Surface Layer Research Articles

Diffusion kinetics of borided of low entropy soft magnetic FeCo alloy

Abstract The growth kinetics of boride layers were investigated by boronizing the FeCo low entropy alloy produced by arc melting reverse vacuum system with the pack boriding method at temperatures of 1173 K, 1223 K, 1273 K and for 2, 4, 6 h. FeCo alloy has a single-phase FCC crystal structure and there are linear cracks and homogeneously distributed point voids in its microstructure. The hardness of FeCo alloy is between 170 HV0.05 and 265 HV0.05. The boride layer appearance has a sawtooth appearance, and the layer thickness varies between 62 µm and 172 µm depending on temperature and time. According to the XRD pattern, (CoFe)B and (CoFe)B2 triple phases are present on the boride layer surface. With pack boriding, the hardness of the boride layer increased up to 2262 HV0.05, and the surface hardness of the alloy improved by 8–10 times. The boride layer activation energy of the FeCo alloy boronized with pack boriding was calculated as 89.065 kJ mol−1.

Unique features of plasmonic absorption in ultrafine metal nanoparticles: unity and rivalry of volumetric compression and spill-out effect

Abstract We present a solution to a longstanding challenge in nanoplasmonics and colloid chemistry: the anomalous optical absorption of noble metal nanoparticles in the ultrafine size range of 2.5–10 nm, characterized by a rapid long-wavelength shift in plasmon resonance as the particle size increases. Our investigation delves into the impact of alterations in electron density along the radial direction of nanoparticles and the resulting variations in dielectric constants on the spectral positioning of the plasmon resonance. We explore the interplay of the spill-out effect, volumetric compression, and their combined impact in different experimental conditions on electron density variation within the particle volume and its blurring at the particle boundary. The latter effectively forms a surface layer with altered dielectric constants and a size-independent extent. As particle size decreases, the influence of the surface layer becomes more pronounced, especially when its extent is comparable to the particle radius. These findings are specific to ultrafine plasmonic nanoparticles and highlight their unique properties.

Sheaths are diverse and abundant cell surface layers in archaea.

Prokaryotic cells employ multiple protective layers crucial for defense, structural integrity, and cellular interactions in the environment. Archaea often feature an S-layer, with some species possessing additional and remarkably resistant sheaths. The archaeal sheath has been studied in Methanothrix and Methanospirillum, revealing a complex structure consisting of amyloid proteins organized into rings. Here, we conducted a comprehensive survey of sheath-forming proteins (SH proteins) across archaeal genomes. Structural modeling reveals a rich diversity of SH proteins, indicating the presence of a sheath in members of the TACK superphylum (Thermoprotei), as well as in the methanotrophic ANME-1. SH proteins are present in up to 40 copies per genome and display diverse domain arrangements suggesting multifunctional roles within the sheath, and potential involvement in cell-cell interaction with syntrophic partners. We uncover a complex evolutionary dynamic, indicating active exchange of SH proteins in archaeal communities. We find that viruses infecting sheathed archaea encode a diversity of SH-like proteins and we use them as markers to identify 580 vOTUs potentially associated with sheathed archaea. Structural modeling suggests that viral SH proteins can form complexes with the host SH proteins. We propose a previously unreported egress strategy where the expression of viral SH-like proteins may disrupt the integrity of the host sheath and facilitate viral exit during lysis. Together, our results significantly expand knowledge of the diversity and evolution of the archaeal sheath, which has been largely understudied but might have an important role in shaping microbial communities.

Origin of Persisting Photoresponse of One-Year Aged Two-Dimensional Lead Halide Perovskites Stored in Air under Dark Conditions.

Two-dimensional halide perovskites are promising for advanced photonic, optoelectronic, and photovoltaic applications. However, their long-term stability is still a critical factor limiting their implementation into further commercial applications. Here, we present an environmental stability analysis of BA2(MA)n-1PbnI3n+1 (BA = C4H12N+, MA = CH6N+) two-dimensional perovskites with the lowest quantum well thicknesses of n = 1 and n = 2, after 1 year of aging under ambient humidity, oxygen content, and light conditions. We observed that both crystal phases (n = 1 and 2) degraded similarly, resulting in the removal of organic components and crystal decomposition into PbI2, Pb oxides, and Pb hydroxides. However, we have found a significant difference between their aging under ambient light and dark conditions, affecting their degraded morphology and photoactivity. Both crystal phases exposed to ambient light aged into a morphology characterized by the formation of several pinholes and voids, accompanied by photoluminescence degradation. Samples stored under dark conditions surprisingly preserved their photoluminescence activity, which morphologically aged into microrod structures. We conclude that the observed loss of photoactivity of 2D perovskites aged under ambient light is attributed to photoaccelerated degradation processes causing faster crystal surface photo-oxidation accompanied by a creation of multiple I vacancies and hydration of the inner crystal. The retainment of photoactivity in 2D perovskites aged under dark conditions is attributed to slower surface oxidation processes into Pb salts, as confirmed by X-ray photoemission spectroscopy. The formed surface layer even allows for a layer-by-layer degradation and acts as a protection barrier against further additional loss of I atoms and the consequent hydration of the inner part of samples. We demonstrate that light is the most critical external factor accelerating 2D perovskite degradation processes in ambient air and thus affecting their long-term stability. We conclude in this work that perovskite material structural engineering together with their surface passivation or encapsulation strategical techniques applied is an essential step for their further application into long-term stable commercial devices.

Direct graphene growth on low-alloy and mild steel surfaces controlled by carbon solubility and surface microstructural transformations during chemical vapor deposition

This study demonstrates for the first time, graphene grown directly on the iron-rich surfaces of bulk 8620 low-alloy and 1018 mild steel by chemical vapor deposition, a key step toward developing thin graphene coatings with strong graphene-steel bonding. Low growth temperatures of 660 °C–680 °C, were used to manipulate the steel's carbon solubility, confining carbon diffusion and microstructural transformations to the surface regions, with the bulk relatively unchanged. For 1018, a growth temperature of 680 °C resulted in a multilayer graphene coating with 80 % coverage. The alloying elements in 8620 improved graphene formation by influencing the surface microstructure transformations at these growth temperatures, with graphene coverage up to 95 %. The surface microstructure for 8620 affected graphene formation, seen in growths at 660 °C where a few-layer graphene coating formed from a cementite surface layer, and for growths at 680 °C where multi-layer graphene covered a pearlite dominant surface microstructure. Contact angle measurements confirmed the hydrophobicity of the graphene coating and electrochemical testing by potentiodynamic polarization and electrochemical impedance spectroscopy confirmed the 101 mV improvement to corrosion potential and an increase in impedance up to 18.23 kΩ. These detailed results regarding the direct growth of graphene as a coating layer on highly oxidation-sensitive steel surfaces suggest that this process is achievable through manipulating carbon solubility at the steel's surface by controlling temperature, alloy composition and surface microstructure transformations. These methods could be leveraged in developing protective graphene coatings for various iron-based alloys.

Field Performance of Asphalt Mixture Modified with Reactive Isocyanate Based Modifier

The reactive isocyanate-based modifier chemically reacts with asphalt components, overcoming the issues of increased viscosity and phase separation encountered with conventional modified binders. It can be used to modify binders to meet the highest performance grades currently specified by state highway agencies. This project aimed to demonstrate the constructability of an asphalt mixture modified with the reactive isocyanate-based modifier in the field and compare its performance with that of a control mixture. The project involved milling an approximately 5.0-cm (2-in) thick surface layer of two 30.5-m (100-foot) sections with similar foundation support. One section was resurfaced with a reactive isocyanate-modified mixture and the other with a conventional SBS-modified mix. The mixtures have shown no significant difference in field performance and laboratory performance test results. This study has provided insights into the field applicability of reactive isocyanate-based modifiers in asphalt mixtures, facilitating the ongoing efforts to develop durable road surfaces.

Study on the nano-cutting mechanism of monocrystalline silicon material with an amorphous layer by molecular dynamics simulations

Monocrystalline silicon is prone to brittle fracture during the nano-cutting process. Surface modification through ion implantation to create an amorphous layer on monocrystalline silicon significantly enhances its processability. This paper conducted molecular dynamics simulations to deeply reveal the nanometric cutting mechanism for monocrystalline silicon with an amorphous layer. The influence of the amorphous layer on material removal, subsurface damage, cutting forces, stress distribution, and temperature profiles was analyzed and thoroughly discussed. The calculating results reveal that primary material removal mode transitions from shearing to extrusion under the influence of the amorphous layer. The presence of an amorphous layer can efficiently reduce stress concentration and defects in the nanometric machining process. When the thickness of the amorphous layer equals the cutting depth of the tool, subsurface damage is reduced to approximately 2 nm, indicating that an optimal surface quality is achieved. When the thickness of the amorphous layer reaches more than cutting depth, the hydrostatic stress of the monocrystalline silicon part is significantly lower than the phase transition threshold of 12 GPa, which greatly reduces the occurrence of phase transition. Furthermore, the formation and evolution of shear bands are the primary reasons for the fluctuations in cutting force. The cutting temperature is closely related to structural transformations. The heat generated by shear slip in monocrystalline silicon material is higher than the heat generated by plastic deformation of material in the amorphous layer. Moreover, the heat energy produced by plastic deformation of amorphous layer atoms exceeds that generated by structural transformation of monocrystalline silicon atoms. This work reveals the nanometric cutting behavior of the monocrystalline silicon material with amorphous layer surfaces based on phase transformation. It can provide effective references for the preparation of amorphous layer thickness and selection of cutting parameters in nanometric cutting process of the monocrystalline silicon with amorphous layer surfaces.

Mechanical Properties Optimization and Microstructure Analysis of Pure Copper Heterostructured Laminates via Rolling

Heterogeneous metallic structures constitute a novel class of materials with excellent mechanical properties. However, the existing process for obtaining heterostructures from a single material does not meet large-scale industrial requirements. In this study, a pure copper heterostructured laminate (HSL) composed of a surface elongated-grain layer and a central equiaxed-grain layer was fabricated by rolling bonding and annealing. To study the effect of the interface on the mechanical properties of gradient-structured materials, both laminate metal composite (LMC) and non-composite laminate (NCL) were fabricated by cold-rolling pretreatment of the center layer (60% reduction) and cold-rolling bonding of the whole blank (67% reduction). Then, the HSL was obtained by controlling the post-annealing regimes, the microstructure of each layer was optimized, and a larger degree of microstructural heterogeneities, such as grain size, misorientation angle, and grain orientation, was obtained, which resulted in obvious mechanical differences. Tensile tests of the HSL, surface layer, center layer, and NCL specimens revealed that the HSL annealed at 300 °C for 1 h had a significantly higher strength than the center layer and a higher elongation than the surface layer. The HSL had a tensile strength and elongation at fracture of 278.08 MPa and 46.2%, respectively, indicating a good balance of strength and plasticity. The improved properties were primarily attributed to the strengthening or strain hardening due to the inhomogeneous deformation of the heterogeneous layers in the laminate and the mutual constraint acquired by the distinct layers with strong mechanical differences. The HSL had an interfacial bonding strength of 178.5 MPa, which played a vital role in the coordinated deformation of the heterogeneous layers. This study proposes an HSL design method that effectively simplifies the process of obtaining heterostructures in homogeneous materials by controlling the cumulative deformation of the surface and center layers.

Taxon-specific contributions of microeukaryotes to biological carbon pump in the Oyashio region

Abstract Microeukaryotes are critical components of sinking particles contributing to carbon export from the surface to deep oceans. However, the knowledge of the sinking microeukaryotic communities and their dynamics is currently limited. In this study, we applied 18S rRNA gene metabarcoding to investigate the microeukaryotic communities in sinking and suspended particles distinguished by marine snow catchers (MSC) during spring in the Oyashio region. Sinking particles displayed distinct communities and lower diversity than suspended particles. The community compositions of the sinking particles varied with depth, suggesting that microeukaryotes were selectively disaggregated or decomposed during settling. Prymnesiophyceae and diatoms were effectively removed, as indicated by their decreased abundance in sinking particles at increasing depths. Conversely, Dinophyceae maintained a higher abundance in sinking particles across depths, indicating resistance to disaggregation and decomposition. Spirotrichea and heterotrophic Dinophyceae were enriched in sinking particles, while marine stramenopiles (MAST) groups were enriched in suspended particles. The heterotrophs in the deeper layers were mainly transported from the surface layers by increasing their relative abundance towards deep layers, indicating that they contributed to the transformation processes of sinking particles. Overall, our results demonstrate the functional differences among microeukaryotes in the biological carbon pump.

What intrinsic factors affect the central corneal thickness?

The cornea is one of the tissues responsible for covering and protecting the inner structures of the eye. Central corneal thickness (CCT) is defined as the distance between the anterior epithelial surface and the posterior surface of the endothelial layer. This parameter plays a very important role regarding intraocular pressure (IOP) measurement, evaluation of corneal uniformity, selection of a suitable technique for corneal refractive surgery and the planning of surgical procedures to overcome corneal disease. This comprehensive review elucidates the multifaceted factors influencing the central corneal thickness. Recognising the impact of these factors not only enhances our understanding of corneal dynamics but also contributes significantly to the refinement of diagnostic and therapeutic strategies in ophthalmology.

Hydrodynamic simulation of coastal reservoir in response to flow control: a numerical study of the Saemangeum reservoir

Coastal reservoirs (CRs) are important water resources worldwide, but environmental problems can arise due to limited material mixing caused by the blocked propagation of tidal waves. The Saemangeum Reservoir is a large brackish reservoir in South Korea; owing to its complex fluctuation characteristics, accurate reproduction of its three-dimensional (3D) circulation and material distribution characteristics remains a challenge. Here, we aimed to improve the reproducibility of the Delft3D model through long-term precision monitoring and analyze problems occurring in CRs. The model reproduced the hydraulic flow and stratification phenomena in CRs. The Richardson number ( R i ) was higher than 100, and the Stratification Index ( SI ) was higher than 1 due to the density difference between the surface and bottom layers. The stratification strength of the Saemangeum Reservoir was, therefore, considered high. Moreover, a two-layer circulation occurred due to the strength of the eddy and the horizontal gradient of salinity. When the sluice gate was expanded, the area and number of days where hypoxia occurred decreased. It would also mitigate the retention of materials caused by the eddy and improve circulation. The findings of this study can be used as foundational data for solving and managing hydraulic problems within CRs.

On the engineering of higher-order Van Hove singularities in two dimensions

The properties of correlated electron materials are often intricately linked to Van Hove singularities (VHS) in the vicinity of the Fermi energy. The class of these VHS is of great importance, with higher-order ones—with power-law divergence in the density of states—leaving frequently distinct signatures in physical properties. We use a new theoretical method to detect and analyse higher-order VHS (HOVHS) in two-dimensional materials and apply it to the electronic structure of the surface layer of Sr2RuO4. We then constrain a low energy model of the VHS of the surface layer of Sr2RuO4 against angle-resolved photoemission spectroscopy and quasiparticle interference data to analyse the VHS near the Fermi level. We show how these VHS can be engineered into HOVHS.

Layer symmetry and irradiation dominate the oxidation capability of birnessite on biogenic isoprene

The climate-active gas isoprene (C5H8) is one of the most abundant biogenic volatile organic compounds (VOCs). Soil is one of the significant sinks for isoprene, yet the role played by the naturally abundant birnessite in the soil surface layer during the oxidation of isoprene remains largely unknown. This study investigates the reactions of isoprene with triclinic and hexagonal birnessite on the Earth's surface environments. Hexagonal birnessite exhibits a superior oxidation capacity than triclinic birnessite, rapidly oxidizing isoprene. The transformation of birnessite from triclinic to hexagonal increases the number of interlayer Mn(III) octahedra, which creates numerous sites for isoprene oxidation. In-situ DRIFTS and DFT calculations indicate that abundant electrophilic active species on the surface of hexagonal birnessite, such as interlayer Mn(III) octahedra and 1O2, oxidize isoprene by attacking conjugated double bonds. Furthermore, birnessite exhibits excellent photoelectric response and photothermal effects, enabling sunlight irradiation under natural conditions to accelerate the oxidation of isoprene by birnessite. The findings of this study elucidates the critical role of birnessite in the oxidation of isoprene and shed light on the fate of isoprene in soil minerals.

Manufacturing the current flow diverter architecture in REBCO tapes using silver inkjet printing

Abstract A low normal zone propagation velocity (NZPV) combined with critical current inhomogeneities favor the nucleation of destructive hot spots in rare-earth barium copper oxide (REBCO) tapes. Increasing the NZPV using the current flow diverter (CFD) concept is a promising solution to mitigate the risk of developing hot spots. The fabrication method of CFD REBCO tapes implies several steps consisting in masking, silver etching, mask removal, and silver deposition, which takes time and remains a barrier to the implementation of a low-cost industrial production of long-length CFD REBCO tapes. This work presents a cost-effective and maskless CFD fabrication approach that relies on inkjet printing (IJP) of silver patterns directly on top of the REBCO layer to create a non-uniform interfacial resistance between the silver and the REBCO surface, along the width of the tape. The parameters of IJP and oxygen annealing were optimized to obtain highly conductive silver patterns deposited on the surface of the REBCO layer. CFD REBCO tapes were successfully fabricated using commercial REBCO tapes and the proposed method without degrading the superconducting properties. Experimental measurements revealed an increase of the NZPV by a factor of 6-7 compared to commercial REBCO tapes.

Space exposure test of hardwood specimens in the International Space Station

To design a wooden satellite and select the appropriate wood species, we conducted a space exposure test of wood on the International Space Station (ISS). The space exposure test used the Japanese Experiment Module “Kibo” on the Exposed Experiment Bracket Attached on i-SEEP (ExBAS), which is connected to the exposed facility of the ISS. Three wood species considered candidates for the structure of a wooden satellite were used in the exposure test: honoki (Magnolia obovata), yamazakura (Cerasus jamasakura), and dakekanba (Betula ermanii). In the outgassing test conducted in preparation for the space exposure test, the collected volatile condensable materials (CVCM) of the three wood species were below the critical value; however, the total mass loss (TML) exceeded the critical value. However, this was not a problem, because most of the mass loss was due to water evaporation. A space exposure test was conducted for 10 months in 2022. Consequently, no change was observed in the weight of the exposed specimen, and no erosion due to atomic oxygen (AO) was observed. The exposure test was scheduled to be carried out in the forward direction of the ISS travel; however, owing to equipment trouble, it was installed in the opposite direction. This is because an insufficient AO flux collided with the specimen. In terms of wood color, the brightness of the three species decreased owing to space exposure, and saturation increased in two wood species, except for yamazakura. A thin-film layer was observed on the surface of the aluminum cover to which the exposed specimen was fixed, which may have also formed on the surface of the wood specimen, reducing its brightness. However, because the hue angle did not change significantly, only a slight deterioration of the surface layer owing to vacuum ultraviolet was observed. The results confirmed that the wood had hardly deteriorated in space for approximately 10 months.

Enhanced strength-ductility synergy in a gradient hetero-structured CrCoNi medium-entropy alloy

A CrCoNi medium-entropy alloy (MEA) with gradient hetero-structure (GHS) composing of gradient nanostructured surface layer and hetero-structured matrix was prepared via a two-step process: pre-cold rolling (CR) deformation and subsequent annealing followed by surface mechanical grinding treatment (SMGT) and secondary annealing. The GHS CrCoNi exhibits an excellent synergy of strength and ductility, as evidenced by a yield strength of approximately 1.2 GPa and a uniform elongation of about 20%. The GHS displays a pronounced hetero-deformation induced (HDI) hardening effect, whereby the central layer (CL) and surface layer (SL) undergo local strain hardening in a mutually compatible manner. This process facilitates the multiplication and accumulation of geometrically necessary dislocations (GNDs) at intra- and inter-layer hetero-interfaces and also activates the deformation faulting and twinning in both CL and SL, thus enhancing the overall mechanical response. The interlayer compatible deformation observed in the GHS significantly bolsters the sustainability of strain hardening at the microscopic scale. This effect is of significant importance in redistributing stress and strain more rationally across the entire GHS sample, effectively reducing the risk of localized deformation failures. This study offers insight into the correlation between macroscopic strain hardening and micromechanical behavior in gradient-/hetero-structured materials.

Fatigue-induced fracture failure of acrylic-polycarbonate laminated aircraft canopy

The fatigue-induced fracture failure of the aircraft canopy occurred in the poly(methyl methacrylate) (PMMA) layer laminated on polycarbonate (PC) during flight. For more than 24 years, the aircraft had been operated at high altitudes and supersonic flight. To identify the root cause and the mechanism for the formation of the fracture, the fracture surfaces were investigated. The fracture morphologies were characterized using optical microscope (OM) and scanning electron microscope (SEM).In macroscopic observations, the main crack showed a total length of approximately 1.6 m from the front to the right of the crack stop groove when viewed from the front of the canopy. The main crack ran about 0.9 m including partly curved line from the front part to the upper middle one and then reached about 0.7 m in a straight line perpendicular to the right of the crack stop groove. There were two crack ends in the main crack: one was at the lower part of the front, the other was at the right end of the crack stop groove. Numerous macro-cracks visible to the naked eye were distributed only on the front surface of the canopy.In microscopic examination, the voids on the front surface of the outer PMMA layer were formed by the friction heat with air during the supersonic flight. The voids served as the origins, the actual starting point of the crack. The voids slowly grew to macro-cracks vertically or horizontally by the thermal stress during flying at high altitudes. Cracks proceeded in the direction of 90 degrees while being bisected in V-shapes downward from the surface of the PMMA layer with the action of thermal tension. The crack growth represents the typical characteristics of the fatigue crack: multi-origins, ratchet marks, and beach marks. The main crack grew further, forming a slight curved line by connecting adjacent macro-cracks arranged in an almost vertical direction. When crack growth reached a critical point, the catastrophic fracture progressed rapidly from the primary origin of the fatigue crack to both ends due to the action of lateral force. Fast crack zones on both sides showed the same dimple and river patterns.This study explains that the combined and synergistic interaction of the fatigue crack and environmental stresses iteratively occurred on the front surface in the outer PMMA layer of the aircraft canopy due to the continual exposure to high altitudes and supersonic flights, consequently resulting in the fatigue-induced fracture failure.

Atributos microbiológicos em Latossolo Vermelho cultivado com cana-de-açúcar na região de cerrado do Brasil Central

ABSTRACT The contribution of plant residues throughout the sugarcane cycles favors the increase of organic matter and the activity of microorganisms in the soil, especially in the surface layers. Soil texture also has an important effect on ecological processes and soil quality. In this context, the objective of this study was to evaluate soil biological attributes in different sugarcane cultivation cycles under mechanized harvesting in an Oxisol in the Savanna region of Central Brazil. The study was conducted in commercial areas under sugarcane cultivation during the 2018/2019 season, which were considered homogeneous in terms of soil and climatic conditions, with the source of variation among the areas being the cultivation cycles (C1: one cultivation cycle; C3: three cultivation cycles; C7: seven cultivation cycles) and a savanna vegetation area selected as a reference. Microbiological variables were determined in two layers, 0-0.1 and 0.1-0.2 m. The variables related to microbial biomass and texture were subjected to principal component analysis. Areas with longer sugarcane cultivation cycles show higher proportion of microbial biomass carbon in the total organic carbon in subsurface layers (microbial quotient). The performance of the soil microbial community, as expressed by total organic carbon and microbial biomass nitrogen indicators, was associated with higher presence of clay and silt, i.e., soil particles smaller than 0.02 mm.

Surface iron concentration gradient: A strategy to suppress Mn3+ Jahn-Teller effect in lithium manganese iron phosphate

To address the low energy density of LiFePO4 (LFP) for electric vehicles and high-voltage energy storage, LiMn0.5Fe0.5PO4 (LMFP) provides a potential solution but faces performance degradation due to Mn3+-induced Jahn-Teller distortion and Mn ion dissolution during cycling. This study proposes a surface engineering strategy to enhance LMFP’s electrochemical performance by increasing surface iron concentration and reducing manganese content, based on the electronic differences between Mn3+ and Fe3+ in MO6 octahedra. Density Functional Theory (DFT) calculations confirmed the viability of this approach by analyzing volume changes and binding energies with HF during charging. Guided by DFT, an LMFP@LFP/C material was synthesized with a high-iron-concentration surface layer (∼2 nm), as observed through AC-STEM. Post-cycling TEM analysis and corrosion simulations demonstrated that LMFP@LFP/C suppresses Mn ion dissolution and stabilizes the crystal lattice compared to unmodified LMFP/C. Electrochemical tests showed that LMFP@LFP/C has superior electronic conductivity and faster lithium-ion diffusion. It delivered an initial discharge capacity of 150.82 mAh g−1 at 0.1C, surpassing LMFP/C (147.65 mAh g−1). At 1C, LMFP@LFP/C retained 95.85 % of its capacity after 500 cycles, significantly outperforming LMFP/C (74.18 %). This surface modification strategy advances phosphate-based cathode materials for electric vehicles and renewable energy applications.

Space Environmental Effects on Multifunctional Radiation Shielding Materials

AbstractThe two primary material requirements for a crewed habitat or spacecraft to operate beyond low earth orbit (LEO) include effective radiation shielding against the space radiation and secondary neutron environment and sufficient structural and thermal integrity. In this context it is mandatory to study the effect of long duration space environment on any proposed multifunctional radiation shielding material. In this paper we discuss two radiation shielding composite architectures and their long duration performance in LEO. Samples were flown on NASA's The Materials International Space Station Experiment (MISSE) platform and their structural, optical, and radiation shielding capabilities were characterized pre and post flight. Results showed composite architecture can be key in determining expected damage irrespective of sample placement orientation on the space station. A surface layer with a protective or sacrificial coating can be instrumental in minimizing property degradation even when exposed to orientations with high estimated sun hours and high fluence of atomic oxygen.