Superconducting Energy Scale Research Articles

Universal relationship between the energy scales of the pseudogap phase, the superconducting state, and the charge-density-wave order in copper oxide superconductors

We report the hole doping dependencies of the pseudogap phase energy scale, $2\Delta_{\rm PG}$, the anti-nodal (nodal) superconducting energy scales $2\Delta^{AN}_{\rm SC}$ ($2\Delta^{N}_{\rm SC}$) and the charge density wave energy scale, $2\Delta_{\rm CDW}$. They have been extracted from the electronic Raman responses of distinct copper oxide families. For all the cuprates studied, we reveal universal doping dependencies which suggest that $2\Delta_{\rm PG}$, $2\Delta^{AN}_{\rm SC}$ and $2\Delta_{\rm CDW}$ are governed by common microscopic interactions and that these interactions become relevant well above the superconducting transition at $T_c$. In sharp contrast, $2\Delta^N_{\rm SC}$ tracks the doping dependence of $T_c$, appearing to be controlled by a different kind of interactions than the energy scales above.

Ultrafast time-resolved x-ray scattering reveals diffusive charge order dynamics in La 2– x Ba x CuO 4

Charge order is universal among high-T c cuprates, but its relation to superconductivity is unclear. While static order competes with superconductivity, dynamic order may be favorable and even contribute to Cooper pairing. Using time-resolved resonant soft x-ray scattering at a free-electron laser, we show that the charge order in prototypical La2-x Ba x CuO4 exhibits transverse fluctuations at picosecond time scales. These sub-millielectron volt excitations propagate by Brownian-like diffusion and have an energy scale remarkably close to the superconducting T c. At sub-millielectron volt energy scales, the dynamics are governed by universal scaling laws defined by the propagation of topological defects. Our results show that charge order in La2-x Ba x CuO4 exhibits dynamics favorable to the in-plane superconducting tunneling and establish time-resolved x-rays as a means to study excitations at energy scales inaccessible to conventional scattering techniques.

Intimate link between charge density wave, pseudogap and superconducting energy scales in cuprates

The cuprate high temperature superconductors develop spontaneous charge density wave (CDW) order below a temperature $T_{CDW}$ and over a wide range of hole doping (p). An outstanding challenge in the field is to understand whether this modulated phase is related to the more exhaustively studied pseudogap and superconducting phases. To address this issue it is important to extract the energy scale $\Delta_{CDW}$ associated with the charge modulations, and to compare it with the pseudogap (PG) $\Delta_{PG}$ and the superconducting gap $\Delta_{SC}$. However, while $T_{CDW}$ is well-characterized from earlier works little has been known about $\Delta_{CDW}$ until now. Here, we report the extraction of $\Delta_{CDW}$ for several cuprates using electronic Raman spectroscopy. Crucially, we find that, upon approaching the parent Mott state by lowering $p$, $\Delta_{CDW}$ increases in a manner similar to the doping dependence of $\Delta_{PG}$ and $\Delta_{SC}$. This shows that CDW is an unconventional order, and that the above three phases are controlled by the same electronic correlations. In addition, we find that $\Delta_{CDW} \approx \Delta_{SC}$ over a substantial doping range, which is suggestive of an approximate emergent symmetry connecting the charge modulated phase with superconductivity.

Spectroscopic evidence of a new energy scale for superconductivity in H3S.

The discovery of a superconducting phase in sulfur hydride under high pressure with a critical temperature above 200 K has provided fresh impetus to the search for superconductors at ever higher temperatures. Although this systems displays all the hallmarks of superconductivity, the mechanism through which it arises remains to be determined. Here we provide a first optical spectroscopy study of this superconductor. Experimental results for the optical reflectivity of H3S, under hydrostatic pressure of 150 GPa, for several temperatures and over the range 60 to 600 meV of photon energies, are compared with theoretical calculations based on Eliashberg theory. Two significant features stand out: some remarkably strong infrared active phonons at around 160 meV, and a band with a depressed reflectance in the superconducting state in the region from 450 meV to 600 meV. In this energy range H3S becomes more reflecting with increasing temperature, a change that is traced to superconductivity originating from the electron-phonon interaction. The shape, magnitude, and energy dependence of this band at 150 K agrees with our calculations. This provides strong evidence of a conventional mechanism. However, the unusually strong optical phonon suggests a contribution of electronic degrees of freedom.

Quasiclassical theory of magnetoelectric effects in superconducting heterostructures in the presence of spin-orbit coupling

The quasiclassical theory in terms of equations for the Green's functions (Eilenberger equations) is generalized in order to allow for quantitative description of the magneto-electric effects and proximity-induced triplet correlations in the presence of spin-orbit coupling in hybrid superconducting systems. The formalism is valid under the condition that the spin-orbit coupling is weak with respect to the Fermi energy, but exceeds the superconducting energy scale considerably. On the basis of the derived formalism it is shown that the triplet correlations in the spin-orbit coupled normal metal can be induced by proximity to a singlet superconductor without any exchange or external magnetic field. They contain an odd-frequency even-momentum component, which is stable against disorder. The value of the proximity-induced triplet correlations is of the order of $\Delta_{so}/\varepsilon_F$, that is absent in the framework of the standard quasiclassical approximation, but can be described by our theory. The spin polarization, induced by the Josephson current flowing through the superconductor/Rashba metal/superconductor junction, is also calculated.

Superconducting energy scales and anomalous dissipative conductivity in thin films of molybdenum nitride

We report investigations of molybdenum nitride (MoN) thin films with different thickness and disorder and with superconducting transition temperature 9.89 K $\ge{T_c}\ge$ 2.78 K. Using terahertz frequency-domain spectroscopy we explore the normal and superconducting charge carrier dynamics for frequencies covering the range from 3 to 38 cm$^{-1}$ (0.1 to 1.1 THz). The superconducting energy scales, i.e. the critical temperature $T_c$, the pairing energy $\Delta$, and the superfluid stiffness $J$, and the superfluid density $n_s$ can be well described within the Bardeen-Cooper-Schrieffer theory for conventional superconductors. At the same time, we find an anomalously large dissipative conductivity, which cannot be explained by thermally excited quasiparticles, but rather by a temperature-dependent normal-conducting fraction, persisting deep into the superconducting state. Our results on this disordered system constrain the regime, where discernible effects stemming from the disorder-induced superconductor-insulator transition possibly become relevant, to MoN films with a transition temperature lower than at least 2.78 K.

Three energy scales in the superconducting state of hole-doped cuprates detected by electronic Raman scattering

We explored by electronic Raman scattering the superconducting state of Bi-2212 single crystal by performing a fine tuned doping study. We found three distinct energy scales in A1g, B1g and B2g symmetries which show three distinct doping dependencies. Above p=0.22 the three energies merge, below p=0.12, the A1g scale is no more detectable while the B1g and B2g scales become constant in energy. In between, the A1g and B1g scales increase monotonically with under-doping while the B2g one exhibits a maximum at p=0.16. The three superconducting energy scales appear to be an universal feature of hole-doped cuprates. We propose that the non trivial doping dependence of the three scales originates from Fermi surface topology changes and reveals competing orders inside the superconducting dome.

Functional renormalization group study of an eight-band model for the iron arsenides

We investigate the superconducting pairing instabilities of eight-band models for the iron arsenides. Using a functional renormalization group treatment, we determine how the critical energy scale for superconductivity depends on the electronic band structure. Most importantly, if we vary the parameters from values corresponding to LaFeAsO to SmFeAsO, the pairing scale is strongly enhanced, in accordance with the experimental observation. We analyze the reasons for this trend and compare the results of the eight-band approach to those found using five-band models.

Parametrization of Nambu Vertex in a Singlet Superconductor

We analyze general properties of the effective Nambu two-particle vertex and its renormalization group flow in a spin-singlet superconductor. In a fully spin-rotation invariant form the Nambu vertex can be expressed by only three distinct components. Solving exactly the flow of a mean-field model with reduced BCS and forward scattering interactions, we gain insight into the singularities in the momentum and energy dependences of the vertex at and below the critical energy scale for superconductivity. Using a decomposition of the vertex in various interaction channels, we manage to isolate singular momentum and energy dependences in only one momentum and energy variable for each term, such that the singularities can be efficiently parametrized.

Doping and temperature dependence of the superconducting energy gap in the electron-doped cuprate Pr2−xCexCuO4−δ

In hole-doped cuprate superconductors at low carrier concentrations two energy scales are identified: the superconducting energy gap and the pseudogap. The relation between these energy scales is still a puzzle. In these compounds a measurement of the energy gap is not necessarily a probe of the order parameter. In the electron-doped cuprates the pseudogap does not obscure the superconducting state. Consequently, the superconducting gap can be studied directly in a tunneling experiment. Here we show that by studying superconductor/insulator/superconductor planar tunnel junctions we are able to map the behavior of the gap amplitude for the entire (doping-temperature) phase diagram of the electron-doped cuprate superconductor Pr2-xCexCuO4-δ. The superconducting gap, Δ, shows a BCS-like temperature dependence even for extremely low carrier concentrations. Moreover, Δ follows the doping dependence of Tc. We can therefore conclude that there is a single superconducting energy scale in the electron-doped cuprates.

Single superconducting energy scale in the electron-doped cuprate superconductorPr2−xCexCuO4−δ

The tunneling spectra of the electron-doped cuprate Pr_2-xCe_xCuO4 as a function of doping and temperature is reported. We find that the superconducting gap, delta, shows a BCS-like temperature dependence even for extremely low carrier concentrations (studied here for the first time). Moreover, delta follows the doping dependence of Tc, in strong contrast with tunneling studies of hole-doped cuprates. From our results we conclude that there is a single superconducting energy scale in the electron-doped cuprates.

Two energy scales and close relationship between the pseudogap and superconductivity in underdoped cuprate superconductors

By measuring the low temperature specific heat, the low energy quasi-particle excitation has been derived and analysed in systematically doped La2−xSrxCuO4 single crystals. The Volovik’s relation predicted for a d-wave superconductor has been well demonstrated in wide doping regime, showing a robust evidence for the d-wave pairing symmetry. Furthermore the nodal gap slope vΔ of the superconducting gap is derived and is found to follow the same doping dependence of the pseudogap obtained from ARPES and tunnelling measurement. This strongly suggests a close relationship between the pseudogap and superconductivity. Taking the entropy conservation into account, we argue that the ground state of the pseudogap phase should have Fermi arcs with finite density of states at 0K, and the transport data show that it behaves like an insulator due to probably weak localization. A nodal metal picture for the pseudogap phase cannot interpret the data. Based on the Fermi arc picture for the pseudogap phase it is found that the superconducting energy scale or Tc in underdoped regime is governed by both the maximum gap and the spectral weight from the Fermi arcs. This suggests that there are two energy scales: superconducting energy scale and the pseudogap. The superconductivity may be formed by the condensation of Fermi arc quasiparticles through pairing mediated by exchanging virtue bosons.

Reversible magnetization and critical fluctuations in systematically dopedYBa2Cu3O7−δsingle crystals

The temperature and field dependence of reversible magnetization have been measured on a YBa$_2$Cu$_3$O$_{7-\delta}$ single crystal at six different doping concentrations. It is found that the data above 2 T can be described by the scaling law based on the GL-LLL (lowest Landau level approach based on Ginzburg-Landau theory) critical fluctuation theory yielding the values of the slope of upper critical field $-\mathrm{d}H_{\mathrm{c2}}(T)/\mathrm{d}T$ near $T_\mathrm{c}$. This set of values is self-consistent with that obtained in doing the universal scaling for the six samples. Based on a simple Ginzburg-Landau approach, we determined the doping dependence of the coherence length $\xi$ which behaves in a similar way as that determined from $\xi= \hbar v_\mathrm{F}/E_\mathrm{sc}$ with $E_\mathrm{sc}$ the superconducting energy scale. Our results may suggest a growing coherence length towards more underdoping.

Pseudogap, superconducting energy scale, and Fermi arcs of underdoped cuprate superconductors

Through the measurements of magnetic field dependence of specific heat in $La_{2-x}Sr_xCuO_4$ in zero temperature limit, we determined the nodal slope $v_\Delta$ of the quasiparticle gap. It is found that $v_\Delta$ has a very similar doping dependence of the pseudogap temperature $T^*$ or value $\Delta_p$. Meanwhile the virtual maximum gap at ($\pi,0$) derived from $v_\Delta$ is found to follow the simple relation $\Delta_q=0.46k_BT^*$ upon changing the doping concentration. This strongly suggests a close relationship between the pseudogap and superconductivity. It is further found that the superconducting transition temperature is determined by both the residual density of states of the pseudogap phase and the nodal gap slope in the zero temperature limit, namely, $T_c \approx \beta v_\Delta \gamma_n(0)$, where $\gamma_n(0)$ is the extracted zero temperature value of the normal state specific heat coefficient which is proportional to the size of the residual Fermi arc $k_{arc}$. This manifests that the superconductivity may be formed by forming a new gap on the Fermi arcs near nodes below $T_c$. These observations mimic the key predictions of the SU(2) slave boson theory based on the general resonating-valence-bond (RVB) picture.

Coulomb repulsion, phase stiffnesses, and doping-induced superconductivity from the Mott insulator in thet−t′−U−Jmodel of high-Tccuprates

The electronic $t\text{\ensuremath{-}}{t}^{\ensuremath{'}}\text{\ensuremath{-}}U\text{\ensuremath{-}}J$ model for the $\mathrm{Cu}{\mathrm{O}}_{2}$ plane in high-${T}_{c}$ superconducting cuprates is elaborated. It incorporates both charge transfer $U$ and exchange correlation $J$ with direct $t$ and diagonal ${t}^{\ensuremath{'}}$ hopping. Making use of the Yang concept of the off diagonal long range order (ODLRO) in the reduced density matrix of the electronic system we study the loss of quantum wave coherence (and thereby superconductivity) due to the Coulomb interaction. To this aim the second-quantized Hamiltonian of the model is translated to the phase representation with the help of the topologically constrained path integral formalism. As a result the electrons emerge as composite particles consisting of of spin-carrying neutral fermions and charged topological bosons in a form of ``flux tubes'' with the quantum phase variable dual to the local electron density. The charge carrying bose field forms a collective variable representing the correlated ``sliding'' motion of the entire electronic system. We found that the spin gap $\ensuremath{\Delta}$ which appears in one-particle spectrum is the result of valence bond pairing of neutral fermions without ODLRO and deduce the solution for $\ensuremath{\Delta}$ with ``$d$-wave'' symmetry. In the bosonic sector we derive the effective quantum rotor model along with microscopic phase stiffnesses setting the energy scale for superconductivity and point out the special role played by the diagonal hopping ${t}^{\ensuremath{'}}$. We explore the relationship of the quantum rotor phase model and the Bose-Hubbard system emphasizing the ring topology of quantum phase variable. Furthermore, we obtain the ground state phase diagrams which facilitate the Mott insulator-superconductor transition scenario. We elucidate the role of the chemical potential (doping) and the huge degeneracy of the effective bosonic system in achieving ODLRO with long-range phase coherence in the presence of large Coulomb repulsion. Finally, we discuss a number of relevant issues pertaining to the the present work which include: theoretical aspects of the hierarchy of the energy scales in cuprates, ``spin-charge separation'' concepts, ``local-pair'' and ``phase-fluctuation'' scenarios as well as experimental findings related to the role of the ``$d$-wave'' symmetry of the spin gap and diagonal hopping ${t}^{\ensuremath{'}}$ in cuprates.

Infrared reflectivity measurements of a superconducting energy scale in Rb3c60

AN understanding of the superconductivity and other electronic properties of the alkali-metal-doped fullerenes1 will require measurements of their solid-state physical properties. In the normal state one would like to know the electron effective mass, the Fermi energy and conduction bandwidth, and the mean free path for electron transport; the superconducting state, meanwhile, can be characterized at the most basic level by length and energy scales such as the coherence length, penetration depth and superconducting energy gap. Here we describe the use of far-infrared reflectivity measurements to probe the low-energy response of Rb3C60. We derive a value for the characteristic energy scale associated with reflectivity, which allows us to estimate a value for the gap energy 2δ of 3–5 kTC, in reasonable agreement with tunnelling measurements2. Combining this result with data obtained in previous studies, we estimate other length and energy scales, such as the bandwidth and penetration depth.