Over the last three decades, dye-sensitized solar cells (DSSCs) have received a lot of attention, reaching record efficiencies under AM 1.5G illumination slightly over 10%. However, these values are lower than other competing photovoltaic systems. The performance of DSSCs has to be further enhanced in order to have a substantial influence and application potential in the field of photovoltaics. Herein we propose a new intriguing strategy to take advantage of two concepts well known in the field of photovoltaics, such as the tandem configuration and the bifaciality, never applied at the same time to DSSCs. Thanks to the combination of these strategies, we are noteworthy able to overcome the maximum efficiency ever obtained for a traditional DSSC based on iodide/triiodide redox couple and Ru-based dye, as high as 14.96%. Our findings open the way to further enhancement with optimized DSSCs configuration.
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