Laser triggered, megavolt, megampere gas switches are frequently utilized to synchronize multiple pulsed power driver modules for inertial-confinement fusion, isentropic compression, and radiation physics experiments. The device developed to synchronize the 36 modules of the refurbished Z accelerator at Sandia National Laboratories is a 5.4 MV, 700 kA, sulfur-hexafluoride (SF6) filled, laser triggered gas switch. At this operating level, switch jitter is 5 ns, the prefire rate is less than 0.1%, the average optic lifetime is greater than 200 shots, and the flashover rate is less than 1%. Over 1000 shots on a single-module test facility were conducted while iterating several potential design improvements, including utilizing low-erosion electrode material, varying SF6 pressure, and modifying internal switch geometry all while keeping the basic switch architecture and footprint constant. Results of this development effort are presented herein.