Effect Of Temperature Research Articles

Mucus, airway and plume temperature effects on pMDI-drug delivery in a mouth-throat airway: Experimental and numerical studies

Effective pulmonary drug delivery through pressurized-metered dose inhalers (pMDIs) depends on accurately targeting pharmaceutical aerosols to specific lung areas. Achieving this necessitates a comprehensive understanding of airflow dynamics in the airway and particle transport mechanisms.In this study, a replica of the realistic geometry of the VCU medium-sized mouth-throat (MT) airway was fabricated by rapid prototyping (3D printing) to connect to a next-generation impactor (NGI) setup. The drug concentration deposited in the replica was measured at a constant flow rate of 30 L/min and room temperature using a high-performance liquid chromatography (HPLC) assay. This measurement validated our computational fluid dynamics (CFD) model for simulating particle transport under the same conditions. Large eddy simulation (LES) and discrete phase model (DPM) were employed to model the MT's airflow and particle transport. Using our CFD modeling, we focused on the effects of the temperature distribution of aerosol injection (plume), the influence of inlet air temperature, and the presence of the mucus layer on particle transport and deposition.Our findings revealed that decreasing the plume temperature from 10 °C to −54 °C reduced deposition by approximately 15%, although increasing the average deposited particle sizes within the MT by about 34.5%. The airflow pattern, affected by different plume temperatures, was the prevalent parameter in particle MT deposition. In contrast, the effect of different air inlet temperatures on deposition was negligible. Additionally, incorporating mucus layer features in CFD modelling could further modify the inhaler's efficiency by up to 11%, depending on the specific conditions like diverse plume temperature (−54 °C–10 °C) and airflow temperature conditions (−15 °C–45 °C).

Understanding the phase behavior during CO2 flooding by dissipative particle dynamics

Understanding the phase behavior of a CO2-oil–water surfactant system is critical for carbon dioxide flooding engineering. Using dissipative particle dynamics, we investigate how the alkanes in crude oil are extracted after the injection of supercritical carbon dioxide into the formation, and what effect this extraction has on the miscible and immiscible displacement of carbon dioxide and crude oil. The images of the extraction are exhibited at the molecular level, and the effects of temperature and pressure on the extraction are investigated. The phase distribution of carbon dioxide, oil, and water under immiscible phase is simulated using actual reservoir fluid data based on a comprehensive understanding of extraction. Oil tends to be spread at the interface of carbon dioxide and water when it is immiscible. The miscible pictures were generated under conditions of reduced CO2-oil–water miscible pressure by adding surfactants to the CO2-oil–water system, and the fluid distribution characteristics under immiscible and miscible phases were examined. dissipative particle dynamics (DPD) simulation demonstrates that when the molar proportion of carbon dioxide is less than 0.4, the solid phase surface can always create a water film of varied thickness, regardless of whether the surface charge of the solid phase is positive or negative. As the molar fraction of carbon dioxide increases, the water film’s thickness decreases.

Highly efficient and recyclable chromium/nitrogen-doped carbon nanotube catalysts with unexpected active sites for conversion of fructose into 5-hydroxymethylfurfural

5-Hydroxymethylfurfural (HMF) has great promise as a versatile platform chemical for the synthesis of a wide range of other chemical compounds. The preparation of HMF from carbohydrates for industrial applications, especially fuels and fine chemicals, has received much more attention. In the present study, metal/nitrogen-doped carbon nanotubes (M/N-CNTs) were produced using a one-step carbonization method and used as an exceptional catalyst for converting fructose to HMF. The catalyst structure was determined using Energy-dispersive X-ray Spectroscopy (EDX), X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), High-resolution X-ray Photoelectron Spectrometer (HRXPS), Transmission Electron Microscopy (TEM), Brunauer-Emmett-Teller (BET), and Fourier-transform Infrared Spectroscopy (FT-IR) techniques. The effects of temperature, catalytic loading, substrate feed concentrations, solvents, reusability, and scalability were carried out. This work achieved an excellent yield of HMF (91 % ± 2) utilizing Cr/N-CNTs as a catalyst for producing HMF at 120 °C for 180 min. Furthermore, the Cr/N-CNTs could be recovered and reused in industrial applications without significant loss of the catalytic activity.

Age-Stage, Two-Sex Life Table of Atractomorpha lata (Orthoptera: Pyrgomorphidae) at Different Temperatures

Atractomorpha lata Motschoulsky (Orthoptera: Pyrgomorphidae) has recently emerged as an important agricultural pest in China. Understanding the impact of temperature on its developmental period is crucial for predicting its population dynamics. This study systematically observed the biological characteristics of A. lata at five temperatures (16, 20, 24, 28, and 32 °C) using the age-stage, two-sex life table method. The effects of temperature on the developmental period, survival rate, and fecundity of A. lata were studied using fresh bean leaves as host. The results demonstrated that as temperature increased from 16 °C to 32 °C, the developmental period, preadult time, adult longevity, adult preoviposition period (APOP), and total preoviposition period (TPOP) significantly decreased. The developmental threshold temperatures for various stages were calculated, ranging from 10.47 °C to 13.01 °C, using the linear optimal method. As temperature increased, both the intrinsic rate of increase (r) and the finite rate of increase (λ) also increased, while the mean generation time (T) decreased. The optimal values of the net reproductive rate (R0 = 54.26 offspring), gross reproductive rate (GRR = 185.53 ± 16.94 offspring), and fecundity (169.56 ± 9.93 eggs) were observed at 24 °C. Similarly, the population trend index (I) for A. lata peaked at 24 °C (61.64). Our findings indicate that A. lata exhibits its highest population growth rate at 24 °C, providing a scientific basis for predicting its population dynamics in the field.

Corrigendum to “Effect of temperature on the chemical activation of carbon Nanospheres and their efficiency in supercapacitors” [Diam. Relat. Mater. volume 146 (2024) 111213]

Corrigendum to “Effect of temperature on the chemical activation of carbon Nanospheres and their efficiency in supercapacitors” [Diam. Relat. Mater. volume 146 (2024) 111213]

Blackberry synthetic seeds storage: effects of temperature, time, and sowing substrate

In vitro propagation, is becoming the predominant method for blackberry propagation due to its advantages compared to agamic traditional propagation methods. Synthetic seed technology represents a promising approach to further enhance the productivity of in vitro propagation facilitating the exchange of plant materials among laboratories and contributing to germplasm conservation efforts. This study aimed to establish an optimal protocol for the storage and sowing of synthetic blackberry seeds obtained through the encapsulation of clump bases. The synthetic seeds were sown without storage (Control) and after storage periods of 30, 60, and 120 days at 4 °C and 25 °C in the dark, in three different substrates (agarised, perlite, and potting). After forty-five days from sowing viability, regeneration rate, shoot and root numbers and lengths, as well as fresh and dry weights of the plantlets, were assessed. Results indicated that agarised substrate consistently exhibited favourable outcomes, with sustained regeneration rates and robust plantlet development even after prolonged storage at 4 °C. Synthetic seeds sown in perlite and potting substrates demonstrated enhanced regeneration rates following storage at 4 °C for 60 and 120 days. On the contrary, storage at 25 °C resulted in a notable decline in regeneration rate, highlighting its inadequacy for blackberry synthetic seed conservation purposes. These findings underscore the importance of sowing substrate selection and storage temperature in optimizing the storage and sowing protocols for synthetic blackberry seeds.

On application of molecular dynamics simulation for studying the effect of temperature and heating rate on HTL of biomass

Abstract Hydrothermal liquefaction (HTL) of biomass has garnered increasing attention as a promising pathway for converting solid biomass to liquid biofuels and valuable chemical products. HTL involves processing of biomass in water at high-temperature and high-pressure conditions. The heating rate during this process plays a critical role in determining the yield and composition of the liquefied products. To probe the impact of heating rate, we develop a detailed atomistic model biomass by using cellulose as model compound and place it in a simulated HTL reactor. Our Reactive molecular dynamics simulations are capable of capturing the dynamic chemical reactions and structural changes during HTL. The effect of reaction temperature and heating rates on reaction pathways, product distributions, and reaction kinetics is rigorously analyzed. Our findings reveal that the reaction temperature and heating rate significantly influences the extent of cellulose degradation and the composition of bio-oil product.

Exploring the potential of surface-modified alginate beads for catalytic removal of environmental pollutants and hydrogen gas generation

In this study, hydrogel beads were fabricated using alginate (Algt) polymer containing dispersed nickel phthalocyanine (NTC) nanomaterial. The viscous solution was poured dropwise into a divalent Ca2+ ions, resulting in the formation of hydrogel beads known as NTC@Algt-BDs. The surface of the NTC@Algt-BDs was further modified by coating them with different types of metal ions, yielding metal-coated M+/NTC@Algt-BDs. The adsorbed metal ions i.e., Cu+2, Ag+, Ni+2, Co+2, and Fe+3 were subsequently reduced to zero-valent metal nanoparticles (M0) by NaBH4. The prepared beads were characterized using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) (XPS). Initially, M0/NTC@Algt-BDs were examined for the catalytic reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP). Among them, the Cu0/NTC@Algt-BDs catalyst exhibited the highest reduction rate and therefore, investigated for reduction of different nitrophenols (NPs) and dyes, including 2-nitrophenol (2-NP), 2,6-dinitrophenol (2,6-DNP), methyl orange (MO), potassium ferrocyanide (PFC), congo red (CR), and acridine orange (ArO). The highest reduction rates of 2.019 and 1.394 min−1 were observed for MO and 2-NP, respectively. Furthermore, the fabricated catalysts were employed for the efficient production of H2 gas by NaBH4 methanolysis. Among which the Ag0/NTC@Algt-BDs catalyst showed excellent catalytic production of H2 gas, exhibiting the lowest activation energy (Ea) of 25.169 kJ/mol at ambient temperature. Furthermore, the impact of NaBH4 amount, and catalyst dosage on the reduction of 2-NP and H2 gas production was conducted whereas the effect of temperature on methanolysis of NaBH4 for evolution of H2 gas was studied. The amount of H2 gas was confirmed by GC-TCD system. Additionally, the recyclability of the catalyst was investigated, as it garnered significant research interest.

Effects of temperature on fracture and damage characteristics of deep granite

Investigating the fracture- and failure-related behaviors of rock that is subjected to temperature treatment is important for handling warm rock reservoirs during deep mining of hot dry rock and processing high-level radioactive waste. In this study, we use the semi-circular bending test in combination with acoustic emission (AE) monitoring technology to examine the characteristics of fracture and damage in granite treated at different temperatures and under different fracture modes at a depth of 750 m in the Daliuhang Gold Mine in China. The results showed that the peak load and fracture toughness of granite decreased to varying extents when it was treated at increasingly higher temperatures. The high temperature substantially reduced the bonding capacity of the particles of rock, and led to the formation of a large number of microcracks that dislodged the particles of rock along the edges of the samples. The changes in the AE counts during the different loading phases can be categorized into stabilization, increase, sudden increase, and decay stages. The damage-related variable based on the cumulative AE count revealed that samples treated at and below a temperature of 300 °C were mainly damaged in the late period of loading and exhibited brittle failure. Damage began to accumulate as early as in the middle period of loading in samples treated at temperatures greater than or equal to 600 °C. The results of this study provide a useful reference for mining deeply buried granite under different temperature gradients and fracture modes.

Differential responses of soil bacteria, fungi and protists to root exudates and temperature

The impact of climate warming on soil microbes has been well documented, with studies revealing its effects on diversity, community structure and network dynamics. However, the consistency of soil microbial community assembly, particularly in response to diverse plant root exudates under varying temperature conditions, remains an unresolved issue. To address this issue, we employed a growth chamber to integrate temperature and root exudates in a controlled experiment to examine the response of soil bacteria, fungi, and protists. Our findings revealed that temperature independently regulated microbial diversity, with distinct patterns observed among bacteria, fungi, and protists. Both root exudates and temperature significantly influenced microbial community composition, yet interpretations of these factors varied among prokaryotes and eukaryotes. In addition to phototrophic bacteria and protists, as well as protistan consumers, root exudates determined to varying degrees the enrichment of other microbial functional guilds at specific temperatures. The effects of temperature and root exudates on microbial co-occurrence patterns were interdependent; root exudates primarily simplified the network at low and high temperatures, while responses to temperature varied between single and mixed exudate treatments. Moreover, temperature altered the composition of keystone species within the microbial network, while root exudates led to a decrease in their number. These results emphasize the substantial impact of plant root exudates on soil microbial community responses to temperature, underscoring the necessity for future climate change research to incorporate additional environmental variables.

Investigating the antiviral activity of Erigeron annuus (L.) pers extract against RSV and examining its active components

Ethnopharmacological relevanceThe plants in the genus Erigeron are known to exhibit antiviral activities, including those against the respiratory syncytial virus (RSV). In traditional medicine Erigeron annuus (L.) Pers (EA) has been used in the treatment of pulmonary diseases and acute infectious hepatitis. Aim of this studyThe aim of this study is to determine the optimum extraction method to produce the most potent anti-RSV extract, elucidate its mode and mechanisms of antiviral activity in both in vitro and in vivo models, and identify the chemical structures of the bioactive compounds. Materials and methodsThe whole plant of EA was extracted with ethyl acetate, methanol, ethanol, water, aqueous methanol (60, 80% and 100%) and aqueous ethanol (50, 75% and 95%) using maceration, reflux, and ultrasound-assisted extraction methods. The antiviral activities of the extracts were determined in vitro. The in vitro antiviral activities of the extracts were determined using Hep-2 cells. Four in vitro experiments were performed to determine the mode of antiviral activity of the most active extract, ethyl acetate fraction (EAE) of Erigeron annuus whole plant extract prepared by refluxing with 50% ethanol, by examining its ability to inactivate the virus directly, inhibit viral adsorption and penetration, inhibit viral replication and preventive effect. The effect of temperature and duration of treatment on these modes of action was also determined. The antiviral activity of the EAE was also assessed in vivo in a mouse model. The lung index, viral load, and lung tissue histology were measured. qRT-PCR and ELISA studies were performed to determine the expression of key genes (TLR-3 and TLR-4) and proteins (IL-2, IFN-γ, and TNF-α) related to RSV infection. The most active antiviral compound was isolated using chromatography techniques, and its chemical structure was identified through electrospray triple quadrupole mass spectroscopy and nuclear magnetic resonance spectroscopy. ResultsThe EAE was the most active on RSV. In vitro experiments showed that the antiviral activity of EAE is via direct inactivation, inhibition of entry, and inhibition of the proliferation of the virus. In vivo experiments showed that the EAE effectively inhibited the proliferation of RSV in the lungs and alleviated the lung tissue lesions in RSV-infected mice. The antiviral activity of the EAE is mediated by downregulating the expression of TLR3 and TLR4 in the lung, upregulating the expression of IL-2 and IFN-γ, and downregulating the expression of TNF-α. Apigenin 7-O-methylglucuronide was found to be a major bioactive compound in EAE. ConclusionsThe results of this study confirmed the antiviral activity of EA by inactivating, inhibiting the entry, and inhibiting the proliferation of RSV. The activity is mediated by regulating the immunity and inflammatory mediators. Apigenin 7-O-methylglucuronide is the bioactive compound present in EA.

Performance investigation of a novel free piston Stirling pump for reverse osmosis desalination systems

Renewable energy (RE)-powered desalination technology is considered a cleaner and promising alternative for alleviating energy exhaustion and environmental pollution resulting from traditional desalination. Currently available solar thermal reverse osmosis (RO) desalination systems are based on the organic Rankine cycle. With the aim to expand the driving mode of reverse osmosis desalination as well as simplify the transmission chain and reduce mechanical energy losses, a novel hydraulic free piston Stirling pump (FPSP) is developed and a simple model is designed and tested for conceptual validation. A free piston Stirling pump - powered reverse osmosis desalination system is presented, and a thermodynamic–dynamic coupling model is established. A parametric analysis is performed with an emphasis on the effects of temperatures, charge pressure, spring stiffnesses, damping coefficients, and masses on the system performance, including the frequency, power output, water yield, and efficiency. Results showed that the frequency in the pumping process was higher than that in the suction process because of the different loads. Within the range investigated, the performance improved as the hot-end temperature, charge pressure, spring stiffnesses, and damping coefficient of the power piston increased, while it deteriorated with a decrease in the damping coefficient of the displacer and the piston masses. Specifically, the power output and water yield reached the optimum value as the cold-end temperature was maintained around 310 K. Under representative parameter conditions, the power output could reach 12.15 kW and the water yield was approximately 6.07 × 10−4 m3/s. In addition, the temperatures and charge pressure influence the system efficiency most.

Comparative life-history responses of lacewings to changes in temperature.

Insects play a crucial role in all ecosystems, and are increasingly exposed to higher in temperature extremes under climate change, which can have substantial effects on their abundances. However, the effects of temperature on changes in abundances or population fitness are filtered through differential responses of life-history components, such as survival, reproduction, and development, to their environment. Such differential responses, or trade-offs, have been widely studied in birds and mammals, but comparative studies on insects are largely lacking, limiting our understanding of key mechanisms that may buffer or exacerbate climate-change effects across insect species. Here, we performed a systematic literature review of the ecological studies of lacewings (Neuroptera), predatory insects that play a crucial role in ecosystem pest regulation, to investigate the impact of temperature on life cycle dynamics across species. We found quantitative information, linking stage-specific survival, development, and reproduction to temperature variation, for 62 species from 39 locations. We then performed a metanalysis calculating sensitives to temperature across life-history processes for all publications. We found that developmental times consistently decreased with temperature for all species. Survival and reproduction however showed a weaker response to temperature, and temperature sensitivities varied substantially among species. After controlling for the effect of temperature on life-history processes, the latter covaried consistently across two main axes of variation related to instar and pupae development, suggesting the presence of life-history trade-offs. Our work provides new information that can help generalize life-history responses of insects to temperature, which can then expand comparative demographic and climate-change research. We also discuss important remaining knowledge gaps, such as a better assessment of adult survival and diapause.

Study on Improvement Measures for Construction Performance and Mechanical Properties of Cement Stabilized Porous Basalt

Abstract Cement stabilized porous basalt (CSPB) is prone to early agglomeration into lumps owing to the abundant pores and high moisture absorption of porous basalt, making it difficult to unload the mixture at construction sites in high temperatures and rainy areas. To study the construction performance of a CSPB mixture, a novel test method and a convenient device were proposed to test the workability of the cement stabilized macadam mixture, and the evaluation criteria and evaluation method of the workability were proposed based on the tilt angle test. The influencing factors of the workability of CSPB were investigated, and the results show that temperature, delay time, moisture absorption of aggregate, mixture proportion, and construction technology had significant influences on construction performance. Then measures were recommended to improve the construction performance of CSPB. Considering the influence of construction performance on mechanical strength, the effects of temperature, delay time, water reducer dosage, and cement dosage on the mechanical strength of CSPB were also investigated. The results show that temperature and delay time had significant influence on the mechanical strength. The results of this research are of great significance to the field construction of CSPB.

The effect of temperature and ultrasonic power on the microstructure evolution of coal modified by clean fracturing fluid: an experimental study

The effect of temperature and ultrasonic power on the microstructure evolution of coal modified by clean fracturing fluid: an experimental study

The effect of temperature on mechanical properties of calcium silicate hydrate enhanced by graphene oxide and graphene via molecular simulation study

With the advancement of the construction industry, there is a growing demand for cement materials with enhanced high-temperature resistance. This study utilizes reactive molecular dynamics to investigate the impact of elevated temperatures on the mechanical properties of graphene cement-based materials and the underlying mechanisms. The findings suggest that graphene nanosheets (GN) and graphene oxide (GO) can stabilize the structure of calcium silicate hydrate (C-S-H). Moreover, high temperatures can disrupt the H-bond network in composite structures, but the addition of GO can mitigate this effect. Additionally, elevated temperatures can influence the strength of relevant chemical bonds within the composite structure, leading to degradation in tensile strength and Young's modulus. Nevertheless, the incorporation of GO can enhance the mechanical properties of C-S-H at high temperatures. Conversely, the effect of GN on reducing the tensile strength of C-S-H is not significant and may even decrease the stiffness of C-S-H.

Investigations into the Dynamic Acoustic Response of Lithium-Ion Batteries During Lifetime Testing

Techniques using acoustic waves to interrogate batteries are increasingly investigated in the literature due to the appeal of three main properties: they are non-destructive, relatively low cost and have acquisition rates enabling operando testing. Popular demonstrations attempt to extract degradation markers from acoustic data, by continuous monitoring, and to attribute them to degradation modes. This is founded on the premise that the speed of sound depends on mechanical properties, such as the density and stiffness. Nevertheless, additional sensitivities of an acoustic time-of-flight analysis are often neglected, leading to incomplete experiments that can overstate the capabilities of the technique. In this work, such sensitivities are quantified and the use of pulse tests instead of CCCV protocols is recommended to elucidate the concurrent dynamic evolution of temperature, voltage and acoustic signals. A degradation experiment is performed, with pulse sequences incorporated in periodic reference performance tests. Dynamic parameters are extracted from each pulse; specifically, the dynamic rise of the time-of-flight (ΔToFrise) and temperature (ΔTemprise) signals. Their evolution with degradation is traced and a statistical comparison of the main effects is performed. It is concluded that markers of degradation in the dynamic acoustic response are very subtle, masked by the effects of temperature.

The effect of temperature, pressure, and grind size on Total Dissolved Solids (TDS) and extraction yield of semi-automatic espresso machines

The number of coffee shops in Indonesia has grown from 1,083 stalls in 2016 to over 2,937 booths in 2019, representing a threefold growth. Coffee shop establishments must provide two essential kinds of equipment: espresso machines, which use pressure, and filter machines, which employ infusion. The issue lies in the exorbitant cost and immense power requirements of semi-automatic and automated espresso machines, which necessitate the use of a manual espresso machine for commercial operations. The equipment can generate satisfactory espresso but encounters several challenges; specifically, the espresso generated is characterized by inconsistency, constantly varying in quality. This might arise due to the erratic nature of the manufacturing process. The two objectives of this study are: (1) to design an economically efficient semi-automatic espresso machine capable of producing products that meet the international quality standards set by the Specialty Coffee Association (SCA standard) and (2) to investigate the impact of critical factors such as pressure, temperature, and grind size, on the consistent quality of the resulting coffee (measured by Total Dissolved Solids (TDS) and extraction yield (EXT)). The research employs the Research and Development (RD) methodology. The research findings indicate that the optimal levels of Total Dissolved Solids (TDS) and extraction yield (EXT) may be attained by using a pressure setting of 8 bars, a temperature of 90ºC, and a grind size of 3.2 on the scale. The technique for optimizing the response resulted in Total Dissolved Solids (TDS) levels of 10.03% and extraction yield (EXT) values of 19.56%. The results have been deemed acceptable based on the criteria set by the global standards of Specialty Coffee Association (SCA).

Effect of internal structure and resin deformability on drying rate and stress in convective drying of silica–latex coatings

Latex paint is an aqueous dispersion of nano-sized polymer particles that can form a thin film by itself or mixed with rigid particles. We have developed an apparatus that can simultaneously measure drying rate and stress generation and have investigated the film formation process of a latex-only coating layer under convection drying. In the present study, we adopted the same method to investigate the film formation process of the silica–latex coating layer. As a result, we were able to systematically correlate the drying rate change by the equivalent thickness of latex particles accumulated with silica particles at the drying surface. Furthermore, it is unveiled that the drying rate in the former stage depends on drying temperature, while the drying rate changed to be dominated by silica content after the particle-packing layer was formed over the entire coating layer. On the other hand, the model we proposed for stress generation, considering the temperature effect on latex deformability, was found to be applicable to the present experimental system by replacing a portion of deformable particles with rigid particles.Graphical abstract

Riverine Influences and Seasonal Dynamics: Exploring Carbonate System Variations and Air‐Sea CO2 Fluxes in the Southern Yellow Sea and East China Sea

AbstractIn this work, the seasonal variations of the carbonate system and air‐sea CO2 fluxes were investigated by two cruises in the southern Yellow Sea (SYS) and the East China Sea (ECS), which were significantly influenced by the Changjiang riverine inputs across seasons. Biological‐mediated change of dissolved inorganic carbon (DIC) was first quantitated through a three end‐member mixing model from winter to spring. Our modeling results suggested that DIC addition through biological remineralization persisted in the SYS during winter and spring, while DIC removal was evident in the Changjiang River Plume and the offshore ECS triggered by river inputs in spring. Horizontal and vertical mixing together constituted the largest contribution to the interseasonal variability of partial pressure of CO2 (pCO2) in the SYS (−69.5%), the river plume (−59.3%), and the ECS offshore (−43.8%), followed by temperature effects in the plume area (29.4%), and biological processes in the ECS offshore (24.1%) and the SYS (−7.7%), with air‐sea CO2 exchange contributing the least in both three subregions. The SYS, the river plume, and the ECS offshore all acted as atmospheric CO2 sinks in both winter and spring. Furthermore, their ability to absorb atmospheric CO2 increased from winter to spring, as reflected in a ∼1.8‐fold increase in the overall spring air‐sea CO2 flux compared to winter estimation.