Monitoring water quality in urban rivers is crucial for water resource management since point and non-point source pollution remain a major challenge. However, traditional water quality monitoring methods are costly and limited in frequency and spatial coverage. To optimize the monitoring, techniques such as modeling have been proposed. These methods rely on networks of low-cost multiprobes integrated with IoT networks to offer continuous real-time monitoring, with sufficient spatial coverage. But challenges persist in terms of data quality. Here, we propose a framework to verify the reliability and stability of low-cost sensors, focusing on the implementation of multiparameter probes embedding six sensors. Various tests have been developed to validate these sensors. First of all, a calibration check was carried out, indicating good accuracy. We then analyzed the influence of temperature. This revealed that for the conductivity and the oxygen sensors, a temperature compensation was required, and correction coefficients were identified. Temporal stability was verified in the laboratory and in the field (from 3 h to 3 months), which helped identify the frequency of maintenance procedures. To compensate for the sensor drift, weekly calibration and cleaning were required. This paper also explores the feasibility of LoRa technology for real-time data retrieval. However, with the LoRa gateways tested, the communication distance with the sensing device did not exceed 200 m. Based on these results, we propose a validation method to verify and to assure the performance of the low-cost sensors for water quality monitoring.