Diurnal observations of coincident in situ physical-, electrical-, and surface-based C-band microwave scattering properties of a 16-cm saline snow cover on smooth, moderately saline, first-year sea ice are presented for the transition period between late winter and early melt. Statistical regression analysis and backscatter modeling are employed to explore the scattering mechanisms within the snowpack and to assess associations between backscatter and snow properties for both periods. Our results demonstrate substantial variation in both measured snow properties and C-band microwave backscatter over the diurnal cycle during the late winter period when the difference between maximum and minimum air and snow surface temperature was approximately 5 °C. No such variation in snow properties and backscatter occurred for the early melt period when our case study exhibited a small diurnal variation (~1°C) in air and snow surface temperature. Statistical and modeled results show significant association between the microwave backscatter and snow properties for the top 8 cm of the snowpack. Basal snow properties do not contribute toward total backscatter in either case. As a result, we are certain that the sea ice surface was a negligible scattering interface during both cases. Correlations between backscatter and snow properties are incidence angle dependent, demonstrating the highest association at 50°. Diurnal backscatter from RADARSAT-2 synthetic aperture radar acquisitions support the influence of varying diurnal snow properties on C-band backscatter, showing a difference of ~4 dB for ${ \sigma }_{\vphantom {R_{j}}{\text {hh}}}^{o}$ and ${ \sigma }_{{\text {vv}}}^{o}$ during the late winter period. This difference is reduced to <1 dB for the early melt period.
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