Superconductor Sr Research Articles

Insulator-to-Superconductor Transition upon Electron Doping in a BiS2-Based Superconductor Sr1−xLaxFBiS2

Effects of electron doping on the BiS$_2$-based superconductors Sr$_{1-x}$La$_x$FBiS$_2$ ($0\le x\le 0.6$) have been investigated using the systematically synthesized polycrystals. The pristine compound is a band insulator with the BiS$_2$ layer, which accommodates electron carriers through the La substitution for Sr, as evidenced by the change in x-ray absorption spectra reflecting the occupancy of Bi 6$p$ orbitals. With increasing the carrier density, the resistivity progressively decreases and a bad metallic state appears for $x\ge0.45$, where bulk superconductivity manifests itself below approximately 3 K. The value of $T_{\rm c}$ gradually increases with decreasing $x$ from 0.6 to 0.45 and immediately decreases down to zero at the critical concentration of $x\sim 0.4$, resulting in an insulator-superconductor transition highly sensitive to the carrier density. Thermodynamic measurements furthermore have revealed the possible enhancement of the superconducting coupling strength as the insulating phase is approached. The obtained superconducting phase diagram is markedly different from the broad dome-shaped superconducting phase previously reported for $R$O$_{1-x}$F$_x$BiS$_2$ ($R$: rare-earth ion), suggesting a strong influence of the blocking layer on the superconductivity. Instead all these features are similar to those observed in Li-intercalated ZrNCl superconductor, except for the critical electron concentration of as low as 6% in the latter compound. For the present superconductor, notably, the existence of hole-type carriers has been indicated in the normal state from the Hall effect measurements. The Sr$_{1-x}$La$_x$FBiS$_2$ system providing the phase diagram for the rigid-band doping in the BiS$_2$ layer would be another prototypical example of superconductivity derived from a doped layered band insulator, hosting both hole-like and electron-like Fermi surfaces.

Enhanced spin-triplet superconductivity near dislocations in Sr2RuO4

Superconductors with a chiral p-wave pairing are of great interest because they could support Majorana modes that could enable the development of topological quantum computing technologies that are robust against decoherence. Sr₂RuO₄ is widely believed to be a chiral p-wave superconductor. Yet, the mechanism by which superconductivity emerges in this, and indeed most other unconventional superconductors, remains unclear. Here we show that the local superconducting transition temperature in the vicinity of lattice dislocations in Sr₂RuO₄ can be up to twice that of its bulk. This is all the more surprising for the fact that disorder is known to easily quench superconductivity in this material. With the help of a phenomenological theory that takes into account the crystalline symmetry near a dislocation and the pairing symmetry of Sr₂RuO₄, we predict that a similar enhancement should emerge as a consequence of symmetry reduction in any superconductor with a two-component order parameter.

Evidence from tunneling spectroscopy for a quasi-one-dimensional origin of superconductivity in Sr2RuO4

To establish the mechanism of unconventional superconductivity in Sr$_2$RUO$_4$, a prerequisite is direct information concerning the momentum-space structure of the energy gaps $\Delta_i(k)$, and in particular whether the pairing strength is stronger ("dominant") on the quasi-1D ($\alpha$ and $\beta$) or on the quasi-2D ($\gamma$) Fermi surfaces. We present scanning tunneling microscopy (STM) measurements of the density-of-states spectra in the superconducting state of Sr$_2$RuO$_4$ for $0.1 T_C<T<T_C$, and analyze them, along with published thermodynamic data, using a simple phenomenological model. We show that our observation of a single superconducting gap scale with maximum value $2\Delta \approx 5 T_C$ along with a spectral shape indicative of line nodes is consistent, within a weak-coupling model, with magnetically mediated odd-parity superconductivity generated by dominant, near-nodal Cooper pairing on the $\alpha$ and $\beta$ bands.

Dopant clustering, electronic inhomogeneity, and vortex pinning in iron-based superconductors

We use scanning tunneling microscopy to map the surface structure, nanoscale electronic inhomogeneity, and vitreous vortex phase in the hole-doped superconductor Sr${}_{0.75}$K${}_{0.25}$Fe${}_{2}$As${}_{2}$ with ${T}_{c}=32$ K. We find that the low-$T$ cleaved surface is dominated by a half Sr/K termination with $1\ifmmode\times\else\texttimes\fi{}2$ ordering and ubiquitous superconducting gap, while patches of gapless, unreconstructed As termination appear rarely. The superconducting gap varies by $\ensuremath{\sigma}/\overline{\ensuremath{\Delta}}=16%$ on a $\ensuremath{\sim}$3 nm length scale, with average $2\overline{\ensuremath{\Delta}}/{k}_{B}{T}_{c}=3.6$ in the weak-coupling limit. The vortex core size provides a measure of the superconducting coherence length $\ensuremath{\xi}=2.3$ nm. We quantify the vortex lattice correlation length at 9 T in comparison to several iron-based superconductors. The comparison leads us to suggest the importance of dopant size mismatch as a cause of dopant clustering, electronic inhomogeneity, and strong vortex pinning.

Pressure- and Composition-Induced Structural Quantum Phase Transition in the Cubic Superconductor(Sr,Ca)3Ir4Sn13

We show that the quasi-skutterudite superconductor Sr(3)Ir(4)Sn(13) undergoes a structural transition from a simple cubic parent structure, the I phase, to a superlattice variant, the I' phase, which has a lattice parameter twice that of the high temperature phase. We argue that the superlattice distortion is associated with a charge density wave transition of the conduction electron system and demonstrate that the superlattice transition temperature T(*) can be suppressed to zero by combining chemical and physical pressure. This enables the first comprehensive investigation of a superlattice quantum phase transition and its interplay with superconductivity in a cubic charge density wave system.

Phase-sensitive evidence fordx2−y2-pairing symmetry in the parent-structure high-Tccuprate superconductor Sr1−xLaxCuO2

Even after 25 years of research the pairing mechanism and - at least for electron doped compounds - also the order parameter symmetry of the high transition temperature (high-Tc) cuprate superconductors is still under debate. One of the reasons is the complex crystal structure of most of these materials. An exception are the infinite layer (IL) compounds consisting essentially of CuO2 planes. Unfortunately, these materials are difficult to grow and, thus, there are only few experimental investigations. Recently, we succeeded in depositing high quality films of the electron doped IL compound Sr1-xLaxCuO2 (SLCO), with x approximately 0.15, and on the fabrication of well-defined grain boundary Josephson junctions (GBJs) based on such SLCO films. Here we report on a phase sensitive study of the superconducting order parameter based on GBJ SQUIDs from a SLCO film grown on a tetracrystal substrate. Our results show that also the parent structure of the high-Tc cuprates has dx2-y2-wave symmetry, which thus seems to be inherent to cuprate superconductivity.

New magnetic phase diagram of (Sr,Ca)2RuO4

High-T(c) cuprates, iron pnictides, organic BEDT and TMTSF, alkali-doped C(60), and heavy-fermion systems have superconducting states adjacent to competing states exhibiting static antiferromagnetic or spin density wave order. This feature has promoted pictures for their superconducting pairing mediated by spin fluctuations. Sr(2)RuO(4) is another unconventional superconductor which almost certainly has a p-wave pairing. The absence of known signatures of static magnetism in the Sr-rich side of the (Ca, Sr) substitution space, however, has led to a prevailing view that the superconducting state in Sr(2)RuO(4) emerges from a surrounding Fermi-liquid metallic state. Using muon spin relaxation and magnetic susceptibility measurements, we demonstrate here that (Sr,Ca)(2)RuO(4) has a ground state with static magnetic order over nearly the entire range of (Ca, Sr) substitution, with spin-glass behaviour in Sr(1.5)Ca(0.5)RuO(4) and Ca(1.5)Sr(0.5)RuO(4). The resulting new magnetic phase diagram establishes the proximity of superconductivity in Sr(2)RuO(4) to competing static magnetic order.

Properties of the electron-doped infinite-layer superconductor Sr1−xLaxCuO2epitaxially grown by pulsed laser deposition

Thin films of the electron-doped infinite-layer cuprate superconductor Sr$_{1-x}$La$_x$CuO$_2$ (SLCO) with doping $x \approx 0.15$ were grown by means of pulsed laser deposition. (001)-oriented KTaO$_3$ and SrTiO$_3$ single crystals were used as substrates. In case of SrTiO$_3$, a BaTiO$_3$ thin film was deposited prior to SLCO, acting as buffer layer providing tensile strain to the SLCO film. To induce superconductivity, the as-grown films were annealed under reducing conditions, which will be described in detail. The films were characterized by reflection high-energy electron diffraction, atomic force microscopy, x-ray diffraction, Rutherford backscattering spectroscopy, and electric transport measurements at temperatures down to $T = 4.2\,$K. We discuss in detail the influence of different process parameters on the final film properties.

Importance of grain-boundary Josephson junctions in the electron-doped infinite-layer cuprate superconductor Sr1−xLaxCuO2

Grain boundary bicrystal Josephson junctions of the electron-doped infinite-layer superconductor Sr$_{1-x}$La$_x$CuO$_2$ ($x = 0.15$) were grown by pulsed laser deposition. BaTiO$_3$-buffered $24\,^\circ$ [001]-tilt symmetric SrTiO$_3$ bicrystals were used as substrates. We examined both Cooper pair (CP) and quasiparticle (QP) tunneling by electric transport measurements at temperatures down to 4.2\,K. CP tunneling revealed an extraordinary high critical current density for electron-doped cuprates of $j_c > 10^3\,$A/cm$^2$ at 4.2\,K. Thermally activated phase slippage was observed as dissipative mechanism close to the transition temperature. Out-of-plane magnetic fields $H$ revealed a remarkably regular Fraunhofer-like $j_c(H)$ pattern as well as Fiske and flux flow resonances, both yielding a Swihart velocity of $3.1\cdot10^6\,$m/s. Furthermore, we examined the superconducting gap by means of QP tunneling spectroscopy. The gap was found to be V-shaped with an extrapolated zero temperature energy gap $\Delta_0 \approx 2.4\,$meV. No zero bias conductance peak was observed.

Vortex imaging and vortex lattice transitions in superconducting Sr2RuO4single crystals

Scanning Hall probe microscopy has been used to study vortex structures in very-high-quality single crystals of the unconventional superconductor Sr${}_{2}$RuO${}_{4}$ $({T}_{c}\ensuremath{\cong}1.5$ K). In none of our samples do we find credible evidence for the existence of the spontaneous fields or chiral domains predicted for the expected time-reversal symmetry-breaking order parameter. Even in our highest-quality samples we observe very strong vortex pinning and anomalous broadening of vortex profiles. The best samples also exhibit a clear field-driven triangular to square vortex lattice transition at low fields, as predicted by extended London theory calculations. In stark contrast, slightly less well-ordered samples exhibit pronounced vortex chaining/banding that we tentatively attribute to an extrinsic source of disorder.

Electric transport across Sr1−xLaxCuO2/Au/Nb planar tunnel junctions and x-ray photoelectron and Auger-electron spectroscopy on Sr1−xLaxCuO2thin films

Thin-film planar tunnel junctions with the electron-doped infinite-layer superconductor Sr${}_{1\ensuremath{-}x}$La${}_{x}$CuO${}_{2}$ (SLCO) with $x\ensuremath{\sim}0.15$ as bottom electrode, a thin Au interlayer, and Nb as top electrode were fabricated and characterized. Measurements of electric transport across these junctions provide information on the interface and surface properties of the SLCO thin films. No Cooper pair tunneling is observed; however, nonlinear current-voltage characteristics give evidence for quasiparticle (QP) tunneling across a thin insulating SLCO barrier at the SLCO/Au interface, with a single gap value $\ensuremath{\sim}$$1.4\phantom{\rule{0.28em}{0ex}}$meV, originating from superconducting Nb. The absence of a superconducting SLCO gap in the QP conductance curves indicates a thin normal-conducting SLCO layer below the insulating SLCO barrier. To examine its origin, x-ray photoelectron spectroscopy (XPS) and x-ray Auger-electron spectroscopy (XAES) on SLCO thin films were performed. We observe a Cu valence of +1 in the SLCO surface layer (within $\ensuremath{\sim}$$3\phantom{\rule{0.28em}{0ex}}$nm thickness) and of +2 in deeper regions, as expected for fully oxidized CuO${}_{2}$ planes in the bulk. Hence, the XPS and XAES results for the SLCO films are consistent with the QP tunneling spectra observed for our planar SLCO/Au/Nb junctions.

Penetration of nonintegral magnetic flux through a domain-wall bend in time-reversal symmetry broken superconductors

It has been proposed that the superconductivity of Sr$_2$RuO$_4$ is characterized by pairing that is unconventional and, furthermore, spontaneously breaks time-reversal symmetry. However, one of the key expected consequences, viz., that the ground state should exhibit chiral charge currents localized near the boundaries of the sample, has not been observed, to date. We explore an alternative implication of time-reversal symmetry breaking: the existence of walls between domains of opposing chirality. Via a general phenomenological approach, we derive an effective description of the superconductivity in terms of the relevant topological variables (i.e., domain walls and vortices). Hence, by specializing to the in the in-plane rotationally invariant limit, we show that a domain wall that is translationally invariant along the z axis and includes a bend through an angle $\Theta$ is accompanied by a nonintegral (and possibly nonquantized) magnetic {\it bend flux} of $\big((\Theta/\pi)+n\big)\Phi_0$, with integral $n$, that penetrates the superconductor, localized near the bend. We generalize this result to the situation in which gauge transformations and rotations about the z axis are degenerate transformations of the chiral superconducting order. On the basis of the specialized result and its generalization, we note that any observation of localized, nonquantized flux penetrating a z-axis surface (e.g., via scanned-probe magnetic imaging) can be interpreted in terms of the presence of bent walls between domains of opposing chirality, and hence is suggestive of the existence of time-reversal symmetry-breaking superconductivity.

Phase diagram of superconductivity and antiferromagnetism in single crystals of Sr(Fe1−xCox)2As2and Sr1−yEuy(Fe0.88Co0.12)2As2

We report magnetic susceptibility, resistivity and heat capacity measurements on single crystals of the Sr(Fe1-xCox)2As2 and Sr1-yEuy(Fe0.88Co0.12)2As2 series. The optimal Co concentration for superconductivity in Sr(Fe1-xCox)2As2 is determined to be x ~ 0.12. Based on this we grew members of the Sr1-yEuy(Fe0.88Co0.12)2As2 series so as to examine the effects of well defined, local magnetic moments, on the superconducting state. We show that superconductivity is gradually suppressed by paramagnetic Eu2+ doping and coexists with antiferromagnetic ordering of Eu2+ as long as Tc > TN. For y >= 0.65, TN crosses Tc and the superconducting ground state (as manifested by zero resistivity) abruptly disappears with evidence for competition between superconductivity and local moment antiferromagnetism for y up to 0.72. It is speculated that the suppression of the antiferromagnetic fluctuations of Fe sublattice by coupling to the long range order of Eu2+ sublattice destroys bulk superconductivity when TN > Tc.

Pressure Dependence of Superconducting Transition Temperature on Perovskite-Type Fe-Based Superconductors and NMR Study of Sr2VFeAsO3

We report the pressure dependences of the superconducting transition temperature (T_c) in several perovskite-type Fe-based superconductors through the resistivity measurements up to ~4 GPa. In Ca_4(Mg,Ti)_3Fe_2As_2O_y with the highest T_c of 47 K in the present study, the T_c keeps almost constant up to ~1 GPa, and starts to decrease above it. From the comparison among several systems, we obtained a tendency that low T_c with the longer a-axis length at ambient pressure increases under pressure, but high T_c with the shorter a-axis length at ambient pressure hardly increases. We also report the ^75As-NMR results on Sr_2VFeAsO_3. NMR spectrum suggests that the magnetic ordering occurs at low temperatures accompanied by some inhomogeneity. In the superconducting state, we confirmed the anomaly by the occurrence of superconductivity in the nuclear spin lattice relaxation rate 1/T_1, but the spin fluctuations unrelated with the superconductivity are dominant. It is conjectured that the localized V-3d moments are magnetically ordered and their electrons do not contribute largely to the Fermi surface and the superconductivity in Sr_2VFeAsO_3.

INTRINSIC AND EXTRINSIC ORIGINS OF THE POLAR KERR EFFECT IN A CHIRAL p-WAVE SUPERCONDUCTOR

Recently, the measurement of the polar Kerr effect (PKE) in the quasi two-dimensional superconductor Sr 2 RuO 4, which is motivated to observe the chirality of px + ipy-wave pairing, has been reported. We clarify that the PKE has intrinsic and extrinsic (disorder-induced) origins. The extrinsic contribution would be dominant in the PKE experiment.

Superconductivity in Sr and Co co-doped PrFeAsO

Polycrystalline Sr and Co co-doped superconducting oxypnictides Pr1−ySryFe1−xCoxAsO were synthesized by solid state reaction method, and superconductivity was investigated by measuring resistivity, magnetic susceptibility and thermopower. In the PrFe1−xCoxAsO samples with only Co doping, Tc reaches a maximum of 16K at x=0.075–0.1, and the variation of Tc with Co content (x) is dome-shaped, consistent with the other Co-doped 1111 phase systems such as LaFe1−xCoxAsO and SmFe1−xCoxAsO. In the Co and Sr co-doped Pr0.8Sr0.2Fe1−xCoxAsO system, Tc reaches a maximum of about 16K at x=0.15, and the Tc‐x dome shifts to higher Co content in the phase diagram of Tc versus Co content (x). Our result indicates that Sr doping effectively induces hole-type charge carriers in the PrFeAsO system and the disorder caused by Sr and Co dopants has little effect on Tc. The thermopower data confirms that Sr dopant is hole-type and Co dopant is electron-type. The shift of Tc‐x dome to higher Co content caused by Sr doping implies that the Sr dopant can compensate for the Co doping effect. The results suggest that there could be a universal dependence of Tc on charge carrier density in both hole-type and electron-type oxypnictide superconductors.

Self-doping effect and successive magnetic transitions in superconductingSr2VFeAsO3

We have studied a quinary Fe-based superconductor Sr$_2$VFeAsO$_3$ by the measurements of x-ray diffraction, x-ray absorption, M\"{o}ssbauer spectrum, resistivity, magnetization and specific heat. This apparently undoped oxyarsenide is shown to be self doped via electron transfer from the V$^{3+}$ ions. We observed successive magnetic transitions within the VO$_2$ layers: an antiferromagnetic transition at 150 K followed by a weak ferromagnetic transition at 55 K. The spin orderings within the VO$_2$ planes are discussed based on mixed valence of V$^{3+}$ and V$^{4+}$.

Random Spin–Orbit Coupling in Spin Triplet Superconductors: Stacking Faults in Sr2RuO4 and CePt3Si

The random spin-orbit coupling in multicomponent superconductors is investigated focusing on the non-centrosymmetric superconductor CePt_3Si and the spin triplet superconductor Sr_2RuO_4. We find novel manifestations of the random spin-orbit coupling in the multicomponent superconductors with directional disorders, such as stacking faults. The presence of stacking faults is indicated for the disordered phase of CePt_3Si and Sr_2RuO_4. It is shown that the d-vector of spin triplet superconductivity is locked to be d = k_y x - k_x y with the anisotropy \Delta T_c/T_c0 \sim \bar{\alpha}^2/T_c0 W_z, where \bar{\alpha}, T_c0, and W_z are the mean square root of random spin-orbit coupling, the transition temperature in the clean limit, and the kinetic energy along the c-axis, respectively. This anisotropy is much larger (smaller) than that in the clean bulk Sr_2RuO_4 (CePt_3Si). These results indicate that the helical pairing state d = k_y x - k_x y in the eutectic crystal Sr_2RuO_4-Sr_3Ru_2O_7 is stabilized in contrast to the chiral state d = (k_x \pm i k_y) z in the bulk Sr_2RuO_4. The unusual variation of T_c in CePt_3Si is resolved by taking into account the weak pair-breaking effect arising from the uniform and random spin-orbit couplings. These superconductors provide a basis for discussing recent topics on Majorana fermions and non-Abelian statistics.

Scanning Hall probe microscopy of vortex matter

Scanning Hall probe microscopy (SHPM) is a novel scanned probe magnetic imaging technique whereby the stray fields at the surface of a sample are mapped with a sub-micron semiconductor heterostructure Hall probe. In addition an integrated scanning tunnelling microscope (STM) or atomic force microscope (AFM) tip allows the simultaneous measurement of the sample topography, which can then be correlated with magnetic images. SHPM has several advantages over alternative methods; it is almost completely non-invasive, can be used over a very wide range of temperatures (0.3–300 K) and magnetic fields (0–7 T) and yields quantitative maps of the z-component of magnetic induction. The approach is particularly well suited to low temperature imaging of vortices in type II superconductors with very high signal:noise ratios and relatively high spatial resolution (>100 nm). This paper will introduce the design principles of SHPM including the choice of semiconductor heterostructure for different measurement conditions as well as surface tracking and scanning mechanisms. The full potential of the technique will be illustrated with results of vortex imaging studies of three distinct superconducting systems: (i) vortex chains in the “crossing lattices” regime of highly anisotropic cuprate superconductors, (ii) vortex–antivortex pairs spontaneously nucleated in ferromagnetic-superconductor hybrid structures, and (iii) vortices in the exotic p-wave superconductor Sr 2RuO 4 at milliKelvin temperatures.

Sr2VO3FeAsas compared to other iron-based superconductors

One of the most popular scenarios for the superconductivity in Fe-based superconductors (FeBSC) posits that the bosons responsible for electronic pairing are spin-fluctuations with a wave vector spanning the hole Fermi surfaces (FSs) near $\Gamma$ and the electron FSs near M points. So far all FeBSC for which neutron data are available do demonstrate such excitations, and the band structure calculations so far were finding quasi-nested FSs in all FeBSC, providing for a peak in the spin susceptibility at the desired wave vectors. However, the newest addition to the family, Sr$_{2}$VO$_{3}$FeAs, has been calculated to have a very complex FS with no visible quasi-nesting features. It was argued therefore that this material does not fall under the existing paradigm and calls for revisiting our current ideas about what is the likely cause of superconductivity in FeBSC. In this paper, I show that the visible complexity of the FS is entirely due to the V-derived electronic states. Assuming that superconductivity in Sr$_{2}$VO$_{3}$FeAs, as in the other FeBSC, originates in the FeAs layers, and the superconducting electrons are sensitive to the susceptibility of the FeAs electronic subsystem, I recalculate the bare susceptibility, weighting the electronic states with their Fe character, and obtain a susceptibility that fully supports the existing quasi-nesting model.