To better represent field conditions, the bending performance of reinforced geopolymer concrete (GPC) beams after the coupling effect of freeze-thaw cycling and sustained flexural load was investigated. Two types of GPC (G10 and G50) with different content of fly ash and slag were included and compared with ordinary Portland cement concrete (OPC). The mechanical strength of concrete and bond strength of rebars in concrete before and after freeze-thaw cycles were measured. It was found that the frost resistance of G10 was the weakest followed by OPC and G50. Three scenarios of bending tests on reinforced concrete beams were included: (1) control (without freeze-thaw damage); (2) individual freeze-thaw cycling; (3) coupling effect before bending. Rebound tests were conducted to evaluate frost damages at different areas of the beams as the base to analyze bending behaviors of the beams. The failure mode, load-displacement(strain) relationship, ultimate flexural strength, and bending stiffness of beams from bending tests are analyzed. All beams in scenario (1) were dominant in flexural failure. For scenario (2), G10 and G50 failed in debonding failure due to significant reduction in bond strength, while OPC failed in diagonal tension failure as OPC could sustain bond stiffness, thus preventing debonding failure. For scenario (3), damages in GPC were exacerbated, while damages in OPC were limited.