In operational applications, hyperelastic adhesive joints are exposed to environmental conditions (moisture and temperature) that affect their mechanical performance. The understanding of how the environment can influence the joint durability through both static and cyclic loading is a key aspect to ensure safety and avoid over-dimensioning. The current work presents an investigation of the effect of environment conditions on the diffusion and mechanical performance of two different hyperelastic adhesive joints (a polyurethane and a silicon-modified polymer). To assess the process of moisture mass diffusion, pure adhesive samples were weighted for 387 days when subjected to outdoor weathering conditions. An FEA-diffusion procedure method was demonstrated by (i) predicting the saturation concentration at steady conditions of 40 °C/15% r.h. (40/15) and 40 °C/60% r.h. (40/60), and (ii) predicting the experienced mass change due to outdoor weathering. The reversibility of the effect of conditioning at 40 °C/60% r.h. on the mechanical properties of the adhesives was assessed via quasi-static and fatigue tensile shear testing. The results support the conclusion that conditioning with the surrogate climate of 40 °C/60% r.h. does not cause irreversible damage, as any potential decrease in shear modulus, tensile shear strength and fatigue life due to 40/60 conditioning can be reversed by re-drying at 40/15.
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