Fabrication Of Surfaces Research Articles

Trace amounts of silica and epoxy resin driven MXene-based flexible electrode coupled with good cycle stability

MXene-based flexible electrodes possess advantageous properties, including good electrical conductivity and high specific capacitance. Nevertheless, the lack of cycling stability of these flexible electrodes represents a significant limitation for their further application in wearable technology. In response to this challenge, this study innovatively composites SiO2 nanoparticles with Ti3C2Tx nanosheets and introduces a trace amount of epoxy resin to prepare CC/MXene@SiO2-EP nanostructures, which form a unique three-dimensional structural composite. This method significantly enhanced the interfacial properties, electrochemical performance, and cycling stability of MXene-based flexible electrodes in a straightforward and environmentally benign manner. The introduced epoxy resin acts as an efficient binder to firmly anchor the MXene@SiO2 nanostructures to the carbon cloth surface, which greatly improves the mechanical properties of the flexible devices. The specific capacitance of the CC/MXene@SiO2-EP composite in the three-electrode system was approximately 481.4 F g−1, with a capacity retention of 94.07 % after 8000 cycles. Furthermore, the AC//CC/MXene@SiO2-EP ASC device assembled with activated carbon exhibits an ultra-high energy density of 39.74 W h kg−1 at a power density of 400 W kg−1 and a capacitance retention of up to 96.7 % after 5000 cycles at maximum 90° reciprocal bending. It can be observed that CC/MXene@SiO2-EP composites represent a novel class of flexible electrodes, offering a promising avenue for the advancement of the energy storage field.

Preparation and Properties of GMS/HTSF-Modified Waterborne Polyurethane Fluorine-Free Waterproof and Breathable Film.

Developing a fluorine-free, durable, high-performance waterproof breathable film for fabrics remains a formidable challenge. In this paper, a strategy for the preparation of fluorine-free, durable, and high-efficiency fabric waterproof and breathable membranes using glyceryl monostearate (GMS)/double-ended hydroxy silicone oil (HTSF)-modified waterborne polyurethane was proposed. The orderly orientation of GMS and HTSF gives the fabric excellent water-repellent properties, and the polyurethane macromolecular chain ensures strong adhesion of long-chain alkanes and silicones to the fabric surface. In this paper, the effects of different GMS contents on the stability, chemical structure, particle size, viscosity, water absorption performance, surface morphology, and XPS of a waterborne polyurethane fluorine-free waterproof and breathable membrane (GHWPU) were studied. At the same time, the application properties of GHWPU-treated fabrics, such as waterproof performance, antifouling performance, surface energy, morphology, and air permeability, were discussed. Through the analysis of SEM and XPS, it was found that the folds on the surface of the film were more and more orderly with the increasing content of GMS, and this orderly distribution of water-repellent groups endowed the film with excellent water-repellent ability. When the GMS content was 28 wt %, the finished fabrics had excellent comprehensive properties such as static contact angle of 141.6°, hydrostatic pressure of 96.7 KPa, resistance to more than 30 washes, and air permeability of 119.3 mm/s.

ERT-based fetus monitoring system using wearable conductive fabrics

Abstract During pregnancy, it is important to monitor the health of the fetus and fetal movement count is one of the key parameters that can be used to check the health of the fetus. Consequently, there is growing interest in developing non-invasive passive methods for fetal monitoring techniques that can be used outside of clinical settings. This study introduces a home-use system based on electrical resistance tomography that pregnant mothers can utilize for fetus monitoring. The setup utilizes a conductive fabric, functioning as electronic skin (e-skin), positioned on the mother’s abdomen to detect alterations in the fabric’s electrical characteristics caused by fetal movements. This method is validated through both numerical simulations and experimental investigations, which assess conductivity changes on the fabric’s surface in reaction to localized pressure fluctuations, mimicking fetal motions.

Flexible, breathable, and durable superhydrophobic cotton fabric modified by behenic acid, tung oil, and ZIF-8 with anti-icing and self-cleaning properties

Textiles with self-cleaning and anti-icing capabilities in cold climates are essential for outdoor workers and enthusiasts. Superhydrophobic modification of textile surfaces is effective in imparting these characteristics. Although there are numerous methods available for manufacturing superhydrophobic textiles, careful consideration is warranted for environmental concerns over fluorochemicals, stability of superhydrophobic coatings, and fabric breathability. In this work, we utilized biomass resources such as tung oil and behenic acid, along with zeolitic imidazolate framework (ZIF-8), to modify cotton fabrics, thereby creating an innovative behenic acid/tung oil/ZIF-8 modified cotton (BTZC) fabric with anti-icing and self-cleaning features. This material manifests a unique nanoflower-shaped surface morphology, demonstrating exceptional superhydrophobicity with a static water contact angle (CA) of 162° and a sliding angle (SA) of 2°. Moreover, BTZC excels in its thermal stability, breathability, and resistance to icing. Equally impressive is its robust stability, as evidenced through rigorous testing under continuous washing and abrasion, sustained high and low temperatures, extreme pH environments, and immersion in various chemical solvents. BTZC presents as a fluorine-free, durable, economically viable alternative for outdoor textile applications, marking substantial progress in the utilization of biomass and metal-organic framework materials in the textile industry and promising implications for value enhancement.

Rapid determination of the antimicrobial properties of surfaces using an enzymatic activity surrogate

AbstractTypical approaches for assessing the antimicrobial activity of metals‐based surfaces involve the contact of a bacterial culture with the surface for a period of time, followed by culturing on agar plates to assess the decrease in microbial viability versus controls. This is a time‐consuming methodology requiring at least 24 h to produce a set of results, which can be a bottleneck for productivity in novel materials development. An enzyme‐based method was shown to be a satisfactory and much more rapid surrogate test for this application. A β‐galactosidase solution was applied to copper, silver, and zinc‐based antimicrobial surfaces for up to 1 h, and then the rate of colour development at 578 nm was monitored for a few minutes after addition of the chromogenic enzyme substrate chlorophenol red‐β‐d‐galactopyranoside (CPRG). Highly active antimicrobial surfaces were detected by a lack of colour development, due to enzyme inhibition by the metals. The enzymatic reaction rates were quantified and compared, demonstrating that the copper sample showed the greatest inhibition effect followed by the silver and zinc samples. The antimicrobial activity was quantified using bacteria and the plate count method, and the results correlated well with this enzyme assay, demonstrating that the metals‐based antimicrobial activities of both hard and soft (textile) surfaces could be quickly assessed with this enzyme‐based methodology.

Asymmetrical surface-modified polyester/cotton fabrics for temperature-adaptive moisture and thermal management of human body

Personal moisture and thermal management fabrics that can regulate skin temperature are highly desired for improving human comfort and performance. Here, a symmetric surface modified polyester/cotton fabric (Janus T/C fabric) exhibiting exceptional temperature-adaptive personal moisture and thermal managements was developed. This was achieved by integrating two distinct temperature-sensitive hydrophobic/hydrophilic transition materials through single-sided spray coating technique and in-situ ultraviolet-induced free radical polymerization in 60/40 polyester/cotton blend fabric (T/C fabric, composed of 60 % cotton and 40 % polyester fibers). 2-(2-methoxyethoxy) ethoxyethyl-methacrylate (MEO2MA) was utilized to create lower critical solution temperature (LCST) polymer, while N, N-dimethyl (methacryloylethyl) ammonium propane sulfonate (DMAPS) formed an upper critical solution temperature (UCST) polymer on T/C fabric surface. Fabric’s surface demonstrated a reversible transition in hydrophobicity/hydrophilicity in response to environmental temperature changes. The distinct hydrophobic and hydrophilic surfaces configuration resulted in a remarkable wettability gradient, significantly increased moisture permeability to 6792.5 g/m2·24 h—an increase of 1132.1 g/m2·24 h compared to the 60/40 T/C fabric at 40 °C. Moreover, the Janus T/C fabric provided practical temperature adaptation benefits, offering a cooling effect of approximately 1.2 °C in hot environments and a warming effect of approximately 1.0 °C in cold conditions. These thermal responsive properties make the asymmetric surface-modified polyester/cotton fabric an ideal choice for personalized moisture and thermal management, ensuring optimal comfort across varying temperatures.

Dyeing of Mixed Cotton and Polyester Fabrics with New Dyes—Complexes of Collagen with Transition Metal Ions

Uniform, stable, one-step dyeing of textile fabrics made from a mixture of natural and synthetic fibers using traditional methods remains problematic to this day. As an alternative to traditional methods, a one-step method for dyeing mixed cotton and polyester fabrics with a new natural dye—a complex of collagen and [Formula: see text] and [Formula: see text] ions—was proposed for the first time. Dyeing of pre-prepared cotton, polyester, and cotton–polyester fabrics is carried out by dipping in an aqueous dye solution, squeezing, drying, and heat setting. The influence of the mass ratio of dye components, fixation temperature, and pH of the solution on the degree of dye fixation was determined. A degree of sorption of dyes (14–25%) from the solution onto the surface of fabrics was established, which after heat fixation decreases slightly (1–3%). During washing processes, the copper complex is almost completely washed out from polyester and blended fabrics and remains in small quantities (2.4–3.8%) on the surface of cotton fabrics. After water washing, the degree of fixation of the collagen–chrome complex in fabrics is as follows: in cotton—8–10%, in polyester—10–12%, and in cotton–polyester—8–9%. The color coordinates of cotton and cotton–polyester fabrics hardly change before and after washing, but for polyester fabric, the changes are significant. The mechanism of interaction of the complex dye with the fibers was studied using the Fourier transform infrared method, and the morphology and distribution of the dye on the surface of the samples using the SEM-EDS method. The dye binds to cellulose through ionic and coordination bonds, and to polyester through joint melting. Therefore, unlike pure polyester fabric, cotton and cotton–polyester fabrics demonstrated high color fastness to washing and light fastness. The use of production waste, the exclusion of synthetic dyes and harmful chemicals, and single-stage dyeing of the material reduce the environmental burden.

Sodium alginate/guar gum/multi-walled carbon nanotubes-based hydrophobic Joule thermal textiles for enhanced body thermal management and dehumidification

A sodium alginate (SA), guar gum, and multi-walled carbon nanotube composite solution was prepared using a simple blending method, followed by the construction of alginate/guar gum/multi-walled carbon nanotube fibers and fabrics through complexation with various metal ions (zinc, copper, calcium), featuring multiple hydrogen bonds and ionic complex structures. Specifically, the sodium alginate zinc/guar gum/multi-walled carbon nanotube (SA/GG/Zn2+/MWCNTs) composite fibers exhibited a significant Joule heat effect. By integrating with electronic components such as a temperature control switch, a wearable device capable of operating in cold and humid environments for dehumidification and warming was fabricated. The SA/GG/Zn2+/MWCNTs composite fabric demonstrated excellent hydrophobicity, with a contact angle reaching 145.4°, significantly enhancing its resistance to droplet penetration. Under a 5V voltage, the composite fabric rapidly generated Joule heat, increasing the surface temperature by 5∼7 °C (sensible heat) within just 40 s. Additionally, part of its energy (latent heat) transformed the tiny droplets adhering to the fabric's surface from liquid to gas, achieving dehumidification. This research provides an important theoretical and practical foundation for enhancing the performance and energy efficiency of personal thermal management textiles.

INFLUENCES OF CROSSLINKER AND MOLECULAR WEIGHT OF CHITOSAN ON PHYSICO-CHEMICAL PROPERTIES OF ANTIBACTERIAL TREATED COTTON FABRICS

This study investigated the influences of crosslinking agent and molecular weight on the surface and comfort properties of cotton fabrics treated by chitosan. Two types of chitosan, with molecular weight (2.6 kDa and 187 kDa), with deacetylation degree (DD) of 75%, were used, along with two types of crosslinking agents: citric acid (CA) and dimethylol dihydroxyethyleneurea (DMDHEU). These agents were applied to cotton fabrics for antibacterial treatments. The treated cotton fabrics were evaluated using several quality indicators related to physico-chemical properties, including whiteness (according to ISO 105 J02), breathability (according to ASTM D737:2004), moisture (according to ASTM D 2495-87), and thermal and moisture resistance under steady-state conditions (according to ISO 11092). Moreover, surface features of treated samples were observed through SEM images. The results showed that the antibacterial treatment of fabrics with lower molecular weight (Mw) chitosan was more favorable for the finishing processes, although the whiteness of the treated samples was quite low. Additionally, cotton fabrics treated with the CA agent exhibited better hygroscopicity and vapor transmission, but tended to have more pronounced yellow color, compared to those treated with the DMDHEU agent. These physico-chemical findings clarified the bonding mechanism of cellulose–crosslinker–chitosan in antibacterial treated cotton fabrics.

Bioinspired carbon black deposited polyimide fabric for sustainable water energy harvesting

Water is the source of life and the largest energy carrier on Earth. Various excellent hydrovoltaic technologies have been proposed, but still suffer from issues such as intermittent output, material limitations, and poor flexibility. Here, we proposed a method for fabrication of a hydrovoltaic generator using the flexible polyimide fabric. Carbon black was deposited on the polyimide fabric surface using a simple method of candle flame burning. On the basis of water transport in the fabric and charge separation induced by negatively charged carbon black channels, sustainable hydrovoltaic power generation was achieved by the generator. A single carbon deposited polyimide fabric (CBP) could generate a continuous voltage output of nearly 260 mV by dripping a water drop on one side. Multiple CBP devices were connected in series and parallel to increase output power, which could be applied for the power and energy storage of small electronic devices. This work may provide a convenient strategy for fabricating sustainable flexible hydrovoltaic generators and offer insights for the development of clean power sources.

Circular economy reinforcement through molecular fabrication of textile wastes with microbial synthesized ZnO nanoparticles to have multifunctional properties

The fibrous wastes generated from the mills of textile production can be recycled and converted into high add-values products to be implemented in several applications. The current study aimed to employ commercial free cellulase enzyme to partially hydrolyze (activate) the polyester cotton blended (PET/C) fibrous wastes by creation functional groups such as OH and COOH on their surfaces. The activated fibrous wastes were then modified by coating with ZnO nanoparticles (ZnO-NPs) biosynthesized by actinobacterial cultures free supernatant. The isolate was identified as Streptomyces pseudogriseolus with accession number of OR574241. The conditions that influence the actino-synthesis of ZnO-NPs were optimized and the product was characterized using spectroscopic vision, FTIR, XRD, TEM and SEM. The characteristic ZnO peaks were obviously observed by EDX analysis with 0.38 and 0.75% (wt%), respectively. TEM analyses proved the nanoscale of ZnO-NPs (5–15 nm) which was followed by cytotoxic evaluation for the produced NPs. Fortunately, the tested actino-ZnO-NPs didn’t have any cytotoxicity against human normal fibroblast cell line (BJ1), which means that the product can be safely used in a direct-contact with human skin. The treated PET/C blended waste fabrics coated with ZnO-NPs showed high antimicrobial activity and ultraviolet protection values after functionalization by cellulase. EDX analysis demonstrates the presence of Zn peaks on the coated fabrics compared with their absence in blank and control samples, while SEM images showed the formation of a thin layer of ZnO-NPs on the fabric surface. The obtained smart textile can be applied several needed sectors.

Thermal Degradation and Chemical Analysis of Flame-Retardant-Treated Jute Fabrics.

Jute is an inherent lignocellulosic fiber, consisting of hemicellulose, α-cellulose, and lignin. Industrial ventilation, automotive composites, upholstery, carpets, military uniforms, hospital furnishings, and curtains necessitate the integration of flame-retardance properties into jute fibers. In this investigation, seven weave-structured jute fabrics were treated using an organophosphorus-based flame-retardant (FR) chemical (ITOFLAM CPN) and a crosslinking agent (KNITTEX CHN) by the pad-dry-cure method. The thermal stability, degradation and pyrolysis behavior of jute was measured using a thermogravimetric analyzer (TGA). Surface morphology and element distribution were scrutinized utilizing a scanning electron microscope (SEM) and an energy-dispersive spectrometer (EDS). The ATR-FTIR (Attenuated Total Reflection-Fourier Transform Infrared Spectrometer) technique has been employed for analyzing the composition of chemicals in the jute fabrics. According to the protocols specified in ISO 14184-1, free formaldehyde detection was carried out on the jute fabrics. The flame-retardance property was significantly improved on all of the jute fabrics after FR treatment. FTIR and SEM-EDS studies revealed the presence of FR chemical deposition on the surface of the jute fabrics. TGA analysis indicated that the fabrics treated with FR exhibited premature degradation, leading to the generation of more char compared to untreated samples. The jute fabrics specifically demonstrated a notable enhancement in residual mass, exceeding 50% after FR treatment. However, it is noteworthy that the FR-treated fabrics exhibited an elevated level of free formaldehyde content, surpassing the permissible limit of formaldehyde in textiles intended for direct skin contact. The residual mass loss percentage after ten washes of FR-treated fabrics remained in a range from 32% to 36%. Twill weave designed fabrics (FRD4 and FRD5) clearly showed a lower thermal degradation temperature than the other weaves used in this study.

Intelligent process monitoring of smart polymer composites using large area graphene coated fabric sensor.

Herein, we report the development of an online process monitoring system for vacuum-assisted resin transfer molding (VARTM) process using large area graphene coated in-situ fabric sensor. Besides imparting excellent mechanical properties to the final composites, these sensors provide critical information during the composite processing including detecting defects and evaluating processing parameters. The obtained information can be used to create a digital passport of the manufacturing phase to develop a cost-effective production technique and fabricate high-quality composites. The fabric sensor was produced using a scalable dip-coating process by coating 1-, 3- or 5-layers of thermally reduced graphene oxide (rGO) onto glass fabric surface according to the number of dips of the fabrics into GO solution. The electrical resistances from all electrode pairs were simultaneously and continuously recorded during distinct stages of the VARTM process to determine the relative conductance. During the vacuum cycle, the range of relative conductance increased with the number of coated rGO layers, with the 5-layer rGO-coated sensor showing the highest conductance range of 16.9 %. Additionally, it was observed that the 5-layer coated sensor showed a consistent decrease in conductance during the infusion phase due to the fluid flow pressure dominating the resin electrical conductivity.

One-pot preparation of one-dimensional hierarchically porous carbon@SnO2 nanocomposites for flexible fabric-based supercapacitor electrodes

The design of functional energy storage materials with superior performances has become the focus topic with the growing energy crisis in recent years. Herein, porous carbon nanofibers@tin dioxide (PCNFs@SnO2) composites are prepared by one-pot electrospinning and followed by carbonization. The PCNFs@SnO2 possesses a hierarchically porous structure containing mesopores and micropores. The specific surface area is as high as ∼ 559.4 m2 g−1, and the total pore volume can reach 0.28 cm3 g−1. Meanwhile, the nonwoven fabric surface is coated with a silver layer through the screen printing technique to obtain silver-coated nonwoven fabric (SNF). Importantly, PCNFs@SnO2 and SNF are combined to obtain flexible fabric-based functional materials. As a primary energy application, the prepared PCNFs@SnO2/SNF electrode has a high mass specific capacitance of 583.1 F g−1 at 1 A g−1, a high area specific capacitance of 933 mF cm−2 at 1 mA cm−2, and a good rate capability (70 % at 10 A g−1). The supercapacitor device with two PCNFs@SnO2/SNF electrodes also shows outstanding cycling durability, capacitor retention is as high as ∼ 91.52 %, after 10000 charging/discharging cycles. In brief, our study may provide an innovative route for designing hierarchically porous one-dimensional carbon nanocomposites for supercapacitors with high performances.

Preparation of superhydrophobic polyester fabric for swimsuits using amino silicon micro-emulsion

Enhancement the hydrophobicity of polyester fabric was developed to help the swimming performance of athletes by adding buoyancy, stability and speed. Increasing the hydrophobicity was carried out by chemical treatment of pre-treated polyester fabric with different specifications using amino-silicon (AS) micro-emulsion. The pretreatment of the fabric was carried out either chemically (i.e. saponification) or physically (i.e. plasma radiation) to allow the chemical reaction between AS and polyester fabric. The effect of the treatment on some physical properties of the fabric viz., air and water permeability, wettability, contact angle and wicking were studied. The alteration in the chemical composition of the untreated and treated fabrics was monitored using Fourier Transform Infrared Spectroscopy (FTIR) and X-Ray Diffraction Pattern (XRD). Scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDX) displayed the surface of the polyester fabric after treatment and the distribution of the AS over the fabric. The results showed that treatment of polyester fabric with AS increased the hydrophobicity of the fabric and that was clear from the data of wettability, contact angle and wicking test without any deterioration in the chemical or mechanical properties of the fabric.

Sustainable pre-treatment of cellulose knitwear in digital pigment printing processes

PurposeIn the field of research on the application of digital printing to textile materials, there are still many research issues that arise from the very demanding interaction of digital printing technology and the complex, heterogeneous surface system of textile materials. This is precisely why the area of pre-treatment of textile materials is in need of research, and the purpose of this research was to establish the level of influence of physical and chemical activation of the textile surface with plasma and the possibility of improving the quality of the print and colour reproduction.Design/methodology/approachThe paper deals with the possibility of applying argon and oxygen cold low-pressure plasma in the processing of cellulose knitted fabrics, with the aim of improving the quality of the print and colour reproduction in digital pigment inkjet printing. The selected raw material samples were 100% raw cotton and lyocell. After plasma treatment, the samples were printed by digital ink jet printing with water-based pigment printing ink. An analysis of the micromorphological structure of untreated and plasma-treated samples before and after printing was carried out, and a comparative analysis of the colour of the printed elements was carried out depending on the pre-treatment.FindingsThe conducted research showed a positive influence of plasma pre-treatment on the coverage of the fibre surface with pigments, the uniformity of pigment distribution along the fibre surface and the uniformity of the distribution of the polymeric binder layer. This has a positive effect on colour reproduction. Also, certain improvements in colourfastness to washing were obtained.Research limitations/implicationsConsidering the complexity of the topic, although exhaustive, this research is not sufficient in itself, but opens up new questions and gives ideas for further research that must be carried out in this area.Practical implicationsAlso, this kind of research contributes to the possibility of adopting the idea of industrial plasma transformation, as an ecologically sustainable functionalisation of textiles, which has not yet been established.Originality/valueThis research is certainly a contribution to the establishment of acceptable textile pre-treatment methods in the field of digital printing, as one of the key quality factors in digital textile printing (DTP). Considering the still large number of obstacles and unanswered questions encountered in the field of digital printing on textiles, this kind of research is a strong contribution to the understanding of the fundamental mechanisms of the complex interaction between printing ink and textile.

Numerical calculation of air permeability of warp-knitted jacquard spacer shoe-upper materials based on CFD

Abstract In order to realize the rapid design of warp-knitted jacquard spacer shoe-upper materials and to explore the influence of different fabric surface organization structures on their air permeability, it is proposed to numerically simulate the air permeability performance of jacquard shoe-upper materials using ANSYS fluid analysis. First, four kinds of shoe material specimens with different upper and lower layer mesh alignment relationships are designed and tested, then the corresponding geometric structure models of the fabric are established based on the samples and appropriately processed, and finally the air permeability of the shoe material is numerically simulated and calculated based on computational fluid dynamics. The results show that, under the same conditions, the air permeability of double-sided mesh structure is significantly better than that of single-sided mesh structure, and its air permeability can be optimized by adjusting the relationship between the upper and lower layers of the fabric mesh; the airflow mainly passes through the fabric pores and gaps between the yarns, and the closer the fabric structure is, the more the air flow is hindered, and the worse the air permeability is. The simulation results of the established numerical model are consistent with the measured results, and the error is less than 10%, so it can be used to simulate and predict the air permeability of the warp-knitted jacquard spacer footwear materials, and provide theoretical support for the design and performance research of footwear materials.

Biochemical Evaluation and Structural Characteristics of Copper Coating Cellulose Nonwovens Prepared by Magnetron Sputtering Technology

The research aimed to enhance the aqua-jet/spunlace cellulose nonwoven fabric by deposition of copper coating by magnetron sputtering technology. Plasma technology facilitated the efficient distribution of copper particles on the surface of the cellulose nonwoven fabric, while maintaining free airflow and eliminating the need for additional layers. New cellulose-copper composites exhibit potential in biomedical applications, while minimizing their impact on biological processes such as blood plasma coagulation. Consequently, they can be utilized in the production of dressings, bandages, and other medical products requiring effective protection against bacterial infections. The cellulose-copper composite material was subjected to the physiochemical and biological investigations. The physiochemical analysis included the elemental analysis of composites, their microscopic analysis and the surface properties analysis (specific surface area and total pore volume). The biological investigations consisted of biochemical-hematological tests including the evaluation of the activated partial thromboplastin time and pro-thrombin time. Biodegradable materials based on cellulose nonwoven fabrics with the addition of copper offer a promising alternative to conventional materials. Their innovative properties, coupled with environmental friendliness and minimal impact on biological processes, offer vast application possibilities in healthcare and the production of hygiene products.

Fe3O4@CNTs/PANI/PI fabric with magnetic–dielectric nanonetwork as a highly efficient microwave absorber

Since the matching between the complex permittivity and permeability plays a dominant role in the performance of microwave absorbing, magnetic-dielectric materials have been increasingly used for microwave absorption. In this paper, Fe3O4 nanoparticles anchored on carbon nanotubes (Fe3O4@CNTs) were fabricated via a self-assembled technique. The efficient microwave-absorbing fabric was synthesized by building polyaniline nanofibers (PANI NFs) and Fe3O4@CNTs magnetic–dielectric network on the surface of polyimide (PI) fabric. The results of SEM, FTIR, and XRD demonstrated the presence of Fe3O4@CNTs on the fabric surface. The decomposition temperature (Td) of the fabric was beyond 580.0 °C and the fabric exhibited strong hydrophobicity (water contact angle 125.0°). The Fe3O4@CNTs/PANI/PI fabric possessed a minimum reflection loss (RL) value of −62.61 dB (>99.9 % absorption) with a matching thickness of 1.58 mm. The excellent microwave absorption capacity is attributed to the well impendence match, dielectric and magnetic loss, and the scattering loss of the special cell structure.

Fabrication of Cu2O plated carbon fabrics via electrochemical deposition method

Functional fabrics have many advanced applications to meet the expectations of the end-user industry. There is a variety of approaches to impart functional properties to the fabrics including coatings, the addition of functional fillers, surface modifications, etc. Metallization techniques are also a good candidate to impart functionalities to textile fabrics. On the other hand, Cu2O is a diamagnetic solid that has a variety of applications from flexible electronics to gas sensing. In this study, one of the simplest plating techniques, the electroplating method, was applied to carbon fabric to provide Cu2O coating on the surface which can add the advantages of metal oxides on carbon fabric. The Cu2O particles were observed on the surface of carbon fabric using SEM and the elemental composition of the surface was investigated using the EDS method. The crystal structure of the coating was identified using the X-ray diffraction technique and Raman spectroscopy. To confirm the achieved structure, FTIR analysis was performed as well. The newly fabricated structure can be a promising candidate for supercapacitors, electromagnetic shielding materials, dielectric surfaces, etc.