Increase In Temperature Research Articles

High Temperature-Insensitive Electrostrain Obtained in (K, Na)NbO3-Based Lead-Free Piezoceramics.

Over the last decades, notable progress is achieved in (K, Na)NbO3 (KNN)-based lead-free piezoceramics. However, more studies are conducted to increase its piezoelectric charge coefficient (d33). For actuator applications, piezoceramics need high electric-field induced strain under low electric fields while maintaining exceptional temperature stability across a wide temperature range. In this study, this work developes Li/Sb-codoped KNN (LKNNS) ceramics with high electrostrain by defect engineering and domain engineering. A remarkable strain of 0.43%, along with a giant d33* value of 2177 pm V-1, is attained in the LKNNS ceramic at 20 kV cm-1. The ceramic exhibits a minimal performance decrease of less than 15% over a temperature range from room temperature to 150 °C. The exceptional strain is attributed to the presence of A-site vacancy-oxygen vacancy ( ) defect dipoles and the increase in nano-domains. The hierarchical domain configuration and defect dipoles impede the switched domains from reverting to their original state as temperature increases, furthermore, the elongated dipole moments of caused by rising temperatures compensate for strain reduction results in exceptional temperature stability. This study provides a model for designing piezoelectric materials with exceptional overall performance under low electric fields and across a wide temperature range.

High-Resolution Infrared Reflectance Distribution Measurement Under Variable Temperature Conditions

The bidirectional reflectance distribution function (BRDF) can effectively characterize the reflectance properties of a target, which can be used to correct infrared remote sensing data and improve the accuracy of remote sensing measurements. When the surface temperature changes, the reflectance characteristics of the target usually change, and it is necessary to carry out BRDF measurements under variable temperature conditions. In this paper, a variable-temperature infrared BRDF measurement system based on a robotic arm is developed to realize high-resolution wide-temperature region measurement of BRDF. To improve the measurement accuracy, the shaping optical path was used to expand the laser beam, combined with the laser level to accurately adjust the three-dimensional coordinates of the robotic arm, and the dichotomy method is used to calibrate the detector nonlinearly. A portable heater suitable for the mechanical arm corner mechanism is developed, and fast and high-precision temperature control is realized by proportional integral derivative (PID) control. The specular and diffuse BRDF distributions were measured at room temperature to verify the effectiveness of the system. The BRDF distribution of SUS314 stainless steel samples with different roughness is measured during two temperature increases from 20 °C to 1000 °C, and the changing rule of BRDF under variable temperature environment is summarized, which provides technical support for evaluating the optical properties of high-temperature materials and improving the measurement accuracy of remote sensing data.

Design and evaluation of an active vineyard heating system to simulate temperature increase in the context of climate change

The current study introduces an innovative direct and active heating system designed for precise temperature control in vineyards. This system serves as a valuable tool for investigating the influence of climate change on grapevine physiology and, consequently, the characteristics of the resulting wine. The research took place in an experimental vineyard located in Mendoza, Argentina, with V. vinifera cvs. trained to a vertical shoot positioning trellis system over two consecutive growing seasons. The system design utilized electric hot water tanks and polypropylene pipes attached to the foliage catch wires. Over two growing seasons, the system consistently elevated the ambient air temperatures within the canopy by 2.5 ± 0.12 °C compared to the control group. This temperature increase emulated the temperature projections for Mendoza as forecasted by the IPCC by the end of this century. The system displayed heating uniformity, as evidenced by the absence of both vertical and horizontal temperature gradients. Additionally, the significant variation in mean daytime and night-time temperatures between the control and heated treatments highlighted the effectiveness of the system in modifying temperature conditions on a diurnal basis. The heated treatment applied with this system proved to have an effective biological impact on the physiology of grapevines. In both seasons, plants under the heated treatment advanced their bud break and harvest dates. The study showed a significant growth enhancement in the heated treatment, with apical shoots extending significantly longer than those in the control treatment. Additionally, the total soluble solids content increased in the heating treatment, while yield decreased, for both experimental seasons. These results illustrate the robust performance of the system throughout the entire growth period, regardless of fluctuations in atmospheric conditions. This study establishes a new foundation for future research on grapevine responses to climate change. It also opens the door to the implementation of effective adaptation strategies in vineyards, promising a more resilient and adaptable future for grape cultivation.

Modifying the Refuse Chute Design to Prevent Infection Spread: Engineering Analysis and Optimization

Considering the presence of airborne viruses, there is a need for renovation in refuse chutes, regarded as the first step in recycling household waste in buildings. This study aimed to revise the design of existing refuse chutes in light of the challenging experiences in waste management and public health during the coronavirus pandemic. This research primarily focused on the risks posed by various types of coronaviruses, such as the novel coronavirus (COVID-19) and acute respiratory syndrome (SARS and SARS-CoV), on stainless steel surfaces, with evidence of their survival under certain conditions. Refuse chutes are manufactured from stainless steel to resist the corrosive effects of waste. In examining the existing studies, it was observed that Casanova et al. and Chowdhury et al. found that the survival time of coronaviruses on stainless steel surfaces decreases as the temperature increases. Based on these studies, mechanical revisions have been made to the sanitation system of the refuse chute, thus increasing the washing water temperature. Additionally, through mechanical improvements, an automatic solution spray entry is provided before the intake doors are opened. Furthermore, to understand airflow and clarify flow parameters related to airborne infection transmission on residential floors in buildings equipped with refuse chutes, a computational fluid dynamics (CFD) analysis was conducted using a sample three-story refuse chute system. Based on the simulation results, a fan motor was integrated into the system to prevent pathogens from affecting users on other floors through airflow. Thus, airborne pathogens were periodically expelled into the atmosphere via a fan shortly before the intake doors were opened, supported by a PLC unit. Additionally, the intake doors were electronically interlocked, ensuring that all other intake doors remained locked while any single door was in use, thereby ensuring user safety. In a sample refuse chute, numerical calculations were performed to evaluate parameters such as the static suitability of the chute body thickness, static compliance of the chute support dimensions, chute diameter, chute thickness, fan airflow rate, ventilation duct diameter, minimum rock wool thickness for human contact safety, and the required number of spare containers. Additionally, a MATLAB code was developed to facilitate these numerical calculations, with values optimized using the Fmincon function. This allowed for the easy calculation of outputs for the new refuse chute systems and enabled the conversion of existing systems, evaluating compatibility with the new design for cost-effective upgrades. This refuse chute design aims to serve as a resource for readers in case of infection risks and contribute to the literature. The new refuse chute design supports the global circular economy (CE) model by enabling waste disinfection under pandemic conditions and ensuring cleaner source separation and collection for recycling. Due to its adaptability to different pandemic conditions including pathogens beyond coronavirus and potential new virus strains, the designed system is intended to contribute to the global health framework. In addition to the health measures described, this study calls for future research on how evolving global health conditions might impact refuse chute design.

Impact of land use land cover changes on urban temperature in Jakarta: insights from an urban boundary layer climate model

Urbanization is one of the important drivers of increasing local temperatures. As cities and urban areas evolve, extensive land use and land cover (LULC) changes alter the physical characteristics of surface materials. This modification results in reduced evapotranspiration rates, ultimately contributing to higher surface and air temperatures. This study investigated the impact of urbanization on urban temperature in Jakarta. Urban temperature was simulated for a 20-year time period (1995–2014) by the urban boundary layer climate model UrbClim, using LULC data for both 1995 and 2014. Temperature changes were analysed by assessing the temperature anomaly across different LULC change classes divided into four main classes namely no built-up changes (BB), no green spaces changes (GG), built-up to green spaces (BG), and green spaces to built-up (GB). The study revealed that the conversion of green spaces to built-up areas (GB) had the most significant impact on the increase in air temperature. This was indicated by the mean values of the temperature anomaly of GB of about 0.24°C followed by GG, BB, and BG with the mean values of the temperature anomaly of about 0.20°C, 0.19°C, 0.17°C, respectively. The different temperature anomalies of the LULC change classes indicate that green spaces have an important role in maintaining local climate. Hence, it is important for local government to effectively manage the composition, the quantity, as well as the distribution of green spaces within a city. By looking at temperature anomalies of LULC change classes, the present study provides an alternative approach to many existing methods that provide general information about temperature changes, without specifically analyzing the effects of LULC transformations.

Al Alloy Melting Behavior and Interfacial Reactions with Steel Under Natural Convection

The Al alloy melting behavior and interfacial reactions during the steelmaking process of high-Al automotive steel were investigated in this study. The total dissolution time of Al bars (20 × 20 × 80 mm) in molten steel was quite short, decreasing from 21.4 s to 10.0 s with an increase in bath temperature from 1580 to 1620 °C. The Al alloy melting process at the molten steel temperature of 1600 °C included the formation of a solidified steel layer, the latter’s rapid melting, and Al alloy normal melting, while at 1600 °C, the process included a second increase in the thickness of the solidified layer. Because steel elements such as [Fe], [C], [O], and [N] could diffuse during the whole Al alloy melting process, an Fe (Al)-FeAl-FeAl2-Fe2Al5-Al diffusion layer along the direction of the Al-rich matrix could be found at the Fe–Al interface. Moreover, FexO, Al2O3, and unstable AlN inclusions could be observed in the FeAl layer. This study also investigated how to reduce the number of these easily formed inclusions. Decreasing the pre-heating process time and dissolved oxygen content could be useful in decreasing FexO and Al2O3 inclusion formation. Some small-sized AlN inclusions formed in the center of the Al bars where they could not come into contact with the molten steel directly during the melting process; even for the immersion time of only 1 second, these inclusions were not stable in molten steel at the refining temperature and disappeared during the melting process.

Numerical Investigation of Solar Collector Performance with Encapsulated PCM: A Transient, 3D Approach

This study presents a comprehensive numerical investigation into the thermal performance of solar collectors integrated with encapsulated phase change materials (PCMs) using a transient three-dimensional (3D) approach. The performance of two distinct PCMs—paraffin wax and RT60—was evaluated under varying operational conditions, including seasonal variations, inlet pipe velocities, and inlet temperatures. The results indicate that paraffin wax exhibits a higher peak temperature, reaching approximately 360 K, compared to RT60’s peak of 345 K, making paraffin wax more effective for consistent thermal energy storage. Paraffin wax also maintained higher fluid fractions, with a maximum of 0.9 in summer, indicating superior heat absorption and retention capabilities. In contrast, RT60 demonstrated a quicker phase transition, fully liquefying at a lower fluid fraction, which is advantageous for rapid heat release. Seasonal variations significantly impacted system efficiency, with the highest efficiency observed in June at 365 K and the lowest in December at 340 K. The study also found that lower inlet velocities (e.g., 0.25 L/s) significantly improved heat retention, resulting in higher outlet temperatures, while increasing the inlet temperature from 290 K to 310 K led to a marked increase in outlet temperatures throughout the day. These findings underscore the importance of optimizing PCM selection, inlet velocity, and temperature in enhancing the performance of solar thermal systems, offering quantitative insights that contribute to the development of more efficient and reliable renewable energy solutions.

Synthesis and Mass Spectrometry Structural Assessment of Polyesteramides Based on ε-Caprolactone and L-Phenylalanine

L-Phenylalanine-ε-caprolactone-based polyesteramides (PCPs) were synthesized via melt polycondensation across a diverse range of molar compositions. The copolymer structure was extensively characterized using nuclear magnetic resonance (NMR) and matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS). NMR analysis confirmed the intercalation of the L-Phenylalanine comonomer units within the polyester backbone. MALDI MS characterization further demonstrated the formation of linear PCP chains with carboxyl end groups. A detailed structural analysis through MALDI MS/MS fragmentation indicated that ester bond scission was the predominant fragmentation mechanism, depicting the polyesteramide sequence in the copolymers. The resulting copolymers were primarily amorphous, except for those with molar compositions of 90/10 and 80/20, which exhibited semi-crystalline structures. Additionally, these PCPs showed an increase in glass transition temperatures with higher amino acid contents and demonstrated good thermal stabilities, as evidenced by a 10% mass loss at elevated temperatures.

Research on Safety of Aero-Engine Oil Pipe Under Heating Conditions Based on Fluid–Solid Thermal Coupling

This paper examines the safety of aero-engine pipelines under different heating conditions. Based on the fire test standard documents, a model of an aero-engine oil pipe was constructed, and its safety under heating conditions that meet the standard was analyzed using fluid–solid thermal coupling. The pipe material was stainless steel 1Cr18Ni9Ti, and the oil inside the pipeline was China RP-3 kerosene. To simulate the different working conditions or pump failure scenarios, various kerosene inlet flow rates were used for the calculations. The results indicate that the pipe wall exhibits an uneven temperature distribution under standard heating conditions. As the kerosene flow rate decreases, the pipe wall temperature rises, and heat transfer deterioration occurs. The increase in the pipe wall temperature reduces the material’s strength, while the uneven temperature distribution generates thermal stress, further increasing the safety risk. When the kerosene flow rate is reduced to a certain level, the equivalent stress in the pipe wall exceeds the material’s yield strength, leading to a high risk of rupture.

Study of MHD Casson Nanofluid Flow Over an Inclined Stretching Sheet in Porous Media with Thermal Slip, Chemical Reaction and Radiation Effects

In the current study, the behaviour of Casson nanofluid subjected to magnetohydrodynamic (MHD) flow across an inclined stretched sheet within a porous medium has been investigated numerically. The governing equations are transformed into ordinary differential equations with the corresponding boundary conditions by employing similarity transformations. The solutions of essential equations are achieved by using the 4th-order Runge-Kutta method combined with the shooting technique. The novelty and innovative contribution are showcased through illustrative graphs that scrutinize the effect of factors that impact the velocity, temperature, and concentration profiles within assorted flow scenarios. The primary focal points of the study encompass examining variations in magnetic field strength, angle of inclination, and suction intensity that affect the fluid's velocity moderation, while improved porosity and radiation parameters lead to a rise in fluid temperature. Higher Biot numbers correlate with an increase in fluid temperature. The implications of positive coefficients of heat transfer are crucial across various fields to ensure efficient thermal management ensuring optimal performance and longevity. The numerical data presented is aligned with earlier published results for comparison. Furthermore, the variations in skin friction, Nusselt, and Sherwood numbers driven by different parameters are displayed in tables to highlight significant modifications.

Synthesis of Sustainable Binary Calcium Monosilicate Ceramics from Bio-waste: Effect of Sintering Temperature on Microstructure and Electrical Properties

This study was conducted to synthesise calcium monosilicate ceramics using rice husks and raw eggshells and investigated the effect of sintering temperature on the physical,microstructure and electrical properties of the final product. The high content of calcium and silicon in eggshells and rice husks, respectively promote the use of waste materials in the production of calcium monosilicates by mixing in a molar ratio 1CaO:1SiO2 and fired at different sintering temperatures for 2 hours with a heating rate of 10°C/min. A good correlation between sintering temperature, structural, microstructure, and electrical properties of calcium silicate was observed. The structural and morphological evolutions were characterised by X-ray diffraction (XRD) and scanning electron microscopy (SEM) equipped with electron dispersive X-ray analysis (EDX). XRD analysis showed that the main crystalline phases of synthesised calcium monosilicate are pseudowollastonite (ICSD 98-005-2598) at 1250°C, and the phases of SiO2 also exist in different types of minerals. Besides, a small amount of larnite, Ca2SiO4 was traced at 1100°C and 1200°C. Fourier Transforms Infrared (FTIR) spectra showed the presence of characteristic functional groups in the precursor powder. In Nyquist plots, the summit frequency of the dominant arc decreases with increasing sintering temperatures. It may be attributed to the co-effect of the grain size and pore. A larger value of impedance at a lower frequency suggests an essential role of boundaries in governing the electrical properties of the sintered ceramics. As the sintering temperature increases, the microstructure of the sintered samples becomes denser while conductivity performance decreases. This is due to the reduction of particle interfaces and charge transfer.

Thermo-mechanical coupling characteristics of the shearer’s guiding shoe during the friction

The reliability and longevity of the guiding shoe are crucial for the proper functioning of coal mining machines. The heavy wear of the sliding surface under thermal stress coupling is the primary factor influencing the service life of the guiding shoe. To reveal the heat flow distribution patterns and the thermo-stress coupling mechanisms of the guiding surface, a thermo-mechanical coupling model of the guiding shoe and the pin row is established. The transient thermodynamic behavior of the guiding shoe under different load and speed conditions is studied using the coupled temp-displacement analysis method in Abaqus. The results indicate that the overall temperature of the guiding shoe friction surface experiences a rapid increase during the initial running-in phase, followed by a progressively slower temperature increase over time. Temperature and stress concentration regions on the friction surface primarily localize at the corners of the shoe groove, and the distribution of temperature and stress shows a strong coupling. Furthermore, elevated traction speed and mechanical load exacerbate the thermo-elastic instability of the guiding shoe, consequently augmenting thermal stress on the friction surface. The increase in support load results in significant thermal shock on the lower area of the left side of the guiding shoe. The research provides a reference for exploring the fatigue failure and wear mechanisms of the guiding shoe while considering thermal effects.

Research on working mechanism and structural optimization of high speed bearing of tricone bits based on finite difference method

Abstract In order to analyze the working mechanism of the floating sleeve bearing of the cone bit, the life of floating sleeve bearing was tested. The experimental results show that adhesive wear will form on the bearing surface with the increase of temperature, which is the main cause of bearing failure. And this paper establishes the Reynolds equation and energy equation of the oil film based on the theory of dynamic pressure lubrication of sliding bearings. The equation was numerically solved based on the finite difference method. It determines the rotational speed ratio at the equilibrium based on the trend of the frictional torque. And then corrects the eccentricity in the iterative calculation process so as to analyze the tribological performance of the bearings in equilibrium under different clearance ratios. Among them, the improper configuration of the internal and external clearance ratio leads to the increase of the friction torque and the reduction of the bearing capacity. For floating sleeve bearings, the configuration with large internal clearance and small external clearance should be adopted. Finally, the bearing structure is optimized and numerical calculations show that the tribological performance of the new type bearings is significantly improved compared with that of ordinary cone bit bearings.

The Impact of Climate Change on the Transmission of Vector-borne Diseases and Drug Administration: A Review

Climate change continues to be a big threat to humanity, particularly due to its significant impacts on human health. Although there have been some studies on the impacts of climate change on human health, there is a huge gap on its prospective effects on the transmission of vector-borne diseases and drug administration. Therefore this review provides a comprehensive impacts of climate change on the transmission of vector-borne diseases and drug administration It is estimated that the global temperature on average will potentially rise by 1.0 – 3.0 oC, thus increasing the chance of the emergent and increased rate of transmission of vector-borne diseases. Climate change continues to have a significant impact on overly poor and vulnerable populations across tropical and sub-tropical regions across the world. Some studies have established the influence of climate change on the transmission of diseases due to increasing changes in weather patterns such as rainfall and increase in temperature, as a result of global warming. It is believed that climate change will have a long-term effect on the propagation of diseases, and subsequently affect treatment from drug administration. Rising temperatures and global warming due to climate change can alter disease patterns, drug stability and change drug properties, thus potentially increasing drug toxicity and reducing drug efficacy.

Significant temperature tunability of the band gap in two-dimensional materials

Two-dimensional (2D) materials have great attentions due to their novel physical and chemical properties. The band gap Eg plays a significant role in influencing their applications, which can be changed by the temperature. In this work, taking the Group-IV materials (graphene, silicene, germanene, and stanene) as the examples, we first study the temperature-dependent Eg by employing the state-of-the-art electron-phonon renormalization calculations. It shows that the primary Eg at K-point is almost unchanged while that at Γ-point decreases directly with temperature increase in all the systems (e.g., Eg reduction in stanene from 100 K to 500 K is 0.006 eV at K-point and 0.148 eV at Γ-point, respectively). The differences are originated from the different chemical bond characteristics at band edges, which are π-bonding at K-point but (σ*) σ (anti-) bonding at Γ-point. The latter are more sensitive to the temperature-induced vibrations, such as the out-of-plane acoustic phonon modes in the three buckling systems. The strong sensitivity of σ-bonding to the vibrations can be further examplified by another four 2D systems (P4, InSb, MgCl2, and C2F2), screening from the database MatHub-2d. This phenomenon offers the temperature tunability for the band gaps at Γ-point of 2D materials, which may have more application significances in optoelectronics.

Heat stress: a major threat to ruminant reproduction and mitigating strategies.

Stress is an external event or condition that puts pressure on a biological system. Heat stress is defined as the combination of internal and external factors acting on an animal to cause an increase in body temperature and elicit a physiological response. Heat stress is a set of conditions caused by overexposure to or overexertion at excess ambient temperature and leads to the inability of animals to dissipate enough heat to sustain homeostasis. Heat exhaustion, heat stroke, and cramps are among the symptoms. For the majority of mammalian species, including ruminants, heat stress has a negative impact on physiological, reproductive, and nutritional requirements. Reproductive functions, including the male and female reproductive systems, are negatively affected by heat stress. It decreases libido and spermatogenic activity in males and negatively affects follicle development, oogenesis, oocyte maturation, fertilization, implantation, and embryo-fetal development in females. These effects lead to a decrease in the rate of reproduction and financial losses for the livestock industry. Understanding the impact of heat stress on reproductive tissues will aid in the development of strategies for preventing heat stress and improving reproductive functions. Modification of the microenvironment, nutritional control, genetic development of heat-tolerant breeds, hormonal treatment, estrous synchronization, timed artificial insemination, and embryo transfer are among the strategies used to reduce the detrimental effects of heat stress on reproduction. These strategies may also increase the likelihood of establishing pregnancy in farm animals.

Effect of Morphology and Concentration of CeO2 Nanoceria on the Thermal Stability of Polyvinyl Alcohol Films

Objective: To determine the thermal stability of polyvinyl alcohol films under different concentrations of CeO2 nanoceria. Method: Cerium Oxide doped polyvinyl alcohol (PVA) nano-composites were synthesized by the traditional solution casting method for various concentrations of nano CeO2 by solution combustion method. The thermal properties of prepared PVA-2.5 wt% CeO2, PVA-7.5 wt% CeO2 , PVA-12.5 wt% CeO2, and PVA-25 wt% CeO2 composite films were elucidated by using techniques such as Differential Scanning Calorimetry, Thermogravimetry analysis and Differential Thermal analysis. Findings: The glass transition temperature of the pure PVA is found to be 114°C, whereas it varies between 110°C-120°C for composite films. The melting temperature of the composite films is the same as that of pure PVA except in the case of 7.5wt% CeO2 and 25wt% CeO2 composites. The reduced melting point of these composites elicits a decrease in crystallinity. A 12.5 wt % and 25 wt% CeO2-PVA nano-composite films exhibit an increase in the final degradation temperature, a high specific heat capacity, low mass loss, and a larger residual weight, indicating their potential applicability in thermal coating and thermal sensing applications. Polyvinyl alcohol (PVA) films are being used routinely as a dielectric layer for electrical applications due to the good physiochemical and dialectic properties of the material. An incorporation of CeO2 nanoceria improves not only the thermal but also the mechanical properties of PVA and extends its application for electrical and optical operation. Here in the present study, different concentrations of CeO2 were incorporated with the PVA and analysed for the thermal properties. The study showed that 12.5 wt % and 25 wt% CeO2-PVA nano-composite enhanced PVA film thermal stability. Keywords: PVA-CeO2 Nanocomposites; Differential Scanning Calorimetry; Thermogravimetry Analysis and Differential Thermal Analysis; Physical properties and thermal properties

New Yellow Azo Pyridone Derivatives with Enhanced Thermal Stability for Color Filters in Image Sensors

Two new yellow azo pyridone derivatives, (E)-6-hydroxy-1-(3-methoxypropyl)-4-methyl-2-oxo-5-(p-tolyldiazenyl)-1,2-dihydropyridine-3-carbonitrile (APY-M) and 5,5′-((1E,1′E)-(methylenebis(4,1-phenylene))bis(diazene-2,1-diyl))bis(6-hydroxy-4-methyl-2-oxo-1,2-dihydropyridine-3-carbonitrile) (APY-D), were designed and synthesized as yellow colorants for image sensors. The properties of these new compounds were evaluated in both solution and color filter film forms, focusing on their optical and thermal characteristics. The molar extinction coefficient values of APY-M and APY-D in solution were found to be 2.7 × 105 and 3.0 × 105 L/mol·cm, respectively. The transmittance of the newly synthesized compounds met commercial requirements, showing values below 0.21% at 435 nm and above 97.1% at 530 nm. APY-D exhibited a molar extinction coefficient value in solution that was 1.15 times higher than that of the commercially used yellow colorant Disperse Yellow 241. Both newly synthesized compounds satisfied the decomposition temperature requirement of over 230 °C, which is essential for the color filter manufacturing process in image sensors. In particular, APY-D, with its dimeric structure and increased molecular weight, demonstrated enhanced thermal stability, with a 50 °C increase in decomposition temperature compared to Disperse Yellow 241. Color filter films for image sensors were fabricated using the new compounds, and their thermal resistance was evaluated. APY-D maintained its transmittance due to the enhanced thermal stability provided by its dimer structure and increased molecular weight. Consequently, APY-D is anticipated to be a promising candidate for use as a yellow colorant in image sensors, owing to its excellent optical and thermal properties.

Crystallization Behavior and Structure of CaO–SiO2–Al2O3 Melts Representing the Oxide Inclusions in Si‐Mn Deoxidized Steel

For further optimization of the inclusion plasticization control process of Si‐Mn deoxidized steel, the crystallization behavior and structure of CaO–SiO2–Al2O3 system inclusions are investigated. The crystallization behavior of four typical low melting point CaO–SiO2–Al2O3 inclusions at 1000 to 1250 °C is studied by steel crucible isothermal heating experiment. The obtained results reveal that the glassy stability of the inclusions is high when the composition of low melting point inclusion is located in the eutectic region of tridymite, pseudowollastonite, and anorthite in the ternary phase diagram. However, when the composition of the inclusion is located in the eutectic region of melilite, pseudowollastonite, and anorthite, it is easy to undergo glass‐crystallization transformation and precipitate wollastonite and anorthite crystalline phases when isothermal heating at 1100 to 1200 °C. In addition, the crystallization mode of these inclusions is mainly surface crystallization, and the crystallization degree of inclusions increases with the increase of heat treatment temperature and time. The activation energy of crystallization and the content of nonbridging oxygen in the silicate structure NBO/T can be used to predict the crystallization ability of inclusions. The greater the activation energy of crystallization and the smaller the NBO/T value, the higher the glassy stability of the inclusions.

Heat and mass flux dynamics of tangent hyperbolic nanofluid flow with unsteady rotatory stretching disk over Darcy-Forchheimerporous medium

Abstract The purpose of the research is to examine a tangent hyperbolic nanofluid flowing in three dimensions (3D) axisymmetrically on an unsteady rotatory stretching disk over a DarcyForchheimer porous medium. First order initial value problems (IVPs) are generated from the governing partial differential equations (PDEs) through the use of similarity transformation and linearization. The Runge-Kutta sixth order (RK6) is utilized to solve the IVP system using the shooting technique and the built-in Python software ”fsolve model10.” Articles that have already been published are used to validate the implemented approach. Graphs are used to examine how various parameters affect velocity, temperature, and concentration. Additionally, the behavior of heat, mass flux, and skin friction in response to different parameters is investigated. The study’s findings showed that as the Forchheimer number and velocity slip parameter increased, the nanofluid’s radial and tangential velocities decreased as well. As temperature and concentration slip parameters increase, correspondingly, thicker and thinner boundary layer structures are seen. Both the rates of heat and mass transfers are initiated for an increase Eckert and Prandtl numbers and demotivated for power-law index number.