Sulfide Veins Research Articles

Chemical Composition and Strontium Isotope Characteristics of Scheelite from the Doranasai Gold Deposit, NW China: Implications for Ore Genesis

Scheelite, as a common accessory mineral found in hydrothermal deposits, is an indicator that allows the study of the ore-forming hydrothermal process and the tracing of fluid sources. The Doranasai gold deposit is a large-sized orogenic gold deposit in the South Altai, and orebodies occur as veins in the Devonian Tuokesalei Formation and Permian albite granite dykes. The ores are quartz veins and altered tectonites (rocks). Here, scheelite can be observed in the early-stage milky quartz veins, the middle-stage smoky quartz-polymetallic sulfide veins, and the altered albite granite dykes. In this study, the scheelites of these three types were carefully investigated in terms of texture, element, and isotope geochemistry to understand their ore-forming processes and fluid sources. The results showed that all types of scheelite were rich in Sr and poor in Mo, indicating that their ore-forming fluids had no genetic relation to magmatic–hydrothermal activities. The scheelites were characterized by the enrichment of medium rare earth element (MREE) and positive Eu anomaly in the chondrite-standardized REE patterns. This indicated the REE differentiation between scheelite and fluid, i.e., REE3+ and Na+ were in the form of valence compensation, preferentially replacing Ca2+ and selectively entering the scheelite lattice. The trace element composition of scheelite showed that the ore-forming fluid system was relatively closed, mesothermal, Na-rich, and reductive. The Sr isotope ratio of the scheelite (0.704819–0.70860, average 0.706372) was higher than that of the ore-bearing albite granite dyke (0.704654–0.704735), indicating that the Tuokesalei Formation is the main source for the fluids forming the Doranasai deposit.

Origin of the Bada porphyry Cu–Au deposit, eastern Tibet: Geology and isotope geochemistry (C–O–S–Pb) constraints

Bada is a newly discovered Cu–Au deposit located in the south part of the Yulong porphyry Cu (–Mo–Au) belt (YPCB), eastern Tibet. The Cu–Au mineralization, mainly hosted by the alkali-rich quartz monzonite porphyry (QMP), with minor by the fine-grained monzonitic porphyry (MP) and surrounding strata of the Nanxin Formation. The hydrothermal alteration assemblages recognized at Bada mainly include potassic, phyllic, propylitic, and argillic. The Cu–Au mineralization occurs within the potassic and phyllic alteration zones. Three main metallogenic stages have been identified: stage I ore-barren quartz ± dolomite ± K-feldspar ± pyrite veins, stage IIa dolomite ± quartz + pyrite veins, stage IIb dolomite ± quartz + polymetallic sulfide veins, and stage III dolomite ± calcite veins. The dolomite δ13CPDB values from stage I to III range from –2.2 – –1.8 ‰, –6.8 – –3.4 ‰, to –4.2 – 1.9 ‰. Their δ18OSMOW values vary from 7.7 – 9.8 ‰, 6.5 – 11.9 ‰, to 7.8 – 11.4 ‰, respectively. The corresponding calculated δ18Ofluid values ranging from 6.0 to 6.3 ‰ for stage I, and –1.1 to 4.3 ‰ for stage II, and –1.7 to 1.9 ‰ for stage III. The C–O isotopic compositions imply that the ore-forming fluids were dominated by magmatic water with the input of meteoric water. The narrow δ34S value range of sulfides (1.43 to 6.61 ‰, mean 4.64 ‰) reflects a predominantly magmatic origin for the sulfur. The Pb isotopic compositions of most sulfide samples coincide with the alkali-rich porphyries in the region, indicating that the alkalic porphyries provided the main source of Pb. Combined with the zircon U–Pb age of the ore-bearing porphyry (ca. 35.0 Ma), the Bada deposit is defined as a porphyry Cu–Au deposit in a late-collisional setting. The study of the genesis of Bada provides a better understanding of the Cu–Au mineralization potential of the southern YPCB.

Occurrences of Pd–Pt Bismuthotellurides and a Phosphohedyphane-Like Phase in Sulfide Veins of the Monchepluton Layered Complex, Kola Peninsula, Russia

We describe occurrences of platinum-group minerals (PGM) and an uncommon mineral enriched in Cl, and provide a brief review of Cl-bearing minerals associated with basic–ultrabasic complexes. An unusual phosphohedyphane-like phase (~30 µm), close to CaPb4(PO4)3Cl, occurs in one of the PGM-bearing veins of massive sulfides in the Monchepluton layered complex, Kola Peninsula, Russia. These veins consist of varying amounts of pyrrhotite, pentlandite, chalcopyrite, pyrite and accessory grains of galena; they are fairly abundant in the heavy-mineral concentrate, as are small (<0.1 mm) grains of PGM: michenerite, sperrylite, Bi-enriched members of the merenskyite–moncheite series and kotulskite, also rich in Bi. The PGE mineralization is attributed to a low-temperature deposition at the hydrothermal stage. The pyromorphite–phosphohedyphane solid solution likely formed as a secondary phase under conditions of a progressive build-up of oxygen fugacity via oxidation reactions of a precursor grain of galena and involving Ca, as an incompatible component of the sulfides, in a medium of residual fluid enriched in Cl.

Late Permian orogenic gold mineralization at Haoyaoerhudong, northern China: Constraints from hydrothermal titanite and apatite chemistry

The giant Haoyaoerhudong gold deposit is located on the north margin of the North China Craton. This deposit takes the form of lenticular orebodies hosted by the Mesoproterozoic carbonaceous schist, phyllite, and slate. Gold-related hydrothermal alteration types recognized at Haoyaoerhudong are silicification, sulfidation, biotitization, and graphitization. In addition, titanite and apatite were recorded in hydrothermal system. There are four types of hydrothermal apatite, namely, rounded Ap-S in altered schist, fractured Ap-V1 in quartz–biotite–sulfide veins, anhedral Ap-V2 in quartz–sulfide stringers, and Ap-V3 with abundant fluid inclusions in quartz–sulfide veinlets. As for different titanite types, Ttn-S is found to replace ilmenite in altered schist. Clustered Ttn-V1 is associated with graphite and gold in quartz–biotite–sulfide veins. Anhedral Ttn-V2 generally coexists with pyrrhotite and chalcopyrite in quartz–sulfide stringers. Euhedral Ttn-V3 is intergrown with Ap-V3 in quartz–sulfide veinlets. A U–Pb age of 255.6 ± 2.5 Ma (MSWD = 4.2, n = 27) was obtained for Ttn-V3 via in situ U–Pb analyses, which is younger than the nearby biotite granite (272.9 ± 1.5 Ma MSWD = 2.1, N = 25). The Haoyaoerhudong deposit can therefore be considered the product of a postmagmatic mineralization event at around 256 Ma. Apatite and titanite trace elements are robust tools for tracking fluid pathways in orogenic gold deposits. The enrichment of Mn, Fe, Y, and rare earth elements (REE) is observed in Ap-S but is progressively depleted from Ap-V1 through Ap-V2 to Ap-V3. There are also higher concentrations of Mn, Fe, Mo, Bi, Nb, Ta, Zr, Hf, and REE for Ttn-S than other titanites. Nevertheless, the K, Ba, Sr, and V concentrations are enriched in Ttn-V3, similar to the enrichment of Sr in Ap-V3. The apatite and titanite compositions measured here indicate the low salinity but Sr and alkali metals -enriched ore-forming fluids, typical for orogenic gold systems. Systematic geochemical variations in Eu, Mn, and V concentrations may imply that the ore-forming fluids were slightly oxidized compared to altered schist. The interaction between the carbonaceous schist and hydrothermal fluids would have led to CO2 consumption and apatite, titanite, and graphite formation. We further concluded that Sn vs. Mo, V vs. Th/U, and Zr + Hf vs. Th/U diagrams help to distinguish hydrothermal titanite in orogenic gold deposits from those in porphyry, skarn, and iron oxide–copper–gold deposits.

Origin of the Dayingezhuang gold deposit in the Jiaodong district, eastern China: Insights from trace element character of pyrite and C-O-S isotope compositions

The Dayingezhuang gold deposit is a giant gold deposit in the Jiaodong district, with explored gold reserves of 283 t. After decades of research, sources of ore-forming fluids remain controversial, resulting in continuous controversy on the origin of this deposit. In this study, trace elements of pyrite and C-O-S isotopic data are presented to provide constraints on the ore-forming fluids of the Dayingezhuang gold deposit. Two types of gold-related pyrite were identified. Py1, hosted in quartz-pyrite veins, has subhedral to anhedral textures with developed micro-fissures. Py2, hosted in quartz-polymetallic sulfide veins, is generally subhedral to anhedral and intergrown with polymetallic sulfides. Both Py1 and Py2 are characterized by Co/Ni <1, which supports that the ore-forming fluids are metamorphic fluids with the addition of sedimentary materials. The calcite CO isotope suggests a mantle-derived source mixed with sediments. Combined with the anomalously high δ34S values, the ore-forming fluids that generated the Dayingezhuang gold deposits were most likely originated from the mantle lithosphere which is metasomatized and fertilized by the subducted Paleo-Pacific Plate and its overlying marine sediments. This model is similar to the common genesis of worldwide orogenic type gold deposits which suggests that the Dayingezhuang gold deposit may be of orogenic origin.

Time Limit of Gold Mineralization in Muping–Rushan Belt, Eastern Jiaodong Peninsula, China: Evidence from Muscovite Ar–Ar Dating

Controversy surrounds the genetic relationship between gold mineralization and magmatism, especially in deposits in granite. Jiaodong Peninsula is the leading gold province in China, and most deposits are in Mesozoic granites; moreover, debate on the genesis persists. In eastern Jiaodong, the Muping–Rushan gold belt produces mainly quartz–sulfide vein-type gold, and the Upper Jurassic Kunyushan granite and Late Lower Cretaceous Sanfoshan granite are the wall rock. Precise mineralization ages should be identified to determine whether gold is related to the intrusion. In this study, three gold deposits (Sanjia, Yinggezhuang, and Xipo) from two ore-controlling faults were considered. Muscovites from quartz–sulfide veins and beresite were selected for Argon–Argon dating. The results obtained were 116.51 ± 0.47 Ma, 120.02 ± 0.38 Ma, and 121.65 ± 0.48 Ma for the three deposits, respectively. The mineralization lasted about 5 Ma in the Muping–Rushan gold belt. The test results showed that the mineralization was 16 Ma later than the intrusion time of Kunyushan granite and was earlier than that of Sanfoshan granite. Only the cooling age overlapped with the mineralization age. Previous studies have demonstrated that the ore fluid is of medium–low salinity and medium–low temperature. No typical high–low temperature mineral assemblage exists in the Muping–Rushan gold belt. Hence, gold deposits in Muping–Rushan gold belt could not be categorized as intrusion-related gold type.

Influence of fluid-rock interaction on gold mineralization in the Dongwan deposit, East Qinling, China: Constraints from systematic sulfur isotope and trace element geochemistry

The Dongwan gold deposit is located in the Xiong'ershan area, East Qinling, China, with gold ore bodies hosted in NE-trending hydrothermal alteration zone and quartz + sulfides veins in structures. Here we present systematic field investigation, petrographic observations, in-situ trace elements and sulfur isotope of pyrite, and sulfur isotope of galena and barite to elucidate the genesis and effect of fluid-rock interaction during hydrothermal evolution of the Dongwan gold deposit. Four types of pyrite are recognized based on their occurrences in different hydrothermal veins, structures and paragenetic sequences, as follows: i) Py1 in the stage I quartz-pyrite vein is composed of coarse-grained cubic pyrite (Py1-1) and medium-grained cubic pyrite (Py1-2); ii) Py2 is characterized by fine-grained disseminated pyrite in stage II vein; iii) Py3 is represented by pyrite that occurs together with galena, sphalerite and chalcopyrite in stage III vein. The early stage Py1-1 and Py1-2 are characterized by high Co/Ni ratios and low contents of As, Au and Ag. The main ore-forming stages represented by Py2 and Py3 show lower Co/Ni ratios and higher concentrations of As, Sb, Au, Ag, Pb and Cu. The Ni contents of all pyrite types are < 10 ppm, indicating that the ore-forming fluid was derived from felsic rocks. The δ34S values of the different pyrite generations range between −16.0‰ and −7.4‰, which are attributed to the fractionation between barite and sulfide minerals. The sulfur isotopic composition of the hydrothermal fluid calculated from co-genetic barite and pyrite is 1.2‰, suggesting that the ore-forming materials were possible derived from mantle source, and were correlated with the Late Mesozoic granitic magmatism. The main mechanisms of gold precipitation are fluid-rock interaction and decrease of temperature, which promote the Fe2+ rich Xiong’er Group wall rocks to reduce the hydrothermal fluid and disequilibrate the gold-sulfur complex causing the precipitation of gold. The overall trace elements and sulfur isotopic signatures suggest that the pyrite is of magmatic-hydrothermal origin, and that the ore-forming materials of the Dongwan gold deposit are probably related to post-magmatic fluids derived from the Early Cretaceous granitoid magmatism in the region.

Distal gold mineralization associated with porphyry system: The case of Hongzhuang and Yuanling deposits, East Qinling, China

The Hongzhuang and Yuanling gold deposits are located in the Shiyaogou ore field within the Xiong'ershan area, East Qinling, China, where the ore bodies are hosted in Xiong'er Group and mainly controlled by EW-trending and NE-trending faults. The gold mineralization mechanism and the possible genetic link with the porphyry magmatism and hydrothermal events remain unclear. Here we present results from systematic field investigation, petrographic observation, in situ trace elements and sulfur isotope of pyrite to elucidate the genesis of gold mineralization in these deposits. Based on the occurrences of pyrite in different hydrothermal veins, three types of pyrite are identified from each deposit, including: i) coarse-grained cubic pyrite (HZ-Py1 and YL-Py1) in stage I milky quartz vein; ii) medium- to fine-grained pyrite (HZ-Py2 and YL-Py2) in stage II polymetallic sulfides veins; iii) coarse-grained pyrite (HZ-Py3 and YL-Py3) symbiotic with calcite in stage III quartz-calcite vein. The LA-ICP-MS trace element analyses of pyrite show that Au occurs as invisible nanoparticles or nano-sized inclusions in pyrite through absorption-chemisorption during the growth of pyrite or as nano-sized Au-bearing mineral inclusions. The δ34S values of different generations of pyrite in the Hongzhuang and Yuanling gold deposits range from 3.92‰ to 6.43‰ and 2.82‰ to 4.46‰, respectively, indicating that the ore-forming materials were mainly derived from mantle-related source with affinity to the Late Mesozoic granitic magmatism. The Hongzhuang and Yuanling gold deposits are spatially and temporally correlated with the Shiyaogou pluton and they show consistent material sources. We propose that the hydrothermal Au mineralization in these deposits were the distal products generated from the post-magmatic fluids of the Shiyaogou porphyry system. The stretching and thinning of the early Cretaceous lithosphere led to the upwelling of magma and migration of fluid, forming the Au mineralization in fault structures in the shallow crust.

Towards the fertility trend: Unraveling the economic potential of igneous suites through whole-rock and zircon geochemistry (example from the Tapajós mineral Province, Northern Brazil)

Magmatic hydrothermal mineral deposits axiomatically frame the hosting pluton and the given tectonic setting in which they are inserted. Unsurprisingly, pre-Cambrian porphyry deposits are different than Phanerozoic examples, as collisional or post-collisional deposits are different than arc-related mineralizing systems. As such, this contribution assesses the tectonic framework and the magmatic evolution of the igneous suites present in south-central Amazonian Craton (Tapajós Mineral Province, TMP), and how these parameters translate into metallogenetic potential for the formation of magmatic-hydrothermal copper and gold deposits. For this purpose we gathered whole-rock geochemistry data from selected TMP copper and gold deposits and present new in situ trace-element and U-Pb analyses in zircon grains.The host rocks of the selected mineralizing systems belong either to the older magmatic sequence (OMS, 2.00–1.95 Ga), or to the younger magmatic sequence (YMS, 1.90–1.86 Ga). Whereas OMS presents characteristics of arc-related rocks, YMS represents the evolution towards post-orogenic or collisional setting. OMS might be divided into groups I, II and III granitoids. Group I comprises granites and granodiorites that mark the onset of the arc-magmatism in the TMP at ca. 2011 Ma. In this stage rocks are peraluminous, ferroan, anhydrous, show a strong crustal component and fO2 values close to or below the fayalite-magnetite-quartz buffer (ΔFMQ), yielding metallogenetic unfertile pluton. These rocks correlate with the Cuiú-Cuiú Complex and comprise samples from the Patrocínio and Tocantinzinho deposits. Group II granitoids correlate with the Creporizão Suite and comprise Tocantinzinho, São Jorge, Chapéu do Sol and Patrocínio deposit samples (with extrusive equivalents in the Coringa deposit). Rocks are metaluminous to peraluminous, magnesian to ferroan and mark the evolution of the magmatism towards more oxidizing (0 ≤ ΔFMQ ≤ + 4), hydrous and metallogenetically fertile conditions at ca. 1986 Ma. Mineralized zones are defined by gold bearing sulfide veins and veinlets within the potassic or sericitic alteration halos. Group III comprises rarer high-K, metaluminous, ferroan, anhydrous and reduced syenites and monzonites dated at 1993 and 1974 Ma, generated by decompression melting of metasomatized mantle. By itself, group III rocks should be considered as unfertile batches of magma, however, its interaction with the coeval, more hydrous and oxidized group II melts, confer these magmas their metallogenetic potential. Mineralization in group III rocks is defined by disseminated pyrrhotite – pyrite ± gold within the sericitic, chloritic and/or carbonate alteration zones.YMS comprises intermediate and acid rocks that belong to the Parauari Intrusive Suite and to the Iriri Group. Whereas, intermediate volcanics from YMS evolved on a hydrous and reduced petrologic trend, acid volcanics and the Batalha and Palito granitoids evolved on a dry and reduced trend, reflecting a change on TMP’s tectonic context, from magmatic-arc to a post-orogenic or collisional tectonic setting. Despite the reduced and anhydrous characteristic of the magmas, YMS’s metallogenetic potential is related with remobilization or melting of SCLM or lower crustal Au-rich sulfides formed on the previous magmatic events. Hence, the first pulses of the YMS might be considered as potentially fertile for the formation of Au-rich magmatic-hydrothermal deposits.

Genesis of the Aobaotu Pb–Zn deposit in the southern Great Xing'an Range, NE China: Constraints from geochronology and C–H–O–S–Pb isotopic and fluid inclusion studies

The Aobaotu Pb–Zn deposit (470,700 t; 1.51% Pb, 2.30% Zn) in the southern Great Xing'an Range, northeastern China, is hosted by the Late Jurassic volcanic tuff and structurally controlled by a near‐east–west‐trending fault. Three stages of mineralization were identified, namely, stage I of quartz ± pyrite veins, stage II of quartz–polymetallic sulphide veins, and stage III of late quartz–calcite veins. The quartz and calcite that formed in the three stages were selected for fluid inclusion and C–H–O isotope analyses. The results show that the ore‐forming fluid of the deposit belongs to the H2O–CO2–NaCl system at a medium temperature (concentrated at 220–300°C) and in low salinity (0.7–12.1 wt% NaCl equiv). The δ13C values of the calcite and ankerite are in the range of −8.4 to −4.8‰, indicating that as a source of deep magma. The δDV‐SMOW and values of quartz range from −108 to −88‰ and 4.55 to 5.85‰, respectively, indicating that the initial fluid of the Aobaotu deposit was a mixture of residual magmatic and meteoric water. Sulphur isotope analysis of the sulphide minerals, that is, sphalerite, galena, pyrite, and chalcopyrite, yield δ34S value in a range of 1.44–4.94‰, indicating that sulphur is mainly derived from magma. In addition, the Pb isotopic composition of the sulphides indicates that the ore‐forming material has a mixed crust–mantle source. Zircon U–Pb dating suggests that the formation of the Aobaotu deposit is genetically related to the granodiorite porphyry (130.3 ± 0.9 Ma). The combined geochronology and isotopic evidence suggest that the Aobaotu deposit is a magmatic‐hydrothermal vein‐type Pb–Zn deposit, opposite to a volcanic Pb–Zn deposit as suggested before. The Aobaotu deposit formed in an extensional tectonic setting caused by the rollback of the Palaeo‐Pacific Plate.

The Westwood Deposit, Southern Abitibi Greenstone Belt, Canada: An Archean Au-Rich Polymetallic Magmatic-Hydrothermal System—Part I. Volcanic Architecture, Deformation, and Metamorphism

Abstract The Westwood deposit (4.5 Moz Au) is hosted in the 2699–2695 Ma Bousquet Formation volcanic and intrusive rocks, in the eastern part of the Blake River Group, southern Abitibi greenstone belt. The Bousquet Formation is divided in two geochemically distinct members: a mafic to intermediate, tholeiitic to transitional lower member and an intermediate to felsic, transitional to calc-alkaline upper member. The Bousquet Formation is cut by the synvolcanic (2699–2696 Ma) polyphase Mooshla Intrusive Complex, which is cogenetic with the Bousquet Formation. The deposit contains three strongly deformed (D2 flattening and stretching), steeply S-dipping mineralized corridors that are stacked from north to south: Zone 2 Extension, North Corridor, and Westwood Corridor. The North and Westwood corridors are composed of Au-rich polymetallic sulfide veins and stratabound to stratiform disseminated to massive sulfide ore zones that are spatially and genetically associated with the calcalkaline, intermediate to felsic volcanic rocks of the upper Bousquet Formation. The formation of the disseminated to semimassive ore zones is interpreted as strongly controlled by the replacement of porous volcaniclastic rocks at the contact with more impermeable massive cap rocks that helped confine the upflow of mineralizing fluids. The massive sulfide lenses are spatially associated with dacitic to rhyolitic domes and are interpreted as being formed, at least in part, on the paleoseafloor. The epizonal, sulfide-quartz vein-type ore zones of the Zone 2 Extension are associated with the injection of subvolcanic, calc-alkaline felsic sills and dikes within the lower Bousquet Formation. These subvolcanic intrusive rocks, previously interpreted as lava flows, are cogenetic and coeval with the intermediate to felsic lava flows and domes of the upper Bousquet Formation. The change from fractional crystallization to assimilation- and fractional crystallization-dominated processes and transitional to calc-alkaline magmatism is interpreted to be responsible for the development of the auriferous ore-forming system. The Westwood deposit is similar to some Phanerozoic Au ± base metal-rich magmatic-hydrothermal systems, both in terms of local volcano-plutonic architecture and inferred petrogenetic context. The complex volcanic evolution of the host sequence at Westwood, combined with its proximity to a polyphase synvolcanic intrusive complex, led to the development of one of the few known large Archean subaqueous Au-rich magmatic-hydrothermal systems.

The Westwood Deposit, Southern Abitibi Greenstone Belt, Canada: An Archean Au-Rich Polymetallic Magmatic-Hydrothermal System—Part II. Hydrothermal Alteration, Mineralization, and Geologic Model

Abstract The Westwood deposit, located in the Archean Doyon-Bousquet-LaRonde mining camp in the southern Archean Abitibi greenstone belt, contains 4.5 Moz (140 metric t) of gold. The deposit is hosted in the 2699–2695 Ma submarine, tholeiitic to calc-alkaline volcanic, volcaniclastic, and intrusive rocks of the Bousquet Formation. The deposit is located near the synvolcanic (ca. 2699–2696 Ma) Mooshla Intrusive Complex that hosts the Doyon epizonal intrusion-related Au ± Cu deposit, whereas several Au-rich volcanogenic massive sulfide (VMS) deposits are present east of the Westwood deposit. The Westwood deposit consists of stratigraphically stacked, contrasting, and overprinting mineralization styles that share analogies with both the intrusion-related and VMS deposits of the camp. The ore zones form three distinct, slightly discordant to stratabound corridors that are, from north (base) to south (top), the Zone 2 Extension, the North Corridor, and the Westwood Corridor. Syn- to late-main regional deformation and upper greenschist to lower amphibolite facies regional metamorphism affect the ore zones, alteration assemblages, and host rocks. The Zone 2 Extension consists of Au ± Cu sulfide (pyrite-chalcopyrite)-quartz veins and zones of disseminated to semimassive sulfides. The ore zones are spatially associated with a series of calc-alkaline felsic sills and dikes that crosscut the mafic to intermediate, tholeiitic to transitional, lower Bousquet Formation volcanic rocks. The metamorphosed proximal alteration consists of muscovite-quartz-pyrite ± gypsum-andalusite-kyanite-pyrophyllite argillic to advanced argillic-style tabular envelope that is up to a few tens of meters thick. The North Corridor consists of auriferous semimassive to massive sulfide veins, zones of sulfide stringers, and disseminated sulfides that are hosted in intermediate volcaniclastic rocks at the base of the upper Bousquet Formation. The Westwood Corridor consists of semimassive to massive sulfide lenses, veins, zones of sulfide stringers, and disseminated sulfides that are located higher in the stratigraphic sequence, at or near the contact between calc-alkaline dacite domes and overlying calc-alkaline rhyodacite of the upper Bousquet Formation. A large, semiconformable distal alteration zone that encompasses the North Corridor is present in the footwall and vicinity of the Westwood Corridor. This metamorphosed alteration zone consists of an assemblage of biotite-Mn garnet-chlorite-carbonate ± muscovite-albite. A proximal muscovite-quartz-chlorite-pyrite argillic-style alteration assemblage is associated with both corridors. The Zone 2 Extension ore zones and associated alteration are considered synvolcanic based on crosscutting relationships and U-Pb geochronology and are interpreted as being the distal expression of an epizonal magmatic-hydrothermal system that is centered on the upper part of the synvolcanic Mooshla Intrusive Complex. The North and Westwood corridors consist of bimodal-felsic Au-rich VMS-type mineralization and alteration produced by the convective circulation of modified seawater that included a magmatic contribution from the coeval epizonal Zone 2 Extension magmatic-hydrothermal system. The Westwood Au deposit represents one of the very few documented examples of an Archean magmatic-hydrothermal system—or at least of such systems formed in a subaqueous environment. The study of the Westwood deposit resulted in a better understanding of the critical role of magmatic fluid input toward the formation of Archean epizonal intrusion-related Au ± Cu and seafloor/subseafloor Au-rich VMS-type mineralization.

Genesis of sulfide vein mineralization at the Sakatti Ni-Cu-PGE deposit, Finland

ABSTRACT The Sakatti Ni-Cu-platinum-group element deposit is situated in northern Finland and comprises massive, disseminated, and vein sulfide mineralization. A stockwork is formed by chalcopyrite-rich sulfide veins, which contain exceptionally high platinum-group elements and Au grades. The mineralogy and geochemistry of this stockwork zone ore is documented in this investigation. The results are used to develop the first robust genetic concept and its relationship to massive and disseminated mineralization of the Sakatti deposit. This model is similar to that proposed for many Cu-rich magmatic sulfide ores, most importantly the Cu-rich footwall veins described from the Sudbury Complex in Canada and the Cu-rich ore at Noril'sk-Talnakh in Russia. Detailed petrographic studies using a sample suite from exploration drill core intersecting vein-style mineralization revealed a classic magmatic sulfide assemblage of chalcopyrite ± pyrrhotite, pentlandite, and pyrite. More than 1000 platinum-group mineral grains belonging almost exclusively to the moncheite (PtTe2) – merenskyite (PdTe2) – melonite (NiTe2) solid solution series were identified in the studied samples. Notably, almost two thirds of the platinum-group element-bearing minerals consist of melonite. Some of the platinum-group minerals contain inclusions of Ag-rich gold (AgAu2) and muthmannite (AuAgTe2). Most of the platinum-group minerals occur as inclusions in chalcopyrite, although a few grains are located at base-metal sulfide grain boundaries and in fractures in base-metal sulfides. The whole-rock compositions of the stockwork veins are Cu-rich and are interpreted to represent a fractionated Cu-rich sulfide liquid enriched in Pt, Pd, Au, Ag, As, Bi, Pb, Se, Te, Zn, which separated from a monosulfide solid solution (mss). An intermediate solid solution (iss) solidified from the Cu-rich sulfide liquid, recrystallizing chalcopyrite at &amp;lt;550 °C. Simultaneously, small volumes of intercumulus residual melt contained mainly the precious metals, Bi, and Te due to their incompatibility in iss. Solitary and composite platinum-group minerals as well as Au-minerals crystallized first from the residual melt (&amp;lt;600 °C), followed by a succession of various Bi-, Ag-, and Pb-tellurides (∼540 °C), and finally sphalerite and galena. Melonite crystallized as mostly large, solitary grains exsolved directly from Ni-bearing intermediate solid solution (∼600 °C), shortly after the formation of moncheite and merenskyite from the residual melt. Finally, remobilization of the platinum-group minerals occurred at temperatures of &amp;lt;300 °C, as suggested by the presence of minor amounts of Cl-bearing minerals and ragged grain shapes.

Genesis of the sediment-hosted Haerdaban Zn-Pb deposit, Western Tianshan, NW China: Constraints from textural, compositional and sulfur isotope variations of sulfides

The sediment-hosted Haerdaban Zn-Pb deposit is a newly discovered Zn-Pb deposit in the Sailimu terrane, Western Tianshan (NW China), containing ca. 0.64 Mt of ore at 6.19 wt% Zn and 1.09 wt% Pb. The mineralization consists mainly of veins, breccias and semi-massive sulfide ores within the dolomitic limestone and calcareous slate. Using LA-ICP-MS, this study investigates trace element and sulfur isotope composition of sulfide to constrain the genesis of the deposit. Four pyrite types were identified by variations in texture and composition. Porous pyrite (Py1) shows a significant enrichment in Mn, Ag, Sb, Tl, Ba, Pb, Cu, and Zn, whereas the pyrite overgrowth (Py2) and euhedral pyrite (Py3) are enriched in Co and As, but depleted in all other trace elements. This compositional trend is attributed to the release of trace elements from pyrite during recrystallization from a porous to massive texture. Pyrite (Py4) associated with sphalerite is inclusion-rich, but exhibits a depletion in most trace elements, except Ni and Sb. The underlying carbonaceous sediments are interpreted as a source of Ni, Sb and other metals for the ore-forming fluids. Sphalerite displays a wide variety of colors from dark brown to pale yellow, primarily related to variations in Fe contents. The overall Fe contents (0.25 to 6.12 wt%), Cd contents (524 to 1875 ppm) and Zn/Cd ratios (320 to 1258) in sphalerite are compatible with those of SEDEX Zn-Pb deposit. The contents of other elements in sphalerite are generally low. Calculated temperatures using trace element contents in sphalerite (GGIMFis geothermometer) range from 163 °C to 309 °C, indicating progressive cooling of ore-forming fluid. Pyrite, sphalerite and galena display a wide range of δ34S values from +3.9 to +18.3‰. The association of lower positive δ34S values (+3.9 to +8.8‰) and epithermal suite elements (Ni, As, Sb, and Tl) enrichment in porous pyrite indicate that sulfur in early sulfides was derived from thermochemical sulfate reduction (TSR) with a possible magmatic input. The dominant population of heavier δ34S values (+13.8 to +18.3‰) of massive sulfide support TSR as the main source of sulfur. The intermediate δ34S values (+7.0 to +13.0‰) of vein sulfide are likely a mixing of TSR-derived sulfur with light sulfur leached from diagenetic pyrite. The current data support the classification of Haerdaban as a metamorphosed SEDEX Zn-Pb deposit, where the main mineralization was the product of remobilization and upgrading of early exhalative ores during hydrothermal events.

Sericite 40Ar/39Ar and zircon U-Pb dating of the Liziyuan gold deposit, West Qinling orogen, central China: Implications for ore genesis and tectonic setting

The West Qinling orogen in central China contains several dozens of gold deposits. However, absolute ages of gold mineralization and its relations to regional tectonism, magmatism, and metamorphism remain not tightly constrained for most of these gold deposits. Here we integrate 40Ar/39Ar dating of sericite from various hydrothermal alteration assemblages and U-Pb dating of zircon grains from magmatic rocks within and surrounding the Liziyuan gold deposit in the northern belt of the West Qinling orogen to provide new insights into the age and tectonic setting of gold mineralization. The Liziyuan gold deposit consists of six ore camps (Yuzigou, Liushagou, Jiancaowan, Kuangou, Suishizi, and Yingfang) that are hosted in Ordovician greenschist facies metamorphosed sedimentary-volcanic rocks and, less significantly, the Middle Triassic Tianzishan monzogranite pluton intruding the metamorphic rocks. Gold mineralization consists of auriferous quartz-pyrite veins and subordinate sulfide disseminations in hydrothermally altered wall rocks, with minor calcite-polymetallic sulfide veins in the monzogranite-hosted orebodies. Ore-related alteration assemblages are dominated by quartz, sericite, pyrite, chlorite, and calcite, with gold occurring mostly as native gold grains enclosed in or filling microfractures of pyrite and quartz. Barren alteration assemblages, dominated by K-feldspar, quartz, sericite, and pyrite, are locally developed along eastern margin of the Tianzishan monzogranite. Two sericite aggregates extracted from gold ores in the Liushagou camp yield well-defined 40Ar/39Ar plateau ages of 200.1 ± 1.2 and 198.8 ± 1.1 Ma (2σ), whereas those from barren alteration assemblages in the Tianzishan monzogranite, which hosts the Suishizi ore camp, give rise to older 40Ar/39Ar plateau ages of 211.9 ± 1.2 and 211.3 ± 1.3 Ma (2σ). The Tianzishan monzogranite pluton and several dioritic to granitic stocks and dykes in and surrounding the gold mines have zircon U-Pb ages ranging from 241.3 ± 1.2 to 212.4 ± 0.9 Ma (2σ). These new isotopic ages suggest that the Liziyuan gold deposit formed at the Triassic-Jurassic boundary, arguably representing the youngest orogenic-type gold mineralization event over the northern belt of the West Qinling orogen. Gold mineralization postdates magmatism in the Liziyuan gold deposit at least by about 10 million years, precluding a possible genetic relation between the two. Rather, the ore genesis was likely related to metamorphic fluids released from Paleozoic sedimentary and volcanic rocks in relation to the Qinling orogenesis. In contrast, the barren hydrothermal alteration assemblages were likely caused by fluids exsolved from a magma presumably represented by the ca. 212 Ma diorite dyke. Results presented here, when combined with independent geological and geochemical data, suggest that the Liziyuan gold deposit formed most likely under a post-collisional extensional setting related to the West Qinling orogeny.

Multistage ore-forming processes and metal source recorded in texture and composition of pyrite from the Late Triassic Asiha gold deposit, Eastern Kunlun Orogenic Belt, western China

The Asiha vein-type gold deposit, located in the Eastern Kunlun Orogenic Belt, provides an excellent opportunity for deciphering sources of metals and origins of orogenic intrusion-related gold systems. Within this deposit, four types of pyrite have been distinguished in three stages of hydrothermal activities. Pyrite (Py1) occurs in quartz-pyrite veins (stage I); pyrite (Py2), consisting of core (Py2a) and rim (Py2b), occurs in quartz-polymetallic sulfide veins (stage II); pyrite (Py3) occurs in quartz-pyrite-chalcopyrite veins (stage III). Py1 contains high concentrations of As (median of 2090 ppm) and Au (0.1 ppm). Py2a is enriched in Co (43.1 ppm) and Ni (50.9 ppm), but depleted in As and Au. By contrast, Py2b is enriched in As (7894 ppm) and Au (0.5 ppm), but depleted in Co and Ni. Although, Py3 shows enrichment in Co (1319 ppm) and Ni (1783 ppm), it is usually accompanied with chalcopyrite and visible gold. Three generations of gold-associated pyrite indicate three stages of hydrothermal mineralization, and the variation of metals in pyrite suggest that the ore-forming materials were predominantly derived from felsic magma mixed with different proportion of mafic-volcanic host rocks. U-Pb dating on hydrothermal monazite from stage III constrains the mineralization age at 227 ± 7 Ma, which is coeval with the concealed granite porphyry (228 Ma). The δ34S values of the pyrites vary from +4.8‰ to +8.9‰, which are slightly higher than magmatic pyrite in porphyry (+4.2‰ to +5.6‰). We tentatively propose that the ore-forming materials are closely related to the granite porphyry and the evolved magmatic hydrothermal fluids.

Fluid evolution of the Zhunuo porphyry Cu-Mo deposit in Gangdese Tract, Tibet, China: A fluid-inclusion investigation

The Zhunuo porphyry Cu-Mo deposit in the western part of south Gangdese porphyry copper belt (GPCB), Tibet, is a large porphyry system. The Cu-Mo mineralization of this deposit is mainly associated with a weakly aluminous I-type Miocene granite porphyry pluton that formed in a post-collisional extensional tectonic setting. Field observations and petrographic studies demonstrate that emplacement of the pluton took place in several intrusive pulses, each with associated hydrothermal activities. Early hydrothermal alteration produced a potassic assemblage, overprinted by later phyllic alteration. At least three main stages of mineralization have been identified: (1) early A stage quartz + K-feldspar + minor sulfide veins; (2) middle stage B1-subtype veins composed of quartz + molybdenite + sporadic sulfide and B2-subtype quartz + pyrite + chalcopyrite veins; and (3) late stage pyrite + quartz D veins.Three types of fluid inclusions (FIs) in quartz were identified in the early and middle stages (i.e., CO2 bearing-aqueous vapor (V)-type and liquid (L)-type, and solid (S)-type); only aqueous L-type FIs were observed in the late stage minerals. S-type FIs contain variable solid particles, including halite, calcite, anhydrite (or gypsum), and chalcopyrite, hematite, and an unidentified transparent crystal. Only halite was dissolved during heating. Halite-bearing S-type FIs were mainly homogenized by halite dissolution at 300–470°C (S2-type), corresponding to salinities of 38.9–56.3 wt% NaCl equiv.; and minor halite bearing S-type FIs were homogenized to liquid at 360–520°C via vapor disappearance (S1-type), with salinities of 31.9–56.7 wt% NaCl equiv. Other FIs in minerals of A, B1, B2 and D veins were homogenized at temperatures of 350–550°C, 303–500°C, 305–460°C, and 250–347°C with salinities of 3.4–20.9, 2.6–22.4, 4.8–21.8, and 4.7–18.2 wt% NaCl equiv., respectively. These data suggest that the ore fluids forming the Zhunuo deposit changed from high-temperature, low-moderate salinity, CO2-bearing magmatic fluids to low-temperature, low-salinity and CO2-poor meteoric fluids. Phase separation and cooling caused the precipitation of the abundant chalcopyrite in the middle stage B2-subtype veins. The molybdenite mineralization was caused mainly by the decrease of pressure due to the release of CO2, and by phase separation of fluid in the middle stage as recorded in the B2-subtype veins. This hydrothermal ore-forming system is different from other magmatic-hydrothermal systems in GPCB, but is similar to the typical Cu-Mo porphyry systems, which were initially CO2-bearing as indicated by the presence of abundant CO2-bearing, low-moderate salinity FIs and calcite-bearing S-type FIs.

Saline fluids drive Cu mineralization in Precambrian metasediments: Evidence from the Trans-North China Orogen

Epigenetic hydrothermal Cu-(Co) deposits are widely distributed in the Zhongtiao Mountains within the Paleoproterozoic Trans-North China Orogen in the North China Craton. Here we investigate the Henglingguan Cu deposit hosted in metasediments to gain insights on the fluid evolution characteristics associated with the ore formation. This Cu deposit is characterized by early disseminated mineralization and late quartz-vein type mineralization. The negative sulfur isotope values (about −10‰) of the vein sulfides suggests a sedimentary rock source for sulfur associated with the hydrothermal Cu mineralization. The coexistence of CO2-rich carbonic inclusions and halite-bearing inclusions within a single fluid inclusion assemblage suggests fluid immiscibility in the H2O-NaCl-CO2 system. Based on the fluid phase analysis, our data show that the parent ore fluid was characterized by X(NaCl) of 10 to 20 mol.% (salinity of around 23 to 41 wt% NaCl) and X(CO2) of 10 to 15 mol.% before fluid immiscibility. The estimated temperature–pressure conditions of 320 to 340 °C and 3.5 to 4.0 kbar based on the carbonic fluid inclusions is suggested to be close to the conditions of fluid immiscibility. In-situ composition analyses of fluid inclusions by LA-ICP-MS show that the ore fluids contained Na, Ca, Fe and Mn, and evolved towards Sr-Ba enrichment. The data are consistent with a metamorphic brine derived from the sedimentary rocks. The brine-rich metamorphic fluids were likely derived from the dehydration and decarbonation of evaporitic carbonate rocks developed on the basin margin or a passive continental margin. The decompression during post-collisional exhumation triggered fluid immiscibility resulting in the quartz vein-type Cu mineralization.

Genesis and fluid evolution of the Huangtan Au-Cu deposit in the Kalatag district, Eastern Tianshan, NW China: Constraints from geology, geochronology, fluid inclusions, and H-O-S-Pb isotope geochemistry

The newly discovered Huangtan Au-Cu deposit is located in the central Dananhu - Tousuquan arc of Eastern Tianshan, southern Central Asian Orogenic Belt (CAOB). It is the first Au-dominated volcanogenic massive sulfide (VMS) polymetallic deposit in the Eastern Tianshan. Veinlet-disseminated and massive orebodies are hosted within Early Silurian pyritic phyllic tuff and volcanic breccia and controlled by a secondary fracture zone of the Kalatag fault with extensive hydrothermal alteration. Four primary alteration/mineralization stages have been recognized as follows: (1) Early ore stage (S1), forming mainly ore-barren fine quartz veins with minor gold-bearing sulfides; (2) main ore stage (S2), forming mainly thick quartz veins with abundant coarse-grained subhedral pyrite (S2-1), and plentiful chalcopyrite, sphalerite, barite and Au-bearing sulfide veins (S2-2); (3) late ore stage (S3), which is characterized by plenty of barren quartz–calcite veins with few sulfides; and (4) supergene stage (S4), accompanied by abundant oxide mineralization, including malachite, jarosite and other supergene minerals. From S1 to S3, microthermometric data of fluid inclusions show homogenization temperatures of 263–379 °C (mean = 308 °C), 188-292 °C (mean = 240 °C), and 118-198 °C (mean = 158 °C), respectively, and salinities of 5.3–14.2 (mean = 10.8) wt.% NaCl equiv., 2.8–10.7 (mean = 7.6) wt.% NaCl equiv., and 0.3–14.1 (mean = 2.6) wt.% NaCl equiv., respectively. The ore-forming fluids are characterized by middle-low temperature, low salinity, relatively reduced condition, and an H2O-NaCl ± CO2 ± CH4 system.The δ34S values (−5.25‰ to 0.50‰) and Pb isotopic ratios (206Pb/204Pb = 17.868–19.495, 207Pb/204Pb = 15.446–15.575, and 208Pb/204Pb = 37.350–38.491) suggest that the ore-forming materials came predominantly from a deep-seated magma source with a minor contribution of lower continental crust. The δ18OH2O and δDV-SMOW values of fluid inclusions in each metallogenic stage range from −6.1 to 5.6‰ and −66.8 to −53.9‰, respectively, suggesting the dominant role of magmatic water mixed with convectively circulating heated seawater during fluid evolution. Fluid cooling dilution, local boiling, and fluid mixing were considered as the main mechanisms of metal precipitation. The 40Ar-39Ar plateau age of hydrothermal muscovite from the late ore stage (S3) is 414.4 ± 0.4 Ma, which represents the upper limit age of shallow hydrothermal alteration and Au-Cu mineralization. It is also consistent with the Early Silurian polymetallic metallogenic event in the Kalatag district. The auriferous Huangtan and adjacent Cu-Zn-rich Huangtupo VMS deposits show obvious ore-forming element differences, and constitute a unique VMS metallogenic system in the Eastern Tianshan Orogenic Belt (ETOB), which provides an important research object and new insight for ore prospecting in the peripheral Gobi Desert area.

Mineralization styles, alteration mineralogy, and sulfur isotope geochemistry of volcanogenic massive sulfide deposits in the Shadli Metavolcanics Belt, South Eastern Desert, Egypt: Metallogenic implications

Three distinct occurrences of Zn–Cu–Pb mineralization (Um Samiuki, Hilgit, and Maaqal) in Neoproterozoic island arcs of the Shadli Metavolcanics Belt, South Eastern Desert, Egypt, have been investigated in this study. The Shadli Metavolcanics Belt erupted in two magmatic cycles, with the Older Um Samiuki Metavolcanics group getting overlain by the Younger Hamamid Metavolcanics (YHM) group. The YHM group is characterized by two distinct cycles of volcanism. The studied deposits are mainly hosted by volcanic and volcaniclastic rocks that belong to the first cycle of the YHM group. The host-rock succession was interpreted to have been formed by back-arc extensional volcanism and was then deformed and metamorphosed to the lower greenschist facies. The relationship between the mineral occurrences and host rocks remains poorly constrained and controversial. We report new field observations, paragenetic data, mineral chemistry analyses, and in situ sulfur isotopes to characterize the sulfide mineralization and to gain insights into its genesis. Two mineralization styles have been identified in these deposits. The first style in the Um Samiuki deposit is expressed by two massive mineralized bodies that are mostly stratiform. It is distinguished by sphalerite, chalcopyrite, pyrite, galena, and Ag-bearing minerals; followed by bornite and covellite in decreasing abundance. Less abundant supergene phases include secondary copper minerals and iron oxyhydroxides. The hydrothermal alteration is characterized by sericitization, chloritization, epidotization, and silicification. The second style represents disseminated and vein-type sulfides mainly encountered in Hilgit and Maaqal occurrences. It is characterized by pyrite with minor sphalerite and chalcopyrite. The δ34SV-CDT values range from + 5.44‰ to + 9.08‰ with an average of + 8.11‰ ±1.1‰ (n = 18) for massive mineralized zones and from − 2.25‰ to + 3.78‰ with an average of + 1.06‰ ±2.3‰ (n = 8) for disseminated and vein sulfides. Such a variation in the sulfur isotope signatures may imply that both mineralization styles were derived from the thermochemical sulfate reduction (TSR) of seawater and leaching of basement lithologies in varying quantities, consistent with Volcanogenic Massive Sulfide (VMS) deposits of back-arc basins. The negative δ34SV-CDT values of some sulfides from the disseminated and vein mineralization may be seen as evidence for magmatic SO2 disproportionation. The studied VMS deposits display a close spatial and genetic association with submarine felsic volcanism of the YHM group, and their temporal distribution corresponds closely with the Mozambique Ocean closure stage of the Pan-African Orogeny.