Temperature Dependence Of Conductivity Research Articles

Contribution of strong electron-phonon interaction in the transport properties of La0.8Ca0.2Mn0.5Ni0.5O3 system

La0.8Ca0.2Mn0.5Ni0.5O3 NTC (negative thermal coefficient) thermo-sensitive material was prepared using a conventional solid-state reaction method. From the structural results, we found that the material is pure and crystallizes in the orthorhombic structure with a Pnma space group. It is found that the La0.8Ca0.2Mn0.5Ni0.5O3 ceramic can be used as an NTC thermistor compound in specific temperature sensors and attenuators. Based on Holsten's theory, detailed electrical investigations concerning the nature of the activated small polaron hopping mechanism were reported. The temperature dependence of the DC conductance was used to determine the electrical conduction processes that govern the transport properties of La0.8Ca0.2Mn0.5Ni0.5O3. Hence, the DC mechanisms exhibit changes from the variable range hopping at very low temperatures to the non-adiabatic small polaronic hopping at T = 210 K. In the intermediate temperature range, the semiconductor behavior of La0.8Ca0.2Mn0.5Ni0.5O3 was attributed to the contribution of the tunneling transport process. At various temperatures, the conductance spectra were discussed based on Jonscher and Bruce's laws. Contributions of the overlapping-large-polaron-tunneling, the correlated barrier hopping, the quantum mechanical tunneling, and the non-overlapping small polaron tunneling mechanisms to the transport properties were observed in the dispersive region of the conductance spectra. In addition, Summerfield scaling and corrected Summerfield scaling approaches prove that the charge mobility is temperature-dependent. The positive value of the correction parameter α = 1.2 confirms the presence of interactions in the studied sample.

Influence of part temperature on in-situ monitoring of powder bed fusion of metals using eddy current testing

AbstractPowder bed fusion of metals (PBF-LB/M) is currently the most widely adopted additive manufacturing technology for the fabrication of metal parts. However, the inconsistent quality of PBF-LB/M-manufactured parts and high costs for part certification are impeding wider industrial adoption. In-situ monitoring technologies are expected to enable process control in order to ensure consistent quality, and to replace some of the post-process inspection steps, therefore, reducing part certification costs. Eddy current testing (ECT) is a standardized nondestructive testing technique, which can be used as an in-situ monitoring technology to measure the part quality during the PBF-LB/M build cycle. However, the process-induced complex temperature fields in PBF-LB/M parts during the build cycle are among the most relevant disturbances due to the temperature dependence of the electrical conductivity. This study investigates the process-induced temperature influence on in-situ monitoring of relative density using ECT. Parts made from AlSi10Mg were manufactured on a PBF-LB/M machine and the build cycle was monitored using ECT and an infrared camera, which was used to extract the part surface temperature right before the ECT measurement. The results demonstrate that the temperature increase of the parts during the build cycle decreases the electrical conductivity independently of the relative part density, which was measured via micro-computed tomography. Therefore, a temperature compensation method was proposed and applied demonstrating that a layer-to-layer difference of 0.15 % relative density can be detected via ECT. Consequently, it has been demonstrated that ECT is an effective in-situ monitoring technology for PBF-LB/M, even in the presence of temperature disparities within parts.

Thermal inspection of hybrid nanofluid flows over a stretched cylinder at an oblique stagnation point with variable characteristics

AbstractThe enhanced thermal characteristics of hybrid nanofluids make them more versatile compared to conventional fluids. These improved thermal properties render hybrid nanomaterials highly practical for a wide range of applications, including solar systems, energy production, and cooling processes. In line with this perspective, the current study concentrates on evaluating the thermal performance of two unique hybrid nanofluid flows that impinge obliquely on a stretched cylinder. Two base fluids, FC‐77 and a binary mixture of water and ethylene glycol (50:50)%, have been considered, with the addition of nanoparticles such as single‐walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs). The said model's novelty is enhanced by the temperature dependent viscosity and thermal conductivity. Appropriate transformations are applied to derive a system of ordinary differential equations (ODEs), which are then solved numerically using the bvp4c method. A thorough examination is conducted on the physical phenomenon of pertinent parameters, accompanied by graphical representations. The results revealed that, for the FC‐77 coolant‐based hybrid nanofluid, mounting the particle volume fraction leads to a significant reduction in temperature distribution. Additionally, it is perceived that the presence of a variable viscosity parameter causes a reduction in the surface drag coefficient as well as the axial and tangential velocities. The validity of the proposed flow model is demonstrated by comparing the results with those from an earlier study.

Applications of Nano-biofuel cells for Reiner-Philippoff nanoparticles with higher order slip effects.

Owing to advanced thermal features and stable properties, scientists have presented many novel applications of nanomaterials in the energy sectors, heat control devices, cooling phenomenon and many biomedical applications. The suspension between nanomaterials with microorganisms is important in biotechnology and food sciences. With such motivations, the aim of current research is to examine the bioconvective thermal phenomenon due to Reiner-Philippoff nanofluid under the consideration of multiple slip effects. The assessment of heat transfer is further predicted with temperature dependent thermal conductivity. The radiative phenomenon and chemical reaction is also incorporated. The stretched surface with permeability of porous space is assumed to be source of flow. With defined flow constraints, the mathematical model is developed. For solution methodology, the numerical simulations are worked out via shooting technique. The physical aspects of parameters are discussed. It is claimed that suggested results claim applications in the petroleum sciences, thermal systems, heat transfer devices etc. It has been claimed that the velocity profile increases due to Bingham parameter and Philippoff constant. Lower heat and mass transfer impact is observed due to Philippoff parameter.

Development of High-Performance Polyindole/Silicon Carbide Nanocomposites for Optoelectrical and Sensing Applications.

In this study, silicon carbide (SiC)-reinforced polyindole (PIn) nanocomposites were prepared by a simple in situ polymerization method. The successful reinforcement of the nanofiller within the host matrix was characterized using different analytical techniques. The chemical bonding of SiC in the polymer was identified by the characteristic peak around 800 cm1 using Fourier transform infrared spectroscopy (FT-IR). The increment in intensity of the absorption and enhanced crystallinity of the samples upon the addition of nanofillers were analyzed using UV-vis spectroscopy and X-ray diffraction (XRD). The prepared specimens showed reduced optical bandgap energy (3.188 eV) and Urbach energy (2.315 meV) with an improved refractive index (2.348). The effect of nanoparticles on the surface morphology of the nanocomposites was studied using scanning electron microscopy (SEM), and a uniform dispersion of fillers in the matrix was found for PInSiC7. A high-resolution transmission electron microscopy (HR-TEM) revealed the shape and average particle size of the sample. X-ray electron spectroscopy (XPS) measurements confirmed the formation of the nanocomposite by exhibiting the presence of all elements in the corresponding spectra. The thermal stability and glass transition temperature of the nanocomposites were significantly improved with the addition of SiC. The temperature-dependent AC conductivity, dielectric parameters, complex impedance, and electrical modulus were also evaluated using an impedance analyzer. The increased electrical characteristics of the PInSiC7 sample can be attributed to the uniform spread and strong synergetic interaction of SiC with PIn. The results thus showcased the potential of the samples for use in optical and energy storage applications. This study was also extended to understand the ammonia sensing properties, which make it possible to design and develop gas sensors using the PInSiC nanocomposites.

Temperature dependent dielectric relaxation and current conduction mechanism in Ba and Ti co-doped bismuth ferrite ceramic

Temperature dependent dielectric relaxation and current conduction mechanism in Ba and Ti co-doped bismuth ferrite ceramic

Temperature-dependent conduction and transport mechanisms in pure and Zn-doped MgO nanomaterials

Temperature-dependent conduction and transport mechanisms in pure and Zn-doped MgO nanomaterials

Deep-potential enabled multiscale simulation of gallium nitride devices on boron arsenide cooling substrates

High-efficient heat dissipation plays critical role for high-power-density electronics. Experimental synthesis of ultrahigh thermal conductivity boron arsenide (BAs, 1300 W m−1K−1) cooling substrates into the wide-bandgap semiconductor of gallium nitride (GaN) devices has been realized. However, the lack of systematic analysis on the heat transfer across the GaN-BAs interface hampers the practical applications. In this study, by constructing the accurate and high-efficient machine learning interatomic potentials, we perform multiscale simulations of the GaN-BAs heterostructures. Ultrahigh interfacial thermal conductance of 260 MW m−2K−1 is achieved, which lies in the well-matched lattice vibrations of BAs and GaN. The strong temperature dependence of interfacial thermal conductance is found between 300 to 450 K. Moreover, the competition between grain size and boundary resistance is revealed with size increasing from 1 nm to 1000 μm. Such deep-potential equipped multiscale simulations not only promote the practical applications of BAs cooling substrates in electronics, but also offer approach for designing advanced thermal management systems.

Negative Temperature Coefficient Properties of Natural Clinoptilolite

Negative temperature coefficient (NTC) materials are usually based on ceramic semiconductors, and electrons are involved in their transport mechanism. A new type of NTC material, adequate for alternating current (AC) applications, is represented by zeolites. Indeed, zeolites are single charge carrier ionic conductors with a temperature-dependent electrical conductivity. In particular, electrical transport in zeolites is due to the monovalent charge-balancing cations, like K+, capable of hopping between negatively charged sites in the aluminosilicate framework. Owing to the highly non-linear electrical behavior of the traditional electronic NTC materials, the possibility to have alternative types of materials, showing linearity in their electrical behavior, is very desirable. Among different zeolites, natural clinoptilolite has been selected for investigating NTC behavior since it is characterized by high zeolite content, a convenient Si/Al atomic ratio, good mechanical strength due to its compact microstructure, and low toxicity. Clinoptilolite has shown a rapid and quite reversible impedance change under heating, characterized by a linear dependence on temperature. X-ray diffraction (XRD) has been used to identify the natural zeolite, to establish all types of crystalline phases present in the mineral, and to investigate the thermal stability of these phases up to 150 °C. X-ray photoelectron spectroscopy (XPS) analysis was used for the chemical characterization of this natural clinoptilolite sample, providing important information on the cationic content and framework composition. In addition, since electrical transport takes place in the zeolite free-volume, a Brunauer–Emmett–Teller (BET) analysis of the mineral has also been performed.

Magnetoelectric Properties of Aurivillius-Layered Perovskites

In the present work, we have synthesized rare-earth ion modified Bi4−xRExTi2Fe0.7Co0.3O12−δ (RE = Dy, Sm, La) multiferroic compounds by the conventional solid-state route. Analysis of X-ray diffraction by Rietveld refinement confirmed the formation of a polycrystalline orthorhombic phase. The morphological features revealed a non-uniform, randomly oriented, plate-like grain structure. The peaks evident in the Raman spectra closely corresponded to those of orthorhombic Aurivillius phases. Dielectric studies and impedance measurements were carried out. Asymmetric complex impedance spectra suggested the relaxation of charge carriers belonging to the non-Debye type and controlled by a thermally activated process. Temperature-dependent AC conductivity data showed a change of slope in the vicinity of the phase transition temperature of both magnetic and electrical coupling natures. Based on the universal law and its exponent nature, one can suppose that the conduction process is governed by a small polaron hopping mechanism but significant distortion of TiO6 octahedral. The doping of the A-sites with rare-earth element ions and changes in the concentrations of Fe and Co ions located on the B-sites manifested themselves in saturated magnetic hysteresis loops, indicating competitive interactions between ferroelectric and canted antiferromagnetic spins. The magnetic order in the samples is attributed to pair-wise interactions between adjacent Fe3+–O–Fe3+, Co2+/3+–O–Co3+/2+, and Co2+/3+–O–Fe3+ ions or Dzyaloshinskii–Moriya interactions among magnetic ions in the adjacent sub-lattices. As a result, enhanced magnetoelectric coefficients of 42.4 mV/cm-Oe, 30.3 mV/cm-Oe, and 21.6 mV/cm-Oe for Bi4−xDyxTi2Fe0.7Co0.3O12−δ (DBTFC), Bi4−xLaxTi2Fe0.7Co0.3O12−δ (LBTFC), and Bi4−xSmxTi2Fe0.7Co0.3O12−δ (SBTFC), respectively, have been obtained at lower magnetic fields (<3 kOe). The strong coupling of the Aurivillius compounds observed in this study is beneficial to future multiferroic applications.

Estimation of Ionic Impurities in Poly(propylene Glycol) Diacrylate Monomers/Liquid Crystal E7 Mixtures Using Dielectric Spectroscopy

The study investigated the effect of the molecular weight of three difunctional poly(propylene glycol) diacrylates on the temperature-dependent ionic conductivity of these monomers and their blends with an eutectic nematic liquid crystal mixture (E7). The results revealed two distinct regions. At low temperatures, ionic conduction can be described by the Vogel–Tamman–Fulcher (VTF) equation, while at high temperatures, the conductivity data follow the prediction of the Arrhenius model. The Arrhenius and VTF parameters and their corresponding activation energies were determined using the least squares method. In addition, a conductivity analysis based on an ionic hopping model is proposed. Estimates of ion concentrations and diffusion constants were calculated. It was found that both the ionic concentration and the diffusion constant decrease with the increase in the molecular weight of the monomers. The static dielectric permittivity decreases in the following order: TPGDA, PPGDA540, and PPGDA900. This can be explained by the higher dipole moment of TPGDA, which is caused by an enhanced volume density of carbonyl groups.

A study on temperature dependent dielectric relaxation behaviour and conduction mechanism of La and Ti co-doped bismuth ferrite

A study on temperature dependent dielectric relaxation behaviour and conduction mechanism of La and Ti co-doped bismuth ferrite

Physicochemical properties of ammonium acetate / propionic acid as a novel deep eutectic solvent and its binary mixtures with water in (298.15–353.15) K range

Emergence of deep eutectic solvents as potential replacements for volatile organic solvents has attracted interest of the scientific community in diverse fields of applications. Compared to ionic liquids, which exhibit similarity in many respects with this new class of green solvents, deep eutectic solvents (DESs) show low toxicity, and are easy to prepare from cheap and abundantly available starting materials. Knowledge of physicochemical properties of DESs is a prerequisite for their safe applications in technological fields and to understand the nature of interactions present in these systems. Although physicochemical properties of choline chloride based DESs are widely investigated, similar information on ammonium acetate based DESs is scant.In this work, a novel ammonium acetate/propionic acid deep eutectic solvent (AA/PA DES) is reported which is prepared by mixing ammonium acetate (AA) and propionic acid (PA) in the 1:3 mol ratio and characterized by FTIR, 1H and 13C NMR, TGA and DSC techniques. The density (ρ), sound velocity (u), viscosity (η) and conductivity (κ) of the pure DES and its binary mixtures with water are investigated over the entire composition range and temperatures (298.15–353.15) K. The excess properties, VmE, KSE, Δη, and ΔG*E are calculated and corelated using Redlich-Kister equation (RKE). Temperature dependence of conductivity and viscosity is satisfactorily described by the Vogel – Fulcher – Tamman (VFT) equation rather than Arrhenius equation. The pure DES shows a wide electrochemical potential window ranging from – 1000 mV to + 1000 mV, which coupled with its better solubilizing characteristics, could be exploited for electrochemical work.

Investigation of diabatic imparity involving asymmetric convection in two-dimensional longitudinal fins using lattice Boltzmann solver

This manuscript investigates the effect of diabatic imparity on two-dimensional (2-D) transient fins having naturally obtained non-linear variation of temperature-dependent conductivity. The diabatic imparity arises due to asymmetrical convection coefficient on the surfaces, implemented using different Biot numbers on each respective surface of the fin, which resembles pragmatic industrial applications. The transient solution of 2-D fin has been obtained using a Lattice Boltzmann (LB) solver, firstly, the suitability of 2-D LB formulation is established with the validity of the existing results, and subsequently extending the LB formulation for the present study. The numerical solution is determined under the two types of step-changing boundary conditions at the fin root having (i) heat flow and (ii) temperature. Results have been plotted graphically, and these include instantaneous isotherms, equilibrium isotherms, and threshold iso-temporal lines. Reported results facilitate the fin designer to examine the effect of diabatic imparity on the attainment of steady-state and occurrence of transverse temperature gradient on 2-D transient fin. The reported results provided are pertinent to the pragmatic application and are seldom reported in the literature. The outcomes of the present investigation are eminently informative to practising engineers and will serve as design monograms.

The influence of the volume concentration of hydrogen on the fine structure of the IR absorption spectra and conductivity features in congruent LiTaO3 crystals

A new method for changing the volume concentration of hydrogen in congruent LiTaO3 (lithium tantalate, LT) crystals has been studied. It has been established that pre-treatment of the sample in adipic acid significantly increases the volumetric concentration of hydrogen in the sample during subsequent annealing in a humid atmosphere at a relatively low annealing temperature. First of all, this preserves the LT single crystal in a single-domain state. In contrast to known methods for increasing the volumetric concentration of hydrogen, the proposed method affects the absorption coefficient of the sample in the optical range less than for a congruent LiNbO3 crystal. It has been shown that the type of IR absorption spectrum of OH− groups and the defect structure of the LT crystal significantly depend on the volume concentration of hydrogen in the sample. The study also analyzed the reasons for this effect. The temperature dependences of the electrical conductivity of LT samples with different hydrogen concentrations have been studied. It has been shown that the type of electronic conductivity of LT samples changes when the concentration of OH groups in the crystal increases significantly.

Nanoparticles hybridization in bidirectional flowing of Prandtl–Eyring material with temperature-dependent conductivity: A numerical approach

Due to the vast applications of nanofluids in hybrid cooling processes and their role in improving heat transfer in thermal systems, an attempt has been made to investigate the consequence of temperature-dependent thermal conductivity in the bidirectional flowing of Prandtl–Eyring (PE) hybrid nanomaterial. Zirconium dioxide (ZrO2) and copper (Cu) nanoparticles have been dispersed into an engine oil (EO) to create an effective hybrid nanomaterial. Viscous dissipation, magnetization, linear thermal radiation, and Ohmic heating mechanisms also influence the dynamics of the hybrid nanomaterial. The governing equations have been parameterized by using similarity transformations and the thermophysical properties of nanoparticles. Keller–Box simulations for the modeled problem have been conducted using an in-house code developed in MATHEMATICA. Convergence analysis has been presented and robust validation of the results has been performed to certify the accuracy of the numerical inspection. Post-processing of the results has been carried out by plotting temperature and velocity curves. Drag coefficient and Nusselt number have been formulated and analyzed in tabular forms. The rate of heat transfer is developed with the hybridization of ZrO2 and Cu nanoparticles into the base liquid, while drag forces are enhanced when utilizing PE material as the base liquid.

Thermal diffusivity of inclined magnetized Cross fluid with temperature dependent thermal conductivity: Spectral Relaxation scheme

Understanding and controlling the thermal transport phenomena are crucial in numerous applications. The current research emphasizes thermal diffusivity of an inclined magnetized Cross fluid with temperature-dependent thermal conductivity with a computational iterative spectral relaxation scheme. Cross mathematical model is employed to characterizes non-Newtonian behavior and to uncover viscoelastic properties of fluid. Flow is incorporated under temperature thermal influence and external inclined magnetic strength is considered for thermal variations. Various prominent factors, including cross index, magnetic field, inclination angle, temperature-dependent thermal conductivity are analyzed on the fluid's thermal diffusivity. The flow governing PDEs are converted into system of ODEs by using suitable transformation. Spectral relaxation computation scheme is then used for controlling the new set equations. SRM algorithm controlling subsystems is built through MATLAB. Numerical results are illustrated by MATLAB graphs. Physical quantities such as Sherwood numbers, Nusselt and skin friction coefficient are visually taken place through statistical graphs with two cases of imposed magnetic field. The results of this investigation shed light on how non-Newtonian fluids behave when exposed to temperature changes and magnetic fields and useful in understanding and leverage these effects for specific applications.

Phase transitions of choline dihydrogen phosphate: A vibrational spectroscopy and periodic DFT study.

Choline dihydrogen phosphate, [Chol][H2PO4], is a proton-conducting ionic plastic crystal exhibiting a complicated sequence of phase transitions. Here, we address the argument in the literature around the thermal properties of [Chol][H2PO4] using Raman and infrared microspectroscopy. The known structure of the low-temperature crystal, which contains the anti-conformer of [Chol]+ and hydrogen-bonded dimers of anions, was used to do periodic density functional theory calculations of the vibrational frequencies. Raman spectra indicate that the solid-solid transition at 20 °C is linked to a conformational change to the gauche [Chol] conformer with a concurrent local rearrangement of the anions. The distinct bands of lattice modes in the low-frequency range of the Raman spectra vanish at the 20 °C transition. Given the ease with which metastable crystals can be produced, Raman mappings demonstrate that a sample of [Chol][H2PO4] at ambient temperature can contain a combination of anti- and gauche conformers. Heating to 120 °C causes continuous changes in the local environment of anions rather than melting as suggested by a recent calorimetric investigation of [Chol][H2PO4]. The monotonic change in vibrational spectra is consistent with earlier observations of a very small entropy of fusion and no abrupt jump in the temperature dependence of ionic conductivity along the phase transitions of [Chol][H2PO4].

CONDUCTIVITY OF HAFNIUM OXIDE LMS OBTAINED BY ELECTRON BEAM SPUTTERING

Films of hafnium oxide HfOx with a thickness of about 40 nm were obtained by electron beam sputtering at di erent oxygen ow rates in the chamber. The electrophysical properties of lms in air and vacuum were studied. It is shown that the temperature dependences of lm conductivity, measured in vacuum inthe temperature range from 20 to 180 ◦C, have an activation character with an activation energy of 0.82 ±0.02 eV. It has been suggested that charge transfer in the resulting lms is determined by the activation of electrons into the conduction band from the donor level associated with oxygen vacancies. It was found that the conductivity of lms in air changes greatly with varying oxygen ow, while in vacuum the conductivity is practically independent of the oxygen ow. This indicates signi cant di erences in the surface properties of lms obtained at di erent oxygen ows in the chamber during the deposition process.

Thermal Conductivity of MgSiO3‐H2O System Determined by Machine Learning Potentials

AbstractThermal conductivity plays a pivotal role in understanding the dynamics and evolution of Earth's interior. The Earth's lower mantle is dominated by MgSiO3 polymorphs which may incorporate trace amounts of water. However, the thermal conductivity of MgSiO3‐H2O binary system remains poorly understood. Here, we calculate the thermal conductivity of water‐free and water‐bearing bridgmanite, post‐perovskite, and MgSiO3 melt, using a combination of Green‐Kubo method with molecular dynamics simulations based on a machine learning potential of ab initio quality. The thermal conductivities of water‐free bridgmanite and post‐perovskite overall agree well with previous theoretical and experimental studies. The presence of water mildly reduces the thermal conductivity of the host minerals, significantly weakens the temperature dependence of the thermal conductivity, and reduces the thermal anisotropy of post‐perovskite. Overall, water reduces the thermal conductivity difference between bridgmanite and post‐perovskite, and thus may attenuate lateral heterogeneities of the core‐mantle boundary heat flux.