Technology Office Research Articles

Bringing research into policy: understanding context-specific requirements for productive knowledge brokering in legislatures

Background: Knowledge brokering is suggested as an instrument to improve productive use of research in policy organisations. Previous research asserted that research utilisation is dependent on dynamics of knowledge exchange in institutional settings, but these claims have not received substantial empirical attention (Saarela et al, 2015; Akerlof et al, 2019; MacKillop et al, 2020). Viewing knowledge brokering as the involved role, three specific challenges are identified: high legitimacy requirements for the brokered knowledge and the broker; the need to cater for a wide range of topics, audiences and uses; and the need to compete with other evidence suppliers. Aims and objectives: The research question of the article is: how do legislative knowledge brokers navigate context-specific knowledge transfer challenges presented by their institutional context? Methods: An in-depth interpretive case study of the UK Parliamentary Office of Science and Technology. The analysis includes interviews with parliamentary actors, shadowing and participant observation. Findings: The results substantiate the challenges of legislative knowledge brokering in the UK context and inductively identify a further challenge of demonstrating impact. Legislative knowledge brokers employ multiple strategies to navigate the challenges: co-shape and adhere to the norms of impartiality, mobilise external expertise, collaborate with in-house and external research support actors, employ anticipation techniques, build broker chains, seek understanding of own role and impact. Discussion and conclusion: The article contributes to the understanding of knowledge brokering as a context-dependent role. The conclusions discuss influence of knowledge brokers’ work remit and positionality in deploying strategies to overcome the legislative challenges.

Data Breach Notification Laws and the Cost of Private Debt

We examine the effect of state-level data breach disclosure mandates (DBN laws) on the cost of private debt. Using the staggered passage of DBN laws across the U.S., we document an increase in the cost of private debt for firms affected by these laws. These findings suggest that DBN laws increase lenders’ anticipation of cash flow risk from potential future costs related to data breach disclosures. We further document that the increase in the cost of private debt is more pronounced for firms that (i) belong to industries that are susceptible to data breaches, (ii) report internal control weaknesses, or (iii) disclose cyber security risks in their risk factor disclosures. Additionally, we find that the increase in the cost of private debt is less pronounced in firms that focus on cyber security measures, such as investing in cyber security or appointing a technology officer on their board. We contribute to the debt contracting and disclosure literature by focusing on the proactive response of private lenders after the passage of DBN laws to mitigate ex-ante the risk resulting from potential future data breach disclosures while also shedding light on the cost (financing cost) associated with mandatory disclosure practices.

Pengembangan Media Pembelajaran Video Animasi Berbasis Powtoon pada Mata Pelajaran Teknologi Perkantoran Kelas X SMK Satya Bhakti 2 Jakarta

This study aims to develop video-based interactive learning media using the Powtoon application for Office Technology lessons in class X SMK Satya Bhakti 2 Jakarta. The method used in this research is Research and Development (R&D) with the ADDIE model, which includes the stages of analysis, design, development, implementation, and evaluation. The evaluation results show that the developed learning media is very feasible to use, with an average score of 92.17% from media experts and 96.19% from material experts, both of which fall into the category of ‘Very Feasible.’ This research is expected to increase the effectiveness of learning and attract students' interest in understanding the subject matter.

“He would do nothing in the office”: Work and alienation in cinematic adaptations of Herman Melville’s Bartleby.

This paper analyzes the representation of the office workplace in filmic adaptations of Melville’s short story “Bartleby, the Scrivener”. Following a brief overview of film adaptations of Melville’s short story, this article will discuss Miro Bilbrough’s (2001) and Gerard Amsellem’s (2013) short films, Andreas Honneths (2010) experimental interpretation as well as Laura Naylor and Kristen Kee’s (2017) stop-motion movie. By, for instance, analyzing how the movies try to replicate the first-person narration, find visual images for Melville’s uncinematic descriptive prose, or underline the thematic importance of writing by incorporating different forms of written text, I will firstly examine techniques of intermedial transposition. Since the filmmakers deploy the setting to reimagine or modernize the story, the set design is to be regarded as an essential part of the adaptation process. Paying particular attention to the usage of space, the visual presentation of physical and metaphorical walls, as well as the utilization of non-human entities as ‘actors,’ I will seek to demonstrate how the movies under study reflect contemporary office environments and dynamics of work culture. Updating the nineteenth-century quills and inkpots to modern office technology, for example, allows the directors to reflect upon how electronic communication can cause or reinforce isolation. Different concepts of alienation serve as an essential theoretical framework for the movies. The adaptations concern themselves with social disconnect, engage in questions of ecological alienation, or focus on a political and socioeconomic interpretation of Bartleby’s passive resistance to productivity and consumption.

Geothermal Power, and a Battery as Well

One of geothermal energy’s key advantages is that it’s always on. But making money selling power increasingly requires being able to react to shifts in electric prices by adjusting production up and down. The fact this is a concern now is an indication of the ambition of a new generation of companies that have shown it is possible to use horizontal drilling and fracturing to build subsurface heat exchangers to harvest large amounts of geothermal energy. The geologic potential is huge—there are a lot of places with hot rock at a drillable depth. But monetizing that potential will require grabbing a sizeable share of the market in big states such as California and Texas where the price of electricity can sink toward zero when sunny conditions allow maximum solar power production, and then rebound as the sun sets. This is a pressing concern for Houston-based Fervo Energy because it is one of the first firms in a small pack of innovators to reach the point where it is building a large scale power plant using this emerging technology. Unlike wind and solar, it can deliver power on demand, similar to coal, gas, and nuclear-powered plants that supply baseload power to the electric market. Fervo’s founders play up its ability to deliver power on demand, but they resist the label baseload power provider because, as Jack Norbeck, chief technology officer and cofounder of Fervo, said, “In the future, baseload power will be a thing of the past.” Baseload power plants are not yet an endangered species. There are still large, mostly old fossil-fueled plants providing baseload power that are still around because they were paid for long ago. However, their numbers are declining as they wear out and are hit with demands for costly emission reductions. The initial sales by Fervo’s Cape Station project in Utah will provide baseload power to southern California power suppliers, complying with a unique California rule that requires them to source low-carbon power supplies that are available 24/7. But for new geothermal companies to sell enough power to become significant players in US power markets, they will need to provide what the electricity business describes as “more flexible, dispatchable power.” Big baseload plants ruled the power universe back when regulators set rates high enough to maintain a sizable surplus of generating capacity—ensuring the lights stayed on. Now, in markets such as Texas and California, power pricing rises and falls based on supply and demand, with selling at all times sometimes resulting in very low payments during peak production periods for solar and wind. This is particularly true during seasons where days tend to be sunny and windy with moderate temperatures. “If you are consuming electricity, particularly in the spring and fall, it is an extremely clean grid you are pulling from,” said Christian Gradl, vice president of operations for Fervo during a panel at this year’s Offshore Technology Conference.

The use of School Information System in Strengthening the Management of Government Secondary Schools in Meru District Council

This study investigated the use of the School Information System (SIS) in strengthening the management of government secondary schools in Meru District Council. The study adopted the Technology Acceptance Model (TAM). The Diffusion Innovation theory and Technological Acceptance model guided this study. A qualitative research approach alongside a case study research design was adopted. The targeted population of the study was 1203 including 46 heads of schools, 1083 teachers, 46 academic teachers, 26 ward secondary officers, 01 District Education Officer (DSEO) and 01 District Information Communication Technology Officer (DICTO) of which 37 were drawn. Purposive and simple random sampling techniques were used to get respondents. Interview and questionnaire methods were used to collect data. The study's trustworthiness was maintained through the supervisor’s corrections, expert advice, and following all necessary ethical procedures. The study revealed that the School Information System carries user-friendly features that strengthen the management of government secondary schools such as student information management, and teacher and staff management. However, the facilities are not sufficiently available. Furthermore, the study found that the School Information System greatly enhances data management and analysis, streamlining administrative tasks and resource management, promoting teachers’ accountability and improving communication in government secondary schools. The study recommended that there should be the provision of enough facilities, alternative sources of energy, seminars, and training to promote the implementation and use of School Information System in government secondary schools.

The Effectivity of Trello Task Management Application in Campaign Management Division PT XX

Task management as one of the important aspects of business processes in the current era, through a focus on visibility and utilization of application-based office technology, web, social media, and e-commerce. Through effective task management is the key to success in achieving business goals. So, the use of relevant task management applications such as Trello is needed to organize daily tasks and work. This research uses a descriptive qualitative method with a case study approach. The sampling process was carried out using non-probability and purposive sampling techniques to explore the informants' in-depth understanding of the use of Trello as a project management tool in the organization. The results showed that Trello is effective in organizing work, improving project management processes, and contributing to organizational success. However, there are several recommendations for improvement, including the integration of Trello with communication platforms, increased use of the app's features, and efforts to socialize and evaluate future use of the app. This research highlights the importance of the organization's role in improving the quality of the use of applications and related office systems so that the achievement of organizational goals can be maximized.

Identifikasi Tren Penelitian Efisiensi Technology Transfer Office dengan Pendekatan Bibliometrika pada Database Jurnal Scopus

This study aims to identify the bibliometric characteristics of research related to factors affecting the efficiency of the Technology Transfer Office in the Scopus journal database since the beginning of the topic. The method used in this study is descriptive quantitative. This study identifies research trends, the most influential authors, documents with the most citations, the most occurring words, and other bibliometric information. The sample used was 444 publications in the form of articles and conference papers indexed by Scopus. The analysis tools used were R software version 4.3.2 and bibliometrix package version 4.1. The findings show that research interest in technology transfer efficiency continues to increase to date. Research directions show a continued focus on entrepreneurship and technological change, with additional emphasis on the role of public policy in supporting TTOs. This research contributes some information and insights into the extent to which the topic of office technology transfer efficiency is covered in articles and conference papers found in the Scopus journal database.

Fervo Showed Fractured Geothermal Works, Now Must Do It Bigger, Cheaper, and Soon

Earlier this year, one of the founders of Fervo Energy announced that the geothermal innovator had reached its “Mitchell moment.” Jack Norbeck, chief technology officer for Fervo, likened a test where it used a pair of fractured wells to create water hot enough to generate electricity to the time when Mitchell Energy adopted slickwater fracturing to economically extract large amounts of gas from the ultratight rock in the Barnett Formation. “We have derisked all those core challenges, we reached the Mitchell Energy moment for geothermal,” Norbeck said. By doing all that and supplying 3.5 MW of electricity to the local grid that powers Google facilities, he announced that the firm’s enhanced geothermal system (EGS), had reached the highest level of technical readiness. Now comes the hard part—proving that technical triumph can be turned into something really big. The Mitchell moment in 1997 is remembered because it led to a series of innovations that allowed hydraulic fracturing and horizontal drilling to add enough oil and gas production to move global markets. What has been learned about fracturing in the decades since allowed oil industry veterans at Fervo to effectively use those tools to do what others had failed to accomplish—create high-volume EGS capable of generating power. One big difference between the moments is that Houston-based Fervo’s next step looks like a leap compared to Mitchell’s. After Mitchell’s moment, no innovation was required to sell shale gas from the Barnett or find the oilfield services needed to develop and produce it. Plus, it could learn from the many other companies working in tight rock plays. Its moment was the culmination of years of innovations by oil and service companies who continued finding ways to build on that advance. The endless arguments over who can claim credit for the innovations behind the Mitchell moment are evidence of the size of that support network. Today, Fervo’s efforts are also supported by the oil industry’s service sector and supply chain. Oil company Devon Energy, drilling contractor Helmerich & Payne, and pressure-pumping specialist Liberty Energy are among its early backers. And Fervo is benefiting from the government-funded research and site-evaluation work at the Utah Frontier Observatory for Research in Geothermal Energy (FORGE) site, which is the key site for geothermal testing funded by the US Department of Energy (DOE). But unlike Mitchell, the path to commercial success will require Fervo and others to show they can create large operations to convert the heat they harvest into a cost-competitive commodity in a fast-changing, highly competitive industry. Sage Geosystems recently was added to the short list of geothermal startups with big projects, signing a deal with Meta to build a 150-MW plant somewhere east of the Rockies. Also high on the list is Eavor whose first commercial project will use its closed-loop heating technology for home heating and electric generation in Germany.

(De)centralized governance and the value of platform-based new ventures: The moderating role of teams and transparency

AbstractDrawing on institutional and demand-side perspectives, we investigate performance implications of (de)centralized governance modes in platform-based new ventures, and the conditions under which (de)centralization generates more value. Using a sample of 1,431 Initial Coin Offerings (ICOs), a new source of entrepreneurial finance, we find that centralization of decision-making is positively associated with platforms’ market value. Further, we consider how platform characteristics affect this relationship, finding that both the presence of an experienced Chief Technology Officer (CTO) and project transparency negatively moderate the positive relationship between centralization and market value. Thus, decentralized platforms need leaders with technical experience and project transparency to generate more value. Overall, this study provides a better understanding of the boundary conditions that increase the value of (de)centralized governance.

Research on Security Model of Airport Luggage Remote Office System Based on Zero Trust

With the continuous development of modern information society, remote office equipment itself has many benefits and is widely respected by the public, but at the same time, it also brings many network security issues. In order to help the airport luggage remote office system achieve stability and solve security issues encountered during luggage inspection, an analysis of existing system security risks based on the zero trust concept is conducted, including factors such as data leakage, insufficient monitoring, and incomplete identity authentication. Combined with the characteristics of the luggage system and remote office technology, the security model is ensured to be sufficiently reliable, providing some reference for airlines preparing to implement zero trust airport luggage remote office.

Effect of Catalyst and Electrode Structures on the Operating Current Densities of Liquid Alkaline Water Electrolyzers

Liquid Alkaline Water Electrolyzers (LAWEs) stand out as the technology best-suited for cost-effective hydrogen production. They do not require expensive platinum group metal catalysts and have proven durability afforded by nickel-based electrodes and porous separators. While nickel electrodes and porous separators provide chemical stability in highly alkaline conditions, they do suffer from lower catalytic activity for hydrogen and oxygen evolution reactions (HER and OER), and separators possess higher ohmic resistance due to the absence of ion-conducting groups. Consequently, most LAWEs operate at low current densities ranging from 0.2 to 0.6 A/cm2, resulting in a bulky footprint and comparatively lower energy efficiency due to a reduced hydrogen production rate. To address these challenges, considerable efforts have been directed towards developing thin separators and efficient transition metal-based electrocatalysts for HER and OER in alkaline media. However, the majority of studies related to catalysts are limited to half cells, with only a limited number of catalysts evaluated in relevant LAWE configurations.In this work, we introduce a next-generation Zero-gap LAWE testing capability, benchmarked for performance through H2NEW consortia. Employing this setup, we have evaluated hydrogen and oxygen evolution catalysts under LAWE-relevant conditions on different electrode substrates, each offering a unique electrode structure. Our preliminary findings indicate that Zero-gap LAWEs, when coupled with NiMo cathode and NiFe-type anode catalysts, can operate at current densities exceeding 0.75 A/cm2 at approximately 1.8 V without compromising their short-term durability. In contrast, the benchmark cell exhibited a meager current density of around 0.22 A/cm2. In this presentation, effects of electrode structure, catalyst type, and other relevant parameters related to Zero-gap LAWEs will be discussed in detail. Acknowledgement:This research is supported by the U.S. Department of Energy (DOE) Hydrogen and Fuel Cell Technologies Office through the Hydrogen from Next-generation Electrolyzers of Water (H2NEW) consortium.

(Invited) Fluorinated Linear Carbonate Electrolyte for Lithium-Ion Batteries with Fast-Charging, High Voltage, and Wide Operating Temperatures

Lithium-ion batteries (LIBs) are key solutions to clean energy. Their high energy densities have led to the dominance of LIBs in mobile devices and electric vehicles. However, traditional electrolyte limits their operation at high voltage and extreme environmental temperatures. Here, we designed a new multifunctional electrolyte, in which lithium bis(fluorosulfonyl)imide (LiFSI) is used as salt and fluorinated diethyl carbonate (DFDEC) is used as the major solvent. With this optimized electrolyte, the graphite||LiNi0.8Mn0.1Co0.1O2 (NMC811) full cells are capable of fast-charging and can deliver long-term cycling with a cutoff voltage as high as 4.5V. Specifically, the battery shows the capacity retention of 84.3% after 500 cycles with an average coulombic efficiency (CE) as high as 99.93%. Synchrotron-based characterization suggests the formation of anion derived, LiF-rich interphases on the surfaces of both graphite anode and NMC811 cathode. Thanks to the fast ion transport and stable interphase, the cell in the optimized electrolyte demonstrates stable cycling behavior within a wide operating temperature. At high temperature (60 ºC), the full cell delivers 88.8% of its initial capacity after 130 cycles at a high current density of 1C. At low temperature (-20 ºC), the optimized electrolyte enables a capacity retention of 90.9% after 100 cycles when charging and discharging at 0.2C.Acknowledgment: The work done at Brookhaven National Laboratory was supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technology Office of the U.S. DOE through Applied Battery Research for Transportation (ABRT) program under contract no. DE-SC0012704. The electrodes used in this study were produced at the U.S. Department of Energy’s (DOE) CAMP (Cell Analysis, Modeling and Prototyping) Facility, Argonne National Laboratory. The CAMP Facility is fully supported by the DOE Vehicle Technologies Office (VTO). This research used beamline 7-ID-2 (SST-2) of the National Synchrotron Light Source II, U.S. DOE Office of Science User Facilities, operated for the DOE Office of Science by Brookhaven National Laboratory under contract number DE-SC0012704. SEM measurements for this manuscript were performed at Center for Functional Nanomaterials, a U.S. DOE office of Science User Facility, at Brookhaven National Laboratory under the contract number DE-SC0012704.

Microstructural Characterization of Porous Transport Layer Coatings

The porous transport layer (PTL) is a key component in polymer electrolyte membrane (PEM) water electrolyzers and serves the role of controlling the transport of reactants and products to and from the anode. Maintaining a low interfacial contact resistance between the titanium (Ti) fiber or sinter PTL and the iridium (Ir) anode catalyst is critical to maintaining the performance of the electrolyzer cell. This requires costly precious metal coatings, typically Pt, to inhibit the formation of native oxide layers during long-term cell operation. Strategies to reducing the thickness of these costly coatings including surface treatments, such as etching and abrasion, alternative low-cost coating materials, and implementation of microporous layers. It is crucial to understanding the morphologies and degradation mechanisms of these new strategies in order to accelerate the development of cheaper, more robust PTL coatings.In this work, correlative ex situ characterization methods, including laser confocal microscopy (LCM), focused ion beam (FIB), scanning electron microscopy (SEM), time-of-flight secondary ion mass spectrometry (ToF-SIMS), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and scanning transmission electron microscopy (STEM), are utilized to explore the impact surface treatments, such as etching and abrasion, on the Pt coatings uniformity and surface roughness. The thickness, local topography, and continuity of the Pt coating were quantified and correlated with interfacial contact resistance and electrochemical cell performance measurements. Changes to the thickness and composition of the coatings and oxide layers after single-cell tests will also be reported. Overall, these findings aim to guide the development of PTL treatments and coatings, ensuring the creation of highly durable and efficient PEM water electrolyzers that align with the U.S. Department of Energy's Hydrogen Shot goal of reducing the cost of clean hydrogen production to $1 per kilogram by 2031.Funding for this work was provided by U.S. Department of Energy Office of Energy Efficiency and Renewable Energy, Hydrogen and Fuel Cell Technologies Office through the H2NEW Consortium. Electron microscopy research conducted as part of a user project at the Center for Nanophase Materials Sciences (CNMS), which is a US Department of Energy, Office of Science User Facility at Oak Ridge National Laboratory.

Electrolyte and Cutoff Potential Effects on Cycle Life of Li4Ti5O12/LiNi0.9Mn0.1O2 Batteries for Behind-the-Meter Storage Applications

Behind-the-Meter Storage (BTMS) is a stationary battery energy storage system that is connected to the electrical distribution system on the customer’s side of the utility’s service meter. BTMS systems are used to store electrical energy from the grid as well as inconstant, renewable energy, such as local solar and wind generation. A successful BTMS system will allow the customer to pair their energy generation and storage to optimize electrical consumption from the grid, improving reliability and minimizing cost. For BTMS applications, batteries must be designed and optimized with different set of criteria from other leading segments of the Li-ion battery market, like transportation, due the system being stationary and proximal to the residential or commercial building it’s benefitting. BTMS applications prioritize safety, cost (low/no-critical materials), reliability (20-year calendar life), and durability (10,000 cycle life), while having the ability to (minimally) compromise energy density and rate capability.Lithium titanate (Li4Ti5O12, LTO) is a promising anode candidate for BTMS applications due to its high safety and capacity retention, while maintaining a reasonable 160 mAhg-1 reversable capacity and composition of relatively abundant materials. (1) Specifically, LTO has a high working voltage which helps to prevent Li dendrite formation, improving safety. Furthermore, LTO also has negligible lithiation-based volume change, leading to less mechanical pulverization, or loss of active material, upon cycling. For the cathode, materials with little or no Co are of high interest due to the high cost and low abundance of Co. LiMn2O4 (LMO) has been paired with LTO for BTMS applications in the past due to its safety, low cost (abundancy), and reasonably high operating voltage. (2-4) However, the low capacity of LMO limits energy density and specific energy. While not the highest priority for BTMS applications, increasing energy density will enable deployment in space constrained BTMS applications and decrease total cost. LiNi0.9Mn0.1O2 (LNMO) is a recently developed material with promise due to its high operating voltage and relatively low price. (5) However, Ni-rich layered oxides, including LNMO, tend to struggle with capacity retention during high-voltage cycling due to mechanical pulverization, irreversible phase transitions, and unstable solid-electrolyte interphase.The study presented here focuses on building an understanding of how electrolyte solvent and varied cutoff potentials will impact the cycle life of LTO/LNMO cells. Specifically, a comparison is provided between ethylene carbonate (EC), ethyl methyl carbonate (EMC), fluoroethylene carbonate (FEC), and Gen2 electrolyte solvents with 1M Lithium hexafluorophosphate (LiPF6) salt, cycling to two upper termination potentials, 2.6V and 2.7V. Electrochemical testing and diagnostics (e.g., differential capacity analysis, area specific impedance, constant voltage hold, and rate capability) and post-mortem characterization will be used to understand the aging behavior and failure mechanisms of the 8 cell combinations (four electrolytes and two voltage cutoffs). Cells with FEC electrolyte showed a lower initial capacity compared to cells with Gen2, EMC, and EC cycling at both voltages; however, the cells with FEC showed consistent trends in capacity retention with 2.6V and 2.7V termination potentials, while the cells with the other electrolytes showed much higher rates of capacity loss when cycling to the higher voltage. These results indicate that FEC may play a role in improving durability of high-voltage, Ni-rich electrode systems for use in high-cycle applications, such as BTMS.This work was authored in part by the National Renewable Energy Laboratory, operated by Alliance for Sustainable Energy, LLC, for the U.S. Department of Energy (DOE) under Contract No. DE-AC36-08GO28308. Funding was provided by the U.S. Department of Energy's Vehicle Technologies Office under the Behind-the-Meter Storage (BTMS) Consortium directed by Samuel Gillard and managed by Anthony Burrell. The electrodes used in this manuscript are from Argonne's Cell Analysis, Modeling and Prototyping (CAMP) Facility, which is fully supported by the DOE Vehicle Technologies Office (VTO). The views expressed in the article do not necessarily represent the views of the DOE or the U.S. Government. The U.S. Government retains and the publisher, by accepting the article for publication, acknowledges that the U.S. Government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this work, or allow others to do so, for U.S. Government purposes.

Probing Interfacial Degradation in Solid-State Batteries Using Machine Learning Force Fields

Solid-state batteries (SSBs) are next-generation energy storage technologies with improved safety and potentially higher energy densities compared to conventional Li-ion batteries, which is enabled by using fast ion-conducting solid electrolytes (SEs). However, practical applications of SSBs are hindered by the electro-chemo-mechanical instabilities at interfaces within the SEs (grain boundaries (GBs)) and between SEs and the electrodes, which deteriorates Li transport and the chemical and mechanical integrity of the cell. To mitigate, fundamental understanding of the intrinsic physico-chemical properties at interfaces is required. To this end, we directly probe atomic structures of the interfaces and GBs by performing large-scale atomistic simulations, enabled by validated machine-learning force fields (MLFFs) and resolve the structure-property relationship at complex interfaces that governs Li-ion transport and stability of SSBs.In this talk, we will discuss the characteristics of garnet Li7La3Zr2O12 (LLZO) SE/LiCoO2 (LCO) cathode interfaces as well as the internal interfaces within the LLZO (GBs). It is observed from our simulations that the propensities for interfacial degradation strongly depend on the surface chemistry of LLZO and LCO. Doping LLZO is found to have a segregation effect at the LLZL GBs, here we will discuss its implication towards secondary phase formation and Li transport kinetics. At last, we will address the impact of interfaces on micro-crack propagation behavior in the LLZO-LCO system. In summary, our results reveal how atomic details of the dynamically evolving interfaces dictate the performance of SSBs, and provide guidance for processing and interface design to achieve desired performance .This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract number DEAC52-07NA27344. Authors acknowledge funding support from the Vehicle Technologies Office, Office of Energy Efficiency and Renewable Energy, U.S. Department of Energy and computational resource support from the Innovative and Novel Computational Impact on Theory and Experiment (INCITE) program. This research used resources of the Argonne Leadership Computing Facility, which is a DOE Office of Science User Facility supported under Contract DE-AC02-06CH11357.

Gaseous Nitric Oxide As Probe Molecule for Fe-N-C ORR Electrocatalysts

Iron nitrogen carbon (Fe-N-C) electrocatalysts remain the most promising platinum group metal-free (PGM-free) catalysts for the oxygen reduction reaction (ORR) in polymer electrolyte fuel cells (PEFCs). Although significant progress has been made in recent years in improving both the ORR activity and stability of the Fe-N-C catalysts, further enhancement in the catalyst durability while maintaining the activity is imperative for the practical applications. One of the major factors that hinders the further enhancement of the catalysts is the lack of clear understanding of the nature of the active sites and density of the active sites in the Fe-N-C catalysts due to the complexity of the Fe-N-C catalysts’ composition and structure. Gaseous nitric oxide was proven to be a suitable probe molecule that can bond to Fe and impede the ORR of the Fe-N-C catalysts. In recent years, we have studied the effects of gas-phase adsorption and desorption of nitric oxide on the redox features and ORR activity on Fe-N-C catalysts synthesized by different methods. We have used various characterization tools to quantify the amount of nitric oxide adsorbed and to identify the adsorption sites and geometry, including electrochemical stripping, temperature programmed desorption, and in situ X-ray techniques. The corresponding results obtained will be summarized in this talk. The implication of these results on the nature of the ORR active sites of the Fe-N-C catalysts will be discussed.AcknowledgementsThis work was supported by the U.S. Department of Energy (DOE), Energy Efficiency and Renewable Energy, Hydrogen and Fuel Cell Technologies Office (HFTO) under the auspices of the Electrocatalysis Consortium (ElectroCat 2.0). This work utilized the resources of the Advanced Photon Source, a U.S. DOE Office of Science user facility operated by Argonne National Laboratory for DOE Office. This work was partially authored by Argonne, a U.S. Department of Energy (DOE) Office of Science laboratory operated for DOE by UChicago Argonne, LLC under contract no. DE-AC02-06CH11357.

Hydrogen Contaminant Detectors for Ensuring Hydrogen Fuel Quality

The California Energy Commission tracks Hydrogen Refueling Station (HRSs) installations within California and states that there are 66 light duty retail stations open within the State with another 34 in the planning stages.1 The hydrogen dispensed in these stations is expected to meet SAE J2719 standards for the maximum allowable concentration of various impurities.2 Currently HRSs have their fuel analyzed periodically to verify that they meet fuel specifications. However, this implies that any anomaly in the purification system resulting in contaminated hydrogen can result in significant damage to fuel cell vehicles before being detected. Therefore, the development of hydrogen contaminant detectors that can continuously monitor the hydrogen for impurities like Carbon monoxide (CO) and hydrogen Sulfide (H2S) is of great interest. LANL has developed a hydrogen contaminant detector based on a hydrogen pumping cell that is sensitive to < 200 ppb CO and < 4 ppb H2S.3,4 In this talk we will present details of the working mechanism of this hydrogen contaminant detector and present results from the field testing of the detector at a HRS. Acknowledgements This research is supported by the U.S. Department of Energy Fuel Cell Technologies Office, through the Safety, Codes & Standards (SCS) sub-program (Project Manager: Laura Hill).REFERENCES: https://www.energy.ca.gov/data-reports/energy-almanac/zero-emission-vehicle-and-infrastructure-statistics/hydrogen-refueling.San Marchi, E. S. Hecht, I. W. Ekoto, K. M. Groth, C. LaFleur, B. P. Somerday, R. Mukundan, T. Rockward, T; J. Keller, C. W. James, Int. J. Hydrogen Energy, 42(11), 7263-7274 (2017)Brosha, T. Rockward, C. J. Romero, M. S. Wilson, C. Kreller and R. Mukundan, U.S Patent # 10,490,833 (2019).R. Mukundan, E. L. Brosha, C. J. Romero, D. Poppe, T. Rockward, “Development of an electrochemical hydrogen contaminant detector”, Journal of The Electrochemical Society, 167(14), 147507 (2020)

The Effect of Structural Disorder on Li-Ion Transport in the Inorganic Components of the Electrode-Electrolyte Interfaces of Li-Ion Batteries

Conventional organic electrolytes in Li-ion batteries have an electrochemical window that is too narrow, leading to a decomposition at the cathode and anode surfaces, especially at high voltages. The breakdown of the electrolyte leads to the formation of cathode-electrolyte interphase (CEI) and solid-electrolyte interface (SEI) at the anode. These interfaces are a multicomponent, 3-dimensional heterogeneous structures that span from a few nanometers to micrometers. To understand the atomic-scale impact of the interfaces’ structure and chemistry on function we have run molecular dynamics simulations of the Li-ion diffusivity in the most likely components: LiF, Li2CO3, and Li2O. Our work focuses on identifying the effect of local chemistry and lattice structure in disordered or amorphous component materials on Li-diffusivity. We extract Li-ion diffusivity and the activation energy for Li-ion transport from both machine learning force fields and ab-initio molecular dynamics from the individual components of the interface and explicit interfaces. Post analysis establishes the local correlation between atomic structure, chemistry, and Li-ion migration. If well designed, the SEI and CEI can protect the electrolyte and cathode to prevent further degradation during cycling and thus optimization of battery performance.This work was sponsored by the Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office and was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

(Invited) Battery Manufacturing Needs from the Perspective of DOE's Advanced Materials and Manufacturing Technologies Office

The Department of Energy’s Advanced Materials and Manufacturing Technologies Office (AMMTO) continues to invest in energy storage research, development, and demonstration (RD&D) to help stakeholders improve efficiency, cut costs, and make materials, components, and systems with superior performance. Despite recent promising advances, manufacturing capabilities are still necessary to meet the expected demand for batteries as we move toward a clean energy economy. Strengthening the domestic manufacturing supply chains is also another important task to pursue in parallel. A multi-pronged approach is required to strengthen domestic battery manufacturing and reduce time to commercialization and deployment of transformative technologies. AMMTO recognizes a number of unmet needs that need to be addressed including development of manufacturing processes and equipment that take advantage of the most recent technical advances as well as effective utilization of data-driven analysis and experimentation to assist in manufacturing optimization.In this talk, AMMTO’s perspective on energy storage technology development and manufacturing will be discussed, highlighting current gaps and challenges that need to be addressed. In addition, there will be a robust discussion of a wide variety of DOE’s efforts in the context of technical and manufacturing challenges regarding scale-up and performance that still prevent the electrochemical energy storage community from achieving cost targets and commercial viability.