Smooth Surface Research Articles

Development of Bio-Photoelectrochemical Hybrids for Solar Energy Conversion

Recent advancements in solar energy conversion have identified bio-photoelectrochemical hybrids as one of the most promising sustainable techniques. This study integrates BiVO4 and TiO2 semiconductors with photoautotrophic microorganisms (e.g., Algae) to enhance solar energy conversion. Thin films of these materials were prepared and characterized, revealing a relatively smooth surface for BiVO4 while structures for TiO2 thin films deposited as nanorods. Optical properties showed band gaps of ≤ 3.1 and 2.4 eV for TiO2 and BiVO4, respectively. The point of zero charge of materials was investigated, indicating that naturally occurring biofilm formation might not be favorable for as-prepared materials. To overcome this challenge, we aimed to use polyelectrolytes to enhance attachment of cells on the surface of semiconductor and in this regards we determined the biocompatibility of using this approach. Photoelectrochemical (PEC) measurements were conducted to evaluate solar energy conversion efficiency. This study offers insights into optimizing biosystem attachment, biofilm stability, and PEC performance of coupled semiconductors with photoautotrophic microorganisms as one photoelectrode in PEC cell, advancing sustainable solar energy conversion technologies.

Nitrogen-polar growth of AlN on vicinal (0001) sapphire by MOVPE

We report about metalorganic vapor phase epitaxy of smooth nitrogen-polar AlN templates on vicinal (0001) sapphire substrates. The influence of the V/III ratio, growth temperature, growth rate, as well as sapphire-nitridation time and temperature, were studied. With 4° offcut sapphire, step-flow growth was possible only with V/III ratios below 2. However, the optimal V/III ratio required precise adjustment, possibly dependent on reactor history and geometry. A rather narrow temperature window of less than 40 °C existed for smooth surface morphology. Reducing the temperature affected adatom mobility, eventually disrupting step-flow growth; increasing the temperature favored the formation of high-aspect-ratio defects on the epilayer. A low thermal-budget nitridation step with a short nitridation time of 15 s proved to be effective in controlling polarity without inducing excessive surface damage on the sapphire substrate. The growth rate also influenced surface morphology, with an increase in RMS roughness and step-bunching for faster growths until at growth rates above 1.4 μm/h step-flow growth could no longer occur. Finally, we developed a V/III ratio fine-tuning procedure, whereby the reactor-specific value that induces optimal growth is inferred by growth-rate variations. With this method, N-polar AlN templates with sub-nanometer RMS roughness were demonstrated for both 4° and 2° offcut sapphire substrates.

Isolation and Identification of Morganella morganii from Rhesus Monkey (Macaca mulatta) in China

A bacterium was isolated and identified from the secretion of a rhesus monkey with endometritis. The morphological results showed that the strain exhibited round, convex, gray-white colonies with smooth surfaces and diameters ranging from 1 to 2 mm when cultured on Columbia blood agar at 37 °C for 24 h; on salmonella–shigella agar (S.S.) at 37 °C for 24 h, the colonies appeared round, flat, and translucent. Gram staining showed negative results with blunt ends and non-spore-forming characteristics. Molecular biology results showed that the 16S rRNA sequence of the strain revealed over 96.9% similarity with published sequences of M. morganii from different sources in the NCBI GenBank database. Morphological and molecular biology analysis confirmed that the strain (RM2023) isolated from cervical secretions of rhesus monkey was M. morganii. Drug sensitivity testing demonstrated that the isolated strain (RM2023) was sensitive to ceftriaxone, amikacin, gentamicin, cefazolin, cefuroxime, ceftazidime, levofloxacin, cotrimoxazole, norfloxacin, and tetracycline; moderately sensitive to ampicillin; and resistant to penicillin, vancomycin, ciprofloxacin, and clindamycin. The research findings provide valuable insights for disease prevention in rhesus monkeys and contribute to molecular epidemiological studies.

Optimization of Production Parameters for Fabrication of Gum Arabic/Whey Protein-Based Walnut Oil Loaded Nanoparticles and Their Characterization.

The encapsulation of fatty acids, including walnut oil, within complexes is a promising strategy to address challenges, for instance, low water solubility and susceptibility to oxidation while incorporating these oils into food products. Additionally, encapsulation can effectively mask undesirable odor and flavor. The current study focuses on the optimization of walnut oil nanoparticles (WON) using complexes fabricated from gum arabic and whey protein by applying a response surface methodology. The impact of three different independent variables were determined, such as surfactant mixture (33-66%), walnut oil (5-25%), and sonication time (60-300 s), under three distinct desired conditions (low, medium, and high) on four different responses, i.e., particle size, polydispersity index (PDI), moisture level, and encapsulation efficiency (EE). The findings of the present study indicate that the point prediction-based WON resulted in significantly low particle size (82.94 nm), PDI (0.19), moisture content (3.49%), and high EE (77.26%). Fourier transform infrared spectroscopy (FTIR) study demonstrated the successful encapsulation of walnut oil and wall material into nanocapsules. Differential scanning calorimetry (DSC) verified the improved thermal stability property of WON after incorporation, and scanning electron microscopy (SEM) indicated that the WON had relatively fragile and smooth surfaces, along with the presence of few porous structures. The recorded experimental data from the existing study showed that the developed formulation of WON was potentially useful as a value-added ingredient for food industries.

Solid Lubricant in the Insect Leg Joints: Numerical Simulation of Tribological Properties

AbstractThe behavior of a semi‐solid lubricant from insect leg joints is considered and numerical modeling of its tribological properties is performed. It is shown that elementary lubricant fragments, represented by relatively short cylinders, tend to form clots of different sizes and shapes. The simulation results demonstrate that tribosystem with semi‐solid lubricant is capable of maintaining stability and dynamic equilibrium. The importance of maintaining the relative size of clots and their balanced entry and exit from the tribosystem at an optimal level to ensure stable balance and performance of the joint is emphasized. The function of grooves extending from lubricant‐conducting pores is confirmed to facilitate the distribution of lubricant fragments over smooth contact surfaces where the pores are absent.

Prediction of gas–solid erosion wear of bionic surfaces based on machine learning and unimodal intelligent optimization algorithm

Solid particle erosion wear is an inevitable phenomenon in industrial production, with erosion removal mass serving as a crucial metric for assessing the wear rate per unit area on the impacted surface. Developing predictive models to estimate the degree of mass removal is crucial for effectively controlling, evaluating, and preventing severe damage resulting from solid particle erosion wear. In this study, we constructed a comprehensive dataset comprising smooth and bionic surfaces, encompassing inner, outer, and planar surfaces. The dataset was used in a multifactorial erosion experiment, considering adjustable erosion angles, solid particle incident gas velocities, and solid particle diameter sizes. Through visualization and analysis of the obtained dataset, we identified optimal scenarios for bionic surface erosion resistance, offering insights for structural design against bionic erosion resistance. Furthermore, we compared machine learning algorithms to address the prediction problem, resulting in the selection of the best-performing regression algorithm, SVR (Support Vector Regression). Additionally, we compared the performance of other advanced intelligent optimization algorithms using unimodal benchmark functions, finding that HHO (Harris Hawks Optimization) emerged as the optimal choice for unimodal optimization. Building on HHO, we developed the IHHO (Improved Harris Hawks Optimization)-SVR model, using experimental data from erosion tests as the training dataset. This model can predict gas–solid two-phase flow erosion patterns, encompassing various wall types, solid particle sizes, solid incident gas velocities, and impact angles. Due to its robustness and rapid prediction capabilities, the model is expected to serve as a cost-effective tool for predicting erosion removal mass in gas–solid two-phase flow scenarios.

Effective Promotion of Micro Damping of GO Hybrid PU–PF Copolymer Grinding Wheels on Precision Machining

The influence of damping and friction performance of grinding wheels on precision grinding was explored for the first time. GO hybrid PU-modified PF copolymers were prepared by in situ synthesis and adopted as a matrix for fabricating grinding wheels. FT-IR, DSC, TG, and mechanical property tests showed the optimal modification when PU content was 10 wt% and GO addition was 0.1 wt%. Damping properties were investigated by DMA, and tribological characteristics were measured by sliding friction and wear experiments. The worn surfaces and fracture morphologies of GO hybrid PU–PF copolymers were observed by SEM. Distribution of components on the worn surfaces was explored by Raman mapping and EDS. The research results revealed that the PU component tended to be dispersed around the edges of corundum abrasives acting as a buffer layer of abrasive particles, which could provide micro-damping characteristics for abrasives, making the grinding force more stable during precision machining and facilitating a smoother surface quality of the workpiece.

Aging behavior difference between aqueous coatings and solvent coatings in sulfuric acid environment

Purpose This paper aims to compare the aging behavior of water-based coatings and solvent-based coatings in sulfuric acid environments and to discuss the related mechanism. Design/methodology/approach A sulfuric acid solution with a concentration of 5 Wt.% was selected for immersion test at 23°C. The failure behavior of the coating was studied by combining the transformation rules of the macroscopic morphology and basic properties with the results of electrochemical impedance spectrum analysis. Findings The results showed that the surface smoothness of the water-based coating was lower than that of the solvent-based coating. The glossiness, thickness and hardness of the water-based coating exhibited more significant changes. The electrochemical test also indicated that the water-based coating was infiltrated by a large number of corrosive media, which may have induced corrosion under the coating. In contrast, the solvent-based coating showed good shielding properties, but the adhesion was seriously affected by the corrosive medium. Originality/value This work clarified the difference of failure behavior and mechanism between water-based coatings and solvent-based coatings in acidic environment and provided a theoretical basis for the selection and mechanism research of anticorrosive coatings.

Solvent‐Independent 3D Printing of Organogels

AbstractOrganogels are polymer networks extended by a liquid organic phase, offering a wide range of properties due to the many combinations of polymer networks, solvents, and shapes achievable through 3D printing. However, current printing methods limit solvent choice and composition, which in turn limits organogels' properties, applications, and potential for innovation. As a solution, a method for solvent‐independent printing of 3D organogel structures is presented. In this method, the printing step is decoupled from the choice of solvent, allowing access to the full spectrum of solvent diversity, thereby significantly expanding the range of achievable properties in organogel structures. With no changes to the polymer network, the 3D geometry, or the printing methodology itself, the choice of solvent alone is shown to have an enormous impact on organogel properties. As demonstrated, it can modulate the thermo‐mechanical properties of the organogels, both shifting and extending their thermal stability range to span from ‐30 to over 100 °C. The choice of solvent can also transition the organogels from highly adhesive to extremely slippery. Finally, the method also improves the surface smoothness of prints. Such advances have potential applications in soft robotics, actuators, and sensors, and represent a versatile approach to expanding the functionality of 3D‐printed organogels.

Characterization of holocellulose extracted from agricultural and food processing byproducts via ecofriendly delignification pulping process

AbstractThis study investigated an ecofriendly peracetic acid delignification process to extract holocellulose from various fiber rich plant‐based byproducts (coconut palm spathe/leaf, apple pulp, wine grape pomace, hazelnut shell, and hemp fiber/hurd), and evaluated their physicochemical, morphological, and thermophysical properties in comparison with commercial cellulose nanofibers produced from wood. Holocellulose from coconut palm spathe has long fiber (~846.7 μm), whereas that from wine grape pomace and hazelnut shell exhibits a cylinder shape of particles with short fiber length (~123.8 and ~ 71.1 μm, respectively). Biofilms cast from apple pulp and hemp fiber holocellulose have higher degradation temperature (361 and 358°C, respectively) than biofilms from other materials, thus more thermally stable. All biofilms demonstrate high UV absorbance, and the biofilm cast from apple pulp holocellulose is transparent with smooth surface. Fourier‐transform infrared spectroscopy analysis confirms the presence of cellulose and hemicellulose as the main components in the biofilms, along with traces of residual lignin that remained after the extraction process. This study demonstrates that holocellulose with varied cellulose morphology and polymeric characteristics could be extracted depending on the type of byproducts and be employed to produce sustainable packaging materials.

Wear-resistant and adherent nanodiamond composite thin film for durable and sustainable silicon carbide mechanical seals

In response to environmental concerns, there is a growing demand for durable and sustainable mechanical seals, particularly in high-risk industries like chemical, petroleum, and nuclear sectors. This work proposes augmenting the durability and sustainability of silicon carbide (SiC) ceramic seals with the application of a nanodiamond composite (NDC) film through coaxial arc plasma deposition (CAPD) in a vacuum atmosphere. The NDC coating, with a smooth surface roughness of Ra = 60 nm as substrate, demonstrated a thickness of 1.1 μm at a deposition rate of 2.6 μm/h. NDC film has demonstrated exceptional mechanical and tribological characteristics, such as a hardness (H) of 48.5 GPa, Young's modulus (E) of 496.7 GPa, plasticity index (H/E) of 0.098, and fracture toughness of H3/E2 = 0.46 GPa, respectively. These NDC films showcased commendable adhesion strength (>60 N), negligible wear, and low friction (≤0.18) during dry sliding against a SiC counter material. Raman analysis has confirmed the nanocomposite structure of NDC film, emphasizing the role of highly energetic carbon ions in enhancing film adhesion by forming SiC intermetallic compounds at the interface through the diffusion of silicon atoms from the substrate into the films. The abundance of grain boundaries and rehybridization of carbon sp3 to sp2 bonding is perceived to improve tribological performance. CAPD excels in synthesizing long-life eco-friendly NDC coatings for durable and sustainable mechanical seals, featuring smooth surfaces, superior adhesion, outstanding hardness, and wear resistance, making them high potential candidates for various tribological applications.

Ureteral stents: What your eyes can’t see! An in vitro study

ObjectivesTo characterize and compare in vitro the surfaces of ureteral stents (STENTS) before utilization. MethodsOur in vitro experiment included six unused STENTS models: three double-pigtail with side orifices (ImaJin and Stenostent [Coloplast©,France], TriaSoft [BostonScientific©,USA]), two double-pigtail without side orifice (Vortek-TumorStent [Coloplast©,France], Urosoft-TumorStent [Bard-Angiomed©,Germany]) and one single-pigtail (J-Fil [Rocamed©,Monaco]). STENTS were made of polyurethane except for ImaJin (silicone). For all STENTS, four parts of the stent were specifically analyzed under high-resolution scanning electron microscopy (HR-SEM,FEI-XL40 [Philips©,France]): surface core, lateral orifice, ureteral loop, and black marking surface. Each experiment was repeated with three different samples from three different stents. STENTS analysis included multiple imperfection searches, defined as irregularities>10μm. ResultsAll STENTS presented imperfections with no discernible differences. Imperfections were mainly located on the stent loop and on the lateral orifice. For STENTS without side orifice (J-Fil, Urosoft) imperfections were also reported, on the beveled cut as well as the distal loop orifice. Marking surfaces examinations found defects in the Urosoft and imperfections in the ImaJin and Stenostent. The Triasoft presented a better smoothness on marking surfaces compared to other STENTS. Additional matter was reported on the loop distal orifice for J-Fil and ImaJin but all STENTS presented irregular cross-sectional aeras. ConclusionAll ureteral stents are not perfectly smooth even before utilization. Imperfections were noticed regardless to stent composition or shape, and could play a role in the incrustation phenomenon, is association with inner irregularities, infection, and urine composition. Both manufacturing and material could have an impact on the stent external surface's smoothness. Level of evidence3

Morphological and molecular identification for four new wood-inhabiting species of Trechispora (Basidiomycota) from China.

Four new wood-inhabiting fungi, Trechisporaalbofarinosa, T.bisterigmata, T.pileata and T.wenshanensisspp. nov., are proposed based on a combination of morphological features and molecular evidence. Trechisporaalbofarinosa is characterized by the farinose basidiomata with flocculence hymenial surface, a monomitic hyphal system with clamped generative hyphae, and ellipsoid, warted basidiospores. Trechisporabisterigmata is characterized by the membranous basidiomata with odontioid hymenial surface, rhizomorphic sterile margin, barrelled basidia and subglobose to broad ellipsoid, smooth basidiospores. Trechisporapileata is characterized by the laterally contracted base, solitary or imbricate basidiomata, fan shaped pileus, radially striate-covered surface with appressed scales, odontioid hymenophore surface, and subglobose to broad ellipsoid, thin-walled, smooth basidiospores. Trechisporawenshanensis is characterized by a cottony basidiomata with a smooth hymenial surface, and ellipsoid, thin-walled, warted basidiospores. Sequences of ITS and LSU marker of the studied samples were generated, and phylogenetic analyses were performed with the maximum likelihood, maximum parsimony, and Bayesian inference methods. The phylogenetic tree inferred from the ITS+nLSU sequences highlighted that four new species were grouped into the genus Trechispora.

Near Dry Powder Mixed Electric Discharge Machining of AA7050 Hybrid Composites Utilizing Composite Tool Materials

Electric Discharge Machining (EDM) is a prominent technique for producing components with complex geometry and intricate shapes. However, productivity depends on the selection of optimal input variables. This research investigates EDM and Near-Dry EDM (NDEDM) on AA7050 hybrid composites, exploring the impact of tool materials, Al2O3 powder concentration, and dielectric fluids on Material Removal Rate (MRR) and Surface Roughness (Ra). NDEDM offers a higher MRR due to localized heating and energy concentration, while hydrocarbon oil EDM provides lower Ra due to cooling and lubrication. Tool material properties, thermal conductivity and bonding strength, affect MRR and TWR. Aluminum composite tools via stir casting display a strong bonding interface, leading to efficient energy transfer and higher MRR, while copper composite tools via friction stir processing exhibit weaker bonding, potentially reducing MRR. Hydrocarbon oil significantly lowers TWR due to effective lubrication and cooling, while near dry EDM results in slightly higher TWR. Al2O3 powder enhances MRR, with an optimal concentration of 1 g/l, while higher concentrations hinder MRR. The presence of Al2O3 powder enhanced the surface quality by reducing the size of the recast layers and producing a smoother surface. Globules, craters, microcracks, pock marks and re-casted layers are the noticeable features spotted on the surface. The results were optimized using the TOPSIS optimization technique and process parameters 32 A current, 30 µs Ton, 3 mm gap distance machined under 3 g/l Al2O3 incorporated hydrocarbon oil dielectric medium using copper composites tool proffers optimal machining performance.

Recent Developments in Slippery Liquid-Infused Porous Surface Coatings for Biomedical Applications.

Slippery liquid-infused porous surface (SLIPS), inspired by the Nepenthes pitcher plant, exhibits excellent performances as it has a smooth surface and extremely low contact angle hysteresis. Biomimetic SLIPS attracts considerable attention from the researchers for different applications in self-cleaning, anti-icing, anticorrosion, antibacteria, antithrombotic, and other fields. Hence, SLIPS has shown promise for applications across both the biomedical and industrial fields. However, the manufacturing of SLIPS with strong bonding ability to different substrates and powerful liquid locking performance remains highly challenging. In this review, a comprehensive overview of research on SLIPS for medical applications is conducted, and the design parameters and common fabrication methods of such surfaces are summarized. The discussion extends to the mechanisms of interaction between microbes, cells, proteins, and the liquid layer, highlighting the typical antifouling applications of SLIPS. Furthermore, it identifies the potential of utilizing the controllable factors provided by SLIPS to develop innovative materials and devices aimed at enhancing human health.

Anticancer Therapy with Proteolysis-targeting Chimeras [PROTACs] Targeting Towards the Tumor-microenvironment: Development, Current State and Prospects

Abstract: Targeted protein degradation is a rapidly expanding area that offers hope for novel approaches to combat drug resistance. The creation of heterobifunctional proteolysis-targeting chimeras [PROTACs], a new group of pharmaceutical compounds, has made TPD a useful method for completely getting rid of harmful proteins using regular small-molecule inhibitors. A big plus is that PROTACs can target multi-domain proteins that cannot be broken down. This is the case, particularly for proteins lacking a conserved interaction surface for small-molecule ligands [SMIs] and featuring smooth surfaces. Poor oral bioavailability and pharmacokinetic [PK] and ADMET [absorption, distribution, metabolism, excretion, and toxicity] characteristics are among the long-term issues with traditional PROTACs. Their larger size and more complex structure set them apart from other smallmolecule inhibitors, which is why they are so effective. Clinical studies have been conducted on a plethora of PROTAC compounds in the past 20 years, all with the goal of inducing the degradation of targets relevant to cancer. In this article, we closely examine the major developments and recent advancements in PROTAC technology. We seek to summarize and fully assess PROTAC-based targeted protein degradation studies on "undruggable" targets. Discussing their molecular structure, action mechanism, design concepts, development benefits, and obstacles will help to illustrate the significance of developing highly successful PROTAC-based techniques in treating many illnesses, including cancer treatment resistance.

Functionalized graphene oxide NPs as a nanocarrier for drug delivery system in quercetin/ lurbinectedin as dual sensitive therapeutics for A549 lung cancer treatment

Functionalized graphene oxide nanoparticles (NPs) have emerged as promising nanocarriers for drug delivery in lung cancer therapy. Quercetin and lurbinectedin encapsulated in graphene oxide (GO) NPs are tested for treating A549 lung cancer cells. Spectroscopic analyses show that graphene oxide functionalization creates a transparent, smooth surface for drug loading. Treatment with quercetin/lurbinectedin-loaded GO NPs induces notable cytotoxic effects in lung cancer cells, as evidenced by distinct morphological alterations and confirmed apoptotic cellular death observed through fluorescence microscopy. Additionally, our study highlights the impact of this approach on lung cancer metastasis, supported by qRT-PCR analysis of relative gene expression levels, including p53, Bax, Caspase-3, and Bcl 2, revealing robust molecular mechanisms underlying therapeutic efficacy against A549 and PC9 cell lines. Flow cytometric analyses further confirm the induction of cellular death in lung cancer cells following administration of the nanoformulation. Our findings show that quercetin/lurbinectedin-loaded GO NPs may be a promising lung cancer treatment, opening new avenues for targeted and effective therapies.

Friction-Wear and Noise Characteristics of Friction Disks with Circular Texture.

The reduction of friction-induced noise is a crucial research area for enhancing vehicle comfort, and this paper proposes a method based on circular pit texture to achieve this goal. We conducted a long-term sliding friction test using a pin-on-disc friction and a wear test bench to verify the validity of this method. To compare the friction noise of different surfaces, texture units with varying line densities were machined on the surface of friction disk samples. The resulting friction-wear and noise characteristics of the samples were analyzed in conjunction with the microscopic morphology of the worn surfaces. The results indicate that surfaces with textures can delay the onset of squeal noise, and the pattern of its development differs from that of smooth surfaces. The noise reduction effect is most evident due to the proper distribution of textures that can form furrow-like wear marks at the wear interface. The finite element results demonstrate that this morphology can improve pressure distribution at the leading point and reduce the tendency of system instability.

Surface integrity and rolling contact fatigue behavior of 18CrNiMo7-6 steel subjected to ultrasonic surface rolling process

In this study, the effect of ultrasonic surface rolling process (USRP) on the surface integrity and rolling contact fatigue (RCF) behavior of 18CrNiMo7-6 steel have been conducted. The different static loads and ultrasonic amplitudes on surface morphology, surface roughness, microstructure, microhardness, and residual stress were examined. Results revealed that USRP treatment resulted in a remarkably smooth surface with the surface roughness value Ra of 0.035 μm. Moreover, USRP treatment induced the formation of nanocrystalline and ultrafine crystalline structures on the surface layer. Additionally, the sample surface was subjected to a significant layer of residual compressive stress, reaching a maximum value of approximately −1243 MPa and extending to a depth of around 1500 μm. The surface microhardness had been increased to 808 HV0.2. The comprehensive integration of grain refinement, the increase of surface microhardness, and the induction of residual compressive stress led to an improvement in RCF life.

Microstructural Characterization, Mechanical Performance, and Anti-Corrosive Response of Zinc Multifaceted Coating on Mild Steel

Zinc has attracted significant attention in research due to its cost-effective use as an electrodeposited material, effectively protecting various types of steel from corrosion and wear. However, despite its advantages, zinc has limitations in fully guarding steel against corrosion. Recent studies propose that blending zinc with other metals during the coating process can proficiently shield mild steel from deterioration. The motivation for this study stems from recognizing the restrictions of zinc electrodeposition and the limited exploration of zinc multi-facet composite coatings for mild steel. In this study, the electrodeposition technique was employed to apply a coating to mild steel using zinc and nanoparticles of calcium oxide (CaO) and manganese oxide (MnO2). The coating bath's chemical composition included mass variations of 0-12 g/L for CaO and MnO2, along with 10 g/L each of boric acid, thiourea, and Na2SO4, and 15 g/L of K2SO4 and ZnSO4. The coating process occurred over a twenty-minute period, with a pH of 4.8, voltage set at 3.2V, current density at 1 A/cm2, temperature at 47°C, and stirring rate at 200 rpm. Results obtained from the coated mild steel demonstrated that Zn-6CaO-6MnO2 exhibited the greatest coating thickness at 0.2308 mm, and it showcased impressive corrosion resistance at 2.0618 mm/year. The Zn-CaO-MnO2 coating displayed a substantial deposit of crystallites in its microstructure, assisted by the presence of manganese, contributing to a smoother surface texture.