The search for novel materials has recently brought research attention to alkali metal-based chalcogenides (ABZ) as a new class of semiconducting inorganic materials. Various theoretical and computational studies have highlighted many compositions of this class as ideal functional materials for application in energy conversion and storage devices. This Perspective discusses the expansive compositional landscape of ABZ compositions that inherently gives a wide spectrum of properties with great potential for application. In the present paper, we examine the technique of synthesizing this particular class of materials and explore their potential for compositional engineering in order to manipulate key functional properties. This study presents the notable findings that have been documented thus far in addition to outlining the potential avenues for implementation and the associated challenges they present. By fulfilling the sustainability requirements of being relativity earth-abundant, environmentally benign, and biocompatible, we anticipate a promising future for alkali metal chalcogenides. Through this Perspective, we aim to inspire continued research on this emerging class of materials, thereby enabling forthcoming breakthroughs in the realms of photovoltaics, thermoelectrics, and energy storage.
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