The purpose of this research is to systematically review the state-of-the-art literature on Supply Chain Finance (SCF) and Environmental, Social, and Governance (ESG) and Value Chain within the supply chain management domain. We meticulously screened closely related themes through a systematic literature review of selected fifty-one manuscripts using the PRISMA method. Three-phase approach of planning, conducting and reporting is considered in this review. The outcomes of our review demonstrate the contributions of SCF to decision-making within the supply chain domain. This review highlights synergies, distinctions, and intersections in SCF, ESG, and value chain. Based on themes, the study led to four propositions to develop a comprehensive framework. Additionally, the literature is elucidated based on the approaches employed for SCF development, accompanied by the underlying theories. The categorization primarily separates the literature into two main groups: one focused on theory development, and the other on practical applications, revolving around SCF, ESG, and the value chain. Professionals in corporate settings and academic scholars will likely derive significant value from this review. The study thoroughly reviews, categorizes, and analyzes existing research and offers an integrated framework on SCF, ESG, and the value chain, which can be helpful for professionals. This is the first research that uses a structured approach to analyze studies on a novel topic and propose a framework for SCF, ESG, and value chain.