Temperature Dependence Of Conductivity Research Articles

Analysis of a film-forming amine response in impedance spectra

In this study, a detailed analysis of the dielectric response of a film-forming amine (1,3 N-oleyl propanediamine (OLDA)) in impedance spectra is presented, addressing both "bulk" OLDA and adsorbed OLDA layer on a carbon steel surface. The dielectric response of the “bulk” OLDA in the absence of electrolyte over an extensive temperature range (-150°C to 50°C) was explored by broadband dielectric spectroscopy (BDS). Subsequently, the response of the OLDA adsorbed layer on the steel surface was analysed by electrochemical impedance spectroscopy (EIS), for various immersion times (2 - 100 min) and temperatures (25 - 75°C) in an aqueous NaCl solution.Impedance spectra (BDS and EIS), interpreted through the complex conductivity formalism, showed a resistive behaviour in the mid-frequency range and a capacitive behaviour at higher frequencies. The high frequency capacitive response in EIS spectra was shown to contain contributions from the OLDA layer and from the electrochemical double layer, as well. The temperature dependency of the OLDA conductivity was found to be similar to the temperature dependency of the electrolyte resistance, suggesting that the electrolyte (water and ions) crossed the OLDA layer to reach the steel surface. The presence of gauche defects in the OLDA alkyl chain, revealed by polarization modulation infrared reflection absorption spectroscopy (PM-IRRAS) analyses, may be a contributing factor to the disorder in the adsorbed layer, facilitating electrolyte infiltration.

An analytical study of thermal environment’s effect on the free vibration of FGM double curved FG shells

The main objectif of this work is to examine the thermal environment’s effect of on the free vibration of double curvature shells made of functionally graded materials. A new mathematical model based on higher order shear deformation theory, is developed to incorporate the influence of dependent and independent thermal stresses, which can be uniform, linear, nonlinear, or sinusoidal on the mechanical properties of the double curvature shell. Two material couples, ( S i 3 N 4 / SUS 304 , ZrO 2 /Ti‐6Al‐4V ) , are considered as progressive materials, accounting for temperature-dependent and temperature-independent heat conduction and material properties in the thickness direction. The temperature field is assumed to be uniform across the shell surface but varies only in the thickness direction. The accuracy of the analytical results is validated by comparing them with existing literature results for functionally graded material (FGM) shells with infinite radii under dependent and independent temperature conditions. The study aims to demonstrate the thermal effects on material composition, as well as various specific geometric shapes such as plates, cylinders, spheres and ellipses and how different temperature laws influence the frequencies of vibrating double curvature FGM shells. Both existing theories accurately predict temperature-independent and temperature-dependent vibration responses of the shells. By verifying and comparing the results with the literature, a better agreement is achieved, thereby paving the way for further research in this field.

Tailoring thermoelectric performance of n-type Bi2Te3 through defect engineering and conduction band convergence

Bi2Te3, an archetypical tetradymite, is recognised as a thermoelectric (TE) material of potential application around room temperature. However, large energy gap (ΔEc ) between the light and heavy conduction bands results in inferior TE performance in pristine bulk n-type Bi2Te3. Herein, we propose enhancement in TE performance of pristine n-type Bi2Te3 through purposefully manipulating defect profile and conduction band convergence mechanism. Two n-type Bi2Te3 samples, S1 and S2, are prepared by melting method under different synthesis condition. The structural as well as microstructural evidence of the samples are obtained through powder x-ray diffraction and transmission electron microscopic study. Optothermal Raman spectroscopy is utilized for comprehensive study of temperature dependent phonon vibrational modes and total thermal conductivity ( κ ) of the samples which further validates the experimentally measured thermal conductivity. The Seebeck coefficient value is significantly increased from 235 μVK−1 (sample S1) to 310 μVK−1 (sample S2). This is further justified by conduction band convergence, where ΔEc is reduced from 0.10 eV to 0.05 eV, respectively. To verify the band convergence, the double band Pisarenko model is employed. Large power factor (PF) of 2190 μWm−1K−2 and lower κ value leading to ZT of 0.56 at 300 K is gained in S2. The obtained PF and ZT value are among the highest values reported for pristine n-type bulk Bi2Te3. In addition, appreciable value of TE quality factor and compatibility factor (2.7 V−1) at room temperature are also achieved, indicating the usefulness of the material in TE module.

Small polaron hopping and tunneling transport in Maxwell–Wagner relaxation dominated Al2O3/TiO2 subnanometric laminates

Maxwell–Wagner relaxation dominated Al2O3/TiO2 nanolaminates (ATA NLs) have recently demonstrated their potential for high-density energy storage applications. In this report, we have unraveled the defect-mediated transport mechanisms prevailing in Al2O3/TiO2 sub-nanometric laminates. Temperature-dependent ac conductivity measurements revealed the signature of small polaron hopping in TiO2 active layers and trap-assisted tunneling transport through Al2O3 barrier layers, which was corroborated by resonant photoelectron spectroscopy and temperature-dependent current–voltage measurement. The polaronic defect states, found ∼1 eV below the Fermi level, served as the hopping centers and leakage paths for current. The signature of quantum tunneling transport and the negative differential conductance observed toward higher electric field was attributed to the splitting of delocalized minibands. These transport properties of Al2O3/TiO2 nanolaminates will help in tailoring these materials for next-generation storage capacitors.

Novel crosslinked gum tragacanth electrolyte with enhanced thermal, mechanical and water resistive properties

Although electrolytes prepared from natural substances have taken up research towards a greener future, practical difficulties in their mechanical and water resistive properties are yet to be addressed by many. In this current paper, a natural gum tragacanth is graft copolymerized with tertiary butyl acrylate utilising glutaraldehyde as the crosslinker and ascorbic acid and potassium persulfate as the initiators. From the TGA analysis, enhanced thermal stability is observed in the crosslinked membrane. The DSC analysis reveals that the crosslinked gum exhibits a glass transition temperature (Tg) of 66 °C and a melting temperature (Tm) of 86 °C. The water uptake of the crosslinked membrane was found to be lower than the pure non-crosslinked membrane. The stress-strain curves of the crosslinked electrolyte showed a tensile strength of 3.58Mpa and a percent elongation of 302%. The effect of the crosslinker glutaraldehyde and the ionic salt lithium nitrate is studied with the help of XRD and FTIR. The electrolyte is characterised to be a good ionic conductive membrane as its conductivity value is found to be 4.72 ×10−4 Scm−1 through EIS measurements. The Arrhenius behaviour of temperature-dependent conductivity was studied and the activation energy values for all the films were calculated.

Molecular dynamics study of the temperature dependence of viscosity and thermal conductivity of molten salts FLiNaK and FLiNaK with LaF3 or NdF3

In this work, the temperature dependence of the viscosity and thermal conductivity of molten systems FLiNaK and FLiNaK-MeF3 (Me = La, Nd) was studied using the molecular dynamics method with Born-Mayer-Huggins potential. The dependencies were obtained in the temperature range of 800 < T < 1020 K, as well as for the concentration of lanthanide fluoride additives up to 15 mol.%. The temperature behavior of these kinetic properties is explained based on an MD model of dynamic ionic connectivity. The main contribution to the connectivity of pure FLiNaK ions is made by Li-F ion pairs, and in the presence of LaF3 and NdF3 dissolved in the salt mixture, the connectivity in the system is supplemented by ion pairs formed by lanthanides with fluorine. Both viscosity and thermal conductivity decrease with increasing temperature and rise when lanthanide trifluorides are added to the molten salt.

Study of conduction mechanisms of InSeSb nano-chalcogenide alloys

The electrical conduction mechanisms for bulk samples of In0.1Se0.9−x Sb x (x = 0, 0.04, 0.08 and 0.12) nano-chalcogenide system, synthesized by the melt-quenching technique are investigated through current–voltage (I–V) characteristics. For the detailed study of conduction mechanism pellets of bulk samples are prepared. A thorough examination of electrical conductivity is done in the temperature range of 295–318 K and 0–50 V voltage range. From I–V measurements it is observed that samples are showing ohmic nature at lower field and non-ohmic nature at relatively higher field values. The temperature dependence of DC conductivity is analyzed using the Arrhenius relationship which is found to increase with Sb content. The value of activation energy and pre-exponential factor are calculated, which revealed that the conduction is due to the hopping of charge carriers among the localized states. Different parameters of Mott’s variable range hopping such as degree of disorder T 0, density of localized states N(E F), hopping distance (R hop), and hopping energy (W) are calculated. For the high field conduction process Poole–Frenkel, and Schottky processes are studied.

Электрофизические и температурные характеристики тонких слоёв квантовых точек Ag2S

This paper presents a study of the electrical properties of colloidal silver sulfide quantum dots thin films (Ag2S/SiO2 QDs) and silver sulfide quantum dots decorated with Au plasmon nanoparticles (Ag2S/SiO2/Au QDs). A study of the conductivity temperature dependences was carried out in the temperature range from 300 to 360 K. The activation energy values were obtained from linear approximations of the current-voltage characteristics in Arrhenius coordinates. It has been shown that decorating Ag2S/SiO2 QDs with Au plasmon nanoparticles leads to an increase in the band gap from 0.29 to 0.89 eV. In this work, the ideality factor is calculated and the main conductivity mechanisms of the presented thin-film structures are determined. It has been shown that decorating Ag2S/SiO2 QDs with Au plasmon nanoparticles leads to a change in the conductivity type. According to the Mott-Gurney model, the charge carriers mobility is calculated.

Crystal structure and dielectric properties of Ln2Ti2SiO9 (Ln = Pr and Nd)

Low loss and high dielectric constant materials are essentially desired for wide varieties of applications in electronics and communication technology. Herein the structure and dielectric properties of two titanosilicates, Ln2Ti2SiO9, for Ln = Pr3+ and Nd3+ are reported. Both materials are isostructural and have layered structure with layers of [LnTi2SiO9]3- and Ln3+ ions. Electrical properties of both have been analyzed by using the temperature and frequency dependent permittivity, loss, conductivity and modulus data. At room temperature, appreciable relative permittivity (35 for Nd2Ti2SiO9 and 22 for Pr2Ti2SiO9 over the frequency range of 100 Hz to 5 MHz) and low dielectric loss (like 0.007–0.03 at 100 Hz and 10−4-10−3 at 1 MHz). Analysis of dc-conductivity data of both compounds indicate that the conduction in both materials is due to the correlated barrier hopping (CBH) of polarons. The relaxation peak of modulus spectra indicates more non-Debye like relaxation in Pr2Ti2SiO9 than that in Nd2Ti2SiO9, and that is possibly due to increased correlation in the dynamics of hopping polarons in Pr2Ti2SiO9.

Effect of Eu and Mn co-doping on temperature dependent dielectric relaxation behaviour and electric conduction mechanisms of bismuth ferrite

Effect of Eu and Mn co-doping on temperature dependent dielectric relaxation behaviour and electric conduction mechanisms of bismuth ferrite

Tailoring the electric, dielectric and optical properties of template-free hydrothermally synthesized CuO nanostructures via Co doping

Facile template-free hydrothermal method was utilized for preparing CuO nanostructures (NSs) doped with Co element (Cu1-xCoxO (x = 0.0, 0.02, 0.04, 0.06 and 0.08)). A single-phase monoclinic crystal with changing in morphology from rod-to sphere-like nanoparticles was observed. The temperature dependency of DC electrical conductivity revealed that the shallow and deep donor levels are responsible for the DC conduction in low and high temperature ranges, respectively. The Ac electrical conductivity, dielectric constant and dielectric loss were also measured as functions in frequency and temperature. The frequency dependence of the AC conductivity was well represented by the Jonscher's universal power law. The AC conduction was governed by the Correlated Barrier Hopping model where the inter-well and intra-well hopping mechanisms contribute to the electrical conduction in the low and high frequency ranges, respectively. The activation energies and the barrier height decreased while the dielectric constant and dielectric loss increased with increasing the Co content. The relaxation and deformational polarizations predominate and the overall behavior of dielectric constant fits well with the Koops' model. The Cole-Cole plots indicated a decrease in the sample resistance with increasing temperatures and Co concentrations. UV–vis absorption spectra exhibited two peaks at wavelengths 252 and 323 nm. The optical energy gap was calculated using Tauc's equation and decrease from 2.24 to 2.1 eV with increasing the Co concentrations. The effect of Co-doping on CuO was explored for oxygen evolution reaction (OER) and found a decrease in the overvoltage (μ) about 50 mV at 0.08 ratios, which declares that the doping of Co element enhances the electrical conductivity and feasibility for further electrocatalytic improvement.

Structure and Properties of Na2S-SiS2-P2S5-NaPO3 Glassy Solid Electrolytes.

In the development of sodium all-solid-state batteries (ASSBs), research efforts have focused on synthesizing highly conducting and electrochemically stable solid-state electrolytes. Glassy solid electrolytes (GSEs) have been considered very promising due to their tunable chemistry and resistance to dendrite growth. For these reasons, we focus here on the atomic-level structures and properties of GSEs in the compositional series (0.6-0.08y)Na2S + (0.4 + 0.08y)[(1 - y)[(1 - x)SiS2 + xPS5/2] + yNaPO3] (NaPSiSO). The mechanical moduli, glass transition temperatures, and temperature-dependent conductivity were determined and related to their short-range order structures that were determined using Raman, Fourier transform infrared, and 31P and 29Si magic angle spinning nuclear magnetic resonance spectroscopies. In addition, the conductivity activation energies were modeled using the Christensen-Martin-Anderson-Stuart model. These GSEs appear to be highly crystallization-resistant in the supercooled liquid region where no measurable crystallization below 450 °C could be observed in differential scanning calorimetry studies. Additionally, these GSEs were found to be highly conducting, with conductivities on the order of 10-5 (Ω cm)-1 at room temperature, and processable in the supercooled state without crystallization. For all these reasons, these NaPSiSO GSEs are considered to be highly competitive and easily processable candidate GSEs for enabling sodium ASSBs.

New insights into how temperature affects the electrical conductivity of clay-free porous rocks

SUMMARY Geothermal energy is increasingly important for the global environment and for the sustainable development of our society. Electrical surveys are widely employed for the exploration of geothermal energy, because the electrical geophysical properties provide useful information about the fluids at depth. However, although quantitative interpretation of electrical survey data relies on the knowledge about the effects of temperature on the electrical properties of fluid-bearing rocks, it remains poorly understood about how temperature affects the electrical conductivity of clay-free porous rocks. We bridge this knowledge gap by measuring the electrical conductivity and porosity of five brine saturated clean Berea sandstones with temperature ranging between 25 and 140 °C, and analysing all the factors that impact the rock conductivity. We showed that the effects of surface conductivity on the temperature-dependent electrical conductivity can be negligible, whereas the temperature induced variation in the porosity and pore structure quantitatively characterized in terms of cementation exponent can be more significant. We also found that temperature affects the electrical conductivity of brine saturated Berea sandstones by impacting the brine conductivity, and the pore structure and porosity of the samples, with their importance in a descending order. The results have provided new insights into how temperature affects the electrical conductivity of clay-free porous rocks, and will help to improve the quantitative interpretation of electrical survey data for the exploration of geothermal energy.

Temperature dependences of thermal conductivity of solid heterogeneous crystalline and amorphous materials: An empirical approach to the description in the high-temperature region

This paper presents a detailed analysis of the thermal conductivity behaviors exhibited by a diverse array of nanostructured materials, ranging from multilayer graphene nanocomposites to semiconductor-based nanostructures such as Bi0.5Sb1.5Te3 and In0.53Ga0.47As composites. The investigation extends to superlattices, nanowires, and hybrid nanostructures, encompassing materials like hexagonal boron nitride flakes, iron oxide nanoporous films, and organic-inorganic hybrid materials. The thermal conductivity of these materials is characterized by distinct trends, with some showcasing crystal-like behavior and others demonstrating glass-like characteristics. The analysis employs empirical expressions to discern the contributions of phonons and diffusons in crystal-like materials and incorporates Peierls contributions and Arrhenius-type terms for glass-like behavior. Noteworthy observations include deviations in fitting certain materials at lower temperatures and the identification of negative diffuson contributions in specific cases. These findings contribute to a nuanced understanding of thermal transport in nanostructured materials and have implications for applications in advanced thermal management systems and thermoelectric devices. The extracted parameters provide valuable insights for researchers exploring the thermal conductivity of diverse nanostructured materials.

Crystal structure, oxygen nonstoichiometry and properties of Pr1-xSrxCoO3-δ

The crystal structure, oxygen content and homogeneity range of Pr1-xSrxCoO3-õ solid solutions from room temperature (RT) up to 1100 °C in air were studied. It has been shown that an increase in temperature and Sr content causes an Orthorhombic → Rhombohedral → Cubic transformation of the crystal structure. The heterovalent substitution of Sr2+ for Pr3+ is compensated by an increase in the mean oxidation state of Co ions (zCo) and the formation of oxygen vacancies. The temperature dependences of thermal expansion and conductivity of Pr1-xSrxCoO3-õ solid solutions are explained from the point of view of crystal and defect structure. The diagram of phase relation in the PrCoO3 – “SrCoOz” cross section has been constructed.

Impact of gadolinium doping on BiFeO3-PbZrO3 for energy storage applications: Structural, microstructural, and thermistor properties

The solid-state reaction technique is used to prepare the Gd-doped BiFeO3-PbZrO3 at concentrations x = 0.05, 0.10, 0.15, and 0.20 with chemical formula 0.5(BiGdxFe1-xO3)-0.5(PbZrO3). Room-temperature XRD data are used to compute structural characteristics, such as dislocation density, microstrain, crystallite size, and percentage of crystallinity. The SEM micrographs indicate the spherical, tightly packed nature of materials with limited porosity. The extent to which the composites work at high temperatures (175–400 °C) as NTC thermistors. Understanding the properties of the NTC thermistor requires the calculation of the resistor constant, sensitivity index, and activation energies. Based on the frequency- and temperature-dependent AC conductivity of the composites, a high density of states was calculated.

Temperature and frequency dependence of conductivity, density of states, and dielectric permittivity of ternary metal chalcogenide PbSnSe2 flake

The mechanically cleaved flake of ternary metal chalcogenide PbSnSe2 was transferred onto the interdigitated electrodes to form electrical contacts. The temperature dependent (180 K–250 K) electrical properties were then analyzed employing complex impedance spectroscopy from 2 kHz to 2 MHz. A detailed analysis of Nyquist plots proposed the space charge dependent behavior and negative temperature coefficient of PbSnSe2 flake. The AC conductivity followed Jonscher's power law with s-parameter value being less than unity. The values of s-parameter increased with rise in temperature suggesting the presence of non-overlapping small polaron tunneling (NSPT) in the PbSnSe2 flake. From this NSPT model, tunneling distance, hopping energy, and density of states (DOS) were estimated at temperatures from 180 K–250 K. The dielectric permittivity showed dispersion at lower frequencies and the tangent loss was also found to be directly related to temperature. A single semicircular arc in complex modulus analysis showed the dominance of bulk effect in the material.

Enhanced Performance of Fe/WO3 Terahertz Dielectric Lenses

AbstractHerein transparent iron nanosheets deposited by the ionic coating technique onto glass and WO3 dielectric lenses are studied and characterized. The thickness of Fe nanosheets is varied in the range of 70–350 nm. It is observed that the transmittance and reflectance of the Fe nanosheets are highly affected by the layer roughness. Coating of iron nanosheets onto WO3 dielectric lenses increases the light absorption of WO3 by more than 240 times and red‐shifts the energy bandgap. Remarkable enhancements in the dielectric constant and in the optical conductivity are achieved via Fe coatings. In addition, iron coated dielectric lenses show higher terahertz cutoff limits varying in the range of 1.0–30 THz. Iron nanosheets remarkably increase the free charge carrier density and plasmon frequency in the infrared range of light. Moreover, the temperature dependent electrical conductivity shows high temperature stability and an increased electrical conductivity by more than 7 orders of magnitude by coating WO3 with 70 nm thick Fe nanosheets. The stability of the electrical conductivity at low temperatures and the wide range of terahertz cutoff limits in addition to the well‐enhanced light absorbability makes the iron coated tungsten oxide dielectric lenses promising for multifunction optoelectronic applications.

Contribution of strong electron-phonon interaction in the transport properties of La0.8Ca0.2Mn0.5Ni0.5O3 system

La0.8Ca0.2Mn0.5Ni0.5O3 NTC (negative thermal coefficient) thermo-sensitive material was prepared using a conventional solid-state reaction method. From the structural results, we found that the material is pure and crystallizes in the orthorhombic structure with a Pnma space group. It is found that the La0.8Ca0.2Mn0.5Ni0.5O3 ceramic can be used as an NTC thermistor compound in specific temperature sensors and attenuators. Based on Holsten's theory, detailed electrical investigations concerning the nature of the activated small polaron hopping mechanism were reported. The temperature dependence of the DC conductance was used to determine the electrical conduction processes that govern the transport properties of La0.8Ca0.2Mn0.5Ni0.5O3. Hence, the DC mechanisms exhibit changes from the variable range hopping at very low temperatures to the non-adiabatic small polaronic hopping at T = 210 K. In the intermediate temperature range, the semiconductor behavior of La0.8Ca0.2Mn0.5Ni0.5O3 was attributed to the contribution of the tunneling transport process. At various temperatures, the conductance spectra were discussed based on Jonscher and Bruce's laws. Contributions of the overlapping-large-polaron-tunneling, the correlated barrier hopping, the quantum mechanical tunneling, and the non-overlapping small polaron tunneling mechanisms to the transport properties were observed in the dispersive region of the conductance spectra. In addition, Summerfield scaling and corrected Summerfield scaling approaches prove that the charge mobility is temperature-dependent. The positive value of the correction parameter α = 1.2 confirms the presence of interactions in the studied sample.

Influence of part temperature on in-situ monitoring of powder bed fusion of metals using eddy current testing

AbstractPowder bed fusion of metals (PBF-LB/M) is currently the most widely adopted additive manufacturing technology for the fabrication of metal parts. However, the inconsistent quality of PBF-LB/M-manufactured parts and high costs for part certification are impeding wider industrial adoption. In-situ monitoring technologies are expected to enable process control in order to ensure consistent quality, and to replace some of the post-process inspection steps, therefore, reducing part certification costs. Eddy current testing (ECT) is a standardized nondestructive testing technique, which can be used as an in-situ monitoring technology to measure the part quality during the PBF-LB/M build cycle. However, the process-induced complex temperature fields in PBF-LB/M parts during the build cycle are among the most relevant disturbances due to the temperature dependence of the electrical conductivity. This study investigates the process-induced temperature influence on in-situ monitoring of relative density using ECT. Parts made from AlSi10Mg were manufactured on a PBF-LB/M machine and the build cycle was monitored using ECT and an infrared camera, which was used to extract the part surface temperature right before the ECT measurement. The results demonstrate that the temperature increase of the parts during the build cycle decreases the electrical conductivity independently of the relative part density, which was measured via micro-computed tomography. Therefore, a temperature compensation method was proposed and applied demonstrating that a layer-to-layer difference of 0.15 % relative density can be detected via ECT. Consequently, it has been demonstrated that ECT is an effective in-situ monitoring technology for PBF-LB/M, even in the presence of temperature disparities within parts.