In this paper, we demonstrated the ability of a hexagonal photonic crystal fiber (PCF) with a hollow core infiltrated with nitrobenzene (C6H5NO2) to generate a broad SC spectrum at low peak powers. Due to the non-uniformity of the air hole diameters, our new design allows for simultaneous optimization of features, resulting in near-flat, near-zero dispersion, a small effective mode area, and low attenuation for efficient spectral broadening. We selected two optimal structures from the simulation results to analyze the nonlinear properties and supercontinuum generation. The first fiber, #HF1, with a lattice constant of 1.0[Formula: see text][Formula: see text]m and a filling factor of 0.45, operates in all-normal dispersion and produces spectral SC ranging from 0.81[Formula: see text][Formula: see text]m to 1.919[Formula: see text][Formula: see text]m with a pump wavelength of 1.56[Formula: see text][Formula: see text]m, a pulse duration of 90[Formula: see text]fs, and peak power of 0.133[Formula: see text]kW propagated in a 1 cm fiber length. The #HF2 fiber (lattice constant of 2.0[Formula: see text][Formula: see text]m, filling factor of 0.3) has an extended SC spectrum from 0.792[Formula: see text][Formula: see text]m to 3.994[Formula: see text][Formula: see text]m, a pump wavelength of 1.55[Formula: see text][Formula: see text]m, a pulse width of 110[Formula: see text]fs, a peak power of 0.273[Formula: see text]kW propagated in a 15[Formula: see text]cm fiber length. The proposed fiber may be a new-generation optical fiber suitable for low-peak power all-fiber optical systems to replace glass-core glass fiber.
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