Real-time Measurement Technique Research Articles

Aircraft-engine particulate matter emissions from conventional and sustainable aviation fuel combustion: comparison of measurement techniques for mass, number, and size

Abstract. Sustainable aviation fuels (SAFs) have different compositions compared to conventional petroleum jet fuels, particularly in terms of fuel sulfur and hydrocarbon content. These differences may change the amount and physicochemical properties of volatile and non-volatile particulate matter (nvPM) emitted by aircraft engines. In this study, we evaluate whether comparable nvPM measurement techniques respond similarly to nvPM produced by three blends of SAFs compared to three conventional fuels. Multiple SAF blends and conventional (Jet A-1) jet fuels were combusted in a V2527-A5 engine, while an additional conventional fuel (JP-8) was combusted in a CFM56-2C1 engine. We evaluated nvPM mass concentration measured by three real-time measurement techniques: photoacoustic spectroscopy, laser-induced incandescence, and the extinction-minus-scattering technique. Various commercial instruments were tested, including three laser-induced incandescence (LII) 300s, one photoacoustic extinctiometer (PAX), one micro soot sensor (MSS+), and two cavity-attenuated phase shift PMSSA (CAPS PMSSA) instruments. Mass-based emission indices (EIm) reported by these techniques were similar, falling within 30 % of their geometric mean for EIm above 100 mg per kg fuel (approximately 10 µg PM m−3 at the instrument); this geometric mean was therefore used as a reference value. Additionally, two integrative measurement techniques were evaluated: filter photometry and particle size distribution (PSD) integration. The commercial instruments used were one tricolor absorption photometer (TAP), one particle soot absorption photometer (PSAP), and two scanning mobility particle sizers (SMPSs). The TAP and PSAP were operated at 5 % and 10 % of their nominal flow rates, respectively, to extend the life of their filters. These techniques are used in specific applications, such as on board research aircraft to determine particulate matter (PM) emissions at cruise. EIm reported by the alternative techniques fell within approximately 50 % of the mean aerosol-phase EIm. In addition, we measured PM-number-based emission indices using PSDs and condensation particle counters (CPCs). The commercial instruments used included TSI SMPSs, a Cambustion differential mobility spectrometer (DMS500), and an AVL particle counter (APC), and the data also fell within approximately 50 % of their geometric mean. The number-based emission indices were highly sensitive to the accuracy of the sampling-line penetration functions applied as corrections. In contrast, the EIm data were less sensitive to those corrections since a smaller volume fraction fell within the size range where corrections were substantial. A separate, dedicated experiment also showed that the operating laser fluence used in the LII 300 laser-induced incandescence instrument for aircraft-engine nvPM measurement is adequate for a range of SAF blends investigated in this study. Overall, we conclude that all tested instruments are suitable for the measurement of nvPM emissions from the combustion of SAF blends in aircraft engines.

Investigation of RH Effect on Uncommon Limonene Ozonolysis Products and SOA Formation in Indoor Air with Real Time Measurement Techniques

Investigation of RH Effect on Uncommon Limonene Ozonolysis Products and SOA Formation in Indoor Air with Real Time Measurement Techniques

Nondestructive Quantitative Analysis of Water Potential of Tomato Leaves Using Online Hyperspectral Imaging System

HighlightsWe developed an online measurement system for water potential of tomato plants using hyperspectral imaging.We used Linear Discriminant Analysis to automatically and quickly extract the leaf images.We used SNV scattering correction to remove the spectral variations caused by collecting the defocused leaf images.We developed a prediction model of leaf water potential based on spectral image information.Abstract. Tomatoes have different water requirements in each growing period. Excessive water use or insufficient water supply will affect the growth and yield of tomato plants. Therefore, precise irrigation control is necessary during cultivation to increase crop productivity. Traditionally, the soil moisture content or leaf water potential has been used as an indicator of plant water status. These methods, however, have limited accuracy and are time-consuming, making it difficult to be put into practice in tomato production. This study developed an online hyperspectral imaging system to measure the leaf water potential of tomato nondestructively. Linear Discriminant Analysis was utilized to automatically and quickly extract the leaf images, with the recognition accuracy of 94.68% was achieved. The mathematical processing of Standard Normal Variate scattering correction was used to remove the spectral variations caused by the defocused leave images. The developed leaf water potential prediction model based on the spectral image information attained using the developed system achieved the standard error of calibration of 0.201, coefficient of determination in calibration set of 0.814 and standard error of cross-validation of 0.230, and one minus the variance ratio of 0.755. The obtained performance indicated the feasibility of applying the developed online hyperspectral imaging system as a real-time non-destructive measurement technique for the leaf water potential of tomato plants. Keywords: Hyperspectral imaging system, Machine learning, Tomato, Water potential.

Real-Time Double-Layer Thin Film Thickness Measurements Using Modified Sagnac Interferometer with Polarization Phase Shifting Approach

This paper describes a modified Sagnac interferometer with a self-referenced polarization and phase-shifting technique for real-time thickness measurement of single- and double-layer transparent thin films. The proposed interferometric setup generated outstanding rotating linearly polarized light with a degree of polarization (DOP) of 99.40%. A beam splitter placed at the interferometer output separated the beam into two identical linearly polarized beams. One of the beams served as a reference, while the other served as a sensing arm. The output linear polarizer set at 45° relative to a reference plane was positioned anterior to the photodetectors to get rotating light intensities for phase shift measurement; hence, the intensities at various polarizations of 0°, 45°, and 90° were automatically acquired without any polarizing device adjustments. These intensities were then transformed into a phase retardation introduced by a sample, and the resulting phase shift was eventually converted into film thickness. The samples were properly prepared, with pure BK7 substrate being deposited by WO3-, Ta2O5-, and WO3/Ta2O5 films of known thicknesses. The thickness measurement obtained from the proposed system yielded reading errors of 1.3%, 0.2%, and 1.3/2.5% for WO3-, Ta2O5-, and WO3/Ta2O5 films, respectively. The mathematical theory was effectively demonstrated and empirically confirmed. The experimental results show that the proposed setup has a lot of potential for real-time, non-destructive thickness assessment of transparent thin films without the need to modify polarizing device orientations.

A strategy for on-machine springback measurement in rotary draw bending using digital image-based laser tracking

Rotary draw bending is a commonly used metal forming technique for profile bending. Due to the elastic recovery of the material, springback compensation to control the bent product quality is one of the critical manufacturing issues. The realized bend angle has to be measured for springback compensation before removing the profile from the machine, and the bending process can follow an iterative approach until the product quality is satisfied. However, this trial-and-error is costly for batch production in manufacturing. An on-machine measurement technique is therefore developed to measure springback in rotary draw bending with an affordable laser and a webcam. An image processing technology is integrated with the manufacturing process to track the deformation and measure springback angle in real time, eliminating the need for the workpiece to be transferred to a measurement device. In this paper, bending experiments were conducted with AA6082 rectangular hollow profiles bent at 30°, 45°, 60°, and 90° angles, and springback angles from the conventional manual measurement were compared to that from the on-machine measurement. Since the difference in springback measurement between the proposed and the conventional methods was within 0.15° on average, it is demonstrated that the laser tracking, on-machine measurement is a feasible real-time springback measurement technique for Industry 4.0.

Cytochrome P450 2B6 Amperometric Biosensor for Continuous Monitoring of Propofol

Despite the growing evidence of improved patient outcomes and of a substantially reduced environmental impact of propofol-based total intravenous anesthesia when compared to volatile-based techniques, the vast majority of general anesthetics still use volatile agents for the maintenance phase. A significant reason for this is the lack of suitable point-of-care, real-time blood propofol measurement techniques. Here we present an enzyme-based electrochemical biosensor for the detection of propofol. Deactivated yeast cells expressing the enzyme cytochrome P450 2B6 are immobilized, alongside gold nanoparticles, within a chitosan film upon the surface of a screen printed electrode. In the presence of the cofactor NADPH, the enzyme converts propofol to a quinone/quinol redox pair that can be detected using simple electrochemistry. This approach avoids the issue of electrode fouling that commonly renders electrochemical propofol sensors impractical. The sensor has a limit of detection of 67 ± 7 ng/ml and a sensitivity of 4.2 ± 0.2 nA/ <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mu \text{g}$ </tex-math></inline-formula> /ml/mm <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$^{\mathbf {2}}$ </tex-math></inline-formula> . It has been successfully demonstrated in a serum-like solution and has shown a linear response across the therapeutic range of propofol (1 – <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$10~\mu \text{g}$ </tex-math></inline-formula> /ml). Additionally, the sensor has shown good specificity with regards to potential interfering compounds.

A novel technique for real-time ion identification and energy measurement for in situ space instrumentation

The AGILE (Advanced enerGetic Ion eLectron tElescope) project focuses on the development of a compact low-cost space-based instrument to measure the intensities of charged particles and ions in space. Using multiple layers of fast silicon sensors and custom front-end electronics, the instrument is designed for real-time particle identification of a large variety of elements from H to Fe and spanning energies from 1 to 100 MeV per nucleon. The robust method proposed in this work uses key defining features of electronic signals generated by charged particles (ions) traveling through silicon layers to reliably identify and characterize particles in situ. AGILE will use this real-time pulse shape discrimination technique for the first time in space based instrumentation.

A new technique for real-time measurements of potassium and sodium aerosols based on field-reversal surface ionization

A new method for real-time measurements of potassium and sodium containing aerosol particles is described and verified. The method is based on surface ionization technique and may be used to explore the alkali chemistry related to high temperature chemistry processes. The measurement device is a further development of the simple and cost-effective surface ionization detector previously used for online alkali measurements in combustion and gasification research. The discrimination between sodium and potassium is possible due to differences in their surface desorption kinetics and facilitated by rapidly reversing the field potential between the ion source and the nearby collector. The instrument is evaluated in a series of laboratory experiments using size-selected alkali salt particles containing KCl, NaCl, K2SO4, Na2SO4, KNO3 and NaNO3. The filament temperature was found to be a key influencing factor in order to optimize the strength and Na–K deviation of the observed ion current. The ability to simultaneously report absolute concentrations of Na and K makes the instrument attractive for solid fuel conversion of alkali-rich fuels such as low-grade biomass and to explore behavior deviations of Na and K in high temperature processes.

Time evolution of the scour induced by a ski jump jet

Scour studies are often made at the equilibrium stage when the scour hole is stabilized and no more changes in the scour geometry occur. However, studying the scour time evolution is critical to better understand the erosion process and the main factors that control it in the short and long terms. Scour is a destructive process, therefore, in the absence of non-intrusive and real-time measurement techniques, an experimental analysis of time evolution of scour can be a time-consuming process as, for each considered instant, detailed measurements of the bed geometry must be taken. In this paper, two different strategies are applied to analyse the scour time evolution. Their results are compared and discussed. From the obtained experimental results, empirical relations between different variables were proposed. Further analysis provided scale relationships to adimensionalize the time evolution profiles. To measure the scour geometry, a structure from motion technique is employed.

A Human Expert Based Approach to Heartrate Monitoring System with Automatic Message Sending Via Smartphones

The objective of the paper was to propose a human – expert based approach on a heartbeat calculating and message sending system. Heart related disease is rising among today's population. The need for an accurate yet affordable heart rate is essential to ensure one's health quality. However, in today's market, most heart monitors are expensive and are not user friendly. Our goal is to calculate the heart beat using smart phones that is user friendly and less expensive. In Today's situation 50% percent of people using Smart phones, so in order to make our goal possible we are using the smart phones to calculate the humans heart beat rate accurate. In this project, a real-time heart rate measurement technique called Photo-Plethysmography (PPG) is implemented using simple infrared transmitter and receiver circuit. Our main aim to decrease the death rate of humans due to heart related diseases, so we can assign the smart phones to sending an emergency alert message to the particular persons relatives and to an ambulance or to the nearby doctor resources along with the location of the user when the Blood pressure is increasing/decreasing then normal rate. By sending an alert message the lives of an human will be recovered from critical situation.

Real-time temperature measurement of living cells exposed to microwaves using a temperature-dependent fluorescent dye

Real-time measurement of temperature in living cells exposed to microwaves is challenging because of the low spatial resolution of conventional temperature probes. Here, we established a noninvasive method by using a temperature-dependent fluorescent dye, Rhodamine B (Rho-B) to stain living cells that were exposed to a customized microwave exposure device. The relationship between Rho-B fluorescence and the temperature of living cells, and between Fluo4/AM and the inward inflow of Ca2+ were established. The results showed that the fluorescence intensity changed by 7.9%/°C as the temperature rose from 25 °C to 37 °C. The spatial resolution and temporal resolution of this method were 225 × 225 µm 2 and 1.5 s, respectively. In conclusion, the real-time temperature measurement technique is simple to use and requires no specialized equipment beyond a LSCM. This method can provide real-time information of the temperature changes in cells simultaneously with the investigation of calcium concentration.

FT-IR と質量分析を用いた自動車排気中の リアルタイム炭化水素分析技術の開発

FT-IR と質量分析を用いた自動車排気中の リアルタイム炭化水素分析技術の開発

Calibration-free real-time organic film thickness monitoring technique by reflected X-Ray fluorescence and compton scattering measurement

Most thickness measurement techniques using X-ray radiation are unsuitable in field processes involving fast-moving organic films. Herein, we propose a Compton scattering X-ray radiation method, which probes the light elements in organic materials, and a new simple, non-destructive, and non-contact calibration-free real-time film thickness measurement technique by setting up a bench-top X-ray thickness measurement system simulating a field process dealing with thin flexible organic films. The use of X-ray fluorescence and Compton scattering X-ray radiation reflectance signals from films in close contact with a roller produced accurate thickness measurements. In a high-thickness range, the contribution of X-ray fluorescence is negligible, whereas that of Compton scattering is negligible in a low-thickness range. X-ray fluorescence and Compton scattering show good correlations with the organic film thickness (R2 = 0.997 and 0.999 for X-ray fluorescence and Compton scattering, respectively, in the thickness range 0–0.5 mm). Although the sensitivity of X-ray fluorescence is approximately 4.6 times higher than that of Compton scattering, Compton scattering signals are useful for thick films (e.g., thicker than ca. 1–5 mm under our present experiment conditions). Thus, successful calibration-free thickness monitoring is possible for fast-moving films, as demonstrated in our experiments.

Real-Time Plasma Uniformity Monitoring via Selective Plasma Light Intensity Measurement Using Transparent-LCD-Module-Adapted Optical Emission Spectroscopy

A real-time selective plasma light intensity measurement technique involving optical emission spectroscopy (OES) is proposed for process uniformity monitoring and detection in various plasma regions during semiconductor processing. Among plasma diagnostic techniques, OES is a noncontact plasma measurement technique for process end point and plasma abnormality detection that does not cause any process damage. Therefore, it is mostly used in all plasma-based tools. However, conventional OES systems are incapable of real-time plasma uniformity detection at specific OES sampling times, and therefore, there is a need for improving them. In this study, we show that selective plasma light intensity, including those on the left and right sides of a process chamber, can be measured with transparent-LCD-module-adapted conventional OES for determining process uniformity. The proposed technique can be used to measure the selective plasma light intensity in specific regions of the process chamber, such as the center and edge regions of a wafer, and to thereby analyze the plasma process uniformity.

Energy-Coupling Mechanisms Revealed through Simultaneous Keyhole Depth and Absorptance Measurements during Laser-Metal Processing

The interaction between high-irradiance light and molten metal is the complex multiphysics phenomenon that underpins industrial processes such as laser-based additive manufacturing, welding, and cutting. One aspect that requires careful attention is the formation and evolution of vapor depressions, or keyholes, within the molten metal. The dynamic behavior of these depressions can dramatically change the number of laser-beam reflections and is therefore intrinsically linked to the instantaneous energy coupled into the system. Despite its importance, there is a severe lack of direct in situ, experimental evidence of this relationship, which creates challenges for those who aim to model or control laser-based manufacturing processes. In this work, we combine two simultaneous state-of-the-art real-time measurement techniques (inline coherent imaging and integrating-sphere radiometry) to confirm and explore the definite positive correlation between the highly dynamic vapor-depression geometry and laser energy absorptance. For irradiances resulting in vapor-depression formation ($\ensuremath{\ge}0.49\phantom{\rule{0.1em}{0ex}}{\mathrm{MW}/\mathrm{cm}}^{2}$), we observe excellent correlation (0.86) between the instantaneous depth (down to 800 $\ensuremath{\mu}\mathrm{m}$) and the absorptance (up to 0.92), directly demonstrating their interdependence. In the transition mode, an important regime for additive manufacturing, we observe temporary vapor-depression formation with concomitant changes in absorptance from 0.34 to 0.53. At higher irradiances, we detect stepwise increases in the absorbed laser power with a smoothly increasing keyhole depth, which is a real-time experimental observation of the effect of multiple reflections during laser-metal processing. The value of simultaneous depth and absorption measurements for predictive model validation is presented using ray-tracing simulations, which also confirm the absorption enhancement via incremental increases in the reflection count. This work provides insight into the underlying physics of laser-based metal manufacturing that is useful toward deterministic modeling and real-time process control.

Investigation of the Dynamism of Nanosized SOA Particle Formation in Indoor Air by a Scanning Mobility Particle Sizer and Proton-Transfer-Reaction Mass Spectrometry

Terpenes are VOCs of particular importance, since they are emitted from a wide range of indoor sources and are considered to be precursors of Secondary Organic Aerosol (SOA) formation. It has been proven that SOA particles, especially nanosized ones, pose a threat to human health. In this research, experiments with the application of an environmental chamber and real-time measurement techniques were carried out to investigate in a complimentary way the formation of monoterpene oxidation products and nanosized SOA particles initiated by monoterpene ozonolysis. Proton-Transfer-Reaction Mass Spectrometry with a Time-Of-Flight analyzer (PTR-TOF-MS) and a Scanning Mobility Particle Sizer (SMPS) were applied to determine in real time the dynamism of the formation of the corresponding terpene ozonolysis products and submicron SOA particles. Results proved that firstly, oxidation products were formed, and then, they underwent nucleation and condensation, forming particles whose diameters grew with time. The oxidation products formed were different depending on the type of terpenes applied. The comparison of the results obtained during the experiments with gaseous standard mixtures and real samples commonly present and used in indoor air revealed that the diversified chemical composition of the emission source had implications for both the particle formation initiated by the oxidation of essential oil components and the chemical reactions occurring via the oxidation process. With the instrumentation utilized, the concentration changes at the level of a few ppbv could be monitored.

Current situation of polycyclic aromatic hydrocarbons (PAH) in PM2.5 in a receptor site in Mexico City and estimation of carcinogenic PAH by combining non-real-time and real-time measurement techniques

Air pollution is a public health concern. Polycyclic aromatic hydrocarbons (PAH) are ubiquitous atmospheric pollutants contained in the atmospheric aerosol. PAH in particulate matter with diameters ≤2.5 µm (PM2.5) represent a human health risk due to their toxic properties. In this study, PAH in PM2.5 at a receptor site of Mexico City during the dry cold season were determined. The most abundant PAH (median, 10–90th percentile, pg m−3) were benzo[ghi]perylene (467, 291–697), followed by pyrene (427, 218–642). A decrease around 40% in the carcinogenic PAH onto PM2.5 was calculated with respect to the same PAH measured a decade ago, at the same receptor site, despite of increase in vehicle fleet. The PAH decrease trend agrees with the decrease trend of CO, NO and NO2, released into the air by similar emission sources than PAH. Control emissions strategies implemented by local and federal authorities are discussed. PAH analyses were carried out by non-real-time and real-time methods. The PAH non-real-time method involved PM2.5 sampling, sample treatment and gas chromatography-mass spectrometry analysis. The PAH real-time method involved the use of a photoelectric aerosol sensor (PAS). The PAH determination by non-real time method was selective and efficient, with recoveries between 75 ± 14% and 98 ± 26%. By combining non-real-time and real-time methodologies, multivariate regression models were obtained based on PAS response, NO2 and wind speed to estimate PAH in PM2.5 at low-cost (r2 = 0.59 to r2 = 0.89). Fossil fuel combustion from vehicles was the major source around the sampling site. Diagnostic ratios (DR) based on retene, chrysene, and triphenylene, suggested biomass burning emission sources. Photo-oxidation in sunny months was observed based on benzo[a]pyrene, benzo[ghi]perylene, benz[a]anthracene, indeno[1,2,3-cd]pyrene and black carbon. The correlation analyses suggested transport of PM2.5, O3, BC and SO2 to the sampling site, and local emissions of PAH, NO and CO.

Breathing dissipative solitons in mode-locked fiber lasers

Dissipative solitons are self-localized coherent structures arising from the balance between energy supply and dissipation. Besides stationary dissipative solitons, there are dynamical ones exhibiting oscillatory behavior, known as breathing dissipative solitons. Substantial interest in breathing dissipative solitons is driven by both their fundamental importance in nonlinear science and their practical applications, such as in spectroscopy. Yet, the observation of breathers has been mainly restricted to microresonator platforms. Here, we generate breathers in a mode-locked fiber laser. They exist in the laser cavity under the pump threshold of stationary mode locking. Using fast detection, we are able to observe the temporal and spectral evolutions of the breathers in real time. Breathing soliton molecules are also observed. Breathers introduce a new regime of mode locking into ultrafast lasers. Our findings may contribute to the design of advanced laser sources and open up new possibilities of generating breathers in various dissipative systems.

Rogue waves and analogies in optics and oceanography

We review the study of rogue waves and related instabilities in optical and oceanic environments, with particular focus on recent experimental developments. In optics, we emphasize results arising from the use of real-time measurement techniques, whilst in oceanography we consider insights obtained from analysis of real-world ocean wave data and controlled experiments in wave tanks. Although significant progress in understanding rogue waves has been made based on an analogy between wave dynamics in optics and hydrodynamics, these comparisons have predominantly focused on one-dimensional nonlinear propagation scenarios. As a result, there remains significant debate about the dominant physical mechanisms driving the generation of ocean rogue waves in the complex environment of the open sea. Here, we review state-of-the-art of rogue wave studies in optics and hydrodynamics, aiming to clearly identify similarities and differences between the results obtained in the two fields. In hydrodynamics, we take care to review results that support both nonlinear and linear interpretations of ocean rogue wave formation, and in optics, we also summarise results from an emerging area of research applying the measurement techniques developed for the study of rogue waves to dissipative soliton systems. We conclude with a discussion of important future research directions.

Compact and high-speed Stokes polarimeter using three-way polarization-preserving beam splitters.

We present a new real-time Stokes parameter measurement technique using three polarized beam splitters without mechanical motion or electrical tuning. This system can analyze the polarization state of light at 30kHz, limited only by the speed of the detector analog to digital converters. The optical system is also compact (52×30×25 mm) because it consists only of small volume optical devices. We show that the system can measure arbitrary polarization states with an accuracy of better than 0.006 in the normalized Stokes parameters. We also demonstrate the ability to measure fast dynamic polarization states by analyzing the state produced by a fast rotating quarter-wave plate and the time-dependent stress induced in a PMMA block by hitting the block with a hammer.