity. Furthermore, we reappraised the maturation evolution histories of the source rock in the Huangshanjie and Yangxia formations using the new thermal hirtories, which were consistent with the hydrocarbon charging and accumulation time, as indicated by the homogenization temperature of fluid inclusions. Overall, this study provides valuable insights into the tectono-thermal histories of the eastern KFTB. It enhances our understanding of the tectonic evolution of Central Asia and holds great significance for further hydrocarbon exploration and development in the northern Tarim Basin.

Sulfide Mineralization of Carbonate–Silicate Veins in Early Proterozoic Metabasites of North Karelia: Mineral Assemblages, Mineral Forms of Silver, and Fluid Inclusions

The work presents the first data on sulfide mineralization in carbonate–silicate veins, which are widespread on the islands and coast of the White Sea (North Karelia), associating with Early Proterozoic metamorphosed gabbroid bodies. The veins with Fe–Cu sulfide mineralization up to ore occurrences are localized within metabasite bodies and along their contacts with host gneisses. During the study of the mineral composition of the veins, the main assemblages of sulfide minerals were identified: chalcopyrite –bornite ± chlorite ± selenides and Pb–Ag tellurides (B1); digenite–bornite ± selenides and Pb, Ag, and Pd tellurides (B2); pyrite–bornite ± chalcopyrite (B3); marcasite–pyrite–bornite–chalcopyrite (B4); and siegenite–chalcopyrite ± acanthite ± chlorargyrite. The development of sulfide associations, as well as quartz–chlorite aggregates, was related to the late stage of vein formation. Inductively coupled plasma and laser ablation mass spectrometry analyses showed that bornite from association B1 has the highest silver content (up to 675 ppm) and, in terms of Ag, Se, and Bi contents, is closest to bornite from low-temperature epithermal, skarn, and high-temperature vein deposits. In general, bornite is the main Ag carrier in the studied associations, while digenite containing up to 1000 ppm Ag, as well as discrete silver minerals (selenides, tellurides, acanthite, and chlorargyrite), occur in subordinate quantities. Fluid inclusions in quartz from sulfide associations, as well as from a sulfide-free carbonate–silicate vein, were studied by cryo- and thermometric methods. It is established that mineralization at the late stages of vein formation was related to heterogeneous CO2–H2O–NaCl metamorphic fluid. Carbon dioxide fluid inclusions were captured by vein quartz at temperature of 253–314°C and pressure of 2 ± 1 kbar. Water–salt inclusions were captured in a wider temperature range of 100–500°С. The highest temperature fluid inclusions with temperatures of homogenization 300°С are characteristic of quartz veinlets of the siegenite–chalcopyrite association with Ag sulfide and chlorargyrite.

Genesis of the Yi’nan Tongjing Gold–Copper Skarn Deposit, Luxi District, North China Craton: Evidence from Fluid Inclusions and H–O Isotopes

The Luxi district presents an exceptional research area for the investigation of the significant role played by magma exsolution fluids in the mineralization process of Au–Cu deposits. A particularly noteworthy occurrence within this region is the Yi’nan Tongjing Au–Cu skarn deposit, situated in the central-southern part of the Luxi district. This deposit primarily occurs in the contact zone between the early Cretaceous Tongjing complex and the Proterozoic to Cambrian sequences. The ore formation process observed in this deposit can be categorized into three distinct stages: (I) thermal metamorphism, (II) prograde alteration, and (III) retrograde alteration. The retrograde alteration stage is further divided into four sub-stages: late skarn (III-1), oxide (III-2), sulfide (III-3), and late quartz-calcite (III-4). It is primarily during the III-3 sub-stage that gold mineralization occurs. Petrographic analysis has identified three types of fluid inclusions (FIs) within garnet, quartz, and calcite grains. These include liquid-rich two-phase aqueous FIs, vapor-rich two-phase aqueous FIs, and halite-bearing multi-phase FIs. The homogenization temperatures of fluid inclusions from stages II, III-3, and III-4 range between 430–457 °C, 341–406 °C, and 166–215 °C (first to third quartiles), respectively. The garnet samples from stage II exhibit hydrogen and oxygen isotope compositions (δ18OH2O = 6.8‰ and δD = −73‰) that are indicative of a typical magma source. However, the hydrogen and oxygen isotopes of sub-stages III-1, III-2, and III-3 (δ18OH2O = 7.32‰ to 9.74‰; δD = −107‰ to −81.9‰) fall below the magma water box while the hydrogen and oxygen isotope values of III-4 (δ18OH2O = −5.3‰ to −0.9‰ and δD = −103.8‰ to −67‰) tend to move towards the meteoric water line. Furthermore, the ore-forming fluid displays characteristics of a mixture between the crustal and mantle fluids. The Tongjing complex occurred along a weakened fault zone, initiating a process of thermal metamorphism upon contact with the wall rock. This thermal metamorphism resulted in the formation of diverse assemblages, including hornfels, reaction skarns, and skarnoids. Subsequently, the upward movement of ore-forming fluids triggered exsolution which led to the establishment of a high-temperature, medium-salinity NaCl–H2O system with a single phase at depths ranging from 1–3 km. This marked the formation of the prograde alteration stage. Afterward, the ore-forming fluid underwent water–rock interactions and the admixture of meteoric water at a depth of 1–2 km. These processes facilitated phase separation, commonly referred to as boiling, resulting in the transformation of the ore-forming fluid into higher salinity fluids and lower-density gases. This evolutionary transition ultimately induced the precipitation and liberation of gold and copper from the fluid.