We introduce for the first time a time-resolved temperature measurement technique which relies on temperature-jump luminescence thermometry using NaYF4:Yb3+:Er3+ upconverting nanocrystals. This new time-resolved technique is based on optical thermometry using upconverting nanoparticles (UCNPs) and does not have to infer temperature from changes in the optical properties of the heater or surrounding local environment. We have prepared gold-decorated UCNPs that function as a dual single-heater thermometer system. We measure the time-resolved temperature jump from nanocrystal clusters and compare our results to simulated thermal transfer data generated using finite element methods. The simulated data show that temperature dissipation follows a power law where the temperature change is inversely related to time. This result agrees with a thermal diffusion model where a semi-infinite medium is exposed to a sudden temperature change at its surface, but the simulated results do not agree that the heat transfer p...
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