Techno-economic Analysis Research Articles

Electrothermal mineralization of per- and polyfluoroalkyl substances for soil remediation

Per- and polyfluoroalkyl substances (PFAS) are persistent and bioaccumulative pollutants that can easily accumulate in soil, posing a threat to environment and human health. Current PFAS degradation processes often suffer from low efficiency, high energy and water consumption, or lack of generality. Here, we develop a rapid electrothermal mineralization (REM) process to remediate PFAS-contaminated soil. With environmentally compatible biochar as the conductive additive, the soil temperature increases to >1000 °C within seconds by current pulse input, converting PFAS to calcium fluoride with inherent calcium compounds in soil. This process is applicable for remediating various PFAS contaminants in soil, with high removal efficiencies ( >99%) and mineralization ratios ( >90%). While retaining soil particle size, composition, water infiltration rate, and cation exchange capacity, REM facilitates an increase of exchangeable nutrient supply and arthropod survival in soil, rendering it superior to the time-consuming calcination approach that severely degrades soil properties. REM is scaled up to remediate soil at two kilograms per batch and promising for large-scale, on-site soil remediation. Life-cycle assessment and techno-economic analysis demonstrate REM as an environmentally friendly and economic process, with a significant reduction of energy consumption, greenhouse gas emission, water consumption, and operation cost, when compared to existing soil remediation practices.

Utilizing cost-effective pyrocarbon for highly efficient gold retrieval from e-waste leachate

Addressing burdens of electronic waste (E-waste) leachate while achieving sustainable and selective recovery of noble metals, such as gold, is highly demanded due to its limited supply and escalating prices. Here we demonstrate an environmentally-benign and practical approach for gold recovery from E-waste leachate using alginate-derived pyrocarbon sorbent. The sorbent demonstrates potent gold recovery performance compared to most previously reported advanced sorbents, showcasing high recovery capacity of 2829.7 mg g−1, high efficiency (>99.5%), remarkable selectivity (Kd ~ 3.1 × 108 mL g−1), and robust anti-interference capabilities within environmentally relevant contexts. The aromatic structures of pyrocarbon serve as crucial electrons sources, enabling a hydroxylation process that simultaneously generates electrons and phenolic hydroxyls for the reduction of gold ions. Our investigations further uncover a “stepwise” nucleation mechanism, in which gold ions are reduced as intermediate gold-chlorine clusters, facilitating rapid reduction process by lowering energy barriers from 1.08 to −21.84 eV. Technoeconomic analysis demonstrates its economic viability with an input-output ratio as high as 1370%. Our protocol obviates the necessity for organic reagents whilst obtaining 23.96 karats gold product from real-world central processing units (CPUs) leachates. This work introduces a green sorption technique for gold recovery, emphasizing its role in promoting a circular economy and environmental sustainability.

Boosting electrochemical oxygen reduction to hydrogen peroxide coupled with organic oxidation

The electrochemical oxygen reduction reaction (ORR) to produce hydrogen peroxide (H2O2) is appealing due to its sustainability. However, its efficiency is compromised by the competing 4e− ORR pathway. In this work, we report a hierarchical carbon nanosheet array electrode with a single-atom Ni catalyst synthesized using organic molecule-intercalated layered double hydroxides as precursors. The electrode exhibits excellent 2e− ORR performance under alkaline conditions and achieves H2O2 yield rates of 0.73 mol gcat−1 h−1 in the H-cell and 5.48 mol gcat−1 h−1 in the flow cell, outperforming most reported catalysts. The experimental results show that the Ni atoms selectively adsorb O2, while carbon nanosheets generate reactive hydrogen species, synergistically enhancing H2O2 production. Furthermore, a coupling reaction system integrating the 2e− ORR with ethylene glycol oxidation significantly enhances H2O2 yield rate to 7.30 mol gcat−1 h−1 while producing valuable glycolic acid. Moreover, we convert alkaline electrolyte containing H2O2 directly into the downstream product sodium perborate to reduce the separation cost further. Techno-economic analysis validates the economic viability of this system.

Determination of photovoltaic hydrogen production potential in Portugal: a techno-economic analysis

Determination of photovoltaic hydrogen production potential in Portugal: a techno-economic analysis

MXene: A Roadmap to Sustainable Energy Management, Synthesis Routes, Stabilization, and Economic Assessment.

MXenes with their wide range of tunability and good surface chemistry provide unique and distinctive characteristics offering potential employment in various aspects of energy management applications. These high-performance materials have attracted considerable attention in recent decades due to their outstanding characteristics. In the literature, most of the work is related to specific methods for the preparation of MXenes. In this Review, we present a detailed discussion on the synthesis of MXenes through different etching routes involving acids, such as hydrochloric acid, hydrofluoric acid, and lithium fluoride, and non-acidic alkaline solution, electrochemical, and molten salt methods. Furthermore, a concise overview of the different structural, optical, electronic, and magnetic properties of MXenes is provided corresponding to their role in supporting high thermal, chemical, mechanical, environmental, and electrochemical stability. Additionally, the role of MXenes in maintaining the thermal management performance of photovoltaic thermal systems (PV/T), wearable light heaters, solar water desalination, batteries, and supercapacitors is also briefly discussed. A techno-economic and life cycle analysis of MXenes is provided to analyze their sustainability, scalability, and commercialization to facilitate a comprehensive array of energy management systems. Lastly, the technology readiness level of MXenes is defined, and future recommendations for MXenes are provided for their further utilization in niche applications. The present work strives to link the chemistry of MXenes to process economics for energy management applications.

Techno-Economic Analysis of Grid-Connected PV Power Plants in Different Zones of Egypt

Techno-Economic Analysis of Grid-Connected PV Power Plants in Different Zones of Egypt

Balancing pH and yield: exploring itaconic acid production in Ustilago cynodontis from an economic perspective

BackgroundItaconic acid is a promising bio-based building block for the synthesis of polymers, plastics, fibers and other materials. In recent years, Ustilago cynodontis has emerged as an additional itaconate producing non-conventional yeast, mainly due to its high acid tolerance, which significantly reduces saline waste coproduction during fermentation and downstream processing. As a result, this could likely improve the economic viability of the itaconic acid production process with Ustilaginaceae.ResultsIn this study, we characterized a previously engineered itaconate hyper-producing Ustilago cynodontis strain in controlled fed-batch fermentations to determine the minimal and optimal pH for itaconate production. Under optimal fermentation conditions, the hyper-producing strain can achieve the theoretical maximal itaconate yield during the production phase in a fermentation at pH 3.6, but at the expense of considerable base addition. Base consumption is strongly reduced at the pH of 2.8, but at cost of production yield, titer, and rate. A techno-economic analysis based on the entire process demonstrated that savings due to an additional decrease in pH control reagents and saline waste costs cannot compensate the yield loss observed at the highly acidic pH value 2.8.ConclusionsOverall, this work provides novel data regarding the balancing of yield, titer, and rate in the context of pH, thereby contributing to a better understanding of the itaconic acid production process with Ustilago cynodontis, especially from an economic perspective.

Economic and technical evaluation of on-site electrolysis solar hydrogen refueling station in Corsica: A case study of Ajaccio

The European Union's ambitious target of achieving climate neutrality by 2050 necessitates a transition away from fossil fuels towards renewable energy sources. Hydrogen has emerged as a promising alternative, particularly as a fuel for large-scale transportation, including heavy-duty vehicles. The fleet buses in Ajaccio travel 1 494 007.9 km per year, responsible for 1453.67 tonnes of CO2 emissions annually. Utilizing green hydrogen, derived from renewable sources, can reduce these emissions by 87.3 %. This paper conducts a comprehensive techno-economic analysis of a hydrogen refueling station, aiming to foster the adoption of this technology and gain widespread acceptance. Our objective is to determine the economic viability of a hydrogen station capable of producing 440 kg of hydrogen daily. The Levelized Hydrogen Cost (LHC) is found to be 6.95 €/kg over a 20-year lifespan with electrolyzers operating at a power of 4.5 MW. The total installation cost amounts to 22 324 617 €. Remarkably, the return on investment is realized in the 11th year of operation. Electrolyzers account for 46 % of the system's total CAPEX and 29 % of its OPEX, indicating that advancements in electrolyzer technology will play a crucial role in reducing production costs. Our findings underscore the economic viability of the hydrogen refueling station, with a compelling LHC value indicative of its cost-effectiveness. The successful return on investment within a relatively short timeframe highlights the project's potential as a financially sound and sustainable initiative.

Techno-economic analysis of biomass pelletization as a sustainable biofuel with net-zero carbon emissions

Techno-economic analysis of biomass pelletization as a sustainable biofuel with net-zero carbon emissions

Techno-economic analysis of the production of synthetic fuels using CO2 generated by the cement industry and green hydrogen

Cement industry, due to the decomposition of CaCO3 and the production of clinker, emits large amounts of CO2 into the atmosphere. This anthropogenic gas can be captured and through its synthesis with green hydrogen, methanol and finally synthetic fuels are achieved. By using e-fuel, Europe's climate neutrality objectives could be achieved. However, the energy transition still lacks a clear roadmap, and decisions are strongly affected by the geopolitical situation, the energy demand and the economy. Therefore, different scenarios are analysed to assess the influence of key factors on the overall economic viability of the process: 1) A business-as-usual scenario, EU perspectives 2) allowing e-fuels and 3) improving H2 production processes. The technical feasibility of the production of synthetic fuels is verified. The most optimistic projections indicate future production costs of synthetic fuels will be lower than those of fossil fuels. This is directly related to the cost of green hydrogen production.

Enhancing Renewable Energy Integration in Developing Countries: A Policy-Oriented Analysis of Net Metering in Pakistan Amid Economic Challenges

Net metering (NM) is among the potent regulatory tools used globally for supporting distributed generation and renewable energy sources. This paper examines the trajectory of NM in a developing country such as Pakistan, analyzing the impact of regulatory changes, confidence-building strategies, hindering factors, and technical/financial issues. The three-stage methodology involves three components, namely techno-economic analysis, stakeholder engagement surveys, and impact analysis of financing mechanisms. This study emphasizes the importance of clear regulatory and financial frameworks, grid upgrades, and public–private partnerships for technology distribution in the context of a developing country with weak grid utilities and an import–export energy ratio. It also explores the role of financial incentives, such as tax breaks and subsidies, to encourage investment in NM systems from the perspective of lucrative rates, impact on paybacks, and return on investments, and proposes concrete solutions to enhance financial inclusion for ambitious renewable energy goals. Until April 2023, over 56,000 NM/distributed generation facilities were commissioned, with an installed capacity of 950 MW. By May 2024, the number of NM consumers reached ~100,000, with a 1950 MW capacity, nearly doubling. However, the import and export ratio of IESCO changed most, with 61% exports and 39% imports, directly impacting the revenue stream. A total of 60% of banks have adopted actions linked with green banking criteria, aiming to limit their environmental impact. The change in tariff will result in reduced ROI for NM consumers to 20%, and increase the payback period from less than 4 years to 13 years. Government subsidies, tax breaks, and green financing frameworks are proposed to encourage investment, but have been abruptly halted, and were previously at a 6% interest rate. This research aims to provide insights into effective market evaluation methodologies for NM programs and offer policy recommendations to strengthen legislative and institutional frameworks governing NM.

Design and techno-economic analysis of solar energy based on-site hydrogen refueling station

This paper presents a detailed techno-economic review and assessment of a hydrogen refueling station (HRS) powered by a grid-connected photovoltaic (PV) system to address the issues of carbon emissions and energy sustainability in transportation. In the study, the HRS system with 1, 3 and 5 MW PV installed capacity for Ankara, the capital city of Türkiye, is considered for different system lifetimes. In the proposed HRS, on-site hydrogen production is achieved through anion exchange membrane water electrolysis (AEMWE) using a grid-connected PV system, and the produced hydrogen is stored in a cascaded storage system and is utilized at the HRS station. In order to evaluate the cost competitiveness and economic viability of the designed HRS system, the levelized cost of hydrogen (LCOH) is determined by considering the initial investment costs, operating expenses and potential revenue streams. The results show that the HRS capacity, PV installed capacity and system lifetime significantly impact the LCOH. The technoeconomic analysis results show that the best system configuration was determined as 8.54 €/kg H2 in the 20-year long term refueling scenario for a 5 MW installed PV capacity with a daily refueling capacity of 170 kg H2. This study contributes to the development of sustainable energy infrastructure by providing a comprehensive framework for the design, calculation and economic evaluation of PV-integrated hydrogen refueling stations. The results provide valuable information for policymakers, industry stakeholders, and researchers to help achieve a carbon-neutral transportation sector and promote energy sustainability.

Elimination of microplastics, PFAS, and PPCPs from biosolids via pyrolysis to produce biochar: Feasibility and techno-economic analysis

Biosolids from municipal wastewater treatment contain many contaminants of emerging concern, including microplastics (MPs), per- and polyfluoroalkyl substances (PFAS), pharmaceuticals and chemicals from personal care products (PPCPs). Many of these contaminants have very slow biotic or abiotic degradation rates and have been shown to have human and ecological health impacts. Application of biosolids to agriculture, a common disposal method, can result in extended environmental contamination. An approach for eliminating the contaminants is pyrolysis, which can also generate biochar, enhancing carbon sequestration as a side-benefit. We pyrolyzed biosolid samples from an operating facility at various temperatures from 400 to 700 °C with a 2-hour residence time. We then evaluated contaminant removal, which in many cases was 100 %, with only a few residuals. No trace of PFAS was detectable even at 400 °C. Overall mass removal of PPCPs, including PFAS, was over 99.9 %. MP removal via pyrolysis ranged from 91 to 97 %. The biochar contains significant amounts of Fe and P, which make it a useful fertilizer amendment. The techno-economic analysis indicates that pyrolysis may generate significant cost savings, and revenue from the sale of biochar, sufficient to more than cover the investment and operating costs of the dryer and pyrolysis unit.

Techno-economic assessment and carbon pricing analysis for economic feasibility of epoxidized sucrose soyate: A biobased thermoset resin

The substantial environmental issues associated with plastic production have prompted researchers to accelerate the development of environmentally friendly biobased alternatives to reduce reliance on petroleum-based resources and mitigate emissions. Epoxidized Sucrose Soyate (ESS), a high-performance biobased epoxy resin obtained from soybean oil and sucrose, has shown promising potential in polymers and coatings applications. The success of ESS performance necessitates further investigations into its industrial-scale production and viability as an environmentally sustainable alternative to conventional petroleum-based resins. This study consists of a comprehensive techno-economic analysis (TEA) and cradle-to-gate life cycle assessment (LCA) to evaluate the technical, economic, and environmental feasibility of industrial-scale ESS production. The minimum selling price (MSP) of ESS at various production scales was estimated which offers insights into cost optimization. The MSP for 0.1, 1.0, and 10 ton/h processing capacity of sucrose soyate was calculated to be $9.57, $6.74, and $6.62 per kg of ESS, respectively. Relative to a comparable petroleum-based epoxy resin with similar functionality, such as bisphenol A diglycidyl ether (with a price range of $1.8 to $5.2 per kg), larger scales of ESS production have the potential to compete economically. The LCA results demonstrated the superior environmental performance of ESS, especially in the global warming potential category, indicating its potential as a compelling sustainable choice for replacing petroleum-based resins. This combined TEA and LCA study demonstrated the economic viability and environmental benefits of ESS, highlighting its promise as a sustainable alternative for industrial applications.

An Economic Performance Improving and Analysis for Offshore Wind Farm-Based Islanded Green Hydrogen System

When offshore wind farms are connected to a hydrogen plant with dedicated transmission lines, for example, high-voltage direct current, the fluctuation of wind speed will influence the efficiency of the alkaline electrolyzer and deteriorate the techno-economic performance. To overcome this issue, firstly, an additional heating process is adopted to achieve insulation for the alkaline solution when power generated by wind farms is below the alkaline electrolyzer minimum power threshold, while the alkaline electrolyzer overload feature is used to generate hydrogen when wind power is at its peak. Then, a simplified piecewise model-based alkaline electrolyzer techno-economic analysis model is proposed. The improved economic performance of the islanded green hydrogen system with the proposed operation strategy is verified based on the wind speed data set simulation generated by the Weibull distribution. Lastly, the sensitivity of the total return on investment to wind speed parameters was investigated, and an islanded green hydrogen system capacity allocation based on the proposed analysis model was conducted. The simulation result shows the total energy utilization increased from 62.0768% to 72.5419%, and the return on investment increased from 5.1303%/month to 5.9581%/month when the proposed control strategy is adopted.

Techno-Economic Analysis of Atmospheric Water Harvesting Across Climates.

Drinking water scarcity is a global challenge as groundwater and surface water availability diminishes. The atmosphere is an alternative freshwater reservoir that has universal availability and could be harvested as drinking water. In order to effectively perform atmospheric water harvesting (AWH), we need to (1) understand how different climate regions (e.g., arid, temperate, and tropical) drive the amount of water that can be harvested and (2) determine the cost to purchase, operate, and power AWH. This research pairs thermodynamics with techno-economic analysis to calculate the water productivity and cost breakdown of a representative condensation-based AWH unit with water treatment. We calculate the monthly and annual levelized cost of water from AWH as a function of climate and power source (grid electricity vs renewable energy from solar photovoltaics (PV)). In our modeled unit, AWH can provide 1744-2710 L/month in a tropical climate, 394-1983 L/month in a temperate climate, and 37-1470 L/month in an arid climate. The levelized cost of water of AWH powered by the electrical grid is $0.06/L in a tropical climate, $0.09/L in a temperate climate, and $0.17/L in an arid climate. If off-grid solar PV was purchased at the time of purchasing the AWH unit to power the AWH, the costs increase to $0.40/L in an arid climate, $0.17/L in a temperate climate, and $0.10/L in a tropical climate. However, if using existing solar PV there are potential cost reductions of 4.25-5-fold between purchasing and using existing solar PV, and 2-3-fold between using the electrical grid and existing solar PV, with the highest cost reductions occurring in the tropical climate. Using existing solar PV, the levelized cost of AWH is $0.09/L in an arid climate, $0.04/L in a temperate climate, and $0.02/L in a tropical climate.

Solar irrigation potential in Sub-Saharan Africa: a crop-specific techno-economic analysis

In this study, we introduce an integrated modeling framework that combines a hydrologic model, a biophysical crop model, and a techno-economic model to assess solar irrigation potential in Sub-Saharan Africa (SSA) based on seven commonly grown food crops-maize, wheat, sorghum, potato, cassava, tomato, and onion. The study involves determining the irrigation requirements, location-specific capital investment costs, crop-specific profitability, and the cropland area under various cost scenarios (low and high) and soil fertility (low, moderate, near-optimal, and optimal) scenarios. Our research reveals considerable potential for solar irrigation, with profitability and viable cropland areas that vary according to crop type, irrigation system cost scenarios, and soil fertility levels. Our assessment shows that approximately 9.34 million ha of SSA’s current rainfed cropland are hydrologically and economically feasible for solar irrigation. Specifically, maize and onion display the lowest and highest viability, spanning 1–4 million ha and 29–33 million ha, respectively, under optimal soil fertility conditions. In terms of profitability, maize and onion rank as the least and most economically viable crops for solar irrigation, yielding average annual returns of $50-$125/ha and $933-$1450/ha, respectively, under optimal soil fertility conditions. The lower and upper bounds of profitability and cropland range correspond to high-cost and low-cost scenarios, respectively. Furthermore, our study reveals distinct regional differences in the economic feasibility of solar irrigation. Eastern Africa is more economically favorable for maize, sorghum, tomato, and cassava. Central Africa stands out for onion cultivation, whereas West and Southern Africa are more profitable for potato and wheat, respectively. To realize the irrigation benefits highlighted, an energy input of 940-2,168 kWh/ha/yr is necessary, varying by crop and geographic sub-region of the SSA sub-continent. Our model and its results highlights the importance of selecting the right crops, applying fertilizers at the appropriate rates, and considering regional factors to maximize the benefits of solar irrigation in SSA. These insights are crucial for strategic planning and investment in the region’s agricultural sector.

Process Integration for the Production of Bioplastic Monomer: Techno-Economic Analysis and Life-Cycle Assessment

Process Integration for the Production of Bioplastic Monomer: Techno-Economic Analysis and Life-Cycle Assessment

Towards Sustainable Energy Communities: Integrating Time-of-Use Pricing and Techno-Economic Analysis for Optimal Design—A Case Study of Valongo, Portugal

This paper presents a comprehensive analysis of optimal energy community design, leveraging time-of-use pricing mechanisms and techno-economic parameters. Focusing on a case study of Valongo, Portugal, this study explores the intricate interplay between energy infrastructure planning, economic considerations, and pricing dynamics. Through a systematic approach, various factors, such as renewable energy integration, demand–response strategies, and investment costs, are evaluated to formulate an efficient and sustainable energy community model. Time-of-use pricing schemes are incorporated to reflect the dynamic nature of energy markets and consumer behavior. By integrating techno-economic analyses, this study aims to optimize energy resource allocation while ensuring cost-effectiveness and environmental sustainability. The influence of optimized sizes of photovoltaics (PV), battery storage, and electrical vehicles (EVs) on self-sufficiency rates, self-consumption rates and CO2 savings is analyzed. The findings offer valuable insights into the design and implementation of energy communities in urban settings, highlighting the importance of adaptive strategies in the transition towards a resilient and low-carbon energy future. The novelty of this paper lies in its comprehensive approach to energy community design, which integrates time-of-use pricing mechanisms with techno-economic parameters. By focusing on the specific case of Valongo, Portugal, it addresses the unique challenges and opportunities present in urban settings. Additionally, the analysis considers the interaction between renewable energy production, demand profiles and investment costs, providing valuable insights for optimizing resource allocation and achieving both cost-effectiveness and environmental sustainability.

Evaluating the economic and environmental benefits of deploying a national-scale, thermo-chemical plastic waste upcycling infrastructure in the United States

Emerging chemical technologies can upcycle plastic waste by producing high-value polymers and other products. In this work, we study the economic and environmental benefits of deploying an upcycling infrastructure in the continental United States for producing low-density polyethylene (LDPE) and polypropylene (PP) from post-consumer plastic waste. Our analysis is based on a computational framework that integrates techno-economic analysis, life-cycle assessment, and value chain optimization. Our results demonstrate that the infrastructure could generate a market of nearly 20 billion USD per year and that this market is robust to various externalities. Our analysis also indicates that the infrastructure can achieve a plastic-to-plastic degree of circularity of 34% relative to residential plastic waste production, and leads to significant environmental benefits over alternative waste disposal methods, including 69%–75% lower greenhouse gas emissions than waste-to-energy systems and 38 million tonnes of avoided landfill waste per year.