Supra-subduction Zone Ophiolites Research Articles

Magnetic anisotropy of a sub-ophiolitic metamorphic sole (Mersin ophiolite, Turkey)

The Mersin ophiolite of southern Turkey is a well-exposed, Late Cretaceous, Neo-Tethyan supra-subduction zone ophiolite. It is underlain by metamorphic sole rocks inferred to have formed at the top of a down-going plate during subduction. These have a well-developed foliation and lineation observable in the field (defined by the preferred orientations of hornblende and plagioclase crystals). Here we present the first magnetic fabric data reported from the Mersin ophiolite with such settings. Anisotropy of low field magnetic susceptibility ellipsoids in sampled amphibolites have clustered, NW-plunging minimum principal axes representing poles to a SE-dipping magnetic foliation that aligns with the macroscopic metamorphic foliation plane seen in the field. Maximum AMS principal axes define a SE-plunging magnetic lineation that is parallel to the macroscopic metamorphic lineation. Oblate magnetic fabrics at specimen-level and an overall triaxial fabric at locality-level in these rocks are consistent with the development of the dominant metamorphic fabric by a combination of pure shear flattening and simple shearing during the formation and exhumation of the Mersin sole rocks. These observations are compatible with a recent tectonic model for the evolution of the ophiolite based on paleomagnetic data that invokes flattening and exhumation of the down-going slab in an incipient subduction zone during supra-subduction zone spreading.

Multistage petrogenetic evolution of Neoproterozoic serpentinized ultramafic rocks and podiform chromitites at Hagar Dungash, Eastern Desert of Egypt

Podiform chromitites are found in the mantle sections of ophiolites in many places and times in the geologic record. Leading theories for their origin invoke melt-rock reaction processes involving hydrous melts in supra-subduction zone settings. Here we develop a case study of a Neoproterozoic example and a quantitative thermodynamic model of the multistage process leading to nearly monomineralic chromitite pods. We demonstrate that the Hagar Dungash ophiolite of the Eastern Desert of Egypt — despite being dismembered, incomplete, and affected by variable degrees of alteration and metamorphism — is nevertheless plainly a supra-subduction zone ophiolite containing podiform chromitite deposits. Textural, mineralogical, and chemical evidence from the serpentinized ultramafic rocks point to mantle protoliths residual to high degrees of partial melt extraction, characteristic of fore-arc ophiolites. The chromitite pods are distinguished into massive and nodular types; Cr-spinel in the massive type is almost fresh, with intermediate to high Cr# (0.60–0.85) and extremely low Fe3+# (nil-0.04). Cr-chlorite with up to ∼ 15 wt% Cr2O3 is a common interstitial mineral in the chromitites. The observations are consistent with the conceptual multistage model wherein boninitic melt develops as the end-product of melt-harzburgite reaction in the shallow upper mantle. Mixing between this boninitic melt and ascending peridotite-derived basaltic melt drives the liquid deep into the Cr-spinel stability field and precipitates nearly monomineralic chromitite. Our thermodynamic model of this mixing and precipitation process reproduces the mineral chemistry trends of the fresh chromite samples and yields an estimate of the efficiency of chromite production relative to melt flux through the system, which can be applied to development of podiform chromitites in supra-subduction systems worldwide and across geologic eras.

Forearc lava stratigraphy of the Beila Ophiolite, north-central Tibetan Plateau: Magmatic response to initiation of subduction of the Bangong-Nujiang Meso-Tethys Ocean

It has been suggested that boninites and associated volcanic rocks found in supra-subduction zone (SSZ) ophiolites form in a forearc setting, meaning that these rocks could provide crucial constraints on understanding the magmatic response to subduction initiation. Here, we report newly documented forearc basalts (FAB) and boninites from the Beila Ophiolite of the Bangong–Nujiang Suture Zone, north-central Tibetan Plateau. The lava stratigraphy, from bottom to up, includes FAB, basaltic boninites, and boninites, similar to lavas from the Izu–Bonin–Mariana (IBM) forearc. The FAB has geochemical characteristics similar to those of IBM forearc basalts, with nearly flat REE patterns, and shows enrichment in Rb, Ba, Pb, and Sr and depletion in Nb, Ta, and Zr, suggesting an origin by decompression melting of a depleted mantle source with minor input of subducting plate materials. The basaltic boninites and boninites show similar petrological features, as well as porphyritic textures with phenocrysts of olivine, clinopyroxene, and minor orthopyroxene. The basaltic boninites and boninites display uniform major- and trace-element characteristics that are similar to those of typical boninites, with high MgO (>10.78 wt%), Cr, and Ni contents, extremely low TiO2 (<0.21 wt%), rare earth element (REE), and high-field-strength element (HFSE) contents, and U-shaped REE patterns. In addition, the basaltic boninites and boninites have lower ɛNd(t) values than those of the FAB and display variable degrees of influence by slab melts and fluids. Geochemical modeling further suggests that the boninites were generated later during residual highly depleted mantle fluxing by the subducting plate. Together with contemporary boninitic and arc-related magmas along the Bangong-Nujiang Suture Zone and adjacent terranes (the North Lhasa and South Qiangtang), it suggests that the whole Meso-Tethys Ocean was subducted since the Middle Jurassic. Moreover, the Beila lava stratigraphy with FAB overlain by boninite is similar to that found in the IBM forearc and in many ophiolites (e.g., Troodos, Oman, and Xigaze), and represents a continuous geochemical transition from MORB-like to boninitic affinities. This similarity suggests that initiation of subduction might be commonly involved in the formation of ophiolites.

Late Palaeozoic-Neogene sedimentary and tectonic development of the Tauride continent and adjacent Tethyan ocean basins in eastern Turkey: New data and integrated interpretation

The eastern Taurus exemplifies continental rifting, passive margin development, Late Cretaceous melange genesis and ophiolite emplacement. Following Triassic rifting, a carbonate platform developed near sea level in the south (Munzur unit), whereas its northern extension (Neritic-pelagic unit) subsided into deep water during Late Jurassic-Late Cretaceous. Triassic-Cretaceous deep-water sediments and volcanics restore as distal deep-water slope/base of slope units. Jurassic-Cretaceous basic volcanics, interbedded with pelagic sediments, represent emplaced oceanic seamounts. Supra-subduction zone ophiolites formed to the north (c. 93 Ma), probably within an Inner Tauride ocean, and were emplaced southwards by trench-margin collision during latest Cretaceous (c. 75–66 Ma). The margin underwent flexural uplift/erosion and then subsidence/foredeep-infill. Part of the Tauride continent in the south (Malatya Metamorphics) deeply underthrust/subducted northwards, then exhumed rapidly by the late Maastrichtian (c. 65 Ma). To the south, oceanic lithosphere (e.g. Göksun ophiolite) was thrust northward beneath Tauride (Malatya) crust from a more southerly oceanic basin (Berit ocean), and intruded by Late Cretaceous subduction-related granitic rocks (88–82 Ma). Allochthonous units were assembled during the latest Cretaceous, followed by thick-skinned folding/thrusting, generally southwards, related to regional collision tectonics during Mid-Late Eocene. Part of the unmetamorphosed Tauride platform and its over-riding Late Cretaceous allochthon were apparently displaced >60 km northeastwards. Mid-Late Miocene regional collision drove variable folding and re-thrusting, in places northwards. Regional comparisons suggest that the Tauride carbonate platform (Geyik Dağ) narrowed eastwards, such that the palaeogeography of the E Taurides differed from farther west, influencing the late Mesozoic-Cenozoic structural development.

Forced subduction initiation within the Neotethys: An example from the mid-Cretaceous Wuntho-Popa arc in Myanmar

Abstract Despite decades of research, the mechanisms and processes of subduction initiation remain obscure, including the tectonic settings where subduction initiation begins and how magmatism responds. The Cretaceous Mawgyi Volcanics represent the earliest volcanic succession in the Wuntho-Popa arc of western Myanmar. This volcanic unit consists of an exceptionally diverse range of contemporaneously magmatic compositions which are spatially juxtaposed. Our new geochemical data show that the Mawgyi Volcanics comprise massive mid-oceanic ridge basalt (MORB)-like lavas and dikes, and subordinate island arc tholeiite and calc-alkaline lavas. The Mawgyi MORB-like rocks exhibit flat rare earth elements (REEs) patterns and are depleted in REEs, high field strength elements (except for Th) and TiO2 concentrations relative to those of MORBs, resembling the Izu-Bonin-Mariana protoarc basalts. Our geochronological results indicate that the Mawgyi Volcanics formed between 105 and 93 Ma, coincident with formation of many Neotethyan supra-subduction zone ophiolites and intraoceanic arcs along orogenic strike in the eastern Mediterranean, Middle East, Pakistan, and Southeast Asia. Combined with its near-equatorial paleo-latitudes constrained by previous paleomagnetic data, the Wuntho-Popa arc is interpreted as a segment of the north-dipping trans-Neotethyan subduction system during the mid-Cretaceous. Importantly, our restoration with available data provides new evidence supporting the hypothesis of a mid-Cretaceous initiation of this &amp;gt;8000-km-long subduction system formed by inversion of the ∼E-W–trending Neotethyan oceanic spreading ridges, and that this was contemporaneous with the final breakup of Gondwana and an abrupt global plate reorganization.

Petrogenesis of arc-related peridotite hosted chromitite deposits in Sikhoran-Soghan mantle section, South Iran: Evidence for proto-forearc spreading to boninitic stages

The Soghan-Sikhoran ophiolite in southeast Iran (Outer Zagros Ophiolite Belt) is a remnant of a series of Upper Triassic–Cretaceous supra-subduction zone (SSZ) ophiolites that formed along the Zagros suture zone, which is considered as the southern border of the Neo-Tethyan sea. These SSZ ophiolites are older than the Late Cretaceous Zagros ophiolites. The main part of the Soghan-Sikhoran ophiolite comprises layered ultramafic cumulates including dunites, wehrlites, and pyroxenites, and a tectonized mantle section including residual lherzolites, and depleted harzburgites with foliated/discordant dunite lenses. Podiform chromitites are common and are typically surrounded by thin dunitic haloes. Spinels in lherzolite–harzburgite are geochemically characterized by a low Cr# (42.0 to 52.6), and plot in an abyssal peridotite field on geochemical discrimination diagrams, whereas spinel in dunites and high-Cr chromitite spinels (Cr# = 52.4 to 76.4) show geochemical affinities to boninites. Lherzolites and harzburgites have low REE contents and experienced >17 vol% partial melting. The Soghan-Sikhoran ophiolite contains both high Cr# and low Cr# podiform chromitite types. Trace and REE element patterns of Soghan-Sikhoran rocks are similar to those in SSZ peridotites. The studied ophiolites show relatively moderate to high oxygen fugacities (ƒO2), with log units ranging from −0.4 to +0.4 for harzburgites, +0.2 for lherzolites, from − 0.7 to + 2.5 for pyroxenites, from +0.8 to +2.2 for dunites, and from + 0.6 to + 0.8 for chromitites. The moderate to high oxidation state of the studied upper-mantle ophiolitic complexes also suggests a boninitic source in the mantle wedge of the arc setting. The two-pyroxene thermometer yields mean equilibrium temperatures of 879 °C, 895 °C, 912 °C and 912 °C for harzburgites, lherzolites, dunites and pyroxenites, respectively. We therefore interpret that the spinels in the lherzolite-harzburgite crystallized from tholeiitic melt generated due to proto-forearc spreading and formation of the infant arc, whereas high-Cr# spinel in dunites and high-Cr# chromitite crystallized from boninitic melts during the mature arc stage, with an increasing contribution of slab-derived fluids at high ƒO2.

Petrological and geochemical characteristics of the diabase and metasomatised dikes from the Tekirova ophiolite (SW Anatolia, Turkey): Tectonomagmatic evolution of the southern Neotethys

Ophiolites are widespread across the Anatolian plate and formed during the termination of different branches of the Neotethys ocean. The Tekirova ophiolite, situated in the Antalya ophiolite nappes in Southwest Anatolia, originated in the southern branch of the Neotethys. The former ophiolite consists of mantle and crustal sequences, in which, it is predominantly crosscut by the isolated diabasic dikes. Here, we have distinguished two dike types on the basis of their petrographic features and also degree of alteration. The relatively fresh types are generally named as diabase dikes. While the altered types are called as metasomatised dikes, and these dikes display ophitic to subophitic textures. The diabase and metasomatised dikes show enrichment in LILEs and depletion in HFSEs, indicating characteristics of suprasubduction zone ophiolites. This depletion of mobile elements may have been caused by metasomatism. The HFSEs versus HREEs diagrams show that the dikes were formed from 10 to 30% melting of extracted melts from previous mantle melting in which modified by subduction-derived fluids.

Subduction initiation of the western Proto-Tethys Ocean: New evidence from the Cambrian intra-oceanic forearc ophiolitic mélange in the western Kunlun Orogen, NW Tibetan Plateau

Abstract The supra-subduction zone ophiolite or ophiolitic mélange formed in the forearc setting is generally considered to be a key geological record for subduction initiation (SI) with petrological characteristics comparable to the SI-related rock sequence from forearc basalt (FAB) to boninite in the Izu-Bonin-Mariana subduction zone. Nevertheless, the standard FAB and boninite are generally difficult to observe in the forearc rocks generated during SI. Yet, a typical rock sequence indicating the SI of the western Proto-Tethys Ocean is reported for the first time in the Qimanyute intra-oceanic forearc system in the western Kunlun Orogen, Northwest Tibetan Plateau. The magmatic compositions, which range from less to more high field strength element (HFSE)-depleted and large ion lithophile element (LILE)-enriched, are changing from oceanic plagiogranites (ca. 494 Ma) to forearc basalt-like gabbros (FAB-Gs, ca. 487 Ma), boninites, and subsequent Nb-enriched gabbros (NEGs, ca. 485 Ma), which are thus consistent with the Izu-Bonin-Mariana forearc rocks as well as the Troodos and Semail supra-subduction zone-type ophiolites. The geochemical data from the chemostratigraphic succession indicate a subduction initiation process from a depleted mid-oceanic-ridge (MORB)-type mantle source with no detectable subduction input to gradual increasing involvement of subduction-derived materials (fluid/melts and sediments). The new petrological, geochemical, and geochronological data, combined with the regional geology, indicate that the well-sustained FAB-like intrusive magmas with associated boninites could provide crucial evidence for SI and further reveal that the SI of the western Proto-Tethys Ocean occurred in the Late Cambrian (494–485 Ma).

Early Cretaceous radiolarians and chert geochemistry from western Yarlung Tsangpo suture zone in Jiangyema section, Purang county, SW Tibet

Moderately to well-preserved radiolarian faunas belonging to 51 genera and 81 species have been identified in a continuous bedded chert succession in the Jiangyema section in the west segment of the Yarlung Tsangpo suture zone (YTSZ), Purang county, SW Tibet. Based on the occurrence of some characteristic species, especially the evolutionary appearance of age-diagnostic species two radiolarian zones and two subzones are recognized and respectively named as the Cecrops septemporatus zone, Aurisaturnalis carinatus zone, Aurisaturnalis carinatus carinatus subzone and Aurisaturnalis carinatus perforatus subzone. These can be correlated with coeval Hauterivian to upper Barremian radiolarian biozones in both the western Tethys and Japan. They provide a better biostratigraphical framework and reliable age constraints for parts of the Neotethyan Ocean floor that were subducted beneath supra-subduction zone (SSZ) ophiolites in the western part of the YTSZ.Geochemical data indicate that SiO2 contents of bedded cherts range from 79.84 to 94.65% with an average of 89.39%. Comparison of geochemical characteristics on discriminant graphs suggests that the bedded cherts were deposited in a deep oceanic basin near a continental margin. Our results and integration of available radiolarian studies from bedded cherts along the YTSZ suggest that the Neo-Tethys was a deep ocean between the Indian and Eurasian continents in which pelagic sedimentation was on-going until at least the late Barremian.

Mafic rocks with back-arc E-MORB affinity from the Chotanagpur Granite Gneiss Complex of India: relicts of a Proterozoic Ophiolite suite

AbstractThe Proterozoic Chotanagpur Granite Gneiss Complex (CGGC) at the northern boundary of the Central Indian Tectonic Zone (CITZ) of the eastern Indian shield preserves relics of fossilized oceanic back-arc crust. We describe the field, petrographical and geochemical characteristics of the mafic rocks comprising pillow basalts and dolerites from the Bathani area of the northern fringe of the CGGC, eastern India. The basalts consist of plagioclase feldspar, hornblende, opaque minerals (Fe–Ti oxide) and chlorite, and the dolerite consists of plagioclase, hornblende and opaque minerals. Our data indicate that the Bathani mafic rocks have tholeiitic to transitional composition and are overprinted by greenschist facies metamorphic conditions; however, REE and fluid immobile elements preserve their primary geochemical signatures. The (La/Sm)N ratios (1.38–2.15) and chondrite-normalized REE patterns point to an enriched mid-ocean ridge basalt (E-MORB) mantle source. Geochemical characteristics indicate a mixed signature of MORB and arc tholeiite with enrichment of Ba, Th, Eu and Sr, similar to that of back-arc supra-subduction zone ophiolites. These mafic rocks are the product of MORB-like magma derived from a depleted mantle corresponding to &lt; 2% partial melting of spinel lherzolite, enriched by subduction-induced slab metasomatism and melting. The Bathani mafic rocks are representative of the upper part of a supra-subduction zone columnar ophiolite section, which was emplaced onto the present-day northern margin of the CGGC during suturing of the northern and southern Indian block at c. 1.9 Ga during the Nuna amalgamation.

Forearc magmatic evolution during subduction initiation: Insights from an Early Cretaceous Tibetan ophiolite and comparison with the Izu-Bonin-Mariana forearc

Abstract Subduction initiation is a key process in the operation of plate tectonics. Our understanding of melting processes and magmatic evolution during subduction initiation has largely been developed from studies of the Izu-Bonin-Mariana forearc. Many suprasubduction zone ophiolites are analogous to the Izu-Bonin-Mariana forearc sequence. However, whether there are differences between Izu-Bonin-Mariana subduction initiation sequences and suprasubduction zone ophiolites remains unclear. Here, we report field geological, geochemical, and geochronological data from mafic and felsic rocks in the Xigaze ophiolite (southern Tibet) mantle and crustal section; the same types of published data from both this ophiolite and the Izu-Bonin-Mariana forearc are compiled for comparison. The ophiolite section is intruded by various late-stage dikes, including gabbroic pegmatite, diabase, basalt, and plagiogranite. The compositions of clinopyroxene and amphibole suggest that gabbroic pegmatite formed from hydrous high-SiO2 depleted melts, while whole-rock compositions of basaltic and diabase dikes show negative Nb and Ta anomalies, suggesting flux melting of depleted mantle. Along with the mafic rocks, plagiogranite has a roughly constant content of La and Yb with increasing SiO2 contents, implying hydrous melting of mafic amphibolite. Early-stage pillow basalts exhibit geochemical affinities with Izu-Bonin-Mariana forearc basalts, but they are slightly enriched. Synthesized with the regional geological setting and compared with Izu-Bonin-Mariana forearc magmatism, we propose that the transition from mid-ocean ridge basalt–like lavas to subduction-related mafic and felsic dikes records an Early Cretaceous subduction initiation event on the southern flank of the Lhasa terrane. However, the mantle sources and the magmatic evolution in the Xigaze ophiolite are more variable than those for the Izu-Bonin-Mariana forearc.

Precambrian tectonic evolution of Earth: an outline

Abstract Space probes in our solar system have examined all bodies larger than about 400 km in diameter and shown that Earth is the only silicate planet with extant plate tectonics sensu stricto. Venus and Earth are about the same size at 12 000 km diameter, and close in density at 5 200 and 5 500 kg.m-3 respectively. Venus and Mars are stagnant lid planets; Mars may have had plate tectonics and Venus may have had alternating ca. 0.5 Ga periods of stagnant lid punctuated by short periods of plate turnover. In this paper, we contend that Earth has seen five, distinct, tectonic periods characterized by mainly different rock associations and patterns with rapid transitions between them; the Hadean to ca. 4.0 Ga, the Eo- and Palaeoarchaean to ca. 3.1 Ga, the Neoarchaean to ca. 2.5 Ga, the Proterozoic to ca. 0.8 Ga, and the Neoproterozoic and Phanerozoic. Plate tectonics sensu stricto, as we know it for present-day Earth, was operating during the Neoproterozoic and Phanerozoic, as witnessed by features such as obducted supra-subduction zone ophiolites, blueschists, jadeite, ruby, continental thin sediment sheets, continental shelf, edge, and rise assemblages, collisional sutures, and long strike-slip faults with large displacements. From rock associations and structures, nothing resembling plate tectonics operated prior to ca. 2.5 Ga. Archaean geology is almost wholly dissimilar from Proterozoic-Phanerozoic geology. Most of the Proterozoic operated in a plate tectonic milieu but, during the Archaean, Earth behaved in a non-plate tectonic way and was probably characterised by a stagnant lid with heat-loss by pluming and volcanism, together with diapiric inversion of tonalite-trondjemite-granodiorite (TTG) basement diapirs through sinking keels of greenstone supracrustals, and very minor mobilism. The Palaeoarchaean differed from the Neoarchaean in having a more blobby appearance whereas a crude linearity is typical of the Neoarchaean. The Hadean was probably a dry stagnant lid Earth with the bulk of its water delivered during the late heavy bombardment, when that thin mafic lithosphere was fragmented to sink into the asthenosphere and generate the copious TTG Ancient Grey Gneisses (AGG). During the Archaean, a stagnant unsegmented, lithospheric lid characterised Earth, although a case can be made for some form of mobilism with “block jostling”, rifting, compression and strike-slip faulting on a small scale. We conclude, following Burke and Dewey (1973), that there is no evidence for subduction on a global scale before about 2.5 Ga, although there is geochemical evidence for some form of local recycling of crustal material into the mantle during that period. After 2.5 Ga, linear/curvilinear deformation belts were developed, which “weld” cratons together and palaeomagnetism indicates that large, lateral, relative motions among continents had begun by at least 1.88 Ga. The “boring billion”, from about 1.8 to 0.8 Ga, was a period of two super-continents (Nuna, also known as Columbia, and Rodinia) characterised by substantial magmatism of intraplate type leading to the hypothesis that Earth had reverted to a single plate planet over this period; however, orogens with marginal accretionary tectonics and related magmatism and ore genesis indicate that plate tectonics was still taking place at and beyond the bounds of these supercontinents. The break-up of Rodinia heralded modern plate tectonics from about 0.8 Ga. Our conclusions are based, almost wholly, upon geological data sets, including petrology, ore geology and geochemistry, with minor input from modelling and theory.

High-Ca boninitic melt inclusions in lavas of the Troodos ophiolite and a reappraisal of genetic relationships between different lava types

Abstract Boninites in many supra-subduction zone ophiolites are thought to mark the early stage of subduction. The Troodos ophiolite in Cyprus contains a variety of volcanic rocks including the lower pillow lavas and the boninite-bearing upper pillow lavas (UPL). Here we present major, trace element and Pb isotope data for melt inclusions in olivine from the UPL on the northern flank of the Troodos ophiolite. Melt inclusions hosted by high-Mg (Fo = 89.4–93.5) olivine grains have typical high-Ca boninitic compositions with high MgO (11.2–18.4 wt%) and SiO2 (51.2–55.0 wt%) and low TiO2 (0.2–0.6 wt%) contents, in line with the existence of boninites in the northern part of the ophiolite. The melt inclusions have trace element compositions similar to the Troodos boninitic lavas and can be regarded as representing the parental magma of the boninites. The boninitic magmas were derived from high-degrees of partial melting of a refractory source at 1400 °C and 1.5 GPa based on thermobarometers and phase equilibria. The melt inclusions have significantly variable Pb isotopic compositions (208Pb/206Pb = 2.059–2.122; 207Pb/206Pb = 0.828–0.862) and are enriched in fluid-mobile trace elements (e.g., U, Sr, and Pb), indicating that the refractory source was metasomatized by slab fluids. In comparison, recalculation of literature data suggests that the lower pillow lavas were derived from a less refractory and shallower source. We propose a subduction initiation model in which melting of two unique sources was needed to form the chemostratigraphy of lavas in the Troodos ophiolite.

Metamorphic fingerprints of Fe-rich chromitites from the Eastern Pampean Ranges, Argentina

Chromitites hosted in the serpentinized harzburgite bodies from Los Congos and Los Guanacos (Eastern Pampean Ranges, north Argentina) record a complex metamorphic evolution. The hydration of chromitites during the retrograde metamorphism, their subsequent dehydration during the prograde metamorphism and the later-stage cooling, have resulted in a threefold alteration of chromite: i) Type I is characterized by homogeneous Fe3+- and Cr-rich chromite; ii) Type II chromite contains exsolved textures that consist in blebs and fine lamellae of a magnetite-rich phase hosted in a spinel-rich phase; iii) Type III chromite is formed by variable proportions of magnetite-rich and spinel-rich phases with symplectitic texture. Type I chromite shows lower Ga and higher Co, Zn and Mn than magmatic chromites from chromitites in suprasubduction zone ophiolites as a consequence of the redistribution of these elements between Fe3+-rich non-porous chromite and silicates during the prograde metamorphism. Whereas, the spinel-rich phase in Type III chromite is enriched in Co, Zn, Sc, and Ga, but depleted in Mn, Ni, V and Ti with respect to the magnetite-rich phase, due to the metamorphic cooling from high-temperature conditions. The pseudosection calculated in the fluid-saturated FCrMACaSH system, and contoured for Cr# and Mg#, allows us to constrain the temperature of formation of Fe3+-rich non-porous chromite by the diffusion of magnetite in Fe2+-rich porous chromite at &lt;500 ºC and 20 kbar. The subsequent dehydration of Fe3+-rich non-porous chromite by reaction with antigorite and chlorite formed Type I chromite and Mg-rich olivine and pyroxene at &gt;800 ºC and 10 kbar. The ultimate hydration of silicates in Type I chromite and the exsolution of Type II and Type III chromites would have started at ~600 ºC. These temperatures are in the range of those estimated for ocean floor serpentinization (&lt;300 ºC and &lt;4 kbar), the regional prograde metamorphism in the granulite facies (800 ºC and &lt;10 kbar), and subsequent retrogression to the amphibolite facies (600 ºC and 4-6.2 kbar) in the host ultramafic rocks at Los Congos and Los Guanacos. A continuous and slow cooling from granulite to amphibolite facies produced the exsolution of spinel-rich and magnetite-rich phases, developing symplectitic textures in Type III chromite. However, the discontinuous and relatively fast cooling produced the exsolution of magnetite-rich phase blebs and lamellae within Type II chromite. The P-T conditions calculated in FCrMACaSH system and the complex textural and geochemical fingerprints showed by Type I, Type II and Type III chromites leads us to suggest that continent-continent collisional orogeny better records the fingerprints of prograde metamorphism in ophiolitic chromitites.

Mineral compositions and thermobarometry of basalts and boninites recovered during IODP Expedition 352 to the Bonin forearc

AbstractCentral aims of IODP Expedition 352 were to delineate and characterize the magmatic stratigraphy in the Bonin forearc to define key magmatic processes associated with subduction initiation and their potential links to ophiolites. Expedition 352 penetrated 1.2 km of magmatic basement at four sites and recovered three principal lithologies: tholeiitic forearc basalt (FAB), high-Mg andesite, and boninite, with subordinate andesite. Boninites are subdivided into basaltic, low-Si, and high-Si varieties. The purpose of this study is to determine conditions of crystal growth and differentiation for Expedition 352 lavas and compare and contrast these conditions with those recorded in lavas from mid-ocean ridges, forearcs, and ophiolites. Cr# (cationic Cr/Cr+Al) vs. TiO2 relations in spinel and clinopyroxene demonstrate a trend of source depletion with time for the Expedition 352 forearc basalt to boninite sequence that is similar to sequences in the Oman and other suprasubduction zone ophiolites. Clinopyroxene thermobarometry results indicate that FAB crystallized at temperatures (1142–1190 °C) within the range of MORB (1133–1240 °C). When taking into consideration liquid lines of descent of boninite, orthopyroxene barometry and olivine thermometry of Expedition 352 boninites demonstrate that they crystallized at temperatures marginally lower than those of FAB, between ~1119 and ~1202 °C and at relatively lower pressure (~0.2–0.4 vs. 0.5–4.6 kbar for FAB). Elevated temperatures of boninite orthopyroxene (~1214 °C for low-Si boninite and 1231–1264 °C for high-Si boninite) may suggest latent heat produced by the rapid crystallization of orthopyroxene. The lower pressure of crystallization of the boninite may be explained by their lower density and hence higher ascent rate, and shorter distance of travel from place of magma formation to site of crystallization, which allowed the more buoyant and faster ascending boninites to rise to shallower levels before crystallizing, thus preserving their high temperatures.

Early Ordovician Age of Suprasubduction Ophiolites in the Northeastern Part of Central Kazakhstan: U–Th–Pb (SIMS) Dating of Plagiogranites

Suprasubduction zone ophiolites in the Bayanaul and Maikain–Kyzyltas zones in the northeastern part of Central Kazakhstan were studied. U–Pb dating of plagiogranites that constitute the plutonic complexes of the ophiolite sections was performed. The Early Ordovician age estimates of 480 ± 3 Ma for the plagiogranites in the Bayanaul zone and 477 ± 2 Ma in the Maikain-Kyzyltas zone were obtained for the first time. It was demonstrated that the formation time span of the plutonic and volcanosedimentary complexes in the studied ophiolites does not exceed 7–10 Ma.

Melt-rock interaction in the subarc mantle: records from the plagioclase peridotites of the southern Palawan Ophiolite, Philippines

ABSTRACT The interaction between migrating melts and the upper mantle largely affects the composition of the ascending melt and residual peridotites. In island arcs, melt-rock interactions and products which involved highly depleted mantle peridotites are still largely undocumented despite their petrological importance. In this contribution, the petrographic and geochemical signatures of refractory and refertilized peridotites comprising the mantle section of the southern Palawan Ophiolite, Philippines are investigated. The peridotites are dominantly comprised of residual spinel harzburgites with minor dunite and plagioclase peridotites. Spinel harzburgites are similar to other highly depleted residual mantle materials of other suprasubduction zone ophiolites. Plagioclase peridotites, which are cut by gabbroic intrusions, preserve distinct petrological characteristics indicating melt-rock interaction. The melts preserved as gabbroic dikes have signatures transitional between mid-ocean ridge and island arc, and are comparable to back-arc basin lavas. We therefore propose that the plagioclase peridotites were formed due to the reaction between highly depleted mantle peridotites beneath an intraoceanic arc and migrating BABB-like magmas possibly during the incipient stages of back-arc rifting.

Dismembered Ophiolite of the Olkhon Composite Terrane (Baikal, Russia): Petrology and Emplacement

Dismembered ophiolites in the Early Paleozoic Olkhon terrane, a part of the Baikal collisional belt in the southern periphery of the Siberian craton, occur as fault-bounded blocks of ultramafic and mafic rocks from a few meters to hundreds of meters in size. The ultramafic rocks are mainly dunite–harzburgite peridotites with gradual transitions between the lithologies, as well as moderate amounts of enstatitite, wehrlite, and clinopyroxenite, but no lherzolite. Most peridotites have strongly depleted chemistry and a mineralogy corresponding to the harzburgite type usual for ophiolites of suprasubduction zones (SSZ). The mafic rocks are leuco- to melanocratic gabbros with different relative percentages of clinopyroxene, olivine, and plagioclase, which enclose thin layers and lenses of clinopyroxenite and anorthosite. They bear back-arc basin geochemical signatures, a setting inferred for the Neoproterozoic southern Siberian craton. The gabbroic rocks are of two geochemical groups; most of their trace-element patterns show Ta-Nb minimums and Sr maximums common to suprasubduction zone ophiolites. Judging by the Ol + Opx + Chl + Chr mineral assemblages, the Olkhon peridotites underwent low amphibolite and amphibolite regional metamorphism at 500–650 °C. The occurrence of the ultramafic and mafic bodies is consistent with formation in an accretionary wedge metamorphosed during a collisional orogeny. The mantle and crustal parts of the Olkhon ophiolite suite apparently were incorporated into the terrane during the frontal collision of perio-oceanic structures with the Siberian craton. Then, in a later oblique collision event, they became dismembered by strike-slip faulting into relatively small bodies and fault blocks exposed in the present erosional surface.

Slab-controlled elemental–isotopic enrichments during subduction initiation magmatism and variations in forearc chemostratigraphy

Supra-subduction zone (SSZ) ophiolites formed in forearc settings and the Izu–Bonin–Mariana (IBM) in-situ forearc show conversions from normal mid-ocean ridge basalt (MORB) to boninitic affinities, which are widely interpreted as rules for the evolving chemical geodynamics of subduction initiation magmatism (SIM). Nevertheless, forearc sequence generated by subduction initiation need not always include boninitic rocks. Here we reconstruct a forearc chemostratigraphy without boninitic affinity based on the Central Palawan and Amnay (CPA) ophiolites of the west Philippines to show diversity in melt evolution of SIM. Zircon U–Pb dating on the MORB-type Amnay gabbros reveal a 10 m.y. of seafloor spreading from 33 to 23 Ma. These ages together with the progressively enriched zircon in-situ oxygen isotopes (δ18O= 1.62–10.1‰) and whole rock elemental and Nd–Hf isotopic signatures ([La/Yb]N= 0.19–3.45; Nb/Yb= 0.07–5.24; εNd= 2.1–10.2; εHf= 11.2–24.1) indicate that the depleted MORB mantle (DMM)-type source of the Amnay ophiolite was getting enriched by fluxing of aqueous slab fluid in the early stage followed by addition of adakitic and Nb-enriched slab melts in the later stage. This distinct mantle evolution together with higher εHf at a given εNd of the Amnay mafic samples than the contemporaneous South China Sea (SCS) oceanic samples do not support previous interpretation that the Amnay ophiolite was a fragment of the SCS. However, the 33–23 Ma Amnay ophiolite can be the younger part of the 34 Ma forearc-type Central Palawan ophiolite, and both (i.e. the CPA ophiolites) represent on-land fragments of the NW Sulu Sea. We propose that the 34–23 Ma CPA ophiolites and the NW Sulu Sea constitute forearc basin of the late Oligocene–middle Miocene island arc–backarc basin duo of the Cagayan Ridge and SE Sulu Sea, associated with subduction of the Cretaceous to Eocene Proto-SCS since 34 Ma. The CPA ophiolites lack boninite but show geochemical progression from normal to enriched MORB affinities, whose melt evolution differs from that of the IBM SIM. We attribute the differences in SIM and variations in forearc chemostratigraphy to the subduction of a younger slab with thick terrigenous sediment cover of the Proto-SCS versus an older slab with thin pelagic sediment cover of the Pacific Plate.

Neoarchean suprasubduction zone ophiolite discovered from the Miyun Complex: Implications for Archean–Paleoproterozoic Wilson cycle in the North China Craton

The North China Craton (NCC) offers a window to Archean–Paleoproterozoic crustal evolution. Following the amalgamation of microblocks during Neoarchean, the NCC witnessed another protracted Wilson cycle in the Paleoproterozoic with subduction-accretion-collision process. Here we report a newly identified suprasubduction zone ophiolite suite from the Miyun complex in the NCC where a rare and near-complete ophiolite succession is preserved including serpentinite, lherzolite, olivine clinopyroxenite, websterite, gabbro, dolerite, diorite, monzonite, metabasalts and trondhjemite, in association with Banded Iron Formation (BIF). The geochemical features of the suite are consistent with those of suprasubduction ophiolite complexes, with the mafic and intermediate members displaying Island Arc Tholeiite (IAT) and Mid-Ocean Ridge Basalt (MORB) affinity. Zircon grains from lherzolite define three groups of 207Pb/206Pb weighted mean ages at 2500 ± 12 Ma marking the formation age, and 2237 ± 47 Ma, and 1843 ± 30 Ma representing subsequent thermal events. The majority of zircon grains in olivine clinopyroxenite, gabbro, and quartz monzonite yield 207Pb/206Pb weighted mean ages of 2510 ± 19 Ma, 2495 ± 10 Ma, and 2486 ± 21 Ma respectively. Those from the trondhjemite show weighted mean age of 2476 ± 9.4 Ma. The compiled age data from all the rock types in the Miyun suite show two distinct age peaks at ca. 2486 Ma and 1832 Ma, corresponding to the timing of magma differentiation and subsequent metamorphism. The zircon Lu-Hf isotope data display distinct positive ɛHf(t) values in the range 0.35–7.05, suggesting magma derived from Neoarchean to Paleoproterozoic depleted mantle (juvenile) source. The zircon TDM ages show a peak at 2670 Ma, confirming Neoarchean components. The timing of magma formation in the Miyun ophiolite is broadly identical to those of the other rare Neoarchean – early Paleoproterozoic ophiolite suites described from the NCC including those from Yishui and Zunhua. Furthermore, evidence from the recently reported Alaskan-type intrusions and arc root mafic-ultramafic complexes around Miyun complex with ages in the range of 2.4–2.0 Ga suggest continued subduction-related magmatic processes, with final collision in latest Paleoproterozoic at around 1.84 Ga. We propose that following the assembly of ancient microblocks along multiple zones of ocean closure marked by major greenstone belts of 2.6–2.5 Ga, and high-grade metamorphism along the margins of the microblocks during Archean–Paleoproterozoic transition, the NCC went through another major Wilson cycle from early to late Paleoproterozoic involving prolonged subduction, accretion and collision of larger crustal blocks and intervening arc complexes, leading to final cratonization.