Surface Treatment Research Articles

Improving the bonding technology of aluminium sheet used in the construction industry by gas flame surface treatment

Abstract According to current building trends, aluminium sheets can be used as building cladding elements. The advantage is that aluminium has a low density but high strength and resistance to atmospheric corrosion. For a nice appearance, these sheets are coloured with a polyester-based powder coating and are fixed by adhesive bonding on the reverse side. For adhesion, a flexible adhesive is required, and it should be noted that the surface is painted. From a safety point of view, it is important that the strength of the bonded joint does not deteriorate over many years. In our research, we investigate the applicability of gas flame surface treatment technologies to improve the bonding technology of aluminium sheets coated with polyester-based paints. The effectiveness of the surface treatment is tested by surface wettability measurements and, based on the results obtained, test joints are made to test their tensile and shear strength.

Evaluating the effects of pineapple fiber, potato waste filler, surface treatment, and fiber length on the mechanical properties of polyethylene composites for biomedical applications

This study investigates the development of a biocompatible polyethylene composite incorporating natural fiber (pineapple fiber) and potato waste filler for potential use in biomedical applications. The composite was fabricated using compression molding and optimized through Taguchi-based grey relational analysis (GRA), TOPSIS, and artificial neural network (ANN) prediction models. The hybrid combination of these materials has been minimally explored in the biomedical field. Fourier Transform Infrared (FTIR) analysis of the potato filler revealed a peak at 1336 cm⁻1, indicating asymmetric deformation of C-H and C-O functional groups, contributing to enhanced compatibility with the polyethylene matrix. The natural fiber showed uniform distribution, improving stress transfer and flexural properties. The ANN model demonstrated high accuracy, with an r-value of 0.9972. Multi-response optimization identified the best configuration as 3 % NaOH treatment, 3 wt% potato filler, 30 wt% natural fiber, and a fiber length of 1.5 cm, yielding a tensile strength of 22.3 MPa, flexural strength of 23.8 MPa, and impact strength of 18.3 kJ/m2. This fabricated composites were lightweight and biocompatible materials, suitable for biomedical applications.

The effect of forming conditions and treatment process applied to the material on springback

Abstract Heat treatment is often used to optimize the balance between the strength and formability of a material. However, aging during treatment affects the ability to return to its original shape after deformation. In this study, the effects of surface treatments during the painting of mild steel and aging time in the W-temper heat treatment on springback were investigated. Consequently, because of artificial aging during surface treatment, the material precipitates certain phases and enhances the mechanical properties of the material, which leads to the pre-painted mild steel being more sensitive to springback. On the other hand, it is also noted that springback is highly dependent on the transfer time between the W-temper heat treatment of high strength aluminum alloy and forming operations, and the change in shape increases with time. In summary, the springback phenomenon is a result of the interaction between the material properties, treatment procedures, and forming circumstances.

Optimizing Sample Preparation for Destructive Testing in Resistance Spot Welding

Abstract The integrity and reliability of resistance spot welding, a crucial process in various manufacturing industries, are significantly influenced by the quality of sample preparation. This study focuses on advancing the methodologies and practices in the preparation of samples for resistance spot welding destructive tests, aiming to improve the precision and repeatability of the results. We discuss comprehensive approaches encompassing material selection, surface treatment, dimensional accuracy, and alignment procedures, emphasizing the importance of meticulous handling and preparation techniques, A significant focus is placed on the utilization of sophisticated alignment and measurement tools to enhance the consistency of the welding area subjected to destructive testing. our study demonstrates a significant improvement in the reliability and accuracy of welding machine calibration, ultimately contributing to the overall quality of the welding process. By integrating these refined processes, the study highlights a significant improvement in the reliability of welding tests, contributing to enhanced welding quality and performance in practical applications. Our findings underscore the critical role of detailed and standardized sample preparation in achieving accurate and reliable resistance spot welding destructive test outcomes, providing valuable insights for both industrial applications and further research in welding technology.

Creating an extracellular matrix-like three-dimension structure to enhance the corrosion resistance and biological responses of titanium implants

Background/purposeTitanium (Ti) is extensively used in dental and orthopedic implants due to its excellent mechanical properties. However, its smooth and biologically inert surface does not support the ingrowth of new bone, and Ti ions may have adverse biological effects. The purpose is to improve the corrosion resistance of titanium and create a 3D structured coating to enhance osseointegration through a very simple and fast surface treatment. Materials and methodsThis study investigated the use of sandblasting, acid etching, and NaOH leaching to produce porous Ti implants with enhanced biological activity and corrosion resistance. ResultsThese surface modifications generated a mixed oxide layer resembling the extracellular matrix (ECM), consisting of a dense amorphous TiO2 inner layer (50–100 nm thick) and a TiO2 outer layer with interconnected pores (pore size 50–500 nm; 150–200 nm thick). The inner layer significantly improved corrosion resistance, while the hydrophilic outer layer, with its porous structure, facilitated protein albumin adsorption and promoted the attachment, proliferation, and mineralization of human bone marrow mesenchymal stem cells. ConclusionThe combined surface treatment approach of sandblasting, acid etching, and NaOH leaching offers a comprehensive solution to the challenges associated with titanium implants' biological inertness and corrosion susceptibility. By enhancing both the biological activity and corrosion resistance of Ti surfaces, this protocol holds significant promise for improving dental and orthopedic implants' success rates and longevity. Future studies should focus on in vivo assessments and long-term clinical trials to further validate these findings and explore the potential for widespread clinical adoption.

Laser-zoned treatment of magnesium surfaces with predictable degradation applications

Magnesium metal is a promising material for medical applications due to its biocompatibility and similar modulus of elasticity to human bone. However, its complex corrosion process must be addressed before it can be used clinically to match post-implantation tissue repair. This study aims to regulate material degradation by utilizing laser surface treatment. The surface of pure magnesium was modified using nanosecond and femtosecond laser methods to create various micro-nanostructures, such as chain, streak, column, and groove structures. Surface roughness and wettability tests revealed that the groove structures had higher roughness values. All structures exhibited hydrophilicity, but the femtosecond laser-generated structures were more hydrophilic. Electrochemical tests and immersion experiments demonstrated that femtosecond laser modification significantly improved the corrosion resistance of magnesium metal compared to polished samples. Cytotoxicity experiments showed that the laser-treated magnesium was not cytotoxic. Based on the results, we constructed various structures on the magnesium rods in different regions. As a result, the rods exhibited multi-stage biodegradation behavior in simulated body fluids (SBF). This study presents a novel approach to controlling the degradation sequence of medical metals.

Hybrid Ceramics Cementation Protocols: Scope Review.

Compared to high modulus repair materials such as zirconia and alumina, hybrid polymer-ceramic materials have lower stress concentrations in the tooth structure and bonding interface. The aim of this study is to evaluate viable cementation protocols through an integrative review and meta-analysis. This systematic review was based on the PRISMA criteria. An electronic search was carried out in seven databases: Web of Science, Embase, PubMed, Clinical Trials, Scopus, Cochrane, Periodicals of Capes. The following inclusion criteria were used: hybrid ceramics, surface treatment protocol and which union test was presented, discarding duplicate articles and studies that did not meet the inclusion criteria. The articles were analyzed and selected through the RayYan platform. Of the 160 articles identified, 24 studies were included in this review. The materials used by the authors were the hybrid ceramics: Vita ENAMIC, LAVA ULTIMATE, Cerasmart, Shofu Block, and the possible surface treatment protocols presented involving the use of: HF, Alumina blasting with or without silica, Silane, Laser and adhesive. The tests were carried out at different times and concentrations of the analyzed materials. With the studies that were included in this review, it was possible to show that the corrosion made by HF continues to be the gold standard for the treatment of surfaces in hybrid ceramics. Key words:Hybrid ceramic, Bond Strength, Cementation.

Influence of electrophysical characteristics of plasma electrolytic treatment of 16MnCr5 structural alloy steel on structural and phase changes in the surface and its tribological properties

The possibility of using plasma electrolytic technologies for surface treatment of 16MnCr5 steel in order to increase its wear resistance is shown. The influence of electrophysical characteristics of plasma electrolytic treatment on structural-phase changes of the surface and its tribological properties is studied. A comparison of anodic and cathodic variants of diffusion saturation, as well as subsequent polishing on the results of surface modification is carried out. The complex effect of surface layers strengthened above 1100 HV, including iron carbide and nitride, martensite and retained austenite, to a depth of up to 250 μm with the preservation of a viscous core and the formation of a relatively homogeneous surface with reduced roughness on increasing wear resistance has been revealed. The features of tribological behavior of surfaces formed under different electrophysical parameters of processing, mainly related to the difference in surface microrelief, are shown. The correlation of the Kragelsky-Kambolov criterion as a complex assessment of surface roughness with its wear resistance is shown. The influence of changes in sliding speed and friction load on the occurrence and development of leading processes that determine the intensity and nature of destruction of friction surfaces is established.

Effect of faying surface treatments and bolt tightened levels on fretting fatigue performance of slip critical connections with high strength bolts

The experimental investigation focuses on the fretting fatigue performance of M24 high-strength bolt slip critical connections (SCC) under shear load, taking into account the influence factors of faying surface treatments and bolt tightened levels. A novel extensometer supporting device for measuring micro-displacement between connection plates is proposed. The μ-N curves are obtained. Three-dimensional surface morphology scanning and fracture morphology analysis are conducted on the specimens. The results showed that the SCC contact area can be divided into stick, partial slip, and gross slip, with distribution ranges determined for each zone. Meanwhile the fretting fatigue life decreases with the increase of μ and pre-tension. Finally, a prediction of fretting fatigue life is made based on a multiaxial fatigue critical plane model.

Low-Temperature Performance of Acrylonitrile-Butadiene-Styrene and Crumb Rubber Compound–Modified Asphalt Activated by Waste Cooking Oil Surface Treatment

Low-Temperature Performance of Acrylonitrile-Butadiene-Styrene and Crumb Rubber Compound–Modified Asphalt Activated by Waste Cooking Oil Surface Treatment

The impact of surface treatment on Al foil for Cu2ZnSnS4 thin films

The impact of surface treatment on Al foil for Cu2ZnSnS4 thin films

Mechanical and anti-icing performance of superhydrophobic aluminum conductor by anodized oxide technique

Abstract Anodized oxide technology is a traditional surface treatment method used in the material engineering field to enhance the friction, anti-icing, anti-corrosion, and insulation properties of Al-based samples. Considering the anti-icing and insulation performance, anodized oxide technology has great application prospects in overhead transmission lines. In this study, the preparation process of Aluminum (Al) flat plates and Aluminum Cable Steel-Reinforce (ACSR) was explored by using anodizing technology to obtain superhydrophobic properties. Moreover, as the significant performance in the application of transmission lines, the mechanical performance (tensile strength) of Al conductors was evaluated to study the impact of anodized oxidation technology. The results show that anodized oxide technology can improve the tensile strength of aluminum clad steel bars and aluminum-stranded wires in ACSRs. In addition, the hydrophobicity and anti-icing performance of anodized wires can demonstrate potential application prospects in the field of anti-icing.

Effect of adhesives and mechanical surface treatments on the hard relining of CAD-CAM denture bases.

The aim of this study was to evaluate the impact of mechanical roughening, adhesive applications, and aging on the bonding between CAD-CAM denture base materials with distinct chemical contents and hard relining material. A total of 300 denture base specimens were produced by additive, subtractive, and conventional heat-polymerization techniques (N=100). The specimens have been classified into five subgroups based on the particular surface treatments administered (n=20): (1) Hard relining material's adhesive application (control); (2) Tungsten carbide bur application for 1min, and hard reline material's adhesive application; (3) Airborne-particle abrasion (APA) with 110 μm Al2O3, and hard reline material's adhesive application; (4) Scotchbond Universal application; and (5) Visio.link application. Representative specimens from each subgroup were examined under a Scanning Electron Microscope (SEM). Subsequently, self-cure hard relining material was condensed in the center of the specimens. Half of the specimens were thermally aged with 5000 cycles at 5°C-55°C. The shear bond strength (SBS) test was performed, and failure loads were recorded. The data was evaluated by Robust ANOVA and Bonferroni test (p<0.05). No statistically significant difference was obtained between the production techniques (p = 0.051). The lowest SBS was observed in the control group among surface treatments, while mechanical surface treatments and universal adhesive showed the highest SBS for both aged and non-aged groups. Aging caused a significant decrease for all test groups (p=0.001). Mechanical surface treatments and universal adhesive applications are more effective for maintaining adhesion across all production techniques.

Progress in Application of Silane Coupling Agent for Clay Modification to Flame Retardant Polymer.

Polymer composites are widely used in various fields of production and life, and the study of preparing environmentally friendly and flame retardant clay/polymer composites has gradually become a global research hotspot. But how to efficiently surface modify clay and apply it to the field of flame retardant polymers is still a potential challenge. One of the most commonly used surface modification methods is the modification of clay with silane coupling agents. The hydrolysable groups of the silane coupling agent first hydrolyze to generate hydroxyl groups. These hydroxyl groups then undergo a condensation reaction with the hydroxyl groups on the surface of the clay, allowing for organic functional groups to be grafted onto the clay surface. The organic functional groups and polymer matrix react to generate chemical bonds so that the composite material's interface is more closely combined. Thus, the dispersion of clay in the organic polymer material and the compatibility of the two is better, which improves the flame retardant effect of the composite material. This paper introduces the classification of a silane coupling agent and the mechanism and process of silane coupling agent-modified clay, outlines the mechanism of silane coupling agent-modified clay flame retardant polymers, reviews the research results on flame retardant polymers of various clays after surface treatment with silane coupling agents in recent years, and highlights the synergistic flame retardant effect of clay and flame retardant organized by silane coupling agents. Finally, it is found that the current research in the field of silane coupling agent-modified clay in flame retardants is focused on the modification of montmorillonite, sepiolite, attapulgite, and kaolinite by KH-550, KH-560, and KH-570, and the development trends in this field are also prospected.

A comparison of conventional sodium fluoride varnish and nano-sodium fluoride varnish regarding enamel microhardness of deciduous teeth: an in-vitro study.

Dental caries is the most common chronic disease worldwide, and various forms of fluoride are considered useful preventive tools. The production of nanoscale materials can significantly improve their mechanical and chemical properties. The present study compared the microhardness of primary tooth enamel after applying sodium fluoride varnish (conventional) and nano-sodium fluoride varnish. Sixty-eight sound canine teeth were selected in this experimental study. The teeth were mounted so that the buccal surface was exposed. A 3 × 3mm square was obtained on the buccal surface of the crown of each tooth. Enamel surfaces were polished using sandpaper in the presence of water as a coolant. The samples were randomly divided into four groups (n = 17): G1, conventional 5% NaF; G2, 1% nano-NaF; G3, 5% nano-NaF; G4, control. The initial microhardness was measured. Before surface treatment with different fluoride compounds, the samples were placed in a demineralizing solution for two days, and the microhardness of all the samples was re-measured. Then G1, G2, and G3 were treated with the fluoride type specified for each group, and G4 was treated as a control (without treatment). Finally, pH cycling was applied, and the microhardness was measured again. Data were analyzed with SPSS 20, using Repeated measure ANOVA and post-hoc Tukey tests. P < 0.05 was considered significant. Repeated measure ANOVA showed that microharness of G1, G2, G3, and G4 was statistically significant different. Tukey tests showed that the microhardness of G1, G2, and G3 were not significantly different. However, these three groups exhibited significantly more microhardness than the control group (P = 0.024, P = 0.027, and P = 0.010). There was no significant differences in enamel microhardness of deciduous teeth between conventional 5% NaF,1% nano-NaF and 5% nano-NaF.

A review on modern prosthodontic practice using laser.

Lasers are a very appealing technology in many areas of dentistry because of their minimally invasive nature, quick tissue interaction & response, and ability to heal. Numerous investigations on the possible uses of lasers in dentistry have been carried out since Maiman developed the ruby laser in 1960. Numerous applications such as quick prototyping and computer-aided design, and the study of occlusion in complete denture using three-dimensional laser scanning has been used to develop dentures. Its uses are numerous from fixed prosthodontics to dentinal hypersensitivity treatment to surface treatment of base metal alloys. These days, it even encompasses maxillofacial prosthodontics and dental implantology. Hence, it is of interest to review the use of lasers in clinical prosthodontics.

Surface mechanical rolling treatment-introduced gradient nanostructured Inconel 625 alloy with enhanced high-temperature wear resistance

Heterogeneous gradient nanostructures induced through surface treatment of nickel-based superalloys hold significant promise for enhancing wear resistance. In this study, a 700 µm ultra-thick gradient nanostructured (GNS) strengthening layer was fabricated on the surface of an Inconel 625 alloy plate via surface mechanical rolling treatment (SMRT). Subsequently, the tribological behaviors and wear resistance mechanisms of coarse-grained (CG) and GNS samples at temperatures ranging from 25 ℃ to 800 ℃ were comparatively investigated. The results indicated that the gradient nanostructures significantly enhanced the high-temperature wear resistance of the samples, which wear characterized by low coefficient of friction (COF), wear rate and thin friction layer. This enhancement was attributable to the stability and excellent hot hardness of the gradient nanostructures during friction.

Evaluation of a Commercial MoS2 Dry Film Lubricant for Space Applications

Molybdenum disulfide coatings, particularly Microseal 200-1, have been extensively used as dry film lubricants for actuating mechanisms in space applications. Although Microseal 200-1 has historically been a popular choice for space missions, recent assessments indicate a need for reexamination. This study evaluates sliding friction in air and dry gaseous nitrogen atmospheres at ambient temperatures with both linear reciprocating and rotary unidirectional tribo-tests. Measurements are performed for Microseal 200-1 applied on substrates and surface treatments commonly used in aerospace components, particularly stainless steel and a titanium alloy. Our findings indicate that the friction of stainless steel balls sliding on Microseal 200-1-coated disks is significantly influenced by the environment as well as the disk substrate material. The average friction coefficient ranges from 0.12 to 0.48 in air and from 0.04 to 0.41 in dry gaseous nitrogen, and the amount of friction is consistently much higher for the Microseal 200-1 on the stainless steel than on the titanium alloy. Microscopy and surface analyses, including scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray fluorescence, of the coatings on stainless steel substrates reveals that the coatings are sparse and relatively thin, likely a key factor contributing to their high friction. This insight underscores the substrate dependence of this widely used coating and highlights the importance of detailed tribological testing in accurately assessing the tribological performance of commercial dry film lubricants, a key step towards improving the reliability and effectiveness of actuating mechanisms for space applications.

The impact of ultrasonic shock surface treatment technology on the microstructure, mechanical and corrosion properties of FeCrMnCuNiSi high-entropy alloy coating via TIG arc melting

The impact of ultrasonic shock surface treatment technology on the microstructure, mechanical and corrosion properties of FeCrMnCuNiSi high-entropy alloy coating via TIG arc melting

Resolving high-strain-rate scratch behavior of Ti6Al4V in experiment and meshless simulation

The outstanding strength-to-weight ratio and corrosion resistance of titanium have made it the material of choice in the aerospace industry and medicine. The alpha–beta alloy Ti6Al4V is particularly preferred for its excellent mechanical and bio-compatible properties. Despite its advantages, the low thermal conductivity and poor tribological performance of titanium pose significant challenges during manufacturing and in operation. This research offers deep insights into the high strain rate behavior of Ti6Al4V under abrasive load, such as e.g. experienced in machining, by modifying the standard scratch test setup and using optimized Johnson–Cook material parameters to perform Material Point Method (MPM) simulations. The MPM simulations provide accurate predictions of the data gathered through high strain rate scratch experiments. We found an increase in the von Mises stress distribution as well as the normal and tangential forces required to perform a scratch of the same depth as the strain rate increases. The morphology of the scratch profiles also showed an increase in the height of the ridges that form as the scratching speed increases. These findings are in line with the increase in yield strength and work hardening with growing strain rate. This study bridges the gap between simulation models and experimental observations by providing insights for improved machining strategies and surface treatments that can enhance the performance of Ti6Al4V in demanding applications.