Hydrogen Evolution Reaction (HER) in Anion Exchange Membrane Water Electrolyzer(AEMWE) requires fewer electrons compared to the oxygen evolution reaction, which is why research on it started later. However, when using an anion exchange membrane, the hydrogen evolution reaction occurs in multiple steps, and the dissociation of water is requisite first. The water splitting is challenging, hence catalysts that enhance water decomposition are essential. Currently, Platinum supported by carbon is used as the most stable and efficient material for HER. However, due to Platinum is rare and expensive, leading to significant research into alternative materials. Among various non-precious metal candidates, Nickel is known for its superior hydrogen evolution performance. Yet, the performance of Nickel alone is inferior to that of Platinum. Nickel exhibits enhanced performance and durability when combined with other metals due to a synergistic effect. The second metal, such as Copper, Cobalt, Iron, or Molybdenum, shows improved performance when alloyed with Nickel . Amon them Ni–Mo catalyst has shown high activity for HER in AEMWE. Among various Ni/Mo molar ratios, the catalyst showed the highest activity when it was 3. With Ni3Mo as the cathode, a single cell was fabricated using non-noble metal catalysts exclusively. Interestingly, the activation procedure significantly affected the cell performance. The single cell performed better than that with the Pt/C catalyst when the Ni3Mo catalyst was activated at 50 mA/cm2. Molybdenum tends to dissolve once the reaction begins the distribution of Mo in electrodes, membrane, and electrolytes was estimated, confirming Mo dissolution from the cathode. Once the cell was activated, the cell performance was stable without degradation in long-term chronopotentiometry operation, but the performance was degraded by sudden voltage change such as imposing open circuit voltage . The surface structure and reaction mechanism were studied with density functional theory: the Mo-dissolved Ni3Mo(101) surface could promote H2O dissociation, while MoO3 stably adsorbed on the surface weakened H* adsorption, promoting HER. This study provides important insights into the development of efficient catalysts for large-scale hydrogen production.
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