Characterization Of Surface Structure Research Articles

A new dimension in the variability of AGB stars: Convection patterns size changes with pulsation

Context. Stellar convection plays an important role in atmospheric dynamics, wind formation, and the mass-loss processes in asymptotic giant branch stars. However, a direct characterization of convective surface structures in terms of size, contrast, and lifespan is quite challenging, as spatially resolving these features requires the highest angular resolution. Aims. We aim to characterize the size of convective structures on the surface of the O-rich AGB star R Car to test different theoretical predictions based on mixing-length theory from solar models. Methods. We used infrared low-spectral resolution (R ∼ 35) interferometric data in the H-band (∼1.76 μm) obtained by the instrument PIONIER at the Very Large Telescope Interferometer (VLTI) to image the star’s surface at two epochs separated by approximately six years. Using a power spectrum analysis, we estimated the horizontal size of the structures on the surface of R Car. The sizes of the stellar disk at different phases of a pulsation cycle were obtained using parametric model fitting in the Fourier domain. Results. Our analysis supports that the sizes of the structures in R Car are correlated with variations in the pressure scale height in the atmosphere of the target, as predicted by theoretical models based on solar convective processes. We observed that these structures grow in size when the star expands within a pulsation cycle. While the information is still scarce, this observational finding highlights the role of convection in the dynamics of those objects. New interferometric imaging campaigns with the renewed capabilities of the VLTI are envisioned to expand our analysis to a larger sample of objects.

Picosecond Laser Processing of Hierarchical Micro–Nanostructures on Titanium Alloy upon Pre‐ and Postanodization: Morphological, Structural, and Chemical Effects

Recent publications indicate that the order of electrochemical anodization (before or after the laser processing step) plays an important role for the response of bone‐forming osteoblasts—an effect that can be utilized for improving permanent dental or removable bone implants. For exploring these different surface functionalities, multimethod morphological, structural, and chemical characterizations are performed in combination with electrochemical pre‐ and postanodization for two different characteristic microspikes covered by nanometric laser‐induced periodic surface structures on Ti–6Al–4V upon irradiation with near‐infrared ps‐laser pulses (1030 nm wavelength, ≈1 ps pulse duration, 67 and 80 kHz pulse repetition frequency) at two distinct sets of laser fluence and beam scanning parameters. This work involves morphological and topographical investigations by scanning electron microscopy and white light interference microscopy, structural material examinations via X‐ray diffraction, and micro‐Raman spectroscopy, as well as near‐surface chemical analyses by X‐ray photoelectron spectroscopy and hard X‐ray photoelectron spectroscopy. The results allow to qualify the mean laser ablation depth, assess the spike geometry and surface roughness parameters, and provide new detailed insights into the near‐surface oxidation that may affect the different cell growth behavior for pre‐ or postanodized medical implants.

WITHDRAWN: Magnetic field-assisted electrodeposition of ZnCo2O4-rGo nanoelectrodes for enhanced supercapacitor performance

To investigate a convenient, rapid, and environmentally friendly method for the preparation of supercapacitor electrode materials to enhance supercapacitor performance, this study achieved the successful synthesis of ZnCo2O4-rGo (ZCG) nanomaterial electrodes on a nickel foam substrate. These electrodes were then assembled into supercapacitors using Magnetic field-assisted Electrodeposition (MFAED) technology. The surface morphology and structure characterization analysis revealed that the ZCG-4 material exhibited a mesoporous layered nanosheet structure. Moreover, they exhibited a significant specific active surface area of 155.7 m2/g and showed excellent adhesion to the nickel foam substrate. The electrochemical properties of the ZCG nanoelectrode material were studied in a 1 M KOH aqueous solution. The results revealed that the ZCG-4 nanoelectrode displayed low electrochemical impedance (Rs 0.23 Ω, Rct 1.36 Ω, and Zw 0.99 Ω) and a high specific capacitance of 2672 Fg−1. Furthermore, at a current density of 3 Ag−1, the electrode maintained good capacity retention (2672 Fg−1–2529 Fg−1, 94.6 %). Moreover, it retained a significantly high specific capacitance of 1339 Fg−1 even after 6000 cycles under a current density of 20 Ag−1. The supercapacitor assembled with ZCG-4 electrodes exhibits good electrochemical performance, possessing a high capacitance of 5.8F/cm2 at a current density of 1 mA/cm2. Moreover, the ZCG-4 supercapacitor demonstrates outstanding cyclic performance, maintaining 86 % capacity retention following 6000 charge–discharge cycles at a high current density of 30 mA/cm2. The mechanism of magnetic field electrodeposition for preparing ZCG has also been explained using magnetohydrodynamics theory. At a magnetic field strength of 6 T, the ion migration speed is 1.7 × 10−5 m/s, and the addition of the magnetic field effectively increases this speed. An effective magnetic field electrodeposition approach was thus proposed in this investigation to enable the synthesis of high-performance electrode materials and capacitors by combining metal oxide and rGo.

A high-sensitive anisotropic magnetoresistive sensor based on hybrid Ta/NiFe/Ta/Al multilayer structure

High sensitivity is crucial for anisotropic magnetoresistive (AMR) sensors in industrial applications. In this paper, a high- sensitive AMR sensor based on magnetoresistive thin films with Ta/NiFe/Ta/Al four-layer structure is proposed and fabricated. Firstly, the structural parameters were optimized by finite element analysis. Secondly, thin film samples and AMR sensors were prepared. Through the analysis and characterization of reluctance change rate, hysteresis loop, x-ray diffraction and surface morphology and structure, the process parameters were optimized. Finally, the sensor was connected to the designed external circuit, and its technical parameters were tested in a magnetic field test system. The results show that the prepared AMR sensor performs well. It has a high sensitivity of 1.27 mV/V/Oe, a low bridge offset voltage of ±1.64 mV V−1, and a low temperature coefficient of sensitivity of −0.102%/°C. The results contribute to the future development of AMR magnetic field sensor chips.

Iron-doped cross-linked puffed carbon as capacitive anode for the enhancement of bioelectron storage capacity in microbial fuel cells

Microbial fuel cell (MFC) can utilize the metabolism of electroactive microorganisms to remove organic pollutants from wastewater, and the application of capacitive anodes can enhance the power generation capacity of MFC and the energy storage capacity of bioelectronics. This research aimed to create a capacitive anode with a large specific surface area and excellent electrical conductivity. To achieve this aim, iron-doped cross-linked puffed carbon (CPC–Fe) was prepared for the modification of carbon cloth (CC) substrates by a simple one-step expansion carbonization method using FeCl3·6H2O and maltose as raw materials. The surface structure characterization confirms the successful incorporation of Fe atoms, with Fe3O4 accounting for 79.61%. Fe3O4 exhibits excellent specific capacitance characteristics and can also serve as a good conductor for the transmission or reception of electrons generated by electroactive bacteria. Furthermore, the mesoporous volume of CPC-Fe significantly increases, which contributes to the enhancement of the specific capacitance of material and the improvement of charge storage capacity. Based on these advantages, the maximum power density of MFC equipped with CPC-Fe/CC anode reaches 1850.50 mW m−2. The CPC-Fe/CC bioanode has a cumulative total charge of 1076.02 C m−2, showing good capacitive behaviour and exhibiting a significant enrichment effect on Geobacter species. This study demonstrates that the regulation of extracellular electron transfer (EET) process based on bioelectronic reception steps can not only enhance the power generation performance of MFC, but also effectively improve the energy storage capacity of MFC, which offers significant knowledge for the development of electrode design in other bioelectrochemical systems.

Protease-Mediated T1 Contrast Enhancement of Multilayered Magneto-Gadolinium Nanostructures for Imaging and Magnetic Hyperthermia.

In this work, we constructed a multifunctional composite nanostructure for combined magnetic hyperthermia therapy and magnetic resonance imaging based on T1 and T2 signals. First, iron oxide nanocubes with a benchmark heating efficiency for magnetic hyperthermia were assembled within an amphiphilic polymer to form magnetic nanobeads. Next, poly(acrylic acid)-coated inorganic sodium gadolinium fluoride nanoparticles were electrostatically loaded onto the magnetic nanobead surface via a layer-by-layer approach by employing a positively charged enzymatic-cleavable biopolymer. The positive-negative multilayering process was validated through the changes occurring in surface ζ-potential values and structural characterization by transmission electron microscopy (TEM) imaging. These nanostructures exhibit an efficient heating profile, in terms of the specific absorption rates under clinically accepted magnetic field conditions. The addition of protease enzyme mediates the degradation of the surface layers of the nanostructures with the detachment of gadolinium nanoparticles from the magnetic beads and exposure to the aqueous environment. Such a process is associated with changes in the T1 relaxation time and contrast and a parallel decrease in the T2 signal. These structures are also nontoxic when tested on glioblastoma tumor cells up to a maximum gadolinium dose of 125 μg mL-1, which also corresponds to a iron dose of 52 μg mL-1. Nontoxic nanostructures with such enzyme-triggered release mechanisms and T1 signal enhancement are desirable for tracking tumor microenvironment release with remote T1-guidance and magnetic hyperthermia therapy actuation to be done at the diseased site upon verification of magnetic resonance imaging (MRI)-guided release.

Scrutinizing micellar transitions and interfacial properties in mixed micelles comprising sodium dodecyl sulfate and sodium oleate: A tensiometric and scattering insight

Mixed micellar systems play a pivotal role in numerous scientific and industrial applications due to their inimitable solution properties and potential for enhancing solubilization and emulsification processes. The present study unveils the mixed micellization behavior of two anionically charged surfactants, sodium dodecyl sulfate (SDS) and sodium oleate (SO), in aqueous solutions through a combination of solution viscosity, tensiometric and small-angle neutron scattering (SANS) techniques. The dynamic changes in the interfacial properties of the mixed micellar system as a function of the SDS-to-SO ratio are evaluated from surface tension measurements. The results offer an insight into the formation of the stable mixed micelles with the alteration in the critical micelle concentration (CMC) as a function of the composition of both surfactants and the nature of the interaction. Surface tension data disclose the thermodynamic aspects of micelle formation and the influence of surfactant interactions on the surface activity of the system. Complementing the surface tension measurements, SANS analysis was conducted to clarify the structural aspects of the SDS-SO mixed micelles. SANS inferred the micellar size, shape, and aggregation number (Nagg), thereby shedding light on the nanoscale organization of the micellar aggregates in the aqueous solution. By combining SANS and surface tension data, a comprehensive understanding of the mixed micellization behavior of SDS and SO is achieved, addressing both interfacial and structural aspects. A computational simulation approach has also been employed to obtain the optimized parameters, which provide a better understanding of the correlation of SDS and SO molecular orbital energy levels. The results underscore the importance of surface tension and structural characterization techniques to comprehend the behavior of mixed micelles fully.

Characterization of laser-induced surface structures of aluminum in an oxygen-free atmosphere

Brazing of materials with high oxygen affinity, such as aluminum alloys, requires the removal of surface oxides. This is commonly achieved using chemical fluxes. The approach described here utilizes IR-pulsed laser radiation at a pulse duration of 45 ns to remove the oxide layer. To prevent reoxidation, an oxygen-free atmosphere is used by introducing monosilane (SiH4) into the process chamber, which binds the oxygen molecules. The laser-induced surface structuring that occurs during oxide removal of aluminum alloy EN AW-6082 was investigated. Pulse energies between 60 – 300 µJ and different pulse overlaps between 0 – 90 % were analyzed for topography and roughness based on the process atmosphere. The results suggest that the roughness increases significantly only at 90 % overlap. Additionally, laser structuring with high energy and overlap in the presence of O2 results in a porous surface layer, while in the absence of O2, it leads to pillar formation with higher roughness.

Improving robustness for model discerning synthesis process of uranium oxide with unsupervised domain adaptation

The quantitative characterization of surface structures captured in scanning electron microscopy (SEM) images has proven to be effective for discerning provenance of an unknown nuclear material. Recently, many works have taken advantage of the powerful performance of convolutional neural networks (CNNs) to provide faster and more consistent characterization of surface structures. However, one inherent limitation of CNNs is their degradation in performance when encountering discrepancy between training and test datasets, which limits their use widely. The common discrepancy in an SEM image dataset occurs at low-level image information due to user-bias in selecting acquisition parameters and microscopes from different manufacturers. Therefore, in this study, we present a domain adaptation framework to improve robustness of CNNs against the discrepancy in low-level image information. Furthermore, our proposed approach makes use of only unlabeled test samples to adapt a pretrained model, which is more suitable for nuclear forensics application for which obtaining both training and test datasets simultaneously is a challenge due to data sensitivity. Through extensive experiments, we demonstrate that our proposed approach effectively improves the performance of a model by at least 18% when encountering domain discrepancy, and can be deployed in many CNN architectures.

Preparation of inorganic catalysts from ceramic industry wastes for use in the production of biofuel

Catalysts’ surface structural features and characterizations play an important role in many chemical industrial processes among which is biofuel production. Heterogeneous catalysts strongly affect the types of products in catalytic hydrocracking of oils. The present study aims at the preparation of low-cost inorganic catalysts with improved catalytic activity. This will then be used in the production of bio-jet fuel — conforming to ASTM specifications — by hydrocracking of Jatropha oil. Five types of inorganic catalysts have been prepared and tested. The best results were obtained from the catalyst produced from ceramic wastes. It produced the highest bio-jet yield (51%) and the highest freezing point (− 52 °C). A BET surface area of 21.9 m2/g and a "total pore volume" of 0.025877 cm3/g were obtained.

Polyvinyl Alcohol Assisted Iron-Zinc Nanocomposite for Enhanced Optimized Rapid Removal of Malachite Green Dye.

Eliminating hazardous contaminants is a necessity for maintaining a healthy environment on Earth. This work used a sustainable method to create Iron-Zinc nanocomposites with polyvinyl alcohol assistance. Mentha Piperita (mint leaf) extract was used as a reductant in the green synthesis of bimetallic nanocomposites. Doping with Poly Vinyl Alcohol (PVA) caused a reduction in crystallite size and greater lattice parameters. XRD, FTIR, EDS, and SEM techniques were used to establish their surface morphology and structural characterization. The high-performance nanocomposites were used to remove malachite green (MG) dye using the ultrasonic adsorption technique. Adsorption experiments were designed by central composite design and optimized by response surface methodology. According to this study, 77.87% of the dye was removed at the optimum optimized parameters (10.0 mg L-1 was the concentration of MG dye at a time of 8.0 min, pH 9.0, and 0.02 g of adsorbent amount) with adsorption capacity up to 92.59 mg·g-1. The dye adsorption followed Freundlich's isotherm model and the pseudo-second-order kinetic model. Thermodynamic analysis affirmed the spontaneous nature of adsorption due to negative ΔGo values. As a result, the suggested approach offers a framework for creating an effective and affordable technique to remove the dye from a simulated wastewater system for environmental conservation.

Improved visible-light photocatalytic degradation of pollutants under the synergistic effect of BiOI/BiFeWO6 p-n heterojunction and oxygen vacancies

The construction of p-n heterojunctions has become an effective way to develop high performance photocatalysts to remove pollutants from water. Herein, the BiOI/BiFeWO6 composites abundant in oxygen vacancies (OVs) was rationally designed by combining calcination and solvothermal methods to remove different kinds of pollutants, including rhodamine B (RhB), tetracycline (TC), ciprofloxacin (CIP) and hexavalent chromium (Cr(VI)). The surface properties, structural characterizations and photocatalytic activity of BiOI/BiFeWO6 were investigated. Scanning electron microscope (SEM) and transmission electron microscope (TEM) showed that the morphology of BiOI/BiFeWO6 was BiFeWO6 nanoparticles loaded on BiOI sheet structure. The formation of BiOI/BiFeWO6 heterojunction was demonstrated by the shift of the peaks of Bi and I elements in X-ray photoelectron spectroscopy (XPS). Moreover, the existence of OVs was confirmed by the O 1 s spectrum and electron spin resonance (ESR). By comparison with neat BiOI and BiFeWO6, the BiOI/BiFeWO6 composite showed excellent photocatalytic properties under visible light. The strategy that the p-n heterojunction and OVs work together opens up new avenues to fabricate future high-efficiency photocatalysts.

Microfiltration Membranes Modified with Zinc by Plasma Treatment.

Polymer membranes play an important role in various filtration processes. The modification of a polyamide membrane surface by one-component Zn and ZnO coatings and two-component Zn/ZnO coatings is presented in this work. The technological parameters of the Magnetron Sputtering-Physical Vapor Deposition method (MS-PVD) for the coatings deposition process show an impact on the influence on the membrane's surface structure, chemical composition, and functional properties. The characterization of surface structure and morphology were analyzed by scanning electron microscopy. In addition, surface roughness and wettability measurements were also made. For checking the antibacterial activity, the two representative strains of bacteria Escherichia coli (Gram-negative) and Staphylococcus aureus (Gram-positive) were used. The filtration tests showed that polyamide membranes covered with three types of coatings, one-component Zn coatings, ZnO coatings, and two-component Zn/ZnO coatings, presented similar properties. The obtained results show that using the MS-PVD method for modification of the membrane's surface is a very promising perspective in the prevention of biofouling.

Assessment of core-shell nanoparticles surface structure heterogeneity by SAXS contrast variation and ab initio modeling

For the biomedical applications of nanoparticles, the study of their structure is a major step towards understanding the mechanisms of their interaction with biological environment. Detailed structural analysis of particles’ surface is vital for rational design of drug delivery systems. In particular, for core-shell or surface-modified nanoparticles surface structure can be described in terms of shell coating uniformity and shell thickness uniformity around the nanoparticle core. Taken together, these terms can be used to indicate degree of heterogeneity of nanoparticle surface structure. However, characterization of nanoparticle surface structure under physiological conditions is challenging due to limitations of experimental techniques. In this paper, we apply SAXS contrast variation combined with ab initio bead modeling for this purpose. Approach is based on the fact that nanoparticles under study are produced by self-assembly of phospholipid-conjugated molecules that possess moieties with significantly different electron densities enabling SAXS technique to be used to distinguish nanoparticle shell and study its structure. Ab initio single phase and ab initio multiphase modeling based on SAXS curve of nanoparticles in phosphate buffer solution allowed to reconstruct nanoparticle shell coating and assess its uniformity, while serial nanoparticle reconstructions from solutions with gradually increased solvent electron densities revealed relative shell coating thickness around nanoparticle core. Nanoparticle shell structure representation was verified by molecular dynamics simulation and derived full-atom nanoparticle shell structure showed good agreement with SAXS-derived representation. Obtained data indicate that studied nanoparticles exhibit highly heterogeneous surface structure.

Subnanometer accuracy of surface characterization by reflected-light differential interference microscopy

We theorize the surface step characterization by reflected incoherent-light differential interference microscopy with consideration of the optical diffraction effect. With the integration of localization analysis, we develop a quantitative differential interference optical system, by which we demonstrate that the axial resolution of measuring surface height variation is sensitive to the shear distance between the two spatially differentiated beams. We fabricate three nanometer-size steps by photolithography, and successfully characterize their 1D height variations with 0.13 nm axial precision. Our result suggests that the optical differential interference microscopy can be used for real-time characterization of surface structure with a subnanometer accuracy and a large field of view, which is greatly beneficial to the surface characterization of micro/nano-electromechanical systems.

Surface dielectric barrier discharge plasma–treated pork cut parts: bactericidal efficacy and physiochemical characteristics

Maintaining agro-food product safety remains a significant challenge for satisfying local and global consumers in tropical countries. This issue has been growing due to new pathogen strains, low infectious doses, increased virulence, antibiotic resistance, cross-contamination or recontamination of foods, food-contact surfaces, and biocontamination of water within the food production chain. To respond to this situation, we studied the inactivation efficacy of surface dielectric barrier discharge (SDBD) plasma against pathogens on the surface of various pork cut parts, including the loin, hip, belly, liver, and intestine. The SDBD plasma was operated at 0.30 W/cm2 in ambient air, with a gap of 5.0 mm between the plasma generator and the sample surface. Up to 96% germicidal efficiency against surface pathogens were observed, showing after 1 min of SDBD plasma exposure. Visualization of reactive species deposition on the treated surface using KI–starch agar gel reagent indicated a non-uniform distribution of the SDBD-generated reactive species on the treated surface. Following the indirect plasma treatment by the SDBD reactor, the overall color of pork cut samples after plasma treatment was significantly different compared with before. However, the surface morphology and structural characterization of the treated pork cut samples were not significantly altered, and residual nitrites and nitrates were lower than the restriction level for safe consumption. The SDBD reactor should be developed further to produce a uniform distribution of reactive species on the meat surface for the improvement of the decontamination effect without undesirable effects on meat quality parameters.

Stabilization of Pt nanoparticles within MOFs for selective hydrogenation of hazardous 4-nitrophenol to valuable 4-aminophenol: Confinement and synergistic effect

Precious metal nanoparticles (NPs) are a kind of promising hydrogenation catalyst. However, the particle size, stabilization and uniform dispersion of precious metal NPs is always a great challenge. Herein, Pt NPs were synthesized with controlled particle size and uniformly confined within the pores of Fe-BDC MOFs via an eco-friendly polyol reduction method and evaluated for selective hydrogenation of 4-Nitrophenols (4-NiPh) to 4-Aminophenols (4-AmPh). Metal-Organic Frameworks (MOF), a promising host material, provide a large surface area and pore volumes for evenly accommodating the Pt NPs with controlled particle size. The as-prepared Pt/Fe-BDC catalyst exhibited higher catalytic hydrogenation activity under mild conditions. Interestingly, the Pt/Fe-BDC catalyst exhibited superior catalytic activity with low Pt loading (0.47%) than that of the Pt/Fe3O4 catalyst. A series of bulk and surface structural characterizations including XRD, FTIR, TEM, XPS and CO-FTIR, etc., were conducted to examine the outstanding performance of the Pt/Fe-BDC catalyst. The outstanding catalytic hydrogenation performance of Pt/Fe-BDC catalyst was attributed to the large surface area, pore volume and additional functional groups of MOFs. The large surface area and pore volume of Fe-BDC MOFs control the Pt particle size (1.9 ​nm), and high uniform dispersion (59%) due to confinement effect, while the presence of additional functional groups in Fe-BDC MOFs synergistically interacts with Pt species to generate more exposed surface active metallic Pt0.

Atomic Reconstruction and Oxygen Evolution Reaction of Mn3O4 Nanoparticles.

Understanding the chemical states of individual surface atoms and their arrangements is essential for addressing several current issues such as catalysis, energy stroage/conversion, and environmental protection. Here, we exploit a profile imaging technique to understand the correlation between surface atomic structures and the oxygen evolution reaction (OER) in Mn3O4 nanoparticles. We image surface structures of Mn3O4 nanoparticles and observe surface reconstructions in the (110) and (101) planes. Mn3+ ions at the surface, which are commonly considered as the active sites in OER, disappear from the reconstructed planes, whereas Mn3+ ions are still exposed at the edges of nanoparticles. Our observations suggest that surface reconstructions can deactivate low-index surfaces of Mn oxides in OER. These structural and chemical observations are further validated by density functional theory calculations. This work shows why atomic-scale characterization of surface structures is crucial for a molecular-level understanding of a chemical reaction in oxide nanoparticles.

Promotion of biomass pyrolytic saccharification and lignin depolymerization via nucleophilic reagents quenching of the carbonium ions

The condensation of lignin under acidic conditions inhibited the subsequent value-added utilization of lignin, and the condensed lignin covered the biomass surface. Here, a method of benzenesulfonic acid pretreatment combined with nucleophilic reagents promoted pyrolytic saccharification and lignin hydrogenation was reported. The anhydrosugar content in the pyrolysis bio-oil increased from 66.91% to 69.00%, 72.88%, and 72.16% via adding methanol, propionaldehyde, 3-hydroxylic-2-naphthoic acid, respectively. The characterization of the biomass surface structure and the calculation of bond lengths indicated that carbonium ions prefer to bind with the added nucleophilic reagent rather than the lignin fragment. Furthermore, the quenching of the carbonium ions preserved the β-O-4 bond, as demonstrated in 2D NMR. In the subsequent hydrogenation reaction, it was found that methanol facilitated the production of lignin monomer. The calculation also revealed that the quenching of the carbonium ions with methanol reduced the bond-breaking energy of the β-O-4 bond.

Electrochemical oxidation degradation of fungicide 5-chloro-2-methyl-4-isothiazoline-3-one (CMIT) in brine of reverse osmosis by a novel Ti/CB@MXene anode

The electrochemical oxidation purification of reverse osmosis concentrated brine was sustainable water purification technology; however, anode oxidation efficiency and capacity limit its development. According to MXene’s high surface area and structure characterization, a novel Ti/ carbon black (CB) @MXene anode was prepared for the first time for electrochemical oxidation degradation of 5-chloro-2-methyl-4-isothiazoline-3-one (CMIT) in reverse osmosis brine, even though MXene was studied more widely in sulfate radical based AOP and photocatalysis. This anode showed slippy surface and high oxygen evolution potential (2.84 V), suggesting it is hard to be fouled and eliminated the side reaction effect. According to the anode fabrication parameters optimization, the best mass ratio of Ti3C2Tx and CB was 1:1, showing the highest oxygen evolution potential. The reaction parameters including current density and plate spacing were optimized as 5.625 mA/cm2 and 1.0 cm, where the best CMIT degradation efficiency was 89.86 %. This performance was better than DSA and similar with BDD anode, however its stability needs to be improved. The indirect oxidation dominated CMIT degradation as 99.69 % and •OH formation rate was 13.81 L·mol−1·s−1, which was approximately 5.04 fold higher than that of traditional Ti anode. Three possible degradation pathways of CMIT were proposed, as below: electron rich sulfur in SN bond was oxidized to form sulfoxide structure, chlorine was replaced by •OH, olefin double bond was attacked by •OH. The formed intermediates showed less ecotoxicity. The Ti/CB@MXene anode showed better potential in electrochemical oxidation treatment of reverse osmosis brine.