Temperature Dependence Of Stability Research Articles

Reduction in Temperature-Dependent Fiber-Optic Gyroscope Bias Drift by Using Multifunctional Integrated Optical Chip Fabricated on Pre-Annealed LiNbO3

The refractive index change obtained after annealed proton exchange (APE) in lithium niobate (LiNbO3) crystals depends on both the proton exchange process carried out in hot acid and the structure of the crystals. In devices produced by the APE method, dislocations and lattice defects within the crystal structure are considered to be primary contributors to refractive index discontinuities and waveguide instability. In this study, the effects of pre-annealing LiNbO3 crystals at 500 °C on multifunctional integrated optical chips (MIOCs) were investigated through interferometric fiber-optic gyroscope (IFOG) system-level tests. It was observed that the pre-annealing process resulted in an improvement in the optical throughput of MIOCs (from %34 to %51) and the temperature-dependent bias drift stability of the IFOG (from 0.031–0.038°/h to 0.012–0.019°/h). The angle random walk (ARW) was measured as 0.0056 deg/√h.

Interplay between temperature-dependent strengthening mechanisms and mechanical stability in high-performance austenitic stainless steels

Interplay between temperature-dependent strengthening mechanisms and mechanical stability in high-performance austenitic stainless steels

Prediction of the Modal Parameters of The Spindle System in High-speed Dry Hobbing Machine with Thermal Effects

High-speed dry hobbing is an advanced green machining technology for gears. However, thermal issues in the machine tools become serious under the high cutting speed and dry cutting conditions, which result in a nonlinear evolution of the machine tool dynamics, and finally affect the hobbing stability. In view of this, introducing the hob spindle system as the object, this paper intends to investigate the influence of time-varying temperatures on the modal parameters based on the modal tests. Then, a temperature-dependent modal parameters prediction model based on the multi-output Gaussian process regression (MOGPR) is proposed. The experimental results indicated that the modal parameters of the spindle system vary obviously with changing thermal states. The natural frequencies for the first and third modes increased with the temperature rise, while the variation of the natural frequency for the second mode was insignificant. The damping ratios for the first three modes showed a decreasing trend with the temperature rise. The constructed MOGPR model has the capability to effectively predict the modal parameters with the time-varying thermal effects, which can provide a support to build the temperature-dependent hobbing stability boundaries.

Top-down fabrication of active interface between TiO2 and Pt nanoclusters. Part 1: Redispersion process and mechanism

Supported metal nanoclusters (NCs) are regarded as the next generation of catalyst that bridge the nanocatalyst and single-atom catalyst. However, feasible fabrication of thermally stable NCs has remained a daunting challenge. In this paper, the first part of an extended work, we report a simple route to fabricate Pt NCs in size of around 1 nm through redispersion of Pt nanoparticles (NPs) or commercial PtO2 by a calcination treatment. Combining control experiments and detailed DFT simulation, the whole redispersion process was described and evidenced to proceed via a gas-phase trapping way: Under promotion of oxygen atmosphere and high temperature, volatile oxidized Pt monomers were firstly generated and then trapped by surface defects, forming special sites that preferentially induce the growth of clusters on them. The growing clusters have both size- and temperature-dependent stability, resulting a most stable size distribution of around 1 nm when fabricated at 550 °C. This work provides a feasible top-down strategy to fabricate highly dispersed metal clusters.

Fission yeast spindle dynamics and chromosome segregation fidelity show distinct thermosensitivity.

Cellular processes rely on proteins with temperature-dependent stability and activity. While thermosensitivity in biological networks is well-explored, the effect of temperature on complex mechanochemical assemblies, like the spindle, is rarely studied. We examined fission yeast spindle dynamics and chromosome segregation from 15⁰C to 40⁰C. Our findings reveal that these parameters follow U-shaped temperature-dependent curves but reach their minima at different temperatures. Specifically, spindle dynamics peak around 35⁰C, whereas chromosome segregation defects are minimized at 25⁰C. This suggests a scenario in which mitotic errors are tolerated to expedite rapid cell cycle progression.

Exploring the temperature-dependent thermal stability of nano-enhanced phase change materials: An experimental study using eicosane as the base material

Recently, studying phase change materials (PCMs) has brought many researchers' attention to be applied in thermal energy storage and battery thermal management (BTM) applications. Nano-materials have been used recently to improve the advantages of the PCM which makes them suitable materials to be used in thermal management systems. Moreover, the selection of the nanomaterials and the proper concentration of nano-particles in PCM affects the thermophysical characteristics of PCM. According to the fact that PCM requires to be thermally stable, the principal aim of this study is to analyze the thermal stability of PCMs composites by loading different mass fractions of CuO nano-particles. In order to add nano-particles to the eicosane-based PCM, a two-step method has been used. The thermal stability of the Nano-enhanced phase change materials (NePCM) has been measured by using the thermogravimetric analyzer. Results demonstrated that 0.5 wt% is the best value of additive nano-particle which showed a remarkable increment in thermal stability. Therefore, all the presented results indicate the importance of selecting an optimal PCM nano-composite for various applications including NePCM-based thermal energy storage and BTM systems. The brand and model of the device used in this study are Hitachi and STA7000 respectively.

A comprehensive study of the effect of elevated temperature on the extractability and rate of exaggerated and exhaustive extractions of medical devices

The effectiveness of an elevated temperature on the thermodynamic and kinetic properties of the solvent extraction of medical devices is evaluated in this study. The main objective of the current work is to specifically address the question of how effective a temperature of 50 °C, relative to 37 °C, is in improving the extractability and rate of the exaggerated and exhaustive extractions of medical devices. The extractability at equilibrium is related to the extraction partition coefficient, while the extraction rate is related to the corresponding diffusion coefficient. The partition and diffusion coefficients (or the enthalpies of extraction and diffusional activation energies) of solid-liquid extractions for different polymeric materials, solvents, and types of extractables entities at different temperatures are compiled comprehensively from extensive publications in the literature. The collected partition and diffusion coefficients at different temperatures are used to derive the partition enthalpies and diffusional activation energies in this study. The combined 209 partition enthalpies and 262 diffusional activation energies are then used to calculate the ratios of the partition and diffusion coefficients, when the extraction temperature increases from 37 °C to 50 °C. It is concluded from the study that the maximum improvement in extracted chemical amount with this specific temperature increase is about 3-fold, but the median improvement is only 16%. The most probable improvement is 25%. The maximum improvement (or decrease) in extraction time is 3.2-fold by the change in the diffusional coefficient, but the median value is 1.9-fold. The most probable decrease in extraction time is 2.4-fold. The collected data also allow the calculation of the ratio of the diffusion coefficient for a 10 °C increase, and the results are compared with the “factor 10 rule” in the literature on the relationship between the diffusion coefficient and temperature. The explicit conclusions of the study certainly provide evidences (not assumptions) in designing practical and cost-effective exaggerated and exhaustive extractions in the chemical characterization of medical devices, taking into considerations of extraction cycle time, temperature-dependent chemical stability, and the number of repeated extractions.

Strategies of stabilization of zein nanoparticles containing doxorubicin hydrochloride

Hybrid nanoparticles made up of zein and various stabilizers were developed and characterized. In detail, a zein concentration of 2 mg/ml was blended with various amounts of different phospholipids or PEG-derivatives in order to obtain formulations with suitable physico-chemical properties for drug delivery purposes. Doxorubicin hydrochloride (DOX) was used as a model of a hydrophilic compound and its entrapment efficiency, release profile and cytotoxic activity were investigated. Photon correlation spectroscopy showed that the best formulations were obtained using DMPG, DOTAP and DSPE-mPEG2000 as stabilizers of zein nanoparticles, which were characterized by an average diameter of ~100 nm, a narrow size distribution and a significant time- and temperature-dependent stability. The interaction between protein and stabilizers was confirmed through FT-IR analysis, while TEM analysis showed the presence of a shell-like structure around the zein core. The release profiles of the drug from the zein/DSPE-mPEG2000 nanosystems, evaluated at two pHs (5.5 and 7.4), showed a prolonged and constant leakage of the drug. The encapsulation of DOX within zein/DSPE-mPEG2000 nanosystems did not compromise its biological efficacy, demonstrating the potential application of these hybrid nanoparticles as drug carriers.

Ab initio prediction of temperature-dependent stability of heterogeneous B19′ phase in TiNi alloy using atomistically informed Eshelby’s ellipsoidal inclusion

In this study, we energetically predicted the temperature-dependent stability of the heterogeneous B19′ phase in the B2 matrix of TiNi alloys using density functional theory (DFT) and phonon analysis informed Eshelby’s ellipsoidal inclusion. The temperature-dependent eigenstrains and elastic constants for Eshelby’s ellipsoidal inclusion were calculated using DFT and phonon analysis under a quasi-harmonic approximation. The stable orientation of the disk-shaped B19′ phase in the B2 matrix and its total strains were evaluated with respect to temperature using Eshelby’s ellipsoidal inclusion analysis. Using the total strains, the elastically deformed atomic structure of the heterogeneous B19′ phase in the B2 matrix was determined, and its temperature-dependent free energy was calculated using DFT calculations and phonon analysis. Comparing the temperature-dependent free energies of the B2 and elastically deformed B19′ structures, we successfully predicted that the transformation between the two phases occurs at 300 K, which agrees with experimental observations. Moreover, it is shown that the temperature-dependent difference in the elastic constants between the B19′ phase and B2 matrix influences the phase transformation, which is the origin of the shape-memory effect of TiNi alloy.

Reversible switching between two common protein folds in a designed system using only temperature

Naturally occurring metamorphic proteins have the ability to interconvert from one folded state to another through either a limited set of mutations or by way of a change in the local environment. Here, we show in a designed system that it is possible to switch reversibly between two of the most common monomeric folds employing only temperature changes. We demonstrate that a latent 3α state can be unmasked from an α/β-plait topology with a single V90T amino acid substitution, populating both forms simultaneously. The equilibrium between these two states exhibits temperature dependence, such that the 3α state is predominant (>90%) at 5°C, while the α/β-plait fold is the major species (>90%) at 30°C. We describe the structure and dynamics of these topologies, how mutational changes affect the temperature dependence, and the energetics and kinetics of interconversion. Additionally, we demonstrate how ligand-binding function can be tightly regulated by large amplitude changes in protein structure over a relatively narrow temperature range that is relevant to biology. The 3α/αβ switch thus represents a potentially useful approach for designing proteins that alter their fold topologies in response to environmental triggers. It may also serve as a model for computational studies of temperature-dependent protein stability and fold switching.

Physicochemical Stability of Generic Thiotepa Concentrate and Ready-to-Administer Infusion Solutions for Conditioning Treatment

The objective of this study was to determine the physicochemical in-use stability of recently approved Thiotepa Riemser concentrate in the original vial and diluted ready-to-administer (RTA) infusion solutions in prefilled glucose 5% and 0.9% NaCl polyolefin bags. Thiotepa Riemser 10 mg/mL concentrates and infusion solutions (1 mg/mL, 2 mg/mL, 3 mg/mL) were prepared in triplicate and stored at 2-8 °C or 25 °C for 14 days. Thiotepa concentrations were determined using a stability-indicating RP-HPLC assay. In parallel, pH and osmolality were measured. Sub-visible particles were counted on day 0 and 14. Thiotepa Riemser concentrate was revealed to be stable for 14 days when stored at 2-8 °C, or for 24 h when stored at 25 °C. Thiotepa concentrations in infusion solutions stored at 2-8 °C remained above 95% of the initial concentrations for at least 14 days, regardless of the type of vehicle solution. When stored at 25 °C, thiotepa infusion solutions in glucose 5% proved to be physicochemically stable for 3 days (1 mg/mL), 5 days (2 mg/mL) or 7 days (3 mg/mL). Thiotepa infusion solutions in 0.9% NaCl remained physicochemically stable for 5 days (1 mg/mL) or 7 days (2 mg/mL, 3 mg/mL). At these points in time, the specification limit of ≤0.6% monochloro-adduct was fulfilled. In parallel, an elevation of the pH values was registered. Thiotepa concentrates and infusion solutions should be stored at 2-8 °C due to temperature-dependent physicochemical stability, and for microbiological reasons. Glucose 5% infusion solution is recommended as a diluent, and stability-improving nominal 2 mg/mL to 3 mg/mL thiotepa concentrations should be obtained.

Investigating the thermal stability of ultra-small Ag, Au and AuAg alloy nanoparticles embedded in a silica matrix.

Thermal growth kinetics of embedded bimetallic (AuAg/SiO2) nanoparticles are explored and compared with their monometallic (Au/SiO2 and Ag/SiO2) counterparts, as their practical applicability demands stability and uniformity. The plasmonic properties of these nanoparticles (NPs) significantly improve when their size falls in the ultra-small region (diameter < 10 nm), owing to their large active surface area. Interestingly, the bimetallic NPs exhibit better optical properties and structural stability as compared to their monometallic counterparts. This calls for a thorough understanding of the nucleation and temperature-dependent growth to ensure size stability against thermal coarsening that most bimetallic NPs completely lack. Herein, the atom beam sputtered AuAg NPs are systematically analysed over a wide range of annealing temperatures (ATs), and the results are compared with those of Au and Ag NPs. The X-ray photoelectron spectroscopy spectra and other experimental results confirm the formation of AuAg alloy NPs inside the silica matrix. Furthermore, techniques like transmission electron microscopy and grazing-incidence small-/wide-angle X-ray scattering were used to explore the temperature-dependent structural and morphological stability of the NPs. Our results show that the deposited AuAg NPs retain their spherical shape and remain as an alloy for the entire range of ATs. When the AT increases from 25 °C to 800 °C, the size of the NPs also increases from 3.5 to 4.8 nm; beyond that, their size grows substantially to 13.6 nm at 900 °C. We observed that the NPs remain in the ultra-small size range (∼5 nm) until an AT of 800 °C. Beyond that Ostwald ripening is ascribed to be the major cause of particle growth, resulting in an active surface area loss. Based on the outcomes, a three-step nucleation and growth mechanism is proposed.

Analysis methods to determine the bound-state beta-decay half-life of Thallium-205

Bound-state β−-decay is an exotic decay mode that produces temperature-dependent stability in nuclei. A striking example is 205Tl, in part because of its impact on the 205Pb/204Pb cosmochronometer—a short-lived ra-dionuclide clock that can provide unique constraints on s process material in the early solar system. The bound-state β−-decay of 205Tl was measured at GSI, where fully stripped 205Tl81+ ions were produced and stored in the Experimental Storage Ring. Decay occurred during storage producing increased 205Pb daughters with increased storage time. This contribution briefly outlines the experiment and describes analytical corrections required to extract the half-life.

Theory of shallow and deep boron defects in 4H -SiC

Abstract Despite advances toward improving the quality of $p$-type 4H-SiC substrates and layers, we still have no model capable of accounting for the multitude of boron-related optical, junction, and paramagnetic resonance experiments available in the literature. A conspicuous puzzle is the observation of two shallow boron defects with rather distinct axial orientations as found by electron paramagnetic resonance (EPR) and electron nuclear double resonance (ENDOR) data. This feature is not observed in material doped with other group-III elements. Another open issue involves conflicting conclusions from photoluminescence and EPR studies of a deeper boron center, which has been linked to rather distinct models, either based on substitutional or vacancy-related boron defects. We unlock these and other problems by means of first-principles calculations, where the temperature-dependent stability, the electronic activity, and the paramagnetic response of boron defects in 4H-SiC are investigated.

Near-Unity Photoluminescence Quantum Yield of Green-Emitting Graded-Alloy Core/Shell Giant Quantum Dots by z-Type Ligand Passivation for Display Applications

As-synthesized, green-emitting graded-alloy core/shell “giant” quantum dots have outstanding properties that can be utilized for different optoelectronic applications. But often, defects arise upon nonuniform growth of the shell. These surface defects affect the photoluminescence quantum yield (PLQY), lifetime, and stability of the green-emitting graded-alloy core/shell “giant” quantum dots. So, to overcome these surface traps, the graded-alloy core/shell g-QDs were passivated with z-type ligands (ZnCl2, CdCl2, and MgCl2). The change in the PLQY, lifetime, and photoluminescence emission confirmed that the z-type ligands are passivating the trap states of g-QDs by bonding with an unsaturated chalcogenide atom on the surface, and this was confirmed by X-ray photoelectron spectroscopy. All three cases (treated with ZnCl2, CdCl2, and MgCl2) showed outstanding enhancement in the photoluminescence quantum yield. Fascinatingly, the ZnCl2-treated g-QDs showed maximum enhancement in the PLQY from 62% to unity. Furthermore, the photostability test was performed under continuous UV-light irradiation for 24 h, which clearly showed superior photostability. Moreover, the temperature-dependent stability of untreated and treated g-QDs was studied from 10 to 90 °C. Furthermore, the green-emitting down-converted LED was fabricated by utilizing ZnCl2-treated g-QDs, which show great potential for display application.

Short-range order and phase stability of CrCoNi explored with machine learning potentials

We present an analysis of temperature-dependent atomic short-range ordering and phase stability of the face-centered cubic CrCoNi medium-entropy alloy employing a combination of ab initio calculations and on-lattice machine learning interatomic potentials. Temperature-dependent properties are studied with canonical Monte Carlo simulations. At around 975 K a phase transition into an ordered $\mathrm{Cr}{(\mathrm{Ni},\mathrm{Co})}_{2}$ phase (${\mathrm{MoPt}}_{2}$-type) is found. This hitherto not reported state has an ordering energy twice as large than the ordered structures previously suggested. We show that magnetism is not responsible for the observed chemical ordering.

Interface-engineered molybdenum disulfide/porous graphene microfiber for high electrochemical energy storage

Fiber-shaped supercapacitors (F-SCs) have received great interests in future portable electronics and wearable industries due to their high charging capacity, exceptional weavability and long lifespan. However, the stacked micro/nano-structure and poor faradaic activity of fibrous electrode that severely restrict the ion dynamic transport and redox charge storage bring obstacles of low energy density and practical applications. Herein, we report a novel F-SCs electrode made of hierarchical-ordered molybdenum disulfide/porous graphene core-shell microfiber (MoS2/PGF). The MoS2/PGF exhibits highly conductive porous core, large electroactive shell, C-Mo chemical bonds bridge and interface-engineered structure, creating smooth channels and exposed surface for boosting ion kinetics and faradic charge transfer. Significantly, the MoS2/PGF presents high capacitance of 1093 mF cm−2 and steady cycling property in H3PO4 aqueous solution. Moreover, the MoS2/PGF assembled solid-state F-SCs show large energy density of 85.4 µWh cm−2, temperature-dependent stability and good bending capability. Given those outstanding advantages, the F-SCs can be integrated into flexible substrates to power wearable electronic devices, which will remarkably contribute to the development of new energy technology and carbon neutrality fields.

A Fast and Robust Method for Predicting the Phase Stability of Refractory Complex Concentrated Alloys using Pairwise Mixing Enthalpy

The ability to predict the composition- and temperature-dependent stability of refractory complex concentrated alloys (RCCAs) is vital to the design of high-temperature structural alloys. Here, we present a model based on first-principles calculations to predict the thermodynamic stability of multicomponent equimolar solid solutions in a high-throughput manner and apply it to screen over 20,000 compositions. We develop a database that contains pairwise mixing enthalpy of 17 refractory metals using density-functional theory (DFT)-based total energy calculations. To these, we fit thermodynamic solution models that can accurately capture the mixing enthalpy of multicomponent BCC solid solutions. By comparing their energy with DFT-calculated enthalpy of intermetallics from the Materials Project database and using convex hull analyses, we identify the stable phase of any RCCA as a function of temperature. The predicted stability of NbTiZr, NbTiZrV, and NbTiZrVM(M= Mo,Ta,Cr) systems as a function of temperature agree well with prior experimental observations. We apply our model to predict the phase evolution in NbVZr-Tix (0 < x < 1), which is confirmed experimentally using a high-throughput, laser deposition-based synthesis technique. This method provides a fast and accurate way to estimate the phase stability of new RCCAs to expedite their experimental discovery.

FLOWERING LOCUS M isoforms differentially affect the subcellular localization and stability of SHORT VEGETATIVE PHASE to regulate temperature-responsive flowering in Arabidopsis

Temperature is an important environmental cue that affects flowering time in plants. The MADS-box transcription factor FLOWERING LOCUS M (FLM) forms a heterodimeric complex with SHORT VEGETATIVE PHASE (SVP) and controls ambient temperature-responsive flowering in Arabidopsis. FLM-β and FLM-δ, two major splice variants produced from the FLM locus, exert opposite effects on flowering, but the molecular mechanism by which the interaction between FLM isoforms and SVP affects temperature-responsive flowering remains poorly understood. Here, we show that FLM-β and FLM-δ play important roles in modulating the temperature-dependent behavior, conformation, and stability of SVP. Nuclear localization of SVP decreases as temperature increases. FLM-β is required for SVP nuclear translocation at low temperature, whereas SVP interacts with FLM-δ mainly in the cytoplasm at high temperature. SVP preferentially binds to FLM-β at low temperature in tobacco leaf cells. SVP shows high binding affinity to FLM-β at low temperature and to FLM-δ at high temperature. SVP undergoes similar structural changes in the interactions with FLM-β and FLM-δ; however, FLM-δ likely causes more pronounced conformational changes in the SVP structure. FLM-δ causes rapid degradation of SVP at high temperature, compared with FLM-β, possibly via ubiquitination. Mutation of lysine 53 or lysine 165 in SVP causes increased abundance of SVP due to reduced ubiquitination of SVP and thus delays flowering at high temperature. Our findings suggest that temperature-dependent differential interactions between SVP and FLM isoforms modulate the temperature-responsive induction of flowering in Arabidopsis.

Temperature-dependent residual stress and thermal stability studies of multilayer HF-CVD diamond coatings on RB-SiC

Structurally graded multilayer (ML) diamond coatings were deposited on reaction bonded silicon carbide (RB-SiC) using a hot filament chemical vapour deposition (HF-CVD) system via two different routes: a continuous process (C-ML) and a three-step intermittent process (Ix-ML, x being the number of steps). In this study, the temperature-dependent residual stresses and thermal stabilities of the C-ML and Ix-ML coatings after annealing at 100° intervals from 100 °C–800 °C were investigated. Scanning electron microscopy, 2D/3D Raman mapping, cluster analysis, and sp2/sp3 ratio computations were carried out at all stages and the results were compared. The residual stresses of the as-deposited coatings, I1-ML, I2-ML, I3-ML, and C-ML, were compressive with values of −1.09 GPa, −0.90 GPa, −0.62 GPa and −1.35 GPa, respectively, which progressively shifted to the tensile regime on annealing and exhibited values of 0.50 GPa, 0.50 GPa, 0.61 GPa and 1.75 GPa respectively, after annealing at 700 °C. The sp2/sp3 ratios of the C-ML and I3-ML coatings dropped from 0.94% to 0.54% and 1.07% to 0.54%, respectively, as the annealing temperature increased from 100 °C to 700 °C. All coatings were completely oxidised at 800 °C except I3-ML, where patches of the original coating persisted even after annealing at 800 °C.