The slowly forced Duffing system has been found to exhibit unique fast–slow behaviors in descending frequency switching scheme, the typical of which is the sliding bursting, which is instructive for understanding the dynamics of ubiquitous frequency switching systems in scientific research and practical engineering. This paper is devoted to further refining the fast–slow dynamics of the slowly forced Duffing system with another commonly encountered frequency switching scheme, i.e., the ascending frequency switching, characterized by switching the frequency synchronously according to the increase or decrease of state variable values. Taking the forcing amplitude as an example, this paper provides a theoretical way to fully summarize the fast–slow behaviors in frequency switching systems with the variation of parameter values based on the proposed superposition analysis of one- and two-parameter bifurcations of subsystems. As a result, two typical bifurcation structures and eight threshold windows with distinct switching vector fields therein are identified, inducing up to ten different bursting patterns. Among them, several novel fast–slow dynamics, such as multiple jumps hysteresis loop formed by boundary equilibrium bifurcations and the switching failure phenomena, are presented and investigated. In particular, the underlying mechanism of threshold modulation, i.e., the evolution of unconventional bifurcations, is also found. These findings contribute to complementing and contrasting the existing studies on the fast–slow dynamics of frequency switching systems.